Труды сотрудников ИЛ им. В.Н. Сукачева СО РАН

/ O. S. Pokrovsky [et al.] // C. R. Geosci. - 2012. - Vol. 344, Is. 11.12.2013. - P663-677, DOI 10.1016/j.crte.2012.08.003. - Cited References: 81. - This work was supported by ANR "Arctic Metals", LIA "LEAGE", PICS No. 6063, GDRI "CAR WET SIB", grants RFBR-CNRS Nos 12-05-91055, 08-05-00312_a, 07-05-92212-CNRS_a, 08-04-92495-CNRS_a, CRDF RUG1-2980-KR10, Federal Program RF "Kadry" (contract N 14.740.11.0935), and Programs of Presidium RAS and UrORAS. . - 15. - ISSN 1631-0713РУБ Geosciences, Multidisciplinary

Аннотация: Warming of the permafrost accompanied by the release of ancient soil organic carbon is one of the most significant environmental threats within the global climate change scenario. While the main sites of permafrost carbon processing and its release to the atmosphere are thermokarst (thaw) lakes and ponds, the main carriers of carbon and related major and trace elements from the land to the Arctic ocean are Russian subarctic rivers. The source of carbon in these rivers is atmospheric C consumed by chemical weathering of rocks and amplified by plant uptake and litter decomposition. This multidisciplinary study describes results of more than a decade of observations and measurements of elements fluxes, stocks and mechanisms in the Russian boreal and subarctic zone, from Karelia region to the Kamchatka peninsula, along the gradient of permafrost-free terrain to continuous permafrost settings, developed on various lithology and vegetation types. We offer a comprehensive, geochemically-based view on the functioning of aquatic boreal systems which quantifies the role of the following factors on riverine element fluxes: (1) the specificity of lithological substrate; (2) the importance of organic and organo-mineral colloidal forms, notably during the snowmelt season; (3) the phenomenon of lakes seasonal overturn; (4) the role of permafrost within the small and large watersheds; and (5) the governing role of terrestrial vegetation in element mobilization from rock substrate to the river. Care of such a multiple approach, a first order prediction of the evolution of element stocks and fluxes under scenario of progressive warming in high latitudes becomes possible. It follows the increase of frozen peat thawing in western Siberia will increase the stocks of elements in surface waters by a factor of 3 to 10 whereas the increase of the thickness of active layer, the biomass and the primary productivity all over permafrost-affected zone will bring about a short-term increase of elements stocks in labile reservoir (plant litter) and riverine fluxes by a factor of 2. The change of the plant productivity and community composition under climate warming in central Siberia will be the most important factor of major and trace element fluxes increase (probably a factor of 2) from the soil to the river and, finally, to the Arctic Ocean. (c) 2012 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.

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[Pokrovsky, Oleg S.
Viers, Jerome
Dupre, Bernard
Audry, Stephane] Univ Toulouse, CNRS IRD OMP, Geosci Environm Toulouse, F-31400 Toulouse, France
[Chabaux, Francois] CNRS, EOST, UMR 7517, CGS, F-67084 Strasbourg, France
[Gaillardet, Jerome] Inst Phys Globe Strasbourg Paris, Equipe Geochim Cosmochim, F-75005 Paris, France
[Prokushkin, Anatoly S.] VN Sukachev Inst Forest SB RAS, Krasnoyarsk, Russia
[Shirokova, Liudmila S.] Russian Acad Sci, Inst Ecol Problems N, Arkhangelsk, Russia
[Kirpotin, Sergey N.] Tomsk State Univ, Tomsk 634050, Russia
[Lapitsky, Sergey A.] Moscow MV Lomonosov State Univ, Geol Fac, Moscow, Russia
[Shevchenko, Vladimir P.] RAS, PP Shirshov Oceanol Inst, Moscow 117901, Russia

Доп.точки доступа:
Pokrovsky, O.S.; Viers, J...; Dupre, B...; Chabaux, F...; Gaillardet, J...; Audry, S...; Prokushkin, A.S.; Shirokova, L.S.; Kirpotin, S.N.; Lapitsky, S.A.; Shevchenko, V.P.

[Text] / M. L. Bagard [et al.] // Geochim. Cosmochim. Acta. - 2011. - Vol. 75, Is. 12. - P3335-3357, DOI 10.1016/j.gca.2011.03.024. - Cited References: 80. - This work benefited from fruitful discussions with S. Derenne, J. Templier, and T. Weber and from thorough reviews by S. Gislason, Ed Tipper and an anonymous reviewer. We also thank the associate Editor S. Hemming. B. Kieffel, Th. Perronne and E. Pelt are acknowledged for their help in measuring U and Sr isotope ratios. This work was financially supported by the French INSU-CNRS program "EC2CO-Cytrix", and CNRS program "GDRI Car-Wet-Sib". It was also supported by the funding from the Region Alsace, France, and the CPER 2003-2013 "REALISE". MLB benefited the funding of a Ph.D. scholarship from the French Ministry of National Education and Research. This is an EOST-LHyGeS contribution. . - 23. - ISSN 0016-7037РУБ Geochemistry & Geophysics

