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Найдено документов в текущей БД: 68

    Preparation and structural properties of nonlinear optical borates K 2(1-x)Rb 2xAl 2B 2O 7, 0 ˂ x ˂ 0.75
/ V. V. Atuchin [и др.] // J. Alloys Compd. - 2012. - Vol. 515. - P. 119-122, DOI 10.1016/j.jallcom.2011.11.115. - Cited References: 30. - This study was supported by SB RAS (Grant 34) and RFBR Grants 11-02-90706-mob_st and 11-03-00867a. . - ISSN 0925-8388
   Перевод заглавия: Получение и структурные свойства нелинейных оптических боратов K 2(1-x)Rb 2xAl 2B 2O 7, 0 ˂ x ˂ 0.75
РУБ Chemistry, Physical + Materials Science, Multidisciplinary + Metallurgy & Metallurgical Engineering + Aluminum + Crystal structure + Nonlinear optics + Rietveld analysis + Rubidium + Solid solutions + Structural properties + X ray powder diffraction

Аннотация: The structures of K 2(1-x)Rb 2xAl 2B 2O 7, x = 0.25, 0.5, 0.75, have been determined in space group P321 through Rietveld analysis of X-ray powder diffraction data. The solubility limit in K 2(1-x)Rb 2xAl 2B 2O 7 crystals has been estimated as x similar to 0.83-0.9. Nonlinear optical properties of KRbAl 2B 2O 7 have been verified by powder Kurtz-Perry method. Mechanisms of structural parameter variation in K 2Al 2B 2O 7 crystal family have been discussed.

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Доп.точки доступа:
Atuchin, V. V.; Bazarov, B. G.; Gavrilova, T. A.; Grossman, V. G.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bazarova, Zh. G.

    Анализ фазового состава порошков сплава СО–P на основе магнитометрических измерений
/ Л. А. Чеканова [и др.] // Физ. металлов и металловед. - 2013. - Т. 114, Вып. 2. - С. 136-143DOI 10.7868/S0015323013020046 . -
Аннотация: Предложен новый метод количественной оценки фазового состава многофазного ферромагнитного сплава, основанный на измерениях зависимостей намагниченности от температуры и внешнего поля. Проведена характеризация фазового состава ультрадисперсных порошков Co–P. Построены фазовые диаграммы неравновесных твердых растворов Co–P в координатах размер частиц – концентрация фосфора.

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Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Чеканова, Лидия Александровна; Chekanova, L. A.; Денисова, Елена Александровна; Denisova, E. A.; Гончарова, О. А.; Комогорцев, Сергей Викторович; Komogortsev, S. V.; Исхаков, Рауф Садыкович; Iskhakov, R. S.

    Analysis of phase composition of Co-P alloy powders using magnetometric data
/ L. A. Chekanova [et al.] // Phys. Metals & Metallogr. - 2013. - Vol. 114. Is. 2. - P. 122-128DOI 10.1134/S0031918X1302004X . -

Аннотация: A new method for the quantitative estimate of the phase composition of a multiphase ferromagnetic alloy is suggested that is based on measuring the temperature and field dependences of the magnetization. The phase composition of ultrafine Co-P powders is characterized. Phase diagrams of nonequilibrium Co-P solid solutions are constructed on particle size, i.e., the phosphorus concentration coordinates.

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Держатели документа:
Russian Acad Sci, Siberian Branch, Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Siberian State Technol Univ, Krasnoyarsk 660049, Russia

Доп.точки доступа:
Chekanova, L. A.; Чеканова, Лидия Александровна; Denisova, E. A.; Денисова, Елена Александровна; Goncharova, O. A.; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович

    The influence of glass obtaining atmosphere composition on nucleation and grows of the spherulites in SrO•2B2O3 glasses
/ A. I. Zaitsev, A. V. Cherepakhin, A. V. Zamkov // 3 Int. Conf. “Crystallogenesis and mineralogy” : Abstracts Vol. - Новосибирск : Изд-во СО РАН, 2013. - P. 117-118 . - ISBN 978-5-7692-1320-5
   Перевод заглавия: Влияние состава атмосферы при получении стекол на зародышеобразование и рост сферолитов в стеклах состава SrO•2B2O3



