Труды сотрудников института физики

/ G. V. Bondarenko [et al.] // J. Magn. Magn. Mater. - 2013. - Vol. 335. - P. 90-96, DOI 10.1016/j.jmmm.2013.01.037. - Cited References: 35 . - ISSN 0304-8853
Аннотация: The method for investigation of the uniaxial and hexagonal anisotropies in weakly ferromagnetic rhombohedral FeBO3 crystals with the Fe2þ magnetic impurity with the use of the single-ion and pair approximation has been developed. In the framework of this method, a quantitative discrepancy between theoretical and experimental data on a uniaxial field has been eliminated. The energy contributions to the hexagonal anisotropy that are caused by the Dzyaloshinsky–Moriya interaction, the crystal field of Fe3þ ions and the temperature dependence of this anisotropy were analytically treated. The experimental temperature dependence of the hexagonal anisotropy of FeBO3 crystals is explained. It is shown that the compensation point and the typical temperature dependence of the hexagonal anisotropy result from the competition of the contributions of Fe3þ and Fe2þ ions. It is shown that respective considerable contributions to the anisotropy of Fe3þ and Fe2þ ions are made by the cubic symmetry and the uniaxial symmetry of the exchange ‘‘single-ion’’ type. The anisotropy constants for FeBO3 crystal was obtained by using the described results. It was shown, that for the calcite type structure crystals (iron borate and manganese carbonate) with S-state ions, the single ion and pair models (which previously raised doubts in their validity and accuracy) describe the experimental data good enough.

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Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Bondarenko, G. V.; Бондаренко, Геннадий Васильевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Rudenko, V. V.; Руденко, Валерий Васильевич; Sosnin, V. M.; Соснин, Виктор Михайлович; Tugarinov, V. I.; Тугаринов, Василий Иванович; Vorotynov, A. M.; Воротынов, Александр Михайлович

/ V. V. Atuchin [et al.] // J. Phys. Chem. C. - 2012. - Vol. 116, Is. 18. - P. 10162-10170, DOI 10.1021/jp302020f. - Cited References: 64. - We thank Dr. A.M. Ziatdinov for the electron paramagnetic resonance measurements. This study was partly supported by SB RAS (Grant 28). . - ISSN 1932-7447РУБ Chemistry, Physical + Nanoscience & Nanotechnology + Materials Science, Multidisciplinary

Аннотация: A powder sample of CsMnMoO3F3 oxyfluoride has been prepared by solid state synthesis. The pyrochlore-related crystal structure of CsMnMoO3F3 has been refined by the Rietveld method at T = 298 K (space group Fd-3m, a = 10.59141(4) angstrom, V = 1188.123(8) angstrom(3); R-B = 3.44%). The stability of the cubic phase has been obtained over the temperature range T = 110-293 K by heat capacity measurements. Magnetic properties have been measured over the range of T = 2-300 K. The electronic structure of CsMnMoO3F3 has been evaluated by X-ray photoelectron spectroscopy. Chemical bonding effects have been discussed for all metal ions using binding energy difference parameters and wide comparison with related oxides and fluorides. The competition between O-2(-) and F- ions for metal valence electrons has been found.

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Держатели документа:
Atuchin, Victor V.
Gavrilova, Tatyana A.
Kesler, Valery G.] SB RAS, Inst Semicond Phys, Novosibirsk 630090, Russia
Molokeev, Maxim S.
Yurkin, Gleb Yu.
Flerov, Igor N.
Patrin, Gennadii S.] SB RAS, Inst Phys, Krasnoyarsk 660036, Russia
Laptash, Natalia M.] FEB RAS, Inst Chem, Vladivostok 690022, Russia
Flerov, Igor N.
Patrin, Gennadii S.] Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660074, Russia

Доп.точки доступа:
Atuchin, V. V.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Yurkin, G. Yu.; Юркин, Глеб Юрьевич; Gavrilova, T. A.; Kesler, V. G.; Laptash, N. M.; Flerov, I. N.; Флёров, Игорь Николаевич; Patrin, G. S.; Патрин, Геннадий Семёнович