Аннотация: In order to constrain the origin and fluxes of elements carried by rivers of high latitude permafrost-dominated areas, major and trace element concentrations as well as Sr and U isotopic ratios were analyzed in the dissolved load of two Siberian rivers (Kochechum and Nizhnyaya Tunguska) regularly sampled over two hydrological cycles (2005-2007). Large water volumes of both rivers were also collected in spring 2008 in order to perform size separation through dialysis experiments. This study was completed by spatial sampling of the Kochechum watershed carried out during summer and by a detailed analysis of the main hydrological compartments of a small watershed. From element concentration variations along the hydrological cycle, different periods can be marked out, matching hydrological periods. During winter baseflow period (October to May) there is a concentration increase for major soluble cations and anions by an order of magnitude. The spring flood period (end of May-beginning of June) is marked by a sharp concentration decrease for soluble elements whereas dissolved organic carbon and insoluble element concentrations strongly increase. When the spring flood discharge occurs, the significant increase of aluminum and iron concentrations is related to the presence of organo-mineral colloids that mobilize insoluble elements. The study of colloidal REE reveals the occurrence of two colloid sources successively involved over time: spring colloids mainly originate from the uppermost organic-rich part of soils whereas summer colloids rather come from the deep mineral horizons. Furthermore, U and Sr isotopic ratios together with soluble cation budgets in the Kochechum river impose for soluble elements the existence of three distinct fluxes over the year: (a) at the spring flood a surface flux coming from the leaching of shallow organic soil levels and containing a significant colloidal component (b) a subsurface flux predominant during summer and fall mainly controlled by water-rock interactions within mineral soils and (c) a deep groundwater flux predominant during winter which enters large rivers through unfrozen permafrost-paths. Detailed study of the Kochechum watershed suggests that the contribution of this deep flux strongly depends on the depth and continuous nature of the permafrost. (C) 2011 Elsevier Ltd. All rights reserved.

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Держатели документа:
[Bagard, Marie-Laure
Chabaux, Francois
Stille, Peter
Rihs, Sophie] Univ Strasbourg, F-67084 Strasbourg, France
[Bagard, Marie-Laure
Chabaux, Francois
Stille, Peter
Rihs, Sophie] CNRS, EOST, LHyGeS, F-67084 Strasbourg, France
[Pokrovsky, Oleg S.
Viers, Jerome
Dupre, Bernard] Observ Midi Pyrenees, UMR 5563, CNRS, LMTG, Paris, France
[Prokushkin, Anatoly S.] SB RAS, VN Sukachev Inst Forest, Krasnoyarsk, Russia
[Schmitt, Anne-Desiree] Univ Franche Comte, CNRS, UMR 6249, F-25030 Besancon, France

Доп.точки доступа:
Bagard, M.L.; Chabaux, F...; Pokrovsky, O.S.; Viers, J...; Prokushkin, A.S.; Stille, P...; Rihs, S...; Schmitt, A.D.; Dupre, B...

[Text] / G. . Guggenberger [et al.] // Glob. Change Biol. - 2008. - Vol. 14, Is. 6. - P1367-1381, DOI 10.1111/j.1365-2486.2008.01568.x. - Cited References: 72 . - 15. - ISSN 1354-1013РУБ Biodiversity Conservation + Ecology + Environmental Sciences

Аннотация: Boreal permafrost soils store large amounts of organic carbon (OC). Parts of this carbon (C) might be black carbon (BC) generated during vegetation fires. Rising temperature and permafrost degradation is expected to have different consequences for OC and BC, because BC is considered to be a refractory subfraction of soil organic matter. To get some insight into stocks, variability, and characteristics of BC in permafrost soils, we estimated the benzene polycarboxylic acid (BPCA) method-specific composition and storage of BC, i.e. BPCA-BC, in a 0.44 km(2)-sized catchment at the forest tundra ecotone in northern Siberia. Furthermore, we assessed the BPCA-BC export with the stream draining the catchment. The catchment is composed of various landscape units with south-southwest (SSW) exposed mineral soils characterized by thick active layer or lacking permafrost, north-northeast (NNE) faced mineral soils with thin active layer, and permafrost-affected raised bogs in plateau positions showing in part thermokarst formation. There were indications of vegetation fires at all landscape units. BC was ubiquitous in the catchment soils and BPCA-BC amounted to 0.6-3.0% of OC. This corresponded to a BC storage of 22-3440 g m(-2). The relative contribution of BPCA-BC to OC, as well as the absolute stocks of BPCA-BC were largest in the intact bogs with a shallow active layer followed by mineral soils of the NNE aspects. In both landscape units, a large proportion of BPCA-BC was stored within the permafrost. In contrast, mineral soils with thick active layer or lacking permafrost and organic soils subjected to thermokarst formation stored less BPCA-BC. Permafrost is, hence, not only a crucial factor in the storage of OC but also of BC. In the stream water BPCA-BC amounted on an average to 3.9% of OC, and a yearly export of 0.10 g BPCA-BC m(-2) was calculated, most of it occurring during the period of snow melt with dominance of surface flow. This suggests that BC mobility in dissolved and colloidal phase is an important pathway of BC export from the catchment. Such a transport mechanism may explain the high BC concentrations found in sediments of the Arctic Ocean.

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[Guggenberger, Georg
Rodionov, Andrej
Grabe, Matthias] Univ Halle Wittenberg, Inst Agr & Nutr Sci, D-06108 Halle, Germany
[Rodionov, Andrej] Brandenburg Tech Univ Cottbus, Chair Soil Protect & Recultivat, D-03013 Cottbus, Germany
[Shibistova, Olga
Mikheyeva, Natalia
Zrazhevskaya, Galina] RAS, VN Sukachev Inst Forest, Akademgorodok, Krasnoyarsk 660036, Russia
[Grabe, Matthias] Max Planck Inst Biogeochem, D-07745 Jena, Germany
[Kasansky, Oleg A.] RAS, SB, Field Stn Igarka, Permafrost Inst Yakutsk, Igarka 663200, Russia
[Fuchs, Hans] Univ Gottingen, Inst Forest Management & Yield Sci, D-37077 Gottingen, Germany
[Flessa, Heiner] Univ Gottingen, Inst Soil Sci & Forest Nutr, D-37077 Gottingen, Germany

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Guggenberger, G...; Rodionov, A...; Shibistova, O...; Grabe, M...; Kasansky, O.A.; Fuchs, H...; Mikheyeva, N...; Zrazhevskaya, G...; Flessa, H...

