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Найдено документов в текущей БД: 82

    Nonlinear-optical up and down frequency-converting backward-wave metasensors and metamirrors
/ A. K. Popov [et al.] // Proceedings of SPIE - The International Society for Optical Engineering. - 2013. - Vol. 8725. - Ст. 87252E. - P. , DOI 10.1117/12.2015637 . - ISSN 0277-786X
Аннотация: A concept of a family of unique backward-wave photonic devices, such as frequency up and down converting nonlinear-optical mirrors, sensors, modulators, filters and amplifiers is proposed. Novel materials are considered, which support coexistence of ordinary and backward waves and thus enable enhanced nonlinear-optical frequency-conversion processes. Particular properties of short-pulse regime are investigated. В© 2013 SPIE.

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Доп.точки доступа:
Popov, A. K.; Попов, Александр Кузьмич; Nefedov, I. S.; Myslivets, S. A.; Мысливец, Сергей Александрович; Shalaev, M. I.; Slabko, V. V.; Слабко, Виталий Васильевич; Micro- and Nanotechnology Sensors, Systems, and Applications, Conference(5 ; Baltimore, MD)(29 April 2013 - 3 May 2013)

    Infrared absorption investigation of the role of octahedral groups upon the phase transition in the Rb2KMoO3F3 crystal
/ Y. V. Gerasimova [et al.] // Phys. Solid State. - 2013. - Vol. 55, Is. 11. - P. 2331-2334, DOI 10.1134/S1063783413110097. - Cited References: 10. - This study was supported by the Russian Foundation for Basic Research (project no. 12-02-31205_mol_a), the Ministry of Education and Science of the Russian Federation within the framework of the Russian Federal Target Program "Scientific and Scientific-Pedagogical Human Resources for the Innovative Russia" (agreement no. 8379), and the Interdisciplinary Integration Project of the Siberian Branch of the Russian Academy of Science No. 28. . - ISSN 1063-7834
РУБ Physics, Condensed Matter

Аннотация: The infrared absorption spectra of the oxyfluoride Rb2KMoO3F3 have been measured in the frequency range corresponding to stretching vibrations of the Mo-O anion octahedron with the purpose of clarifying their role in the phase transition. A semi-empirical calculation of two possible configurations of quasioctahedral MoO3F3 groups has been performed. The results of the investigations have demonstrated that some octahedra in the crystal structure change the local symmetry from C (3v) to C (2v) due to the phase transition (T = 197 K).

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Держатели документа:
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Russian Acad Sci, Siberian Branch, Inst Geol & Mineral, Novosibirsk 630090, Russia

Доп.точки доступа:
Gerasimova, Y. V.; Герасимова, Юлия Валентиновна; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Vtyurin, A. N.; Втюрин, Александр Николаевич; Ivanenko, A. A.; Иваненко, Александр Анатольевич; Isaenko, L. I.; Ershov, A. E.; Ершов, Александр Евгеньевич; Pogoreltsev, E. I.; Погорельцев, Евгений Ильич; Russian Foundation for Basic Research [12-02-31205_mol_a]; Ministry of Education and Science of the Russian Federation [8379]; Interdisciplinary Integration Project of the Siberian Branch of the Russian Academy of Science [28]

    Изучение роли октаэдрических групп при фазовом переходе в кристалле Rb2KMoO3F3 методом инфракрасного поглощения
/ Ю. В. Герасимова [и др.] // Физ. тверд. тела. - 2013. - Т. 55, Вып. 11. - С. 2215-2217

Аннотация: Получены спектры инфракрасного поглощения оксифторида Rb2KMoO3F3 в области частот, соответствующих валентным колебаниям Mo-O анионного октаэдра, с целью выяснения их роли при фазовом переходе. Проведен полуэмпирический расчет двух возможных конфигураций квазиоктаэдрических групп MoO3F3. Результаты исследований показали, что при фазовом переходе (T=197 K) в структуре кристалла часть октаэдров меняет локальную симметрию с C3v на C2v.

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Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Герасимова, Юлия Валентиновна; Gerasimova, J.V.; Орешонков, Александр Сергеевич; Oreshonkov, A.S.; Втюрин, Александр Николаевич; Vtyurin, A. N.; Иваненко, Александр Анатольевич; Ivanenko, A. A.; Исаенко, Л. И.; Ершов, Александр Андреевич; Ershov, A. A.; Погорельцев, Евгений Ильич; Pogoreltsev, E. I.