Доп.точки доступа:
Cherepakhin, A. V.; Черепахин, Александр Владимирович; Zamkov, A. V.; Замков, Анатолий Васильевич; Зайцев, Александр Иванович; International Conference on Crystallogenesis and Mineralogy (3 ; Sept. 27 – Oct. 1, 2013 ; Novosibirsk)

    Magnetic properties and metastable states of Co-Ir films
/ E. M. Artemiev [et al.] // Bull. Russ. Acad. Sci. Phys. - 2014. - Vol. 78, Is. 2. - P. 134-135, DOI 10.3103/S1062873814020063. - Cited References: 3 . - ISSN 1062-8738
Аннотация: The phase composition, crystal structure, and magnetic properties of Co1 - x Ir x alloy films with x = 0.35-0.8 and fabricated by chemical deposition are studied. Saturation magnetization vs. composition and temperature, coercivity, and magnetization reversal of the films are investigated experimentally. It is shown that in the region of equiatomic composition, Co-Ir films have a two-phase hexagonal close-packed structure that alternates with disordered regions, producing halos in electron diffraction patterns. В© 2014 Allerton Press, Inc.

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Держатели документа:
Siberian Federal University, Krasnoyarsk 660041, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk 660036, Russian Federation
Siberian State Aerospace University, Krasnoyarsk 660014, Russian Federation

Доп.точки доступа:
Artemiev, E. M.; Buzmakov, A. E.; Polyakova, K. P.; Полякова, Клавдия Павловна; Yakimov, L. E.

    Actual composition and structure of manganese ferrite nanoparticles dispersed in the borate glass matrix
/ I. G. Vasilyeva [et al.] // Doklady Chemistry. - 2005. - Vol. 401, Is. 1-3. - P. 47-50, DOI 10.1007/s10631-005-0029-y . - ISSN 0012-5008

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Держатели документа:
Nikolaev Inst. of Inorg. Chemistry, Siberian Division, Russian Academy of Sciences, pr. akademika Lavrent'eva 3, Novosibirsk, 630090, Russian Federation
Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. akademika Lavrent'eva 5, Novosibirsk, 630090, Russian Federation
Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
All-Russia Research Center, Vavilov State Optical Institute, ul. Babushkina 36/1, St. Petersburg, 192371, Russian Federation

Доп.точки доступа:
Vasilyeva, I. G.; Dovlitova, L. S.; Zaikovskii, V. I.; Malakhov, V. V.; Edel'man, I. S.; Эдельман, Ирина Самсоновна; Stepanov, A. S.; Aleksandrov, K. S.; Александров, Кирилл Сергеевич

    Real composition and structure of manganese ferrite nanoparticles dispersed in the K-Al-B-O glasses
/ I. G. Vasil'eva [и др.] // Dokl. Akad. Nauk. - 2005. - Vol. 401, Is. 3. - P. 349-352 . - ISSN 0869-5652

Кл.слова (ненормированные):
Aluminum -- Boron compounds -- Ferrite -- Manganese -- Nanostructured materials -- Particles (particulate matter) -- Structure (composition) -- Borate glasses -- Exchange interaction -- Glass

Аннотация: For the first time the problem of determining real composition and structure of manganese ferrite nanoparticles dispersed borate glasses is solved using differentiating dissolution and high-resolution X-ray electron microscopy techniques. For the first time the nanosize effect of aluminum incorporation in manganese ferrite composition is experimentally shown, thus directly confirming the hypothesis of Al participation in exchange interaction between paramagnetic Fe and Mn ions as diamagnetic diluter.

