Труды сотрудников ИЛ им. В.Н. Сукачева СО РАН

/ F. Pourpoint [et al.] // Chem. Geol. - 2017. - Vol. 452. - P1-8, DOI 10.1016/j.chemgeo.2017.02.004. - Cited References:60. - The Lille group is grateful for funding by the Region Nord/Pas-de-Calais, France, Europe (FEDER), CNRS, Ministere de l'Enseignement Superieur et de la Recherche, Institut Chevreul (FR 2638), CPER, ENSCL, and contract ANR-14-CE07-0009-01. Bruker Company and Fabien Aussenac are warmly acknowledged for providing access to DNP-NMR spectrometer. Guillaume Laurent is also acknowledged for fruitful discussion. Financial support from the IR-RMN-THC FR-3050 CNRS for conducting the research is gratefully acknowledged. . - ISSN 0009-2541. - ISSN 1878-5999РУБ Geochemistry & Geophysics

Аннотация: In a Siberian river, the concentrations of chemical species vary with the hydrological regime. Dissolved Organic Matter (DOM) and aluminum ions show a parallel trend in the course of the hydrological year. However, the speciation of aluminum in this natural environment remains an open question. We propose here a combination of spectroscopic techniques to investigate the proximity between the aluminum atoms and DOM. First, one-dimensional (1D) solid-state Nuclear Magnetic Resonance (NMR), Electron Paramagnetic Resonance (EPR) and 1D and 2D solution NMR spectra were acquired, providing a clear overview of the DOM composition. Second, the sensitivity enhancement yielded by Dynamic Nuclear Polarization enabled the NMR detection of proximities between the Al-27 and C-13 nuclei. Hence, we show that 8.3 +/- 1.3% of the carboxylate groups observed by NMR are connected to the Al3+ ions in the DOM sample. We here demonstrate for the first time how advanced solid-state NMR methods can provide key information about the localization of aluminum in such complex natural materials. (C) 2017 Elsevier B.V. All rights reserved.

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Держатели документа:
Univ Lille, CNRS, ENSCL, UCCS,UMR 8181, F-59000 Lille, France.
Univ Paris 06, CNRS, METIS Milieux Environnementaux Transferts & Inte, UMR 7619, F-75252 Paris 05, France.
Univ Lille, CNRS, LASIR Lab Spect Infrarouge & Raman, UMR 8516, F-59000 Lille, France.
Univ Lille, CNRS, UGSF, UMR 8576, F-59000 Lille, France.
Univ Strasbourg, CNRS, LHyGeS, UMR 7517, F-67084 Strasbourg, France.
CNRS, GET, Observ Midi Pyrenees, UMR 5563, Toulouse, France.
V N Sukachev Inst Forest SB RAS, Akademgorodok 50-28, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Pourpoint, Frederique; Templier, Joelle; Anquetil, Christelle; Vezin, Herve; Trebosc, Julien; Trivelli, Xavier; Chabaux, Francois; Pokrovsky, Oleg S.; Prokushkin, Anatoly S.; Amoureux, Jean-Paul; Lafon, Olivier; Derenne, Sylvie; Region Nord/Pas-de-Calais, France, Europe (FEDER); Ministere de l'Enseignement Superieur et de la Recherche; Institut Chevreul [FR 2638]; CPER; ENSCL [ANR-14-CE07-0009-01]; IR-RMN-THC FR-3050 CNRS