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    Syntheses of (Z,E)-5,7-dodecadienol and (E,Z)-10,12-hexadecadienol, Lepidoptera pheromone components, via zinc reduction of enyne precursors. Test of pheromone efficacy against the Siberian moth
[Text] / A. . Khrimian [et al.] // J. Agric. Food Chem. - 2002. - Vol. 50, Is. 22. - P6366-6370, DOI 10.1021/jf020472s. - Cited References: 24 . - 5. - ISSN 0021-8561
РУБ Agriculture, Multidisciplinary + Chemistry, Applied + Food Science & Technology

Аннотация: Efficient syntheses of (ZE)-5,7-dodecadienol, a pheromone component of the Siberian moth, Dendrolimus superans sibiricus, and (E,Z)-10,12-hexadecadienol, a pheromone component of various Lepidoptera pheromones, were accomplished by cis reduction of the corresponding enynols with activated zinc. The most energetic reagent was zinc galvanized with copper and silver (Zn/Cu/Ag) that achieved rapid and high-yield reduction in methanol-water. The stereoselectivity of semihydrogenation was greater than or equal to98%. A process whereby zinc dust was continuously activated throughout the reduction with an acid was also satisfactory (95-98% cis). Field evaluation of the 1:1 mixture of (Z,E)-5,7-dodecadienol and (Z,E)-5,7-dodecadienal with the Siberian moth in Russia showed that the rubber septa pretreated with compound and stored at -80 degreesC were as effective as freshly treated septa. Moth responses to septa aged in open air indicated that lure effectiveness declined significantly after 2 weeks of aging. Thus, if rubber septa are used as pheromone dispensers in Siberian moth traps monitoring, they should be replaced biweekly with fresh septa for optimal trap effectiveness.

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Держатели документа:
USDA ARS, PSI, Chem Affecting Insect Behav Lab, Beltsville, MD 20705 USA
Morgan State Univ, Dept Chem, Baltimore, MD 21251 USA
Russian Acad Sci, Siberian Branch, VN Sukachev Inst Forest, Dept Forest Zool, Krasnoyarsk 660036, Russia
USDA, APHIS, Otis Methods Dev Ctr, Otis ANGB, MA 02542 USA
USDA ARS, BA, Biometr Consulting Serv, Beltsville, MD 20705 USA

Доп.точки доступа:
Khrimian, A...; Klun, J.A.; Hijji, Y...; Baranchikov, Y.N.; Pet'ko, V.M.; Mastro, V.C.; Kramer, M.H.

    Linking trace gas measurements and molecular tracers of organic matter in aerosols for identification of ecosystem sources and types of wildfires in Central Siberia
/ A. V. Panov [et al.] // IOP Conference Series: Earth and Environmental Science : Institute of Physics Publishing, 2016. - Vol. 48: 9th International Conference and Early Career Scientists School on Environmental Observations, Modelling and Information Systems, ENVIROMIS 2016 (11 July 2016 through 16 July 2016, ) Conference code: 125703, Is. 1, DOI 10.1088/1755-1315/48/1/012017 . -
Аннотация: Summer 2012 was one of the extreme wildfire years in Siberia. At the surface air monitoring station "ZOTTO" (60°48'N, 89°21'E, 114 m a.s.l.) in Central Siberia we observed biomass burning (BB) influence on the ongoing atmospheric measurements within more than 50 % of the time in June-July 2012 that indicates a 30 times greater wildfire signal compared to previously reported ordinary biomass burning signature for the study area. While previous studies thoroughly estimated a relative input of BB into aerosol composition (i.e. size distribution, physical and optical parameters etc.) at ZOTTO, in this paper we characterize the source apportionment of the smoke aerosols with molecular tracer techniques from large-scale wildfires occurred in 2012 in the two prevailing types of Central Siberian ecosystems: complexes of pine forests and bogs and dark coniferous forests. Wildfires in the selected ecosystems are highly differed by their combustion phase (flaming/smoldering), the type of fire (crown/ground), biomass fuel, and nature of soil that greatly determines the smoke particle composition. Anhydrosugars (levoglucosan and its isomers) and lignin phenols taken as indicators of the sources and the state of particulate matter (PM) inputs in the specific fire plumes were used as powerful tools to compare wildfires in different environmental conditions and follow the role and contribution of different sources of terrestrial organic matter in the transport of BB pollutants into the pristine atmosphere of boreal zone in Central Siberia. © Published under licence by IOP Publishing Ltd.

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Держатели документа:
Laboratory of Biogeochemical Cycles in Forest Ecosystems, V.N. Sukachev Institute of Forest, SB RAS, Akademgorodok 50/28, Krasnoyarsk, Russian Federation
International Laboratory of Permafrost Ecosystems, V.N. Sukachev Institute of Forest, SB RAS, Akademgorodok 50/28, Krasnoyarsk, Russian Federation
Laboratory of Forest Fire Research, V.N. Sukachev Institute of Forest, SB RAS, Akademgorodok 50/28, Krasnoyarsk, Russian Federation
Department of Oceanography, Texas A and M University, College Station, TX, United States
Department of Marine Sciences, Texas A and M University, 200 Seawolf Parkway, Galveston, TX, United States
Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, Mainz, Germany
Max Planck Institute for Biogeochemistry, Hans Knoell 10, Jena, Germany

Доп.точки доступа:
Panov, A. V.; Prokushkin, A. S.; Korets, M. A.; Bryukhanov, A. V.; Myers-Pigg, A. N.; Louchouarn, P.; Sidenko, N. V.; Amon, R.; Andreae, M. O.; Heimann, M.