Труды сотрудников института физики

/ K. S. Aleksandrov [et al.] // J. Exp. Theor. Phys. - 2002. - Vol. 94, Is. 5. - P. 977-984, DOI 10.1134/1.1484991. - Cited References: 20 . - ISSN 1063-7761РУБ Physics, Multidisciplinary

Аннотация: New phase transitions induced by hydrostatic pressure in a cubic (under standard conditions) ScF3 crystal are discovered by the methods of polarization microscopy and Raman scattering. The space groups R (3) over barc for Z = 2 and Pnma for Z = 4 are proposed for the high-pressure phases. A nonempirical computation of the lattice dynamics of the crystal is carried out. It is shown that, under normal pressure, the cubic phase is stable down to T = 0 K, while the application of a hydrostatic pressure gives rise to a phonon branch in the vibrational spectrum (between points R and M of the Brillouin zone) with negative values of squares of frequencies. The condensation of soft mode R-5 at the boundary point of the Brillouin zone leads to rhombohedral distortion of the cubic structure with the unit cell volume doubling. The calculated frequencies at q = 0 of the ScF3 lattice in the distorted rhombohedral phase are real-valued; the number and position of frequencies active in Raman scattering are in accord with the experimental values. (C) 2002 MAIK "Nauka/Interperiodica".

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
Russian Acad Sci, Joint Inst Geol Geophys & Mineral, Siberian Div, Novosibirsk 630090, Russia

Доп.точки доступа:
Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Voronov, V. N.; Воронов, Владимир Николаевич; Vtyurin, A. N.; Втюрин, Александр Николаевич; Goryainov, S. V.; Zamkova, N. G.; Замкова, Наталья Геннадьевна; Zinenko, V. I.; Зиненко, Виктор Иванович; Krylov, A. S.; Крылов, Александр Сергеевич

/ K. S. Aleksandrov [et al.] // Phys. Solid State. - 2009. - Vol. 51, Is. 4. - P. 810-816, DOI 10.1134/S1063783409040295. - Cited References: 22. - The authors are grateful to V.I. Zinenko for helpful discussion of the results.This work was conducted in the framework of Integration Project (no. 3.7) of the Russian Academy of Sciences (Siberian Branch). . - ISSN 1063-7834
Аннотация: Pressure-induced phase transitions in the ScF3 crystal were studied using synchrotron radiation diffraction, polarization microscopy, and Raman spectroscopy. The phase existing in the range 0.6-3.0 GPa is optically anisotropic; its structure is described by space group R (3) c (Z = 2), and the transition is due to rotation of ScF6 octahedra around a threefold axis. The pressure dependence of the structural parameters and angle of rotation are determined. The number of Raman spectral lines corresponds to that expected for this structure; above the phase transition point, a recovery of soft modes takes place. At a pressure of 3.0 GPa, a transition occurs to a new phase, which remains metastable as the pressure decreases. The results are interpreted using an ab initio method based on the Gordon-Kim approach.

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Держатели документа:
[Aleksandrov, K. S.
Voronov, V. N.
Vtyurin, A. N.
Krylov, A. S.
Molokeev, M. S.
Pavlovskii, M. S.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Goryainov, S. V.
Likhacheva, A. Yu.] Russian Acad Sci, Siberian Branch, Inst Geol & Mineral, Novosibirsk 630090, Russia
[Ancharov, A. I.] Russian Acad Sci, Siberian Branch, Inst Solid State Chem, Novosibirsk 630091, Russia
ИФ СО РАН

Доп.точки доступа:
Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Voronov, V. N.; Воронов, Владимир Николаевич; Vtyurin, A. N.; Втюрин, Александр Николаевич; Krylov, A. S.; Крылов, Александр Сергеевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Pavlovskii, M. S.; Павловский, Максим Сергеевич; Goryainov, S. V.; Likhacheva, A. Y.; Ancharov, A. I.; Russian Academy of Sciences (Siberian Branch)

/ A. A. Savina [et al.] // J. Solid State Chem. - 2015. - Vol. 225. - P. 53–58, DOI 10.1016/j.jssc.2014.11.023. - Cited References: 66. - The authors are grateful to Dr. K.M. Khal'baeva and Dr. Irina A. Gudkova for their assistance in preparing the compound and taking X-ray single-crystal diffraction data. This study is partly supported by the Russian Foundation for Basic Research (Grants 13-03-01020 and 14-03-00298). V.V.A., A.S.K. and A.S.O. gratefully acknowledge the Ministry of Education and Science of the Russian Federation for a partial financial support. . - ISSN 0022-4596. - ISSN 1095-726X
   Перевод заглавия: Синтез, структурные и спектроскопические свойства ацентричного тройного молибдата Cs2NaBi(MoO4)3РУБ Chemistry, Inorganic & Nuclear + Chemistry, Physical

