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    Effect of mechanical activation on the thermoelectric properties of Sr1-xSmxTiO3 ceramics
/ Y. S. Orlov, S. N. Vereshchagin, S. V. Novikov [et al.] // Ceram. Int. - 2021. - Vol. 47, Is. 20. - P. 28992-28999, DOI 10.1016/j.ceramint.2021.07.060. - Cited References: 31. - This study was supported by the Russian Science Foundation, project no. 19-72-00097 . - ISSN 0272-8842. - ISSN 1873-3956
РУБ Materials Science, Ceramics

Аннотация: The Sr1-xSmxTiO3 (х = 0.025, 0.05, 0.075, 0.1, 0.2) strontium titanate solid solutions were prepared from oxides and carbonates using a conventional ceramic technology based on the mechanochemical activation. The electrical conductivity and Seebeck coefficient of the synthesized compounds were measured in the temperature range from 300 to 800 K. We found that the properties of the samples significantly depend on the preliminary mechanochemical activation. The thermoelectric power factor attains maximum value in the hydrogen reduced samples with concentration of х = 0.05 and 0.075 obtained from nanoparticles: 5.5 μW/(cm · K2) for Sr0.95Sm0.05TiO3 (580 K) and 4.10 μW/(cm · K2) for Sr0.925Sm0.075TiO3 (650 K). An increase in the annealing temperature of mechanically activated samples leads to an even greater increase in electrical conductivity and power factor: 9.2 μW/(cm · K2) for Sr0.925Sm0.075TiO3 (650 K).

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Держатели документа:
Russian Acad Sci, Siberian Branch, Krasnoyarsk Sci Ctr, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Inst Chem & Chem Technol, Krasnoyarsk Sci Ctr, Siberian Branch, Krasnoyarsk 660036, Russia.
Ioffe Inst, St Petersburg 194021, Russia.

Доп.точки доступа:
Orlov, Yu. S.; Орлов, Юрий Сергеевич; Vereshchagin, S. N.; Novikov, S., V; Burkov, A. T.; Borus, A. A.; Борус, Андрей Андреевич; Sitnikov, M., V; Solovyov, L. A.; Volochaev, M. N.; Волочаев, Михаил Николаевич; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Russian Science FoundationRussian Science Foundation (RSF) [19-72-00097]
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