/ A. B. Ptitsyn [et al.] // Geography and Natural Resources. - 2010. - Vol. 31, Is. 2. - P144-147, DOI 10.1016/j.gnr.2010.06.009 . - ISSN 1875-3728
Аннотация: Within the long-term research program on reconstruction of palaeoclimatic characteristics of Central Asia, we carried out a palaeoreconstructions of climate aridity/humidity in the Transbaikalia, based on investigating layered palynological spectra and chemical composition of bottom sediments from Lake Arakhlei. It was found that the humid phases of climate on the time interval 90-2005 used in calculations exhibits a periodicity of 20-45 years, which roughly corresponds to the humidity cycles of Eurasia. В© 2010.

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Держатели документа:
Institute of Natural Resources, Ecology and Cryology SB RAS, Chita, Russian Federation
Institute of Geology and Mineralogy SB RAS, Novosibirsk, Russian Federation
Institute of Forest SB RAS, Krasnoyarsk, Russian Federation
Environmental Change Research Centre, Department of Geography, University College London, United Kingdom
Siberian Federal University, Krasnoyarsk, Russian Federation

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Ptitsyn, A.B.; Reshetova, S.A.; Babich, V.V.; Daryin, A.V.; Kalugin, I.A.; Ovchinnikov, D.V.; Panizzo, V.; Myglan, V.S.

[] / C. -H. Cheng [et al.] // Org. Geochem. - 2014. - Vol. 70. - P53-61, DOI 10.1016/j.orggeochem.2014.02.013 . - ISSN 0146-6380
Аннотация: Amending soil with black carbon (BC) can change the sorption properties of the soil. However, there is some concern based on studies that deal with newly produced BC and barely consider the possible changes in sorption properties for BC after being amended in soil. This study uses newly produced BC and historical BC samples, along with soils containing high levels of historical BC and adjacent soils without visible BC, to compare their diuron, atrazine and Cu2+ sorption properties. Compared with newly produced BC, historical BC exhibited reduced (56-91%) sorption capacity for diuron and atrazine but 2-5 times enhanced sorption capacity of Cu2+. These changes in sorption properties can be interpreted via the formation of surface functional groups in BC. Whereas the sorption capacity for diuron and atrazine was reduced with historical BC, the sorption capacity of BC-containing soils was higher than for the adjacent soils, indicating that BC possessed stronger sorption capacity than non-BC material. A biological assay revealed reduced herbicide efficiency for the newly produced BC, and even the historical BC still exerted an influence on reducing herbicide efficiency. Along with its recalcitrance in environments, BC has a significant long term effect on the toxicity of contaminants and soil fertility. © 2014 Elsevier Ltd.

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Держатели документа:
School of Forestry and Resource Conservation, National Taiwan University, Taipei 106, Taiwan
Department of Crop and Soil Sciences, Cornell University, Ithaca, NY 14850, United States
National Synchrotron Radiation Research Center, Hsinchu 300, Taiwan
Institute of Forest SB RAS, Krasnoyarsk 660036, Russian Federation
Taiwan Agricultural Research Institute, Taichung 413, Taiwan

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Cheng, C.-H.; Lin, T.-P.; Lehmann, J.; Fang, L.-J.; Yang, Y.-W.; Menyailo, O.V.; Chang, K.-H.; Lai, J.-S.

/ F. Pourpoint [et al.] // Chem. Geol. - 2017. - Vol. 452. - P1-8, DOI 10.1016/j.chemgeo.2017.02.004. - Cited References:60. - The Lille group is grateful for funding by the Region Nord/Pas-de-Calais, France, Europe (FEDER), CNRS, Ministere de l'Enseignement Superieur et de la Recherche, Institut Chevreul (FR 2638), CPER, ENSCL, and contract ANR-14-CE07-0009-01. Bruker Company and Fabien Aussenac are warmly acknowledged for providing access to DNP-NMR spectrometer. Guillaume Laurent is also acknowledged for fruitful discussion. Financial support from the IR-RMN-THC FR-3050 CNRS for conducting the research is gratefully acknowledged. . - ISSN 0009-2541. - ISSN 1878-5999РУБ Geochemistry & Geophysics

Аннотация: In a Siberian river, the concentrations of chemical species vary with the hydrological regime. Dissolved Organic Matter (DOM) and aluminum ions show a parallel trend in the course of the hydrological year. However, the speciation of aluminum in this natural environment remains an open question. We propose here a combination of spectroscopic techniques to investigate the proximity between the aluminum atoms and DOM. First, one-dimensional (1D) solid-state Nuclear Magnetic Resonance (NMR), Electron Paramagnetic Resonance (EPR) and 1D and 2D solution NMR spectra were acquired, providing a clear overview of the DOM composition. Second, the sensitivity enhancement yielded by Dynamic Nuclear Polarization enabled the NMR detection of proximities between the Al-27 and C-13 nuclei. Hence, we show that 8.3 +/- 1.3% of the carboxylate groups observed by NMR are connected to the Al3+ ions in the DOM sample. We here demonstrate for the first time how advanced solid-state NMR methods can provide key information about the localization of aluminum in such complex natural materials. (C) 2017 Elsevier B.V. All rights reserved.