    Magnetic properties and morphology of manganese ferrite nanoparticles in glasses
/ I. Edelman [et al.] // IOP Conf. Ser.: Mater. Sci. Eng. - 2011. - Vol. 25, Is. 1. - Ст. 012017, DOI 10.1088/1757-899X/25/1/012017 . -

Кл.слова (ненормированные):
Average diameter -- Borate glass -- Co-doped -- Electron magnetic resonance -- Magnetic and magneto-optical properties -- Magnetic behaviour -- Magnetic circular dichroisms -- Magnetic nanoparticles -- Magnetically ordered material -- Manganese ferrite nanoparticles -- Manganese ferrites -- Morphological characteristic -- Paramagnetic ions -- Resonance field -- Size and shape -- Static magnetization -- Temperature dependence -- Temperature dependent -- Variable temperature -- Visible and near infrared -- Alumina -- Dichroism -- Ferrite -- Glass -- Iron oxides -- Magnetic properties -- Magnetic resonance -- Magnetocrystalline anisotropy -- Manganese -- Manganese oxide -- Nanoparticles -- Paramagnetism -- Silicates -- Spectroscopy -- Nanomagnetics

Аннотация: Static magnetization (SM), magnetic circular dichroism (MCD) and electron magnetic resonance (EMR) studies are reported of borate glasses 22.5 K 2O-22.5 Al 2O 3-55 B 2O 3 co-doped with iron and manganese oxides. In as-prepared glasses the paramagnetic ions usually are in diluted state; however, if the ratio of the iron and manganese oxides in the charge is 3/2, magnetic nanoparticles are found already in as-prepared glass. After additional thermal treatment all glasses show magnetic behaviour, MCD and EMR due to the presence of magnetic nanoparticles with characteristics close to those of manganese ferrite. By computer simulating the EMR spectra at variable temperatures, their morphological characteristics are deduced: relatively broad size and shape distribution with average diameter of ca. 3-4 nm. The characteristic temperature-dependent shift of the apparent resonance field is explained by a strong temperature dependence of the magnetocrystalline anisotropy in the nanoparticles. The potassium-alumina-borate glasses containing magnetic nanoparticles represent a novel class of materials: "transparent magnets". Indeed, they remain transparent in a part of visible and near infrared spectral range while showing magnetic and magneto-optical properties characteristic of magnetically ordered materials.

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Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна; Artemenko, A.; Curely, J.; Kliava, J.; Zaikovskiy, V. I.; Stepanov, S.; Baltic Conference on Silicate Materials(5 ; 2011 ; May ; 23-25 ; Riga, Latvia)

    Применение оптоэлектронных устройств для наблюдения доменных структур в ферромагнитных материалах
/ А. В. Чжан [и др.] // Изв. вузов. Приборостроение. - 2012. - T. 55, № 12. - С. 30-32. - Работа выполнена при поддержке гранта РФФИ №11–0200695-А . - ISSN 0021-3454
   Перевод заглавия: Application of optoelectronic devices for observation of domain structures in ferromagnetic materials
Аннотация: Показана возможность использования устройств, снабженных приборами с зарядовой связью, для определения магнитных характеристик ферромагнитных материалов.
The possibility of the use of domain structures for determination of magnetic characteristics of ferromagnetic materials is demonstrated.

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Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Чжан, Анатолий Владимирович; Chzhan, A. V.; Задворный, А. Г.; Середкин, Виталий Александрович; Seredkin V.A.; Патрин, Геннадий Семёнович; Patrin G.S.

    Evans hole in internal modes IR spectrum of WO3F33-ions in (NH4)(3)WO3F3 crystal
/ J. V. Gerasimova, A. N. Vtyurin // Chem. Phys. Lett. - 2012. - Vol. 523. - P. 144-147, DOI 10.1016/j.cplett.2011.12.041. - Cited References: 11. - We would like to thank Prof. E. M. Aver'yanov for discussion, and V. A. Ouskin for the technical assistance. This work has been supported by the Russian Foundation for Basic Researches, Grant No. 11-02-98002-r_sibir_a. . - ISSN 0009-2614
РУБ Chemistry, Physical + Physics, Atomic, Molecular & Chemical

Аннотация: Infrared absorption of (NH4)(3)WO3F3 compound has been studied. Profile of asymmetric band in 600-1000 cm (1) range associated with polar W-O vibrations of WO3F33- ions is explicable on the basis of multi-oscillatory dynamics with account of damping. Complex profile with Evans holes proves that internal modes of WO3F33- anions in the fluorine-oxygen octahedron interact due to the effects of the local field. (C) 2011 Elsevier B. V. All rights reserved.