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Держатели документа:
Inst. Neorganicheskoj Khimii SO RAN, Novosibirsk, Russian Federation

Доп.точки доступа:
Vasil'eva, I. G.; Dovlitova, L. S.; Zajkovskij, V. I.; Malakhov, V. V.; Edel'man, I. S.; Эдельман, Ирина Самсоновна; Stepanov, A. S.; Aleksandrov, K. S.; Александров, Кирилл Сергеевич

    Structure and composition of Fe-Si interfaces in (Fe/Si)3 multilayer nanostructures
/ J. Bartolomé [et al.] // Third Asian school-conference on physics and technology of nanostructured materials (ASCO-NANOMAT 2015) : proceedings. - Vladivostok : Dalnauka, 2015. - Ст. PS.20.02i. - P. 18-19 . - ISBN 978-5-8044-1556-4


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Доп.точки доступа:
Bartolomé, J.; Badía-Romano, L.; Rubín, J. ; Magén, C.; Bürgler, D. E.; Rubio-Zuazo, J.; Castro, G. R. ; Varnakov, S. N.; Варнаков, Сергей Николаевич; Yakovlev, I. A.; Яковлев, Иван Александрович; Tarasov, I. A.; Тарасов, Иван Анатольевич; Belyaev, B. A.; Беляев, Борис Афанасьевич; Lyashchenko, S. A.; Лященко, Сергей Александрович; Platunov, M. S.; Платунов, Михаил Сергеевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Asian School-Conference on Physics and Technology of Nanostructured Materials(3 ; 2015 ; Aug. ; 19-26 ; Vladivostok); Азиатская школа-конференция по физике и технологии наноструктурированных материалов(3 ; 2015 ; авг. ; 19-26 ; Владивосток)

    Composition and morphology of Fe-Si interfaces and (Fe/Si)3 multilayer nanostructures
/ J. Bartolomé [и др.] // 20th Int. Conf. on Magnetism (ICM-2015) : book of abstracts. - 2015. - Ст. WE.J.2_I1


Материалы конференции


Доп.точки доступа:
Bartolomé, J.; Badía-Romano, L.; Rubín, J. ; Bartolomé, F.; Magén, C.; Bürgler, D. E.; Rubio-Zuazo, J.; Castro, G. R. ; Varnakov, S. N.; Варнаков, Сергей Николаевич; Yakovlev, I. A.; Яковлев, Иван Александрович; Tarasov, I. A.; Тарасов, Иван Анатольевич; Platunov, M. S.; Платунов, Михаил Сергеевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; International Conference on Magnetism(20 ; 2015 ; Jul ; 5-10 ; Barselona, Spain)

    Effects of composition modulation on the luminescence properties of Eu3+ doped Li1-xAgxLu(MoO4)2 solid-solution phosphors
/ F. Cheng [et al.] // Dalton Trans. - 2015. - Vol. 44, Is. 41. - P. 18078-18089, DOI 10.1039/c5dt02760h. - Cited References: 42. - The present work was supported by the National Natural Science Foundations of China (Grant No. 51272242, 51572023, 51511130035), Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), Beijing Youth Excellent Talent Program (YETP0635), the Funds of the State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences (RERU2015022), and the excellent tutor section of the Fundamental Research Funds for the Central Universities of China University of Geosciences, Beijing (2-9-2015-028). This work was also partly supported by the Russian Foundation for Basic Research (Grant No. 15-52-53080 GFEN_a). . - ISSN 1477-9226
   Перевод заглавия: Влияние модуляции состава на люминесцентные свойства твердотельного люминофора Li1-xAgxLu(MoO4)2 допированного Eu3+
РУБ Chemistry, Inorganic & Nuclear