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Держатели документа:
Univ Lille, CNRS, ENSCL, UCCS,UMR 8181, F-59000 Lille, France.
Univ Paris 06, CNRS, METIS Milieux Environnementaux Transferts & Inte, UMR 7619, F-75252 Paris 05, France.
Univ Lille, CNRS, LASIR Lab Spect Infrarouge & Raman, UMR 8516, F-59000 Lille, France.
Univ Lille, CNRS, UGSF, UMR 8576, F-59000 Lille, France.
Univ Strasbourg, CNRS, LHyGeS, UMR 7517, F-67084 Strasbourg, France.
CNRS, GET, Observ Midi Pyrenees, UMR 5563, Toulouse, France.
V N Sukachev Inst Forest SB RAS, Akademgorodok 50-28, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Pourpoint, Frederique; Templier, Joelle; Anquetil, Christelle; Vezin, Herve; Trebosc, Julien; Trivelli, Xavier; Chabaux, Francois; Pokrovsky, Oleg S.; Prokushkin, Anatoly S.; Amoureux, Jean-Paul; Lafon, Olivier; Derenne, Sylvie; Region Nord/Pas-de-Calais, France, Europe (FEDER); Ministere de l'Enseignement Superieur et de la Recherche; Institut Chevreul [FR 2638]; CPER; ENSCL [ANR-14-CE07-0009-01]; IR-RMN-THC FR-3050 CNRS

/ J. Cui, Z. Zhu, X. Xu [et al.] // Soil Biol. Biochem. - 2020. - Vol. 142. - Ст. 107720, DOI 10.1016/j.soilbio.2020.107720 . - ISSN 0038-0717
Аннотация: The impact of increasing amounts of labile C input on priming effects (PE) on soil organic matter (SOM) mineralization remains unclear, particularly under anoxic conditions and under high C input common in microbial hotspots. PE and their mechanisms were investigated by a 60-day incubation of three flooded paddy soils amended with13C-labeled glucose equivalent to 50–500% of microbial biomass C (MBC). PE (14–55% of unamended soil) peaked at moderate glucose addition rates (i.e., 50–300% of MBC). Glucose addition above 300% of MBC suppressed SOM mineralization but intensified microbial N acquisition, which contradicted the common PE mechanism of accelerating SOM decomposition for N-supply (frequently termed as “N mining”). Particularly at glucose input rate higher than 3 g kg?1 (i.e., 300–500% of MBC), mineral N content dropped on day 2 close to zero (1.1–2.5 mg N kg?1) because of microbial N immobilization. To cope with the N limitation, microorganisms greatly increased N-acetyl glucosaminidase and leucine aminopeptidase activities, while SOM decomposition decreased. Several discrete peaks of glucose-derived CO2 (contributing >80% to total CO2) were observed between days 13–30 under high glucose input (300–500% of MBC), concurrently with CH4 peaks. Such CO2 dynamics was distinct from the common exponential decay pattern, implicating the recycling and mineralization of 13C-enriched microbial necromass driven by glucose addition. Therefore, N recycling from necromass was hypothesized as a major mechanism to alleviate microbial N deficiency without SOM priming under excess labile C input. Compound-specific 13C-PLFA confirmed the redistribution of glucose-derived C among microbial groups, i.e., necromass recycling. Following glucose input, more than 4/5 of total 13C-PLFA was in the gram-negative and some non-specific bacteria, suggesting these microorganisms as r-strategists capable of rapidly utilizing the most labile C. However, their 13C-PLFA content decreased by 70% after 60 days, probably as a result of death of these r-strategists. On the contrary, the 13C-PLFA in gram-positive bacteria, actinomycetes and fungi (K-strategists) was initially minimal but increased by 0.5–5 folds between days 2 and 60. Consequently, the necromass of dead r-strategists provided a high-quality C–N source to the K-strategists. We conclude that under severe C excess, N recycling from necromass is a much more efficient microbial strategy to cover the acute N demand than N acquisition from the recalcitrant SOM. © 2020 Elsevier Ltd

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Держатели документа:
Key Laboratory of Agro-ecological Processes in Subtropical Region & Changsha Research Station for Agricultural and Environmental Monitoring, Institute of Subtropical Agriculture, Chinese Academy of Sciences, Hunan, 410125, China
State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Gongdong, 510640, China
Jiangsu Provincial Key Laboratory for Bioresources of Coastal Saline Soils, Jiangsu Coastal Biological Agriculture Synthetic Innovation Center, Yancheng Teachers' University, Yancheng, 224002, China
Key Laboratory of Ecosystem Network Observation and Modeling, Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing, 100101, China
School of Environment, Natural Resources & Geography, Bangor University, Gwynedd, LL57 2UW, United Kingdom
Department of Agricultural Soil Science, Department of Soil Science of Temperate Ecosystems, University of G?ttingen, G?ttingen, Germany
Institute of Environmental Sciences, Kazan Federal University, Kazan, 420049, Russian Federation
Agro-Technological Institute, RUDN University, Moscow, 117198, Russian Federation
Departamento de Ciencias Quimicas y Recursos Naturales, Universidad de La Frontera, Temuco, Chile
VN Sukachev Institute of Forest, SB-RAS, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Cui, J.; Zhu, Z.; Xu, X.; Liu, S.; Jones, D. L.; Kuzyakov, Y.; Shibistova, O.; Wu, J.; Ge, T.