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Держатели документа:
[Gerasimova, Ju V.
Vtyurin, A. N.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Vtyurin, A. N.; Втюрин, Александр Николаевич; Герасимова, Юлия Валентиновна

    Numerical simulations of metamaterial-based infrared sensor for remote environmental monitoring
/ A. K. Popov, S. A. Myslivets ; , Conference code: 102606) // Opt.InfoBase Conf. Papers. - 2011. - Conference code: 102606. . - ISBN 21622701. - ISBN 9781557529145

Аннотация: The possibility of creation of all-optically controlled, remotely actuated and interrogated, ultraminiature nonlinear-optical sensor, which utilizes negative-index metamaterial and can be exploited for the remote environmental sensing is shown and numerically simulated. © 2011 Optical Society of America.

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Доп.точки доступа:
Myslivets, S. A.; Мысливец, Сергей Александрович; Попов, Александр Кузьмич; Computational Optical Sensing and Imaging (2011 ; Jul. ; 10-14 ; Toronto)

    Numerical simulations of metamaterial-based infrared sensor for remote environmental monitoring
/ A. K. Popov, S. A. Myslivets ; Fourier Transform Spectroscopy (10 July - 14 July 2011 ; Toronto) // Opt.InfoBase Conf. Papers. - 2011. - Conference code: 102614. . - ISBN 21622701. - ISBN 9781557529145

Аннотация: The possibility of creation of all-optically controlled, remotely actuated and interrogated, ultraminiature nonlinear-optical sensor, which utilizes negative-index metamaterial and can be exploited for the remote environmental sensing is shown and numerically simulated. © 2011 Optical Society of America.

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Доп.точки доступа:
Myslivets, S. A.; Мысливец, Сергей Александрович; Fourier Transform Spectroscopy(2011 ; Jul. ; 10-14 ; Toronto)

    Numerical simulations of metamaterial-based infrared sensor for remote environmental monitoring [3]
/ A. K. Popov, S. A. Myslivets // Opt.InfoBase Conf. Papers. - 2011. - Conference code: 102597. . - ISBN 2162-2701. - ISBN 9781557529145

Аннотация: The possibility of creation of all-optically controlled, remotely actuated and interrogated, ultraminiature nonlinear-optical sensor, which utilizes negative-index metamaterial and can be exploited for the remote environmental sensing is shown and numerically simulated. © 2011 Optical Society of America.

Scopus


Доп.точки доступа:
Myslivets, S. A.; Мысливец, Сергей Александрович; Applied Industrial Optics: Spectroscopy, Imaging and Metrology (2011 ; Jul. ; 10-14 ; Toronto)

    The 5-(isopropylidene)-2-thiobarbituric acid: Preparation, crystal structure, thermal stability and IR-characterization
/ N. N. Golovnev [et al.] // J. Mol. Struct. - 2014. - Vol. 1068. - P. 216-221, DOI 10.1016/j.molstruc.2014.04.024. - Cited References: 30. - V.V.A. is grateful to the Ministry of Education and Science of Russian Federation for the financial support of the investigation. . - ISSN 0022-2860. - ISSN 1872-8014
   Перевод заглавия: 5-(изопропилиден)-2-тиобарбитуровая кислота: Синтез, кристаллическая структура, термическая стабильность и ИК характеризация
РУБ Chemistry, Physical

Аннотация: 5-(Isopropylidene)-2-thiobarbituric acid (1), C7H8N2O2S, has been crystallized by reacting 2-thiobarbituric acid with excessing acetone for 5–6 days under ambient conditions. The pale yellow crystals have been investigated using X-ray single crystal and powder techniques and characterized by differential scanning calorimetry, thermogravimetry and infrared spectroscopy. The compound crystallizes in the monoclinic system with a = 8.8268(19) Å, b = 12.044(3) Å, c = 8.0998(19) Å, β = 105.388(6)°, Z = 4, V = 830.2(3) Å3, space group P21/c. The geometric parameters of the heterocycle of the molecule 1 are similar to those found previously for the molecule of thionedicarbonyl tautomer in polymorphic modifications of 2-thiobarbituric acid. Infrared spectroscopy also evidences the thionedicarbonyl structure of the 1 heterocyclic ring. Intermolecular NH⋯O hydrogen bonds join the molecules in the chains along b axis. The 1 compound is thermally stable up to 230.0 °С and melts with decomposition at 261.4 °C. The results of mass spectrometric analysis are consistent with the structural parameters found by X-ray diffraction methods.