/ G. X. Cao [et al.] // Phys. Rev. Lett. - 2012. - Vol. 108, Is. 23. - Ст. 236401, DOI 10.1103/PhysRevLett.108.236401. - Cited References: 41. - We thank H. Habermeier, D. Mandrus, B. C. Sales, I. Eremin, I. I. Mazin, and P. J. Hirschfeld for useful discussions. G. Cao acknowledges support from NSFC (No. 10804068, 10774097). M. M. K. acknowledges support from RFBR (Grant No. 09-02-00127), Presisium of RAS program "Quantum physics of condensed matter" N5.7, Integration Grant of SBRAS-UrBRAS N40, and Russian FCP (GK 16.740.12.0731), and The Dynasty Foundation and ICFPM. Work at ORNL was supported by the Department of Energy, BES, Materials Science and Engineering Division. . - ISSN 0031-9007РУБ Physics, Multidisciplinary

Аннотация: We report electronic transport measurements on high quality floating zone grown NaxCoO2 and Na0.41CoO2·0.6H2O single crystals. We find an in-plane electronic scattering minimum near 11 K and a clear charge ordering at approximately 50 K. The electronic and magnetic properties in hydrated and nonhydrated Na0.41CoO2 samples are similar at higher temperature, but evolve in markedly different ways below ∼50 K, where a strong ferromagnetic tendency is observed in the hydrated sample. Model calculations show the relationship of this tendency to the structure of the Fermi surface. The results, particularly the clear differences between the hydrated and nonhydrated material show a substantially enhanced ferromagnetic tendency upon hydration. Implications for superconductivity are discussed.

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Держатели документа:
[Cao, Guixin
Gao, Yuze
Le Tacon, Mathieu
Lin, Chengtian] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany
[Cao, Guixin] Shanghai Univ, Dept Phys, Shanghai 200444, Peoples R China
[Cao, Guixin] Univ Tennessee, Dept Mat Sci & Engn, Knoxville, TN 37996 USA
[Korshunov, Maxim M.] Univ Florida, Dept Phys, Gainesville, FL 32611 USA
[Korshunov, Maxim M.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Korshunov, Maxim M.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Singh, David J.] Oak Ridge Natl Lab, Div Mat Sci & Technol, Oak Ridge, TN 37831 USA

Доп.точки доступа:
Cao, G. X.; Korshunov, M. M.; Коршунов, Максим Михайлович; Gao, Y. Z.; Le Tacon, M.; Singh, D. J.; Lin, C. T.

/ V. A. Dudnikov [et al.] // J. Exp. Theor. Phys. - 2012. - Vol. 114, Is. 5. - P. 841-849, DOI 10.1134/S106377611203003X. - Cited References: 28. - This work was supported by the Ural Branch of the Russian Academy of Sciences and Siberian Branch of the Russian Academy of Sciences (project no. 40), the Russian Foundation for Basic Research (project nos. 09-02-00171-a, 10-02-00251), program 2.3 of the Department of Physical Sciences of Russian Academy of Sciences, and Nonprofit Dinastiya Foundation. . - ISSN 1063-7761РУБ Physics, Multidisciplinary

Аннотация: The temperature dependence of the static magnetization of polycrystalline rare-earth cobaltite GdCoO3 is measured in the temperature range 2-800 K. The magnetic behaviors of GdCoO3 and Gd3+ are found to be different at temperatures above room temperature, which is caused by the appearance of a contribution from Co3+ ions at high temperatures. The temperature dependence of the magnetic susceptibility of GdCoO3 is determined by the magnetization of rare-earth gadolinium ions and the additional paramagnetic contribution induced by the thermally excited magnetic terms of Co3+ ions. The LDA + GTB method is used to calculate the electronic structure of GdCoO3 in the temperature range 0-300 K with allowance for strong electron correlations. The energy spectrum of GdCoO3 is found to have intragap states that decrease the dielectric gap width with increasing temperature.

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Держатели документа:
[Dudnikov, V. A.
Ovchinnikov, S. G.
Orlov, Yu S.
Kazak, N. V.
Patrin, G. S.
Yurkin, G. Yu] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Dudnikov, V. A.] Reshetnev Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
[Ovchinnikov, S. G.
Patrin, G. S.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Michel, C. R.] Univ Guadalajara, Guadalajara 44430, Jalisco, Mexico

Доп.точки доступа:
Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Orlov, Yu.S.; Орлов, Юрий Сергеевич; Kazak, N. V.; Казак, Наталья Валерьевна; Michel, C. R.; Patrin, G. S.; Патрин, Геннадий Семёнович; Yurkin, G.Yu.; Юркин, Глеб Юрьевич

/ A. V. Malakhovskii [et al.] // XV Int. Feofilov symp. on spectroscopy of crystals doped with rare earth and transition metal ions. - Kazan, 2013. - Ст. PI_4. - P. 112
   Перевод заглавия: Влияние f-f электронных переходов на локальные свойства в окрестности возбужденных ионов в тригональных алюмо- и ферроборатах
Аннотация: Представлены результаты изучения спектров поглощения кристаллов TbFe3(BO3)4, TmAl3(BO3)4, YbAl3(BO3)4, DyFe3(BO3)4 и Nd0.5Gd0.5Fe3(BO3)4. Показано, что геометрия локального окружения и локальные магнитные свойства могут меняться в процессе f-f электронных переходов.