/ V. Mavromatis, A. S. Prokushkin, M. A. Korets [et al.] // Chem. Geol. - 2020. - Vol. 540. - Ст. 119547, DOI 10.1016/j.chemgeo.2020.119547 . - ISSN 0009-2541
Аннотация: Constraining the mechanisms controlling the riverine flux of major cations and their isotopes including that of Mg to the World Ocean is one of the challenges in Earth surface isotope geochemistry. In an attempt to identify the main factors affecting the Mg isotopic composition of large rivers including vegetation, climate and lithology of the watershed, we studied the largest, in terms of discharge, Siberian river, Yenisey, and 20 of its main tributaries, during spring flood, summer flow and winter. The working hypothesis was that the influence of bedrock composition is most pronounced in winter, when the soils are frozen and the rivers are fed by deep underground waters. Thus, we anticipated that the presence of permafrost will help to distinguish the impact of surface processes, linked to biological uptake and release, and deep soil/underground transport of Mg from mineral sources. In contrast to these expectations, no sizable differences in the Mg isotope composition of the river water (±0.1‰) for both the Yenisey tributaries and its main channel has been observed between the spring flood (May) and the winter (March) period. Those two periods are characterized by the differences of discharge and degree of lithological impact on element source in the river water. Regardless of the season, there was no straightforward control of lithology (relative abundance of carbonates, basalts, granites and sedimentary rocks) on ?26Mg in the main tributaries of the Yenisey river. Our findings suggest that the use of riverine Mg isotope signature for tracing weathering mechanisms and dominant lithological impact is not straightforward at the scale of large rivers whose watersheds present multiple lithologies, variable climatic conditions and vegetation types. © 2020 Elsevier B.V.

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Держатели документа:
Geosciences Environnement Toulouse (GET), CNRS, UMR 5563, Observatoire Midi-Pyrenees, 14 Av. E. Belin, Toulouse, 31400, France
V.N. Sukachev Institute of Forest, SB RAS, Akademgorodok 50/28, Krasnoyarsk, 660036, Russian Federation
BIO-GEO-CLIM Laboratory, Tomsk State University, Tomsk, Russian Federation
N. Laverov Federal Center for Arctic Research, IEPN, Russian Academy of Science, 23 Naber. Sev. Dviny, Arkhangelsk, Russian Federation

Доп.точки доступа:
Mavromatis, V.; Prokushkin, A. S.; Korets, M. A.; Chmeleff, J.; Mounic, S.; Pokrovsky, O. S.

/ J. Cui, Z. K. Zhu, X. L. Xu [et al.] // Soil Biol. Biochem. - 2020. - Vol. 142. - Ст. 107720, DOI 10.1016/j.soilbio.2020.107720. - Cited References:80. - The study was supported by the National Key Research and Development Program of China (2017YFD0800104), the National Natural Science Foundation of China (41430860, 41771337, 41977093 and 31872695), State Key Laboratory of Organic Geochemistry, GIGCAS (SKLOG-201728), Hunan Province Base for Scientific and Technological Innovation Cooperation (2018WK4012), the Youth Innovation Team Project of Institute of Subtropical Agriculture, Chinese Academy of Sciences (2017QNCXTD_GTD), NSFC-RFBR joint project (N 19-54-53026) and Innovation Groups of National Natural Science Foundation of Hunan Province (2019JJ10003). We thank the Public Service Technology Center, Institute of Subtropical Agriculture, Chinese Academy of Sciences for technical assistance. The publication was supported by the Government Program of Competitive Growth of Kazan Federal University and with the support of the "RUDN University program 5-100." . - ISSN 0038-0717РУБ Soil Science

Аннотация: The impact of increasing amounts of labile C input on priming effects (PE) on soil organic matter (SOM) mineralization remains unclear, particularly under anoxic conditions and under high C input common in microbial hotspots. PE and their mechanisms were investigated by a 60-day incubation of three flooded paddy soils amended with(13)C-labeled glucose equivalent to 50-500% of microbial biomass C (MBC). PE (14-55% of unamended soil) peaked at moderate glucose addition rates (i.e., 50-300% of MBC). Glucose addition above 300% of MBC suppressed SOM mineralization but intensified microbial N acquisition, which contradicted the common PE mechanism of accelerating SOM decomposition for N-supply (frequently termed as "N mining"). Particularly at glucose input rate higher than 3 g kg(-1) (i.e., 300-500% of MBC), mineral N content dropped on day 2 close to zero (1.1-2.5 mg N kg(-1)) because of microbial N immobilization. To cope with the N limitation, microorganisms greatly increased N-acetyl glucosaminidase and leucine aminopeptidase activities, while SOM decomposition decreased. Several discrete peaks of glucose-derived CO2 (contributing >80% to total CO2) were observed between days 13-30 under high glucose input (300-500% of MBC), concurrently with CH4 peaks. Such CO2 dynamics was distinct from the common exponential decay pattern, implicating the recycling and mineralization of C-13-enriched microbial necromass driven by glucose addition. Therefore, N recycling from necromass was hypothesized as a major mechanism to alleviate microbial N deficiency without SOM priming under excess labile C input. Compound-specific C-13-PLFA confirmed the redistribution of glucose-derived C among microbial groups, i.e., necromass recycling. Following glucose input, more than 4/5 of total C-13-PLFA was in the gram-negative and some non-specific bacteria, suggesting these microorganisms as r-strategists capable of rapidly utilizing the most labile C. However, their C-13-PLFA content decreased by 70% after 60 days, probably as a result of death of these r-strategists. On the contrary, the C-13-PLFA in gram-positive bacteria, actinomycetes and fungi (K-strategists) was initially minimal but increased by 0.5-5 folds between days 2 and 60. Consequently, the necromass of dead r-strategists provided a high-quality C-N source to the K-strategists. We conclude that under severe C excess, N recycling from necromass is a much more efficient microbial strategy to cover the acute N demand than N acquisition from the recalcitrant SOM.