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Держатели документа:
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Kirensky Inst Phys SB RAS, Krasnoyarsk 660036, Russia
Krasnoyarsk Sci Ctr SD RAS, Krasnoyarsk 660036, Russia
Russian Acad Sci, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia

Доп.точки доступа:
Golovnev, N. N.; Головнёв, Николай Николаевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Tarasova, L. S.; Atuchin, V. V.; Vladimirova, N. I.

    Infrared absorption spectrum of HoFe3(BO3)4 crystal
/ S. N. Sofronova [et al.] // Vib. Spectrosc. - 2014. - Vol. 72. - P. 20-25, DOI 10.1016/j.vibspec.2014.02.005. - Cited References: 18. - The work was partially supported by the RFBR through Grants No. 13-02-00825 and 13-02-98041, SS-4828.2012.2. . - ISSN 0924-2031. - ISSN 1873-3697
РУБ Chemistry, Analytical + Chemistry, Physical + Spectroscopy
Рубрики:
MAGNETOELASTIC INTERACTIONS
   IRON

   GDFE3(BO3)4

Кл.слова (ненормированные):
Holmium ferroborate -- Infrared absorption

Аннотация: Infrared (IR) absorption spectra of HoFe3(BO3)4 crystal have been obtained in spectral range 30–7000 cm−1 at temperatures from 4 to 423 K. Vibrational frequencies have been simulated with ‘Lady’ software package both for high-temperature and low-temperature phases. The experimental spectra have been analyzed on the basis of calculated data, and interpreted within the framework of internal vibrations of ionic complexes of HoFe3(BO3)4 crystal lattice. The spectral range under study was observed to have no Davydov splitting of internal vibrational modes due to unit cell multiplication. No effects of magnetic ordering on the IR spectra of the crystal under study were observed in the low-temperature range.

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Держатели документа:
Kirensky Inst Phys SB RAS, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660079, Russia

Доп.точки доступа:
Sofronova, S. N.; Софронова, Светлана Николаевна; Gerasimova, Y. V.; Герасимова, Юлия Валентиновна; Vtyurin, A. N.; Втюрин, Александр Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Shestakov, N. P.; Шестаков, Николай Петрович; Ivanenko, A. A.; Иваненко, Александр Анатольевич; RFBR [13-02-00825, 13-02-98041, SS-4828.2012.2]

    Remote sensing with nonlinear negative-index metamaterials
/ A. K. Popov, S. A. Myslivets // Proceedings of SPIE - The International Society for Optical Engineering. - 2014. - Vol. 9157. - Ст. 91573B, DOI 10.1117/12.2059728. - Cited References: 15. - This work was supported in parts by the Air Force Office of Scientific Research (Grant No FA950-12-1-298), by the National Science Foundation (Grant No ECCS-1346547) and by the Presidium of the Siberian Branch of the Russian Academy of Sciences (Grants No. 43 and No. 101). . - ISSN 978-16284. - ISSN 0277-786X
РУБ Optics + Physics, Applied

Аннотация: A concept of the remotely actuated and interrogated four-wave mixing photonic sensor, which employs the negative-index photonic materials, is described. Unique electromagnetic properties of such a metamaterial enable enhancement of frequency conversion and redirection of the signals which carry important information for environmental probing. Four-wave mixing process allows for independent engineering of resonantly enhanced optical nonlinearities and negative refractive index. © 2014 SPIE.