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Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Gnatchenko, S. L.; Kachur, I. S.; Piryatinskaya, V. G.; Sukhachev, A. L.; Сухачев, Александр Леонидович; Sokolov, A. E.; Соколов, Алексей Эдуардович; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна; International Feofilov symposium on spectroscopy of crystals doped with rare earth and transition metal ions (15 ; 2013 ; Sept. ; 16-20 ; Казань)

/ A. L. Sukhachev [et al.] // XV Int. Feofilov symp. on spectroscopy of crystals doped with rare earth and transition metal ions. - Kazan, 2013. - P. 113
   Перевод заглавия: Магнитооптическая активность f-f переходов в тригональных алюмо- и ферроборатах
Аннотация: Представлены результаты изучения спектров поглощения и магнитного кругового дихроизма и магнитооптической активности (МОА) f-f переходов в кристаллах DyFe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4, ErAl3(BO3)4, TmAl3(BO3)4, YbAl3(BO3)4. Обнаружено, что МОА большинства переходов не следует закону Кюри-Вейсса. Это явление объяснено теоретически.

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Доп.точки доступа:
Sukhachev, A. L.; Сухачев, Александр Леонидович; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Kutsak, T. V.; Strokova, A. Yu.; Sokolov, A. E.; Соколов, Алексей Эдуардович; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна; International Feofilov symposium on spectroscopy of crystals doped with rare earth and transition metal ions(15 ; 2013 ; Sept. ; 16-20 ; Казань)

/ S. L. Gnatchenko [et al.] // XV Int. Feofilov symp. on spectroscopy of crystals doped with rare earth and transition metal ions. - Kazan, 2013. - Ст. PI_7. - P. 115

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Доп.точки доступа:
Gnatchenko, S. L.; Kachur, I. S.; Piryatinskaya, V. G.; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна; International Feofilov symposium on spectroscopy of crystals doped with rare earth and transition metal ions(15 ; 2013 ; Sept. ; 16-20 ; Казань)

/ A. D. Vasiliev [et al.] // Acta Crystallogr. C. - 2013. - Vol. 69, Pt. 12. - P. 1462–1466 ; Spec. is. Interplay of crystallogr., spectrosc. and theor. meth. for solving chem. prob., DOI 10.1107/S010827011303076X . - ISSN 0108-2701
   Перевод заглавия: Расположение ионов Rh3+ в гран-триамминтрихлоридродии из порошковых данных и в мероэдрически двойникованном кристалле гран-триамминтринитрародия
Аннотация: The rhodium complexes [RhCl3(NH3)3], (I), and [Rh(NO3)3(NH3)3], (II), are built from octa­hedral RhX3(NH3)3 units; in (I) they are isolated units, while in (II) the units are stacked in columns with partially filled sites for the Rh atoms. The octa­hedra of monoclinic crystals of (I) are linked by N-H...Cl hydrogen bonds and the Rh3+ ions are located on the mirror planes. In the trigonal crystals of (II), the discontinuous `columns` along the threefold axis are linked by N-H...O hydrogen bonds. The structure of (I) has been solved using laboratory powder diffraction data, the structure of (II) has been solved by single-crystal methods using data from a merohedrally twinned sample. Both compounds possess low solubility in water.

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Держатели документа:
Kirensky Inst Phys SB RAS, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Nikolaev Inst Inorgan Chem SB RAS, Novosibirsk 630090, Russia

Доп.точки доступа:
Vasiliev, A. D.; Васильев, Александр Дмитриевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Baidina, I. A.; Belyaev, A. V.; Vorob`eva, S. N.