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Держатели документа:
Chinese Acad Sci, Inst Subtrop Agr, Key Lab Agroecol Proc Subtrop Reg, Changsha 410125, Hunan, Peoples R China.
Chinese Acad Sci, Inst Subtrop Agr, Changsha Res Stn Agr & Environm Monitoring, Changsha 410125, Hunan, Peoples R China.
Chinese Acad Sci, State Key Lab Organ Geochem, Guangzhou Inst Geochem, Gongdong 510640, Peoples R China.
Yancheng Teachers Univ, Jiangsu Prov Key Lab Bioresources Coastal Saline, Jiangsu Coastal Biol Agr Synthet Innovat Ctr, Yancheng 224002, Peoples R China.
Chinese Acad Sci, Key Lab Ecosyst Network Observat & Modeling, Inst Geog Sci & Nat Resources Res, Beijing, Peoples R China.
Bangor Univ, Sch Environm Nat Resources & Geog, Bangor LL57 2UW, Gwynedd, Wales.
Univ Gottingen, Dept Agr Soil Sci, Dept Soil Sci Temperate Ecosyst, Gottingen, Germany.
Kazan Fed Univ, Inst Environm Sci, Kazan 420049, Russia.
RUDN Univ, Agrotechnol Inst, Moscow 117198, Russia.
Univ La Frontera, Dept Ciencias Quim & Recursos Nat, Temuco, Chile.
RAS, SB, VN Sukachev Inst Forest, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Cui, Jun; Zhu, Zhenke; Xu, Xingliang; Liu, Shoulong; Jones, Davey L.; Kuzyakov, Yakov; Shibistova, Olga; Wu, Jinshui; Ge, Tida; National Key Research and Development Program of China [2017YFD0800104]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China [41430860, 41771337, 41977093, 31872695]; State Key Laboratory of Organic Geochemistry, GIGCAS [SKLOG-201728]; Hunan Province Base for Scientific and Technological Innovation Cooperation [2018WK4012]; Youth Innovation Team Project of Institute of Subtropical Agriculture, Chinese Academy of Sciences [2017QNCXTD_GTD]; NSFC-RFBR joint project [N 19-54-53026]; Innovation Groups of National Natural Science Foundation of Hunan Province [2019JJ10003]; Government Program of Competitive Growth of Kazan Federal University; RUDN University program 5-100

/ V. Mavromatis, A. S. Prokushkin, M. A. Korets [et al.] // Chem. Geol. - 2020. - Vol. 540. - Ст. UNSP 119547, DOI 10.1016/j.chemgeo.2020.119547. - Cited References:65. - The study was supported by RFFI (RFBR) grant No 19-55-15002 and by the French national programmes INSU-LEFE and INSU-SYSTER. The editor, J. Gaillardet and four anonymous reviewers are thanked for their constructive comments on our manuscript. . - ISSN 0009-2541. - ISSN 1872-6836РУБ Geochemistry & Geophysics

Аннотация: Constraining the mechanisms controlling the riverine flux of major cations and their isotopes including that of Mg to the World Ocean is one of the challenges in Earth surface isotope geochemistry. In an attempt to identify the main factors affecting the Mg isotopic composition of large rivers including vegetation, climate and lithology of the watershed, we studied the largest, in terms of discharge, Siberian river, Yenisey, and 20 of its main tributaries, during spring flood, summer flow and winter. The working hypothesis was that the influence of bedrock composition is most pronounced in winter, when the soils are frozen and the rivers are fed by deep underground waters. Thus, we anticipated that the presence of permafrost will help to distinguish the impact of surface processes, linked to biological uptake and release, and deep soil/underground transport of Mg from mineral sources. In contrast to these expectations, no sizable differences in the Mg isotope composition of the river water (+/- 0.1%) for both the Yenisey tributaries and its main channel has been observed between the spring flood (May) and the winter (March) period. Those two periods are characterized by the differences of discharge and degree of lithological impact on element source in the river water. Regardless of the season, there was no straightforward control of lithology (relative abundance of carbonates, basalts, granites and sedimentary rocks) on delta Mg-26 in the main tributaries of the Yenisey river. Our findings suggest that the use of riverine Mg isotope signature for tracing weathering mechanisms and dominant lithological impact is not straightforward at the scale of large rivers whose watersheds present multiple lithologies, variable climatic conditions and vegetation types.

WOS

Держатели документа:
Observ Midi Pyrenees, CNRS, GET, UMR 5563, 14 Av E Belin, F-31400 Toulouse, France.
SB RAS, VN Sukachev Inst Forest, Akademgorodok 50-28, Krasnoyarsk 660036, Russia.
Tomsk State Univ, BIO GEO CLIM Lab, Tomsk, Russia.
Russian Acad Sci, N Laverov Fed Ctr Arctic Res, IEPN, 23 Naber Sev Dviny, Arkhangelsk, Russia.