Аннотация: Double molybdate scheelite-type solid-solution phosphors Li1−xAgxLu1−y(MoO4)2:yEu3+ were synthesized by the solid state reaction method, and their crystal structures and luminescence properties were investigated in detail. The composition modulation and structural evolution of this series of samples were studied and the selected AgEu(MoO4)2, AgLu(MoO4)2, LiLu(MoO4)2 and LiEu(MoO4)2 phases were analyzed based on the Rietveld refinement. Depending on the variation of the Li/Ag ratio in Li1−xAgxLu1−y(MoO4)2:yEu3+ phosphors, the difference in the luminescence properties of Li1−xAgxLu1−y(MoO4)2:yEu3+ phosphors was ascribed to two factors, one reason could be assigned to the coupling effect and the nonradiative transition between the energy levels of LixAg1−xLu(MoO4)2 matrices and the activator Eu3+, another could be due to the near ultraviolet energy absorption and transmission efficiency between the charge-transfer (CT) band of O2−–Mo6+ and the 4f → 4f emissive transitions of Eu3+. The ultraviolet-visible diffuse reflection spectra (UV-vis DRS) and Raman spectra analysis were also used to verify the above mechanism.

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Держатели документа:
School of Materials Sciences and Technology, China University of Geosciences, Beijing, China
School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China

Доп.точки доступа:
Cheng, F.; Xia, Zhiguo; Molokeev, M. S.; Молокеев, Максим Сергеевич; Jing, X.

    Codon usage trajectories and 7-cluster structure of 143 complete bacterial genornic sequences
/ A. . Gorban, T. . Popova, A. . Zinovyev // Physica A. - 2005. - Vol. 353. - P. 365-387, DOI 10.1016/j.physa.2005.01.043. - Cited References: 46 . - ISSN 0378-4371
РУБ Physics, Multidisciplinary

Аннотация: Three results are presented. First, we prove the existence of a universal 7-cluster structure in all 143 completely sequenced bacterial genomes available in Genbank in August 2004, and explained its properties. The 7-cluster structure is responsible for the main part of sequence heterogeneity in bacterial genomes. In this sense, our 7 clusters is the basic model of bacterial genome sequence. We demonstrated that there are four basic "pure" types of this model, observed in nature: "parallel triangles", "perpendicular triangles", degenerated case and the flower-like type. Second, we answered the question: how big are the position-specific information and the contribution connected with correlations between nucleotide. The accuracy of the mean-field (context-free) approximation is estimated for bacterial genomes. We show that codon us-age of bacterial genomes is a multi-linear function of their genomic G+C-content with high accuracy (more precisely, by two similar functions, one for eubacterial genomes and the other one for archaea). Description of these two codon-usage trajectories is the third result. All 143 cluster animated 3D-scatters are collected in a database and is made available on our web-site: http://www.ihes.fr/similar to zinovyev/7clusters. (c) 2005 Elsevier B.V. All rights reserved.

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Держатели документа:
Univ Leicester, Dept Math, Leicester LE1 7RH, Leics, England
RAS, SB, Inst Computat Modelling, Krasnoyarsk, Russia
Bures Sur Yvette & Bioinformat Serv Inst Curie, Inst Hautes Etudes Sci, Paris, France
ИВМ СО РАН
Department of Mathematics, University of Leicester, Leicester, University Road, Leicester LE1 7RH, United Kingdom
Institute of Computational Modelling, SB RAS, Krasnoyarsk, Russian Federation
Institut des Hautes Etudes Scientifiques, Bures-sur-Yvette and Bioinformatics Service of Institut Curie, Paris, France

Доп.точки доступа:
Popova, T.; Zinovyev, A.

    Phase composition of nanocrystalline iron films deposited in a nitrogen atmosphere
/ G. I. Frolov, V. S. Zhigalov, O. A. Bayukov // Phys. Solid State. - 1999. - Vol. 41, Is. 10. - P. 1669-1671, DOI 10.1134/1.1131050. - Cited References: 14 . - ISSN 1063-7834
РУБ Physics, Condensed Matter

Аннотация: The phase composition of iron films prepared by pulsed-plasma deposition in a controlled nitrogen atmosphere is investigated by Mossbauer spectroscopy. The observed changes in the phase composition are dictated by the nanocrystalline structure of the samples and the dynamics of the substrate temperature during film deposition. (C) 1999 American Institute of Physics. [S1063-7834(99)02110-3].