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Доп.точки доступа:
Myslivets, S. A.; Мысливец, Сергей Александрович; International Conference on Optical Fibre Sensors (23 ; 2014 ; Jun. ; 2 - 6 ; Santander, Spain); International conference on optical fibre sensors(23 ; 2014 ; Jun. ; 2-6 ; Santander, Spain)

    Near-infrared luminescence and color tunable chromophores based on Cr3+-Doped Mullite-Type Bi2(Ga,Al)4O9 solid solutions
/ C. Liu [et al.] // Inorg. Chem. - 2015. - Vol. 54, Is. 4. - P. 1876-1882, DOI 10.1021/ic502779d. - Cited References: 26. - The present work was supported by the National Natural Science Foundations of China (Grants 51002146, 51272242), Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), Beijing Youth Excellent Talent Program (YETP0635), the Funds of the State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University (KF201306), and Fundamental Research Funds for the Central Universities (FRF-TP-14-005A1). . - ISSN 0020-1669
   Перевод заглавия: Ближняя инфракрасная люминесценция и перестраиваемые цвет хромофоры построенные на допированных Cr3+ твердых растворах Bi2(Ga,Al)4O9 со структурой муллита.
РУБ Chemistry, Inorganic & Nuclear

Аннотация: Cr3+-activated mullite-type Bi2Ga(4-x)AlxO9 (x = 0, 1, 2, 3, and 4) solid solutions were prepared by the solid state reaction, and their spectroscopic properties were investigated in conjunction with the structural evolution. Under excitation at 610 nm, Bi2[Ga(4-y)Aly]3.97O9:0.03Cr3+ (y = 0, 1, 2, 3, and 4) phosphors exhibited broad-band near-infrared (NIR) emission peaking at ?710 nm in the range 650?850 nm, and the optimum Cr3+ concentrations and concentration quenching mechanism were determined. Except for the interesting NIR emission, the body color changed from white (at x = 0) to green (at x = 0.08) for Bi2Ga4?xO9:xCr3+, and from light yellow (at x = 0) to deep brown (at x = 0.08) for Bi2Al4?xO9:xCr3+, respectively. Moreover, as a result of variable Al/Ga ratio, the observed body color for Bi2[Ga(4-y)Aly]3.97O9:0.03Cr3+ (y = 0, 1, 2, 3, and 4) varied from deep brown to green. The relationship between the observed colors and their diffuse reflectance spectra were also studied for the understanding of the different absorption bands. The results indicated that Cr3+-doped Bi2Ga(4-x)AlxO9 solid solutions appeared as the bifunctional materials with NIR phosphors and color-tunable pigments.

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Держатели документа:
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China.
China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China.
RAS, SB, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.

Доп.точки доступа:
Liu, C.; Xia, Zhiguo; Chen, M.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Liu, Q.

    Chemical visualization of asphaltenes aggregation processes studied in situ with ATR-FTIR spectroscopic imaging and NMR imaging
/ A. A. Gabrienko [et al.] // J. Phys. Chem. C. - 2015. - Vol. 119, Is. 5. - P. 2646-2660, DOI 10.1021/jp511891f. - Cited References:78. - This research was performed under the UNIHEAT project. The authors wish to acknowledge the Skolkovo Foundation and BP for financial support. The authors thank BP for providing samples of crude oil . - ISSN 1932-7447
РУБ Chemistry, Physical + Nanoscience & Nanotechnology + Materials Science, Multidisciplinary

Аннотация: Crude oil phase behavior and asphaltene precipitation have been studied by two complementary chemical imaging methods for the first time. ATR-FTIR spectroscopic imaging approach has revealed the chemical composition of agglomerated and precipitated asphaltenes upon dilution with a flocculant. Asphaltenes, containing oxygen and nitrogen heteroatomic functional groups, have been detected to be least stable. Aromatic abundant asphaltenes have been observed to have relatively high solubility in crude oil/heptane blends. NMR imaging approach, capable of imaging in the bulk of crude oil samples, has demonstrated that n-heptane causes aggregation which can lead to the stable suspension or to the sedimentation followed by the formation of deposits, depending on flocculant concentration. These processes have been monitored for small and large amounts of heptane added to crude oil. The data obtained by ATR-FTIR spectroscopic imaging and NMR imaging have been correlated to propose a possible link between the chemical structure of asphaltenes and a mechanism of the formation of deposits.

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Держатели документа:
Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn, London SW7 2AZ, England.
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia.
Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
UNICAT Ltd, Novosibirsk 630090, Russia.
BP Prod North Amer Inc, Refining & Logist Technol, Naperville, IL 60563 USA.
Novosibirsk State Univ, Novosibirsk 630090, Russia.