/ A. V. Malakhovskii [et al.] // Chem. Phys. - 2014. - Vol. 428. - P. 137–143, DOI 10.1016/j.chemphys.2013.11.008. - Cited References: 43. - The work was supported by the Russian Foundation for Basic Researches grant 12-02-00026, by the Russian President Grants SS-1044.2012.2 and 4828.2012.2, by project No 3.9.5 PSB RAS, and by the Ministry of Education and Science of Russian Federation grant 8365 . - ISSN 0301-0104. - ISSN 1873-4421
   Перевод заглавия: Спектроскопические свойства монокристалла ErAl3(BO3)4РУБ Chemistry, Physical + Physics, Atomic, Molecular & Chemical

Аннотация: Single crystal of ErAl3(BO3)4 was grown and its structure was studied. Polarized absorption spectra of ErAl3(BO3)4 single crystal were measured in the spectral range 1670–330 nm (6000–30000 cm−1). The Judd–Ofelt spectroscopic parameters have been determined: Ω2 = 4.87 × 10−20 cm2, Ω4 = 2.49 × 10−20 cm2, Ω6 = 2.72 × 10−20 cm2. These parameters have been used to calculate the radiative transition probabilities, the multiplet luminescence branching ratios and the fluorescence life times of the manifolds. The luminescence spectra due to transitions 2H11/2 → 4I15/2 (526 nm), 4S3/2 → 4I15/2 (548 nm), 4F9/2 → 4I15/2 (662 nm), 2H11/2 → 4I13/2 + 4I9/2 → 4I15/2 (800 nm) and 4S3/2 → 4I13/2 (855 nm) were recorded in α, σ and π polarizations. The most intensive luminescence belonged to 4S3/2 → 4I15/2 transition (548 nm).
Поляризованные спектры поглощения ErAl3 (BO3) 4 монокристалла были измерены в спектральном диапазоне 1670-330 нм (6000-30000 см-1). Спектроскопические параметры Джадда-Офельта были определены как: Ω2 = 4,87 • 10-20 см2, Ω4 = 2.49 • 10-20 см2, Ω6 = 2,72 • 10-20 см2. Параметры были использованы для расчета вероятностей излучающих переходов, мультиплетные отношения люминесценции раскола и времена жизни мультиплетов. Спектры люминесценции за счет переходов 2П11 / 2 → 4I15 / 2 (526 нм), 4S3 / 2 → 4I15 / 2 (548 нм), 4F9 / 2 → 4I15 / 2 (662 нм), 2П11 / 2 → 4I13 / 2 + 4I9 / 2 → 4I15 / 2 (800 нм) и 4S3 / 2 → 4I13 / 2 (855 нм) были записаны в α, σ и π поляризации. Наиболее интенсивное свечение принадлежало переходу 4S3 / 2 → 4I15 / 2 (548 нм).

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Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Kutsak, T. V.; Куцак, Т. В.; Sukhachev, A. L.; Сухачев, Александр Леонидович; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Krylov, A. S.; Крылов, Александр Сергеевич; Gudim, Irina A.; Гудим, Ирина Анатольевна; Molokeev, M. S.; Молокеев, Максим Сергеевич

/ I. Edelman [et al.] // IOP Conf. Ser.: Mater. Sci. Eng. - 2011. - Vol. 25, Is. 1. - Ст. 012017, DOI 10.1088/1757-899X/25/1/012017 . -
Аннотация: Static magnetization (SM), magnetic circular dichroism (MCD) and electron magnetic resonance (EMR) studies are reported of borate glasses 22.5 K 2O-22.5 Al 2O 3-55 B 2O 3 co-doped with iron and manganese oxides. In as-prepared glasses the paramagnetic ions usually are in diluted state; however, if the ratio of the iron and manganese oxides in the charge is 3/2, magnetic nanoparticles are found already in as-prepared glass. After additional thermal treatment all glasses show magnetic behaviour, MCD and EMR due to the presence of magnetic nanoparticles with characteristics close to those of manganese ferrite. By computer simulating the EMR spectra at variable temperatures, their morphological characteristics are deduced: relatively broad size and shape distribution with average diameter of ca. 3-4 nm. The characteristic temperature-dependent shift of the apparent resonance field is explained by a strong temperature dependence of the magnetocrystalline anisotropy in the nanoparticles. The potassium-alumina-borate glasses containing magnetic nanoparticles represent a novel class of materials: "transparent magnets". Indeed, they remain transparent in a part of visible and near infrared spectral range while showing magnetic and magneto-optical properties characteristic of magnetically ordered materials.