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Держатели документа:
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН

Доп.точки доступа:
Zhigalov, V. S.; Жигалов, Виктор Степанович; Bayukov, O. A.; Баюков, Олег Артемьевич; Фролов, Георгий Иванович

    Heat capacity study of relaxors BaTi0.65Zr0.35O3 and BaTi0.60Zr0.40O3
/ M. . Gorev [et al.] // J. Phys.: Condens. Matter. - 2006. - Vol. 18, Is. 17. - P. 4407-4416, DOI 10.1088/0953-8984/18/17/026. - Cited References: 21 . - ISSN 0953-8984
РУБ Physics, Condensed Matter

Аннотация: The heat capacity of two relaxors BaTi(1-x)ZrxO(3) (x = 0.35, 0.40) was measured using adiabatic calorimetry in the temperature range 100-360 K. The Cp(T) dependence of both compositions is characterized by the presence of two diffuse anomalies near the Burns temperature T-d and the temperature of the maximum in permittivity T-m in the temperature ranges 250-350 K and 120 200 K. The anomalous heat capacity near T-d was analysed taking into account the distribution of Zr concentration in nanoregions leading to the distribution of their transition temperatures into the polar phase. Excess heat capacity near Tm was discussed in the framework of the spherical random bond-random field model. The results are compared with the data obtained by the same procedures for PbMg1/3Nb2/3O3 studied experimentally earlier.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
CNRS, CEMES, F-31055 Toulouse, France
ИФ СО РАН
L V Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
CEMES-CNRS, 31055 Toulouse, France

Доп.точки доступа:
Gorev, M.; Bondarev, V.; Sciau, P.; Savariault, J. M.

    Magnetic cooling of composition ferromagnetics
/ E. V. Babkin, G. I. Barinov, K. O. Urinov // Pisma Zhurnal Tek. Fiz. - 1991. - Vol. 17, Is. 5. - P. 10-12. - Cited References: 2 . - ISSN 0320-0116
РУБ Physics, Applied


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Доп.точки доступа:
Barinov, G. I.; Urinov, K. O.

    2 regions of amorphous state in the equiatomic composition copd alloy-films
/ E. M. Artemiev, A. S. Komalov, A. A. Smyk // Fiz. Tverd. Tela. - 1983. - Vol. 25, Is. 3. - P. 949-950. - Cited References: 2 . - ISSN 0367-3294
РУБ Physics, Condensed Matter


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Доп.точки доступа:
Komalov, A. S.; Smyk, A. A.

    Raman spectra and phase composition of MnGeO3 crystals
/ A. S. Oreshonkov [et al.] // J. Raman Spectrosc. - 2016. - Vol. 47, Is. 5. - P. 531-536, DOI 10.1002/jrs.4816. - Cited References:21. - The work was partially supported by the RFBR through grants no. 13-02-00825.; O.A.S. and K.A.S. are partially supported by the Ministry of Science and Education of the Russian Federation. . - ISSN 0377-0486. - ISSN 1097-4555
   Перевод заглавия: Раман спектры и фазовый состав кристаллов MnGeO3
РУБ Spectroscopy

Аннотация: MnGeO3 single-crystal samples have been synthesized by optical zonal melting and spontaneous crystallization. X-ray crystal analysis showed the first sample to be a two-phase one with phase ratio as follows: 17% - monoclinic C2/c, and 83% - orthorhombic Pbca; the phase ratio of the second sample was unknown. Raman spectra have been produced for these samples. Lattice dynamics has been simulated and polarization dependencies of lines' intensities have been analyzed to interpret experimental Raman spectra and to attribute lines to the spectra of monoclinic and orthorhombic phases. Copyright (C) 2015 John Wiley & Sons, Ltd.

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Держатели документа:
RAS, Kirensky Inst Phys, SB, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660036, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.