Доп.точки доступа:
Gabrienko, A. A.; Morozov, E. V.; Морозов, Евгений Владимирович; Subramani, V.; Martyanov, O. N.; Kazarian, S. G.; Skolkovo Foundation; BP

    The cis-trans isomer transformation, spectroscopic and thermal properties of Li, Na, K 1,3-diethyl-2-thiobarbiturate complexes
/ N. N. Golovnev [et al.] // Polyhedron. - 2015. - Vol. 85. - P. 493-498, DOI 10.1016/j.poly.2014.09.011. - Cited References:42. - The study has been carried out within the public task of the Ministry ofEducation and Science of the Russian Federation for research engineeringat the Siberian Federal University in 2014. V.V.A. is partly supportedby the Ministry of Education and Science of the Russian Federation. . - ISSN 0277-5387
   Перевод заглавия: Трансформация цис-транс изомеров, спектроскопические и термические свойства Li, Na, K 1,3-диэтил-2-тиобарбитуратных комплексов
РУБ Chemistry, Inorganic & Nuclear + Crystallography

Аннотация: Three new complexes of 1,3-diethyl-2-thiobarbituric acid (C8H11N2O2S, HDETBA) with Li+, Na+, K+ alkali ions were synthesized. The complexes have been prepared by neutralization of 1,3-diethyl-2-thiobarbituric acid with the corresponding metal hydroxide in aqueous solution. The colorless crystals have been investigated using X-ray single crystal and powder techniques and characterized by differential scanning calorimetry, thermogravimetry and infrared spectroscopy. The compounds of MDETBA with M = Li and M = Na crystallize in the monoclinic lattice with a = 10.678(1) Å, b = 7.2687(9) Å, c = 13.202(2) Å, β = 108.841(2)°, Z = 4, V = 969.8(2) Å3, S.G. P21/n and a = 10.534(2) Å, b = 7.604(1) Å, c = 14.186(1) Å, β = 108.964(4)°, Z = 4, V = 1074.6(3) Å3, S.G. P21/n, respectively. Сompound KDETBA crystallizes in the orthorhombic lattice with a = 4.2541(6) Å, b = 14.739(2) Å, c = 16.635(3) Å, Z = 4, V = 1043.1(3) Å3, S.G. P212121. In Li(I) and Na(I) complexes, the DETBA− ion is in cis-configuration and, in the K(I) complex, this ion is in trans-configuration. The reason for the transformation from cis- to trans-configuration has been rationalized.

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Держатели документа:
Siberian Fed Univ, Dept Chem, Krasnoyarsk 660041, Russia
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia
SB RAS, Inst Chem & Chem Technol, Lab Catalyt Convers Small Mol, Krasnoyarsk 660036, Russia
SB RAS, Irkutsk Favorsky Inst Chem, Phys Chem Lab, Irkutsk 664033, Russia
Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia

Доп.точки доступа:
Golovnev, N. N.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Vereshchagin, Sergey N.; Sterkhova, I. V.; Atuchin, V. V.; Ministry of Education and Science of the Russian Federation

    Synthesis, crystal structure, and enhanced luminescence of garnet-type Ca3Ga2Ge3O12:Cr3+ by codoping Bi3+
/ C. Y. Liu [et al.] // J. Am. Ceram. Soc. - 2015. - Vol. 98, Is. 6. - P. 1870-1876, DOI 10.1111/jace.13553. - Cited References:24. - This work was supported by the National Natural Science Foundations of China (grant nos. 51002146, 51272242), Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), Beijing Youth Excellent Talent Program (YETP0635), the Funds of the State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University (KF201306) and Fundamental Research Funds for the Central Universities (FRF-TP-14-005A1). . - ISSN 0002. - ISSN 1551-2916
   Перевод заглавия: Синтез, кристаллическая структура и улучшенная люминесценция граната Ca3Ga2Ge3O12:Cr3+ содопированного Bi3+
РУБ Materials Science, Ceramics

