Труды сотрудников ИЛ им. В.Н. Сукачева СО РАН

[Text] / J. Viers [et al.] // Geochem. Trans. - 2015. - Vol. 16. - Ст. 3, DOI 10.1186/s12932-015-0018-0. - Cited References:81. - This work was supported by the GDRI Car-Wet-Sib, the ANR CESA "Artic Metals" (France), RSF 14-24-0013, and the grant "BIO-GEO-CLIM" of the Russian Ministry of Education and Research and Tomsk State University (No 14.B25.31.0001). . - ISSN 1467-4866РУБ Geochemistry & Geophysics

Аннотация: Stable Zn isotopes fractionation was studied in main biogeochemical compartments of a pristine larch forest of Central Siberia developed over continuous permafrost basalt rocks. Two north-and south-oriented watershed slopes having distinctly different vegetation biomass and active layer depth were used as natural proxy for predicting possible future climate changes occurring in this region. In addition, peat bog zone exhibiting totally different vegetation, hydrology and soil temperature regime has been studied. The isotopic composition of soil profile from Central Siberia is rather constant with a delta Zn-66 value around 0.2 parts per thousand close to the value of various basalts. Zn isotopic composition in mosses (Sphagnum fuscum and Pleurozium schreberi) exhibits differences between surface layers presenting values from 0.14 to 0.2 parts per thousand and bottom layers presenting significantly higher values (0.5 - 0.7 parts per thousand) than the underlain mineral surface. The humification of both dead moss and larch needles leads to retain the fraction where Zn bound most strongly thus releasing the lighter isotopes in solution and preserving the heavy isotopes in the humification products, in general accord with previous experimental and modeling works [GCA 75:7632-7643, 2011]. The larch (Larix gmelinii) from North and South-facing slopes is enriched in heavy isotopes compared to soil reservoir while larch from Sphagnum peatbog is enriched in light isotopes. This difference may result from stronger complexation of Zn by organic ligands and humification products in the peat bog compared to mineral surfaces in North- and South-facing slope. During the course of the growing period, Zn followed the behavior of macronutrients with a decrease of concentration from June to September. During this period, an enrichment of larch needles by heavier Zn isotopes is observed in the various habitats. We suggest that the increase of the depth of rooting zone, and the decrease of DOC and Zn concentration in soil solution from the root uptake zone with progressively thawing soil could provoke heavy isotopes to become more available for the larch roots at the end of the vegetative season compared to the beginning of the season, because the decrease of DOC will facilitate the uptake of heavy isotope as it will be less retained in strong organic complexes.

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Держатели документа:
Univ Toulouse 3, CNRS, IRD, GET OMP,UMR CNRS 5563, F-31400 Toulouse, France.
VN Sukachev Inst Forestry SB RAS, Krasnoyarsk 660036, Russia.
Tomsk State Univ, BIO GEO CLIM Lab, Tomsk 634050, Russia.
UB RAS, Inst Ecol Problems North, Lab Freshwater & Marine Ecosyst, Arkhangelsk, Russia.
Univ Strasbourg, CNRS, LHYGES EOST, F-67084 Strasbourg, France.

Доп.точки доступа:
Viers, Jerome; Prokushkin, Anatoly S.; Pokrovsky, Oleg S.; Kirdyanov, Alexander V.; Zouiten, Cyril; Chmeleff, Jerome; Meheut, Merlin; Chabaux, Francois; Oliva, Priscia; Dupre, Bernard; GDRI Car-Wet-Sib; ANR CESA "Artic Metals" (France); RSF [14-24-0013]; grant "BIO-GEO-CLIM" of the Russian Ministry of Education and Research; Tomsk State University [14.B25.31.0001]

/ F. Pourpoint [et al.] // Chem. Geol. - 2017. - Vol. 452. - P1-8, DOI 10.1016/j.chemgeo.2017.02.004. - Cited References:60. - The Lille group is grateful for funding by the Region Nord/Pas-de-Calais, France, Europe (FEDER), CNRS, Ministere de l'Enseignement Superieur et de la Recherche, Institut Chevreul (FR 2638), CPER, ENSCL, and contract ANR-14-CE07-0009-01. Bruker Company and Fabien Aussenac are warmly acknowledged for providing access to DNP-NMR spectrometer. Guillaume Laurent is also acknowledged for fruitful discussion. Financial support from the IR-RMN-THC FR-3050 CNRS for conducting the research is gratefully acknowledged. . - ISSN 0009-2541. - ISSN 1878-5999РУБ Geochemistry & Geophysics

Аннотация: In a Siberian river, the concentrations of chemical species vary with the hydrological regime. Dissolved Organic Matter (DOM) and aluminum ions show a parallel trend in the course of the hydrological year. However, the speciation of aluminum in this natural environment remains an open question. We propose here a combination of spectroscopic techniques to investigate the proximity between the aluminum atoms and DOM. First, one-dimensional (1D) solid-state Nuclear Magnetic Resonance (NMR), Electron Paramagnetic Resonance (EPR) and 1D and 2D solution NMR spectra were acquired, providing a clear overview of the DOM composition. Second, the sensitivity enhancement yielded by Dynamic Nuclear Polarization enabled the NMR detection of proximities between the Al-27 and C-13 nuclei. Hence, we show that 8.3 +/- 1.3% of the carboxylate groups observed by NMR are connected to the Al3+ ions in the DOM sample. We here demonstrate for the first time how advanced solid-state NMR methods can provide key information about the localization of aluminum in such complex natural materials. (C) 2017 Elsevier B.V. All rights reserved.

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Держатели документа:
Univ Lille, CNRS, ENSCL, UCCS,UMR 8181, F-59000 Lille, France.
Univ Paris 06, CNRS, METIS Milieux Environnementaux Transferts & Inte, UMR 7619, F-75252 Paris 05, France.
Univ Lille, CNRS, LASIR Lab Spect Infrarouge & Raman, UMR 8516, F-59000 Lille, France.
Univ Lille, CNRS, UGSF, UMR 8576, F-59000 Lille, France.
Univ Strasbourg, CNRS, LHyGeS, UMR 7517, F-67084 Strasbourg, France.
CNRS, GET, Observ Midi Pyrenees, UMR 5563, Toulouse, France.
V N Sukachev Inst Forest SB RAS, Akademgorodok 50-28, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Pourpoint, Frederique; Templier, Joelle; Anquetil, Christelle; Vezin, Herve; Trebosc, Julien; Trivelli, Xavier; Chabaux, Francois; Pokrovsky, Oleg S.; Prokushkin, Anatoly S.; Amoureux, Jean-Paul; Lafon, Olivier; Derenne, Sylvie; Region Nord/Pas-de-Calais, France, Europe (FEDER); Ministere de l'Enseignement Superieur et de la Recherche; Institut Chevreul [FR 2638]; CPER; ENSCL [ANR-14-CE07-0009-01]; IR-RMN-THC FR-3050 CNRS