Доп.точки доступа:
Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Gerasimova, J. V.; Герасимова, Юлия Валентиновна; Ershov, A. A.; Ершов, Александр Андреевич; Krylov, A. S.; Крылов, Александр Сергеевич; Shaykhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Vtyurin, A. N.; Втюрин, Александр Николаевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Terent'ev, K. Yu.; Терентьев, Константин Юрьевич; Mikhashenok, N. V.; Михашенок, Наталья Владимировна; RFBR [13-02-00825]; Ministry of Science and Education of the Russian Federation

    Типоморфизм арсенопирита золоторудных месторождений Благодатное и Олимпиада (Енисейский кряж)
/ А. М. Сазонов [и др.] // Минералогия. - 2016. - № 3. - С. 53-70. - Библиогр.: 24. - Работа выполнена при финансовой поддержке Министерства образования и науки РФ, программа «Организация проведения научных исследований», № 1025 и Фонда Михаила Прохорова (договор № АМ-94/15 и АМ-35/16).
   Перевод заглавия: Typomorphism of arsenopyrite from the Blagodatnoye and Olimpiada gold ore deposits (Yenisei ridge)
Аннотация: Присутствие арсенопирита является показателем золотоносности гидротермальной минерализации в месторождениях Олимпиада и Благодатное, где производится около 40 т золота ежегодно. Парагенетические ассоциации арсенопирита, морфология зёрен, кристаллическая структура и химический состав характеризуются значительной неоднородностью в пределах одного зерна, соседних зёрен, разновозрастных генераций, в различных участках рудных тел и в месторождениях. Кристаллизация минерала осуществлялась в интервале температур < 300–542.5 °С при изменчивой активности серы в растворах (log αS2 ⋍ -5.7... -14.6) как в различных пробах, так и зёрнах, принадлежащих одной выборке. Повышенные концентрации золота и других благородных металлов отмечены в арсенопиритах с избытком серы и с избытком мышьяка.
The presence of arsenopyrite is an indicator of gold in hydrothermal mineralization of the Olimpiada and Blagodatnoye deposits producing about 40t of gold annually. The paragenetic associations of arsenopyrite, the morphology of grains, the crystal structure and chemical composition are characterized by significant heterogeneity within a single grain, neighbouring grains, generations of different ages, in different parts of ore bodies and deposits. Mineral crystallization occurred in the temperature range of < 300–542.5 °С, with variable sulphur activity in solutions (log αS2⋍ –5.7…–14.6). The increased concentrations of gold and other precious metals are noted in arsenopyrite with excess of sulphur and excess of arsenic with reduced structural and chemical stoichiometry.

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Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Сазонов, А. М.; Кирик, С. Д.; Сильянов, С. А.; Баюков, Олег Артемьевич; Bayukov, O. A.; Тишин, П. А.

    Tuning of photoluminescence and local structures of substituted cations in xSr2Ca(PO4)2-(1 - x)Ca10Li(PO4)7:Eu2+ phosphors
/ M. Chen [et al.] // Chem. Mater. - 2017. - Vol. 29, Is. 3. - P. 1430-1438, DOI 10.1021/acs.chemmater.7b00006. - Cited References: 37. - The present work was supported by the National Natural Science Foundation of China (Grants 91622125 and 51572023), Natural Science Foundations of Beijing (2172036), and Fundamental Research Funds for the Central Universities (FRF-TP-15-003A2). . - ISSN 0897-4756
   Перевод заглавия: Управляемая люминесценция и локальная структура замещаемых катионов в люминофоре xSr2Ca(PO4)2-(1-x)Ca10Li(PO4)7:Eu2+
Аннотация: Local structure modification in solid solution is an essential part of photoluminescence tuning of rare earth doped solid state phosphors. Herein we report a new solid solution phosphor of Eu2+-doped xSr2Ca(PO4)2-(1 - x)Ca10Li(PO4)7 (0 ≤ x ≤ 1), which share the same β-Ca3(PO4)2 type structure in the full composition range. Depending on the x parameter variation in xSr2Ca(PO4)2-(1 - x)Ca10Li(PO4)7:Eu2+, the vacancies generated in the M(4) site enable the nonlinear variation of cell parameters and volume, and this increases the magnitude of M(4)O6 polyhedra distortion. The local structure modulation around the Eu2+ ions causes different luminescent behaviors of the two-peak emission and induces the photoluminescence tuning. The shift of the emission peaks in the solid solution phosphors with different compositions has been discussed. It remains invariable at x ≤ 0.5, but the red-shift is observed at x > 0.5 which is attributed to combined effect of the crystal field splitting, Stokes shift, and energy transfer between Eu2+ ions. The temperature-dependent luminescence measurements are also performed, and it is shown that the photoionization process is responsible for the quenching effect.