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Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна; Artemenko, A.; Curely, J.; Kliava, J.; Zaikovskiy, V. I.; Stepanov, S.; Baltic Conference on Silicate Materials(5 ; 2011 ; May ; 23-25 ; Riga, Latvia)

/ A. M. Kuzmenko [et al.] // Diffusion and Defect Data Pt.B: Solid State Phenomena. - 2012. - Vol. 190. - P. 269-272, DOI 10.4028/www.scientific.net/SSP.190.269 . - ISBN 9783037854365
Аннотация: Various resonance modes were observed in the transmission spectra of rare-earth iron borates RFe 3(BO 3) 4 (R = Nd 3+, Sm 3+, Gd 3+) at the frequency range 100-600 GHz, which were attributed to collective magnetic excitations in the exchange coupled Fe- and R-subsystems, i.e. antiferromagnetic (Fe) resonance and electron transitions in the R-ions. Strong interaction of the Fe and R oscillations was revealed and theoretically analyzed taking into account feature of the R-ion ground state. Intensities of the coupled modes (contributions to magnetic permeability) strongly depend on a difference of Fe and R ions g-factors that allows defining the sign of the latter. In particular, an appreciable intensity of exchange (Nd) modes in NdFe 3(BO 3) 4 is caused by g Nd?,|| < 0 whereas in GdFe 3(BO 3) 4 with gGd ? gFe ? 2 the exchange (Gd) modes were hided due to compensation of Fe and Gd contributions. In SmFe 3(BO 3) 4, despite a negligible Sm g-factor, the Sm modes were clear observed due to their excitation via coupling with the Fe-subsystem. В© (2012) Trans Tech Publications.

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Доп.точки доступа:
Kuzmenko, A. M.; Кузьменко А.М.; Mukhin, A. A.; Ivanov, V.Yu.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Moscow International Symposium on Magnetism(5 ; 2011 ; Aug. ; 21-25 ; Moscow)

/ J. V. Gerasimova, A. N. Vtyurin // Chem. Phys. Lett. - 2012. - Vol. 523. - P. 144-147, DOI 10.1016/j.cplett.2011.12.041. - Cited References: 11. - We would like to thank Prof. E. M. Aver'yanov for discussion, and V. A. Ouskin for the technical assistance. This work has been supported by the Russian Foundation for Basic Researches, Grant No. 11-02-98002-r_sibir_a. . - ISSN 0009-2614РУБ Chemistry, Physical + Physics, Atomic, Molecular & Chemical

Аннотация: Infrared absorption of (NH4)(3)WO3F3 compound has been studied. Profile of asymmetric band in 600-1000 cm (1) range associated with polar W-O vibrations of WO3F33- ions is explicable on the basis of multi-oscillatory dynamics with account of damping. Complex profile with Evans holes proves that internal modes of WO3F33- anions in the fluorine-oxygen octahedron interact due to the effects of the local field. (C) 2011 Elsevier B. V. All rights reserved.

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Держатели документа:
[Gerasimova, Ju V.
Vtyurin, A. N.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Vtyurin, A. N.; Втюрин, Александр Николаевич; Герасимова, Юлия Валентиновна

/ D. A. Ikonnikov [et al.] // Opt. Mater. - 2012. - Vol. 34, Is. 11. - P. 1839-1842, DOI 10.1016/j.optmat.2012.05.016. - Cited References: 23. - The work was supported by Ministry of Education and Science of Russian Federation (Contract 16.740.11.0150), by Russian Foundation for Basic Researches Grant 12-02-00026, Grant of President of Russian Federation for support of leading scientific schools No. SS-4828.2012.2, Grant No. SFU.F12, and Projects No. 28, 43 and No. 101 of SB RAS. . - ISSN 0925-3467РУБ Materials Science, Multidisciplinary + Optics

Аннотация: Absorption spectra of the Nd3+ ions in an orthorhombic δ-BiB3O6 single crystal were measured in the spectral range 11,000-20,500 cm-1. The f-f transition intensities were analyzed in terms of the Judd-Ofelt theory, and the following parameters of the theory were obtained: Ω2 = 6.35 × 10-20 cm2, Ω4 = 4.86 × 10-20 cm 2, and Ω6 = 11.233 × 10-20 cm 2. The strengths, spontaneous emission probabilities, branching ratios, spectroscopic quality factor and excited state radiative lifetime were calculated for laser transitions from the 4F3/2 state to 4IJ manifold. Spectroscopic properties of Nd 3+:δ-BiB3O6 crystal favor lasing at 1.3 μm, where this crystal possesses near non-critical phase matching for second harmonic generation. © 2012 Elsevier B.V. All rights reserved.

