Рубрики:
LIQUID-CRYSTAL
SCATTERING
PHASES
MATRIX
ORDER
DYES
Кл.слова (ненормированные):
Absorption -- Band structure -- Impurities -- Molecular dynamics -- Polarization -- Spectrum analysis -- Distribution function -- Local field parameters -- Splitting -- Temperature dependence -- Nematic liquid crystals
LIQUID-CRYSTAL
SCATTERING
PHASES
MATRIX
ORDER
DYES
Кл.слова (ненормированные):
Absorption -- Band structure -- Impurities -- Molecular dynamics -- Polarization -- Spectrum analysis -- Distribution function -- Local field parameters -- Splitting -- Temperature dependence -- Nematic liquid crystals
Аннотация: The polarized electronic absorption spectra, orientation ordering, and the special local field features were studied for push-pull linear dye molecules with strong donor-acceptor electronic conjugation of terminal fragments in the matrix of a nematic liquid crystal. The temperature-induced inversion of the sign of the splitting of polarized impurity absorption bands was observed. This effect was shown to be caused by the statistical character of orientation ordering of impurity molecules and manifestation of the higher moments of the orientation distribution function. The dependence of local field parameters (Lorentz tensor components) of impurity molecules on their orientation ordering was established. This dependence was used to reproduce the temperature dependence of the orientation order parameter of the matrix. (C) 2004 MAIK "Nauka / Interperiodica".
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
Res Inst Organ Intermediates & Dyes, Dolgoprudnyi 141700, Moscow Oblast, Russia
ИФ СО РАН
Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Research Institute of Organic Intermediates and Dyes, Dolgoprudnyi, Moscow oblast, 141700, Russian Federation
Доп.точки доступа:
Rumyantsev, V. G.; Аверьянов, Евгений Михайлович