Доп.точки доступа:
Mavromatis, Vasileios; Prokushkin, Anatoly S.; Korets, Mikhail A.; Chmeleff, Jerome; Mounic, Stephanie; Pokrovsky, Oleg S.; RFFI (RFBR) [19-55-15002]; French national programmes INSU-LEFE; INSU-SYSTER

/ S. N. Vorobyev, Y. Kolesnichenko, M. A. Korets, O. S. Pokrovsky // Water. - 2021. - Vol. 13, Is. 15. - Ст. 2093, DOI 10.3390/w13152093 . - ISSN 2073-4441
Аннотация: Transport of carbon, major and trace elements by rivers in permafrost-affected regions is one of the key factors in circumpolar aquatic ecosystem response to climate warming and permafrost thaw. A snap-shot study of major and trace element concentration in the Lena River basin during the peak of spring flood revealed a specific group of solutes according to their spatial pattern across the river main stem and tributaries and allowed the establishment of a link to certain landscape parameters. We demonstrate a systematic decrease of labile major and trace anion, alkali and alkaline-earth metal concentration downstream of the main stem of the Lena River, linked to change in dominant rocks from carbonate to silicate, and a northward decreasing influence of the groundwater. In contrast, dissolved organic carbon (DOC) and a number of low-soluble elements exhibited an increase in concentration from the SW to the NE part of the river. We tentatively link this to an increase in soil organic carbon stock and silicate rocks in the Lena River watershed in this direction. Among all the landscape parameters, the proportion of sporadic permafrost on the watershed strongly influenced concentrations of soluble highly mobile elements (Cl, B, DIC, Li, Na, K, Mg, Ca, Sr, Mo, As and U). Another important factor of element concentration control in the Lena River tributaries was the coverage of the watershed by light (for B, Cl, Na, K, U) and deciduous (for Fe, Ni, Zn, Ge, Rb, Zr, La, Th) needle-leaf forest (pine and larch). Our results also suggest a DOC-enhanced transport of low-soluble trace elements in the NW part of the basin. This part of the basin is dominated by silicate rocks and continuous permafrost, as compared to the carbonate rock-dominated and groundwater-affected SW part of the Lena River basin. Overall, the impact of rock lithology and permafrost on major and trace solutes of the Lena River basin during the peak of spring flood was mostly detected at the scale of the main stem. Such an impact for tributaries was much less pronounced, because of the dominance of surface flow and lower hydrological connectivity with deep groundwater in the latter. Future changes in the river water chemistry linked to climate warming and permafrost thaw at the scale of the whole river basin are likely to stem from changes in the spatial pattern of dominant vegetation as well as the permafrost regime. We argue that comparable studies of large, permafrost-affected rivers during contrasting seasons, including winter baseflow, should allow efficient prediction of future changes in riverine ‘inorganic’ hydrochemistry induced by permafrost thaw. © 2021 by the authorsLicensee MDPI, Basel, Switzerland.

Scopus

Держатели документа:
BIO-GEO-CLIM Laboratory, Tomsk State University, 35 Lenina, Tomsk, 634050, Russian Federation
V.N. Sukachev Institute of Forest of the Siberian Branch of Russian Academy of Sciences—Separated Department of the KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Geosciences and Environment Toulouse, UMR 5563 CNRS, University of Toulouse, 14 Avenue Edouard Belin, Toulouse, 31400, France
N. Laverov Federal Center for Integrated Arctic Research, Russian Academy of Sciences, 23 Nab. Northern Dvina, Arkhangelsk, 163002, Russian Federation

Доп.точки доступа:
Vorobyev, S. N.; Kolesnichenko, Y.; Korets, M. A.; Pokrovsky, O. S.

/ S. N. Vorobyev, Y. Kolesnichenko, M. A. Korets, O. S. Pokrovsky // Water. - 2021. - Vol. 13, Is. 15. - Ст. 2093, DOI 10.3390/w13152093. - Cited References:75. - This research was funded by RSF, grant number 18-17-00238-P and by RFBR, grants No 19-55-15002, 20-05-00729_a. . - ISSN 2073-4441РУБ Environmental Sciences + Water Resources

Аннотация: Transport of carbon, major and trace elements by rivers in permafrost-affected regions is one of the key factors in circumpolar aquatic ecosystem response to climate warming and permafrost thaw. A snap-shot study of major and trace element concentration in the Lena River basin during the peak of spring flood revealed a specific group of solutes according to their spatial pattern across the river main stem and tributaries and allowed the establishment of a link to certain landscape parameters. We demonstrate a systematic decrease of labile major and trace anion, alkali and alkaline-earth metal concentration downstream of the main stem of the Lena River, linked to change in dominant rocks from carbonate to silicate, and a northward decreasing influence of the groundwater. In contrast, dissolved organic carbon (DOC) and a number of low-soluble elements exhibited an increase in concentration from the SW to the NE part of the river. We tentatively link this to an increase in soil organic carbon stock and silicate rocks in the Lena River watershed in this direction. Among all the landscape parameters, the proportion of sporadic permafrost on the watershed strongly influenced concentrations of soluble highly mobile elements (Cl, B, DIC, Li, Na, K, Mg, Ca, Sr, Mo, As and U). Another important factor of element concentration control in the Lena River tributaries was the coverage of the watershed by light (for B, Cl, Na, K, U) and deciduous (for Fe, Ni, Zn, Ge, Rb, Zr, La, Th) needle-leaf forest (pine and larch). Our results also suggest a DOC-enhanced transport of low-soluble trace elements in the NW part of the basin. This part of the basin is dominated by silicate rocks and continuous permafrost, as compared to the carbonate rock-dominated and groundwater-affected SW part of the Lena River basin. Overall, the impact of rock lithology and permafrost on major and trace solutes of the Lena River basin during the peak of spring flood was mostly detected at the scale of the main stem. Such an impact for tributaries was much less pronounced, because of the dominance of surface flow and lower hydrological connectivity with deep groundwater in the latter. Future changes in the river water chemistry linked to climate warming and permafrost thaw at the scale of the whole river basin are likely to stem from changes in the spatial pattern of dominant vegetation as well as the permafrost regime. We argue that comparable studies of large, permafrost-affected rivers during contrasting seasons, including winter baseflow, should allow efficient prediction of future changes in riverine 'inorganic' hydrochemistry induced by permafrost thaw.