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Держатели документа:
[Malakhovskii, A. V.
Sukhachev, A. L.
Zaitsev, A. I.
Aleksandrovsky, A. S.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Ikonnikov, D. A.
Zaitsev, A. I.
Aleksandrovsky, A. S.] Siberian Fed Univ, Krasnoyarsk, Russia
[Jubera, V.] Univ Bordeaux, CNRS, ICMCB, F-33608 Pessac, France

Доп.точки доступа:
Ikonnikov, D. A.; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Zaitsev, A. I.; Зайцев, Александр Иванович; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Jubera, V.

/ A. V. Malakhovskii [et al.] // J. Alloys Compd. - 2012. - Vol. 529. - P. 38-43, DOI 10.1016/j.jallcom.2012.03.066. - Cited References: 51. - The work was supported by the Russian Foundation for Basic Researches grant 12-02-00026, by the Russian President Grants SS-1044.2012.2 and SS-4828.2012.2, by Ministry of Education and Science of Russian Federation (Contract 16.740.11.0150), by grant no. SFU.F12 and by Projects No. 28, 43 and No. 101 of SB RAS. . - ISSN 0925-8388РУБ Chemistry, Physical + Materials Science, Multidisciplinary + Metallurgy & Metallurgical Engineering

Аннотация: The polarized absorption spectra of trigonal single crystal Nd0.5Gd0.5Fe3(BO3)4 were measured in the spectral range 10,000–22,000 cm−1. The d–d and f–f transitions spectra were separated. The f–f transitions intensities were analyzed in terms of the Judd–Ofelt theory in a ferroborate with huntite structure for the first time, and the following parameters of the theory were obtained: Ω2 = 4.4 × 10−20 cm2, Ω4 = 8.04 × 10−20 cm2, and Ω6 = 8.25 × 10−20 cm2. The strengths, spontaneous emission probabilities, branching ratios, spectroscopic quality factor and excited state lifetime were calculated for transitions from the 4F3/2 state to 4IJ manifold. All the obtained spectroscopic characteristics were compared with those of alumoborates with the same crystal structure.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Leont'ev, A. A.; Леонтьев, Андрей Александрович; Gudim, I. A.; Гудим, Ирина Анатольевна; Krylov, A. S.; Крылов, Александр Сергеевич; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич

/ A. V. Malakhovskii [et al.] // Eur. Phys. J. B. - 2012. - Vol. 85, Is. 2. - P. 80, DOI 10.1140/epjb/e2012-20953-1. - Cited References: 70. - The work was supported by the Russian Foundation for Basic Researches Grant 12-02-00026 and by Russian President Grant NSh-1044.2012.2. . - ISSN 1434-6028РУБ Physics, Condensed Matter

Аннотация: Influence of the partial substitution of paramagnetic Fe3+ ions by diamagnetic Ga3+ ions in the trigonal crystal GdFe3 (BO3)4 on its optical and magnetic properties is studied and discussed in connection with problems common for all antiferromagnets containing 3d 5 ions. Polarized optical absorption spectra and linear birefringence of GdFe3 (BO3)4 and GdFe2.1Ga0.9 (BO3)4 single crystals have been measured in the temperature range 85–293 K. Specific heat temperature dependence (2–300 K) and structure of GdFe2.1Ga0.9 (BO3)4 crystal have been also studied. As a result of substitution of 30% Fe to Ga the Neel temperature diminishes from 38 till 16 K, the strong absorption band edge shifts on 860 cm-1 (0.11 eV) to higher energy and the d-d transitions intensity decreases substantially larger than the Fe concentration does. Strong absorption band edge is shown to be due to Mott-Hubbard transitions. Correlation between position of the strong absorption band edge and the Neel temperature of antiferromagnets has been revealed. Properties of the doubly forbidden d-d transitions in the studied crystals and in other antiferromagnets are explained within the framework of the model of the exchange-vibronic pair absorption, which is theoretically analyzed in detail. The model permitted us to determine the connection between parameters of d-d absorption bands (intensity, width and their temperature dependences), on the one hand, and the exchange, spin-orbit and electron-lattice interactions, on the other hand.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Vasil'ev, A. D.; Васильев, Александр Дмитриевич; Leont'ev, A. A.; Леонтьев, Андрей Александрович; Kartashev, A. V.; Карташев, Андрей Васильевич; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна

/ N. Golovnev, M. Molokeev // Acta Crystallographica Section C Crystal Structure Communications. - 2013. - Vol. 69, Pt. 7. - P. 704-708, DOI 10.1107/S0108270113014078 . - ISSN 0108-2701
Аннотация: The structures of the LiI and NaI salts of 2-thiobarbituric acid (2-sulfanylidene-1-3-diazinane-4,6-dione, H 2TBA) have been studied. μ-Aqua-octaaquabis(μ-2- thiobarbiturato-κ2 O:O′)bis(2-thiobarbiturato-κO) tetralithium(I) dihydrate, [Li4(C4H3N 2O2S)4(H2O)9]·2H 2O, (I), crystallizes with four symmetry-independent four-coordinated LiI cations and four independent HTBA- anions. The structure contains two structurally non-equivalent LiI cations and two non-equivalent HTBA- anions (bridging and terminal). Eight of the coordinated water ligands are terminal and the ninth acts as a bridge between LiI cations. Discrete [Li4(HTBA)4(H2O)9] ·2H2O complexes form two-dimensional layers. Neighbouring layers are connected via hydrogen-bonding interactions, resulting in a three-dimensional network. Poly[μ2-aqua-tetraaqua(μ4-2- thiobarbiturato-κ4 O:O:S:S)(μ2-thiobarbiturato- κ2 O:S)disodium(I)], [Na2(C4H 3N2O2S)2(H2O) 5] n , (II), crystallizes with six-coordinated NaI cations. The octahedra are pairwise connected through edge-sharing by a water O atom and an O atom from the μ4-HTBA- ligand, and these pairs are further top-shared by the S atoms to form continuous chains along the a direction. Two independent HTBA- ligands integrate the chains to give a three-dimensional network. © 2013 International Union of Crystallography.

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Держатели документа:
Siberian State Univ, Krasnoyarsk 660041, Russia
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич

/ V. L. Kirillov [et al.] // Mater. Chem. Phys. - 2014. - Vol. 145, Is. 1-2. - P. 75-81, DOI 10.1016/j.matchemphys.2014.01.036. - Cited References: 46. - This work was supported by the Interdisciplinary Integration Project no. 45 of the Siberian Branch of the Russian Academy of Sciences for 2012-2014. . - ISSN 0254-0584. - ISSN 1879-3312РУБ Materials Science, Multidisciplinary

Аннотация: A one-pot synthesis method for the controllable growth of magnetite nanoparticles directly during the process of co-precipitation using citrate ions was developed. The effects of the concentration of citrate ions and the solution pH on the characteristics of magnetite particles with sizes in the range of 4-10 nm synthesized by the method of co-precipitation were studied. The results showed that the specified concentration of citrate ions allowed the preparation of magnetite particles with a definite size that exhibited superparamagnetic behaviour in a particular temperature range. As the concentration ratio of citrate to iron ions was increased from 0 to 0.11, the average size of the prepared magnetite particles decreased from 10.5 to 4.4 nm. As a result, the superparamagnetic blocking temperature decreased from 300 to 20 K, the saturation magnetisation decreased from 50 to 20 emu g(-1), and the average magnetic moment decreased from 8000 mu(B) to 340 mu(B) (at T = 300 K). The obtained experimental data proved that the size effects of the magnetite nanoparticles can be attributed to the capping of the magnetite surface by adsorbed citrate ions. Thus, the suggested approach allows magnetite nanoparticles to be prepared with an optimum particle size around superparamagnetic threshold that prevents their irreversible agglomeration and simultaneously allows them to be removed from a solution at an acceptable rate. (C) 2014 Elsevier B.V. All rights reserved.

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Держатели документа:
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Kirillov, V. L.; Balaev, D. A.; Балаев, Дмитрий Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Shaikhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Martyanov, O. N.; Siberian Branch of the Russian Academy of Sciences

/ V. V. Men'shikov [et al.] // Phys. Solid State. - 2014. - Vol. 56, Is. 3. - P. 468-472, DOI 10.1134/S1063783414030196. - Cited References: 21 . - ISSN 1063-7834. - ISSN 1090-6460РУБ Physics, Condensed Matter

Аннотация: A method for calculating the contribution of exchange interaction to uniaxial anisotropy with the use of g' factors has been worked out using CoCO3 crystals as an example. The calculated contribution of dipole-dipole interactions to the anisotropy of CoCO3 is 0.93 cm(-1). The sum of the contributions to the anisotropy constant of CoCO3 with the inclusion of the dipole-dipole interactions is 36.1 cm(-1).