Аннотация: Garnet-type compound Ca3Ga2Ge3O12 and Cr3+-doped or Cr3+/Bi3+ codped Ca3Ga2Ge3O12 phosphors were prepared by a solid-state reaction. The crystal structure of Ca3Ga2Ge3O12 host was studied by X-ray diffraction (XRD) analysis and further determined by the Rietveld refinement. Near-infrared (NIR) photoluminescence (PL) and long-lasting phosphorescence (LLP) emission can be observed from the Cr3+-doped Ca3Ga2Ge3O12 sample, and the enhanced NIR PL emission intensity and LLP decay time can be realized in Cr3+/Bi3+ codped samples. The optimum concentration of Cr3+ in Ca3Ga2Ge3O12 phosphor was about 6 mol%, and optimum Bi3+ concentration induced the energy-transfer (ET) process between Bi3+ and Cr3+ ions was about 30 mol%. Under different excitation wavelength from 280 to 453 nm, all the samples exhibit a broadband emission peaking at 739 nm and the intensity of NIR emission increases owing to the ET behavior from Bi3+ to Cr3+ ions. The critical ET distance has been calculated by the concentration-quenching method. The thermally stable luminescence properties were also studied and the introduction of Bi3+ can also improve the thermal stability of the NIR emission.

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Держатели документа:
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China.
China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China.
SB RAS, LV Kirensky Phys Inst, Lab Crystal Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Liu, Chengyin; Xia, Zhiguo; Molokeev, M. S.; Молокеев, Максим Сергеевич; Liu, Quanlin

    Infrared absorption spectra of a Nd0.5Ho0.5Fe3(BO3)4 crystal
/ Y. V. Gerasimova [et al.] // Phys. Solid State. - 2016. - Vol. 58, Is. 1. - P. 155-159, DOI 10.1134/S106378341601011X. - Cited References: 15. - This study was supported in part by the Russian Foundation for Basic Research (project no. 12-02-00825). . - ISSN 1063-7834
РУБ Physics, Condensed Matter
Рубрики:
HoFe3(BO3)4

Аннотация: Infrared absorption spectra of a Nd0.5Ho0.5Fe3(BO3)4 crystal in the spectral range of 30–1700 cm–1 have been measured at temperatures from 6 to 300 K. The experimental spectra have been analyzed based on the semiempirical calculation of the lattice dynamics and the analysis of correlation diagrams of borate complexes. No changes associated with structural phase transitions have been detected in the temperature range of measurements; the effect of magnetic ordering on the infrared absorption spectra has not been observed.

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Доп.точки доступа:
Gerasimova, Y. V.; Герасимова, Юлия Валентиновна; Sofronova, S. N.; Софронова, Светлана Николаевна; Gudim, I. A.; Гудим, Ирина Анатольевна; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Vtyurin, A. N.; Втюрин, Александр Николаевич; Ivanenko, A. A.; Иваненко, Александр Анатольевич

    Bi2(Sn0.95Cr0.05)2O7: Structure, IR spectra, and dielectric properties
/ S. S. Aplesnin [et al.] // Ceram. Int. - 2016. - Vol. 42, Is. 4. - P. 5177-5183, DOI 10.1016/j.ceramint.2015.12.040. - Cited References: 45. - This work was supported by the Russian Foundation for Basic Research Projects no. 15-42-04099 r_siberia_a, Siberian Branch of Science and NAS of Belarus “Electronic and magnetic phase transitions in materials with magnetoelectric affect” and government work no. 114090470016. . - ISSN 0272-8842
РУБ Materials Science, Ceramics

Аннотация: Infrared absorption spectra of the bismuth pyrostannate Bi2(Sn0.95Cr0.05)2O7 were investigated in the frequency range 350-1100 cm-1 at temperatures of 110-525 K. Four frequency regions with split absorption lines are distinguished. Softening of frequencies at the structural transitions was observed. The maxima of permittivity measured in the frequency range 1-200 kHz at temperatures 100-400 K were determined. It was found that the magnetic susceptibility changes its sign in the low-temperature region. The correlation between anomalies in the magnetic susceptibility, permittivity, and absorption line intensity was established. Softening of frequencies is explained by the variation in the coefficient of thermal expansion of the lattice. The temperature behavior of permittivity is described using the Debye model. © 2015 Elsevier Ltd and Techna Group S.r.l.

