Аннотация: The method to investigate "single-ion" exchange anisotropy (as predicted by the pair model) is treated by exploration of several isostructural diamagnetic crystals containing magnetic impurities. The electron paramagnetic resonance (EPR) spectra were observed for ferric borate isostructural crystals MBO(3): Fe(3+) (M = Ga, In, Lu, Sc). The experimental dependences of the spin-Hamiltonian axial parameters of the second-order D(S) and fourth-order (a-F)(cS) versus total pair spin S are presented. The contributions arising from the distortion of the parent crystal lattice MBO3 under magnetic dilution are estimated. The microscopic derived expressions for the "single-ion" contribution to the anisotropy are also presented. The present experimental data enable estimation of the "single- ion" exchange contribution for FeBO(3), MnCO(3), and alpha-Fe(2)O(3) crystals at T= 0 K. The quantitative estimations for EPR are in satisfactory agreement among themselves and with the experimental data.
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Держатели документа:
LV Kirenskii Inst Phys, SB RAS, Krasnoyarsk 660036, Russia
ИФ СО РАН
L.V. Kirensky Institute of Physics SB RAS, 660036 Krasnoyarsk, Russian Federation
Доп.точки доступа:
Men'shikov, V. V.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Rudenko, V. V.; Руденко, Валерий Васильевич; Sudakov, A. N.; Tugarinov, V. I.; Тугаринов, Василий Иванович; Vorotynov, A. M.; Воротынов, Александр Михайлович