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Доп.точки доступа:
Men'shikov, V. V.; Меньшиков, Виктор Васильевич; Rudenko, V. V.; Руденко, Валерий Васильевич; Tugarinov, V. I.; Тугаринов, Василий Иванович; Vorotynov, A. M.; Воротынов, Александр Михайлович; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич

/ N. G. Zamkova, V. I. Zinenko, A. S. Shinkorenko // Ferroelectrics : Special Issue: Professor Wolfgang Kleemann in honor of his 70th birthday. - 2012. - Vol. 426. - P. 132-138, DOI 10.1080/00150193.2012.671657. - Cited References: 9. - This work was supported by the Russian Foundation for Basic Research (project no. 09-02-00067) . - ISSN 0015-0193. - ISSN 1563-5112РУБ Materials Science, Multidisciplinary + Physics, Condensed Matter

Аннотация: Vibration frequencies of instable ferroelectric modes, as well as dependencies of crystal energy on ion's displacement amplitudes of these modes in doped compounds Ca1–x A x Ti1–x/4□ x /4O3 (space group Pbmn) with А–Sc3+, In3+, La3+, Bi3+ (□–vacancy) have been calculated in the framework of generalized nonparametric Gordon–Kim model. To compensate excessive positive charge the vacancies were considered to be at Ti4+ sites. Calculations were carried out in the «average» crystal approximation for the impurity concentration x = 0.25. For this purpose 40 atoms’ supercell sets with the different ordering of the heterovalent ions Ca2+ and impurity А3+ have been considered. Every type of impurity has been found to induce ferroelectric instability in doped compounds.

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Держатели документа:
[Zamkova, N. G.
Zinenko, V. I.
Shinkorenko, A. S.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk, Russia

Доп.точки доступа:
Zinenko, V. I.; Зиненко, Виктор Иванович; Shinkorenko, A. S.; Шинкоренко, Алексей Сергеевич; Замкова, Наталья Геннадьевна

/ S. X. Yu [et al.] // ECS J. Solid State Sci. Technol. - 2014. - Vol. 3, Is. 8. - P. R159-R163, DOI 10.1149/2.0071408jss. - Cited References: 33. - The present work was supported by the National Natural Science Foundations of China (Grant No. 51002146, No. 51272242), Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in the University of the Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), Beijing Youth Excellent Talent Program (YETP0635) and the Funds of the State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University (KF201306). Z. G. Xia is also grateful for the financial support from University of Science and Technology Beijing. V.V.A. gratefully acknowledge the Ministry of Education and Science of the Russian Federation for the financial support. . - ISSN 2162-8769. - ISSN 2162-8777
   Перевод заглавия: Синтез и люминесцентные свойства синего люминофора Li3Sc2(PO4)3:Eu2+РУБ Materials Science, Multidisciplinary + Physics, Applied

Аннотация: A new blue-emitting phosphor Li3Sc2(PO4)3:Eu2+ was synthesized by a high temperature solid-state reaction method, and the crystal structure and photoluminescence properties were investigated in detail. The preferred crystallographic position of the Eu2+ ions in the Li3Sc2(PO4)3 host were determined from the structural analysis and spectroscopic properties. The as-prepared phosphor gave an intense blue emission band centered at 439 nm with the CIE coordinate of (0.1540, 0.0317) upon the excitation of the near ultraviolet light. The critical quenching concentration of Eu2+ in Li3Sc2(PO4)3:Eu2+ was about 15 mol%, and the corresponding concentration quenching mechanism was verified to be the dipole-quadrupole interaction. The fluorescence lifetime of Eu2+ emission and the thermal stable luminescence property have been investigated. Li3Sc2(PO4)3:Eu2+ was found to be a promising candidate as a blue-emitting n-UV convertible phosphor for the application in white light emitting diodes (w-LEDs).

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Держатели документа:
China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
SB RAS, LV Kirensky Phys Inst, Lab Crystal Phys, Krasnoyarsk 660036, Russia
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielectr Mat, Novosibirsk 630090, Russia

Доп.точки доступа:
Yu, Shixin; Xia, Zhiguo; Molokeev, M. S.; Молокеев, Максим Сергеевич; Miao, Hao; Atuchin, V. V.