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Держатели документа:
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Akademgorodok 50, Krasnoyarsk, Russian Federation
Siberian State Aerospace University, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Aplesnin, S. S.; Аплеснин, Сергей Степанович; Udod, L. V.; Удод, Любовь Викторовна; Sitnikov, M. N.; Shestakov, N. P.; Шестаков, Николай Петрович

    First outer-sphere 1,3-diethyl-2-thiobarbituric compounds [M(H2O)6](1,3-diethyl-2-thiobarbiturate)2·2H2O (M = Co2+, Ni2+): Crystal structure, spectroscopic and thermal properties
/ N. N. Golovnev [et al.] // Chem. Phys. Lett. - 2016. - Vol. 653. - P. 54-59, DOI 10.1016/j.cplett.2016.04.059. - Cited References: 50. - The study was carried out within the public task of the Ministry of Education and Science of the Russian Federation for research engineering of the Siberian Federal University in 2015-2016. V.V. A. is grateful to the Ministry of Education and Science of the Russian Federation for the financial support of the investigation. X-ray data were obtained with use the analytical equipment of Krasnoyarsk Center of collective use of SB RAS. . - ISSN 0009-2614
   Перевод заглавия: Первые соединения с внешнесферным 1,3-диэтил-2-тиобарбитуратом [M(H2O)6](1,3-диэтил-2-2тиобарбитурат)2·2H2O (M=Co2+, Ni2+): кристаллическая структура, спектроскопия и тепловые свойства
РУБ Chemistry, Physical + Physics, Atomic, Molecular & Chemical

Аннотация: Two new d-element compounds, [Co(H2O)6](Detba)2·2H2O (1) and [Ni(H2O)6](Detba)2·2H2O (2) (HDetba - 1,3-diethyl-2-thiobarbituric acid) were synthesized and characterized by single-crystal and powder X-ray diffraction analysis, TG-DSC and FT-IR. Structural analysis revealed that (1) and (2) are discrete structures, in which M2+ ion (M = Co, Ni) is six-coordinated by water molecules and it forms an octahedron. The outer-sphere Detba- ions and H2O molecules participate in O-H?(O/S) intermolecular hydrogen bonds which form the 2D layer. Thermal decomposition includes the stage of dehydration and the following stage of oxidation of Detba- with a release of CO2, SO2, H2O, NH3 and isocyanate gases. © 2016 Elsevier B.V. All rights reserved.

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Держатели документа:
Department of Chemistry, Siberian Federal University, 79 Svobodny Aven., Krasnoyarsk, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, bld. 38, Akademgorodok 50, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, 47 Seryshev Str., Khabarovsk, Russian Federation
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, 13 Lavrentiev Aven., Novosibirsk, Russian Federation
Functional Electronics Laboratory, Tomsk State University, 36 Lenin Aven., Tomsk, Russian Federation
Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, 2 Pirogov Str., Novosibirsk, Russian Federation

Доп.точки доступа:
Golovnev, N. N.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Lesnikov, M. K.; Atuchin, V. V.

    Structural heterogeneity of diamond-containing detonation material
/ A. . Korets, A. . Krylov, E. . Mironov // Eur. Phys. J. - Appl. Phys. - 2010. - Vol. 52, Is. 1. - P. 10901-10905, DOI 10.1051/epjap/2010126. - Cited References: 17 . - ISSN 1286-0042
РУБ Physics, Applied

Аннотация: Diamond-containing material (DCM) synthesized by detonation was separated into fractions. Raman and infrared spectra and X-ray diffraction patterns of the individual fractions were measured. The particles of this material were characterized by the variable ratio of the diamond (sp(3)) and non-diamond components. The distribution of sp(3)-grains in the particles was of complicated character. The fine DCM particles contained an insignificant amount of diamond. The influence of density fluctuations on the DCM formation is discussed.

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Держатели документа:
[Korets, A.] Siberian Fed Univ, Krasnoyarsk 660074, Russia
[Krylov, A.] SB RAS, Inst Phys, Krasnoyarsk 660036, Russia
[Mironov, E.] Filial Irkutsk State Univ Railway Engn, Krasnoyarsk Inst Railway Transport, Krasnoyarsk 660028, Russia
ИФ СО РАН
Siberian Federal University, 26 Kirensky str., 660074 Krasnoyarsk, Russian Federation
Institute of Physics, SB RAS, 660036 Krasnoyarsk, Russian Federation
Krasnoyarsk Institute of Railway Transport, Filial of Irkutsk State University of Railway Engineering, 89, L. Ketskhoveli str., 660028 Krasnoyarsk, Russian Federation

Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Mironov, E.