Аннотация: New ternary molybdate Cs2NaBi(MoO4)3 is synthesized in the system Na2MoO4–Cs2MoO4–Bi2(MoO4)3. The structure of Cs2NaBi(MoO4)3 of a new type is determined in noncentrosymmetric space group R3c, a=10.6435(2), c=40.9524(7) Å, V=4017.71(13) Å3, Z=12 in anisotropic approximation for all atoms taking into account racemic twinning. The structure is completely ordered, Mo atoms are tetrahedrally coordinated, Bi(1) and Bi(2) atoms are in octahedra, and Na(1) and Na(2) atoms have a distorted trigonal prismatic coordination. The Cs(1) and Cs(2) atoms are in the framework cavities with coordination numbers 12 and 10, respectively. No phase transitions were found in Cs2NaBi(MoO4)3 up to the melting point at 826 K. The compound shows an SHG signal, I2w/I2w(SiO2)=5 estimated by the powder method. The vibrational properties are evaluated by Raman spectroscopy, and 26 narrow lines are measured.

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Держатели документа:
SB RAS, Baikal Inst Nat Management, Lab Oxide Syst, Ulan Ude 670047, Russia.
Buryat State Univ, Dept Chem, Ulan Ude 670000, Russia.
SB RAS, Rzhanov Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia.
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia.
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia.
SB RAS, Nikolaev Inst Inorgan Chem, Lab Crystal Chem, Novosibirsk 630090, Russia.
Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia.
SB RAS, Kirensky Inst Phys, Lab Mol Spectroscopy, Krasnoyarsk 660036, Russia.
SB RAS, Nikolaev Inst Inorgan Chem, Lab Epitaxial Layers, Novosibirsk 630090, Russia.
Novosibirsk State Univ, Lab Res Methods Composit & Struct Funct Mat, Novosibirsk 630090, Russia.
SB RAS, Kirensky Inst Phys, Lab Crystal Struct, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Dept Photon & Laser Technol, Krasnoyarsk 660079, Russia.
SB RAS, Inst Automat & Elect, Lab Condenced Matter Spectroscopy, Novosibirsk 630090, Russia.

Доп.точки доступа:
Savina, A. A.; Atuchin, V. V.; Solodovnikov, S. F.; Solodovnikova, Z. A.; Krylov, A. S.; Крылов, Александр Сергеевич; Maximovsky, E. A.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Pugachev, A. M.; Khaikina, E. G.; Russian Foundation for Basic Research [4828.2012.2, 12-02-31205]; Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" [8379]

/ M. B. Smirnov [et al.] // J. Phys. Chem. C. - 2015. - Vol. 119, Is. 36. - P. 20801-20809, DOI 10.1021/acs.jpcc.5b05540. - Cited References: 36. - This work was supported by the international collaboration program between the Centre National de la Recherche Scientifique (CNRS) of France and the Russian Foundation for Basic Research (RFBR), LIBASTRAM CNRS Project 6094, and RFBR Grant 13-03-91052. . - ISSN 1932-7447РУБ Chemistry, Physical + Nanoscience & Nanotechnology + Materials Science, Multidisciplinary

Аннотация: Structure, electronic states, and vibrational dynamics of γ-LiV2O5 were studied by combined use of quantum-chemical calculations and Raman spectroscopy. The spin-polarized DFT+U calculations correctly mimic the structural changes induced by the Li intercalation into the V2O5 framework. The analysis of the density of electronic states shows that the electrons of Li atoms are transferred to the Vb atoms and are aligned in ferromagnetic order. The charge distribution in the system reflects the change of valence state of the Vb atoms from 5+ to 4+, and it is in line with changes of Vb–O bond lengths. The calculated Raman spectrum of the γ-LiV2O5 structure is in line with the experimental Raman spectra that allows a reliable assignment of all prominent Raman peaks. Comparison of the spectra of γ-LiV2O5 and γ'-V2O5 indicates spectral signatures of structural changes induced by the Li insertion into the γ'-V2O5 lattice. Results of the study present the opportunity of using Raman spectroscopy for characterization of structural modifications of the vanadate framework upon intercalation of guest species.