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Держатели документа:
Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
State Key Laboratory of Tribology, Tsinghua University, Beijing, China

Доп.точки доступа:
Chen, M.; Xia, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Wang, T.; Liu, Q.

    Structure and magnetic properties of titanium nickelide nanoparticles synthesized by pulsed laser ablation method
/ A. K. Drozdova [et al.] // J. Phys. Conf. Ser. - 2017. - Vol. 857, Is. 1. - Ст. 012007, DOI 10.1088/1742-6596/857/1/012007. - Cited References: 9 . - ISSN 1742-6588
   Перевод заглавия: Структура и магнитные свойства наночастиц никелида титана, синтезированных методом импульсной лазерной абляции
Аннотация: We have successfully synthesized magnetic titanium nickelide nanoparticles with equiatomic composition by pulsed laser ablation method. Using transmission electron microscopy and microanalysis was revealed that particles represent the homogeneous conglomerates containing identical amount of Ni and Ti atoms. The magnetization value of nanoparticles was estimated.

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Доп.точки доступа:
Drozdova, A. K.; Cherepanov, V. N.; Svetlichny, V. A.; Kveglis, L. I.; Volochaev, M. N.; Волочаев, Михаил Николаевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; International Conference on Films and Coatings(13 ; 18-20 April 2017 ; St. Petersburg)

    Composition design, optical gap and stability investigations of lead-free halide double perovskite Cs2AgInCl6
/ J. Zhou [et al.] // J. Mater. Chem. A. - 2017. - Vol. 5, Is. 29. - P. 15031-15037, DOI 10.1039/c7ta04690a. - Cited References: 42. - The present work was supported by the National Natural Science Foundation of China (Grants 91622125 and 51572023), Natural Science Foundations of Beijing (2172036), and Fundamental Research Funds for the Central Universities (FRF-TP-16-002A3). XZ acknowledges the support from the National Key Research and Development Program of China Grant No. 2016YFB0700700. . - ISSN 2050-7488
   Перевод заглавия: Моделирование состава, оптический зазор и исследования стабильности безсвинцового галогенидного двойного перовскита Cs2AgInCl6
Аннотация: The discovery of lead-free double perovskites provides a feasible way of searching for air-stable and environmentally benign solar cell absorbers. Herein we report the design and hydrothermal crystal growth of double perovskite Cs2AgInCl6. The crystal structure, morphology related to the crystal growth habit, band structure, optical properties, and stability are investigated in detail. This perovskite crystallized in a cubic unit cell with the space group Fm3m and is composed of [AgCl6] and [InCl6] octahedra alternating in a ordered rock-salt structure, and the as-obtained crystal size is dependent on the hydrothermal reaction time. Cs2AgInCl6 is a direct gap semiconductor with a wide band gap of 3.23 eV obtained experimentally and 3.33 eV obtained by DFT calculation. This theoretically predicted and experimentally confirmed optical gap is a prototype of the band gaps that are direct and optically allowed except at the single high-symmetry k-point, which didn't raise interest before but have potential applications in future technologies. Cs2AgInCl6 material with excellent moisture, light and heat stability shows great potential for photovoltaic and other optoelectronic applications via further band gap engineering. © 2017 The Royal Society of Chemistry.

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Держатели документа:
Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Shenzhen Key Laboratory of Micro-Nano Photonic Information Technology, College of Electronic Science and Technology, Shenzhen University, Guangdong, China
College of Optoelectronic Engineering, Shenzhen University, Guangdong, China

Доп.точки доступа:
Zhou, J.; Xia, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhang, X.; Peng, D.; Liu, Q.