WOS

Держатели документа:
Tomsk State Univ, BIO GEO CLIM Lab, 35 Lenina, Tomsk 634050, Russia.
Russian Acad Sci, Dept KSC, SB RAS, VN Sukachev Inst Forest,Siberian Branch, Krasnoyarsk 660036, Russia.
Univ Toulouse, Geosci & Environm Toulouse, UMR 5563, CNRS, 14 Ave Edouard Belin, F-31400 Toulouse, France.
Russian Acad Sci, N Laverov Fed Ctr Integrated Arctic Res, 23 Nab Northern Dvina, Arkhangelsk 163002, Russia.

Доп.точки доступа:
Vorobyev, Sergey N.; Kolesnichenko, Yuri; Korets, Mikhail A.; Pokrovsky, Oleg S.; Pokrovsky, Oleg; RSFRussian Science Foundation (RSF) [18-17-00238-P]; RFBRRussian Foundation for Basic Research (RFBR) [19-55-15002, 20-05-00729_a]

/ Л. В. Карпенко // География и природные ресурсы. - 2023. - № 4. - P90-98DOI 10.15372/GIPR20230409
   Перевод заглавия: CONTENT OF RARE-EARTH ELEMENTS IN THE PEAT DEPOSIT OF THE HIGH BOG IN THE VALLEY OF THE DUBCHES RIVER (KRASNOYARSK KRAI)

ГРНТИ

68.05

68.47.03

Аннотация: Проведено исследование валового содержания редкоземельных элементов (скандия, иттрия, лантана, церия, празеодима, неодима, самария, европия, гадолиния, тербия, диспрозия, гольмия, эрбия, тулия, иттербия и лютеция) в торфяной залежи верхового болота в долине р. Дубчес (Красноярский край). Выявлено, что возраст придонного слоя торфа составляет 13 617 ± 190 кал. л. н. Рассмотрены основные источники поступления редкоземельных элементов в торфяную залежь болота. Это подстилающие породы, атмосферные аэрозоли, региональные и локальные лесные пожары, геохимия торфов. Отмечено, что атмосферные аэрозоли и региональные лесные пожары мало влияли на концентрацию элементов в исследованных торфах. Основными источниками привноса редкоземельных элементов в торфяную залежь служили подстилающие породы и окислительно-восстановительная среда в инициальный период формирования болота. В ходе исследования установлено, что содержание редкоземельных элементов в верховых, переходных и низинных торфах ниже кларка, а все элементы рассеяны. В верховых и переходных видах торфа наиболее рассеяны церий, тербий и гольмий, а в низинных - церий и тербий. При этом концентрации скандия и иттербия в низинных видах торфа близки к кларку почв. Сделан вывод, что в различных видах верхового и переходного торфов концентрация редкоземельных элементов вниз по профилю почти не изменяется. Их незначительное накопление отмечено только в приповерхностных слоях 0,30-0,35 м. В пирогенных прослойках на глубинах 2,65, 2,90, 3,15 и 3,25 м зафиксировано повышенное содержание почти всех редкоземельных элементов относительно вышележащего слоя торфа. В низинных видах торфа в интервале глубин 4,0-3,75 м отмечена максимально высокая концентрация всех элементов. Высказано предположение о том, что основным источником поступления редкоземельных элементов в инициальной стадии развития болота могли служить постилающие породы древнего ледникового происхождения.
A study was made of the gross content of rare-earth elements (scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, tulium, ytterbium and lutetium) in the peat deposit of the high bog in the Dubches River valley (Krasnoyarsk krai). It was revealed that the age of the bottom peat layer is 13 617 ± 190 cal BP. The main sources of rare-earth elements entering the peat deposit of the bog are considered. They are underlying rocks, atmospheric aerosols, regional and local forest fires, and peat geochemistry. It was noted that atmospheric aerosols and regional forest fires had little effect on the concentration of elements in the peat studied. The main sources of input of rare-earth elements into the peat deposit were the underlying rocks and the oxide-recovery environment at the initial period of the formation of the bog. During the study it was found that the content of rare-earth elements in the upper, transitional and lowland peats is below the clarke number and all the elements are dispersed. Cerium, terbium, and holmium are most dispersed in the upper and transitional types of peat, and cerium and terbium in the lowland ones. The concentrations of scandium and ytterbium in the lowland peat types are close to the soil clarke. It is concluded that the concentration of rare-earth elements in different types of highland and transitional peats down the profile not almost change. Their insignificant accumulation is noted only in the near-surface layers of 0.30-0.35 m. In pyrogenic interlayers at the depths of 2.65, 2.90, 3.15, and 3.25 m, increased content of almost all rare-earth elements relative to the overlying layer of peat was recorded. In the lowland types of peat in the depth interval of 4.0-3.75 m, the highest concentration of all elements was noted. It is suggested that the main source of rare-earth elements in the initial stage of bog development could be the bedrock of ancient glacial origin.

РИНЦ

Держатели документа:
Sukachev Institute of Forest, Siberian Branch, Russian Academy of Science, 50, bil. 28, Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Karpenko, Lyudmila Vasil'yevna