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Держатели документа:
Faculty of Physics, St. Petersburg State University, Petrodvorets, St. Petersburg, Russian Federation
Ioffe Physical Technical Institute, Polytekhnicheskaya 26, St. Petersburg, Russian Federation
Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, Dubna, Russian Federation
Laboratoire de Spectrochimie Infrarouge et Raman, UMR 8516 CNRS-, Universite de Lille, Sciences et Technologies, Villeneuve dAscq, France
Institut de Chimie et des Materiaux Paris Est, ICMPE/GESMAT, UMR 7182 CNRS-, Universite Paris Est-Creteil, 2 rue Henri Dunant, Thiais, France
Kirensky Institute of Physics, Akademgorodok, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Smirnov, M. B.; Roginskii, E. M.; Kazimirov, V. Y.; Smirnov, K. S.; Baddour-Hadjean, R.; Pereira-Ramos, J. P.; Zhandun, V. S.; Жандун, Вячеслав Сергеевич

/ M. A. Prosnikov [et al.] // J. Phys.: Condens. Matter. - 2017. - Vol. 29, Is. 2. - Ст. 025808, DOI 10.1088/0953-8984/29/2/025808. - Cited References:32. - This research was supported by the Russian Science Foundation, grant No. 16-12-10456. . - ISSN 0953-8984. - ISSN 1361-648XРУБ Physics, Condensed Matter

Аннотация: A group of recently synthesized orthorhombic Pnma crystals PbMBO4 (M = Cr, Mn, Fe) demonstrates a number of unusual structural and magnetic properties. We report on polarized Raman scattering study of the lattice and magnetic dynamics in single crystals of an antiferromagnet PbFeBO4 below and above T-N = 114 K. Polarization properties of the observed magnetic excitations below T-N as well as intense quasi-elastic scattering support the quasi-one-dimensional character of the magnetic structure of PbFeBO4. Frequency overlapping of magnetic excitations and low-frequency phonons in the range of 90-200 cm-1 leads to pronounced asymmetric anomalies thus confirming intrinsic coupling of magnetic and lattice subsystems. This conclusion is also supported by observation of anomalous temperature behaviour of higher frequency phonons in the vicinity of T-N. Experimental investigations are supported by relevant magnetic symmetry analysis which allows us to explain previously observed anomalous results.

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Держатели документа:
Russian Acad Sci, Ioffe Phys Tech Inst, St Petersburg 194021, Russia.
SB Russian Acad Sci, LV Kirensky Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Prosnikov, M. A.; Smirnov, A. N.; Davydov, V. Yu; Sablina, K. A.; Саблина, Клара Александровна; Pisarev, R. V.; Russian Science Foundation [16-12-10456]

/ S. S. Aplesnin [et al.] // Mater. Res. Express. - 2018. - Vol. 5, Is. 11. - Ст. 115202, DOI 10.1088/2053-1591/aaddd9. - Cited References: 33. - This study was supported by the Russian Foundation for Basic Research project N 18-52-00009 Bel_a, No 18-32-00079 mol_a, the state order No 3.5743.2017/6.7. . - ISSN 2053-1591РУБ Materials Science, Multidisciplinary

Аннотация: To establish the existence of dipole glass in the chromium-substituted bismuth pyrostannate solid solutions, the frequency and temperature dependences of the permittivity have been measured in the temperature range of 300–750 K. The field and dynamic dependences of polarization in the temperature range of 80–550 K have been determined. Using the Raman scattering spectra, the absence of inversion center has been established. The maximum of electrical resistance has been found in the vicinity of the dipole moment freezing point. The carrier type has been determined from the thermopower data. The polarization relaxation is shown to be nonexponential. The experimental data are explained within the model of dipole glass in the α- phase and the model of charged crystalline domain walls with the electron-polarization relaxation mechanism above the α–β structural transition.

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Держатели документа:
SB RAS, Kirensky Inst Phys, Fed Res Ctr KSC, Krasnoyarsk 660036, Russia.
Reshetnev Siberian State Univ Sci & Technol, Krasnoyarsk 660037, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Inst Solid State Phys, LV-1063 Riga, Latvia.

Доп.точки доступа:
Aplesnin, S. S.; Аплеснин, Сергей Степанович; Udod, L. V.; Удод, Любовь Викторовна; Sitnikov, M. N.; Kretinin, V. V.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Mironova-Ulmane, N.; Russian Foundation for Basic Research [N 18-52-00009 Bel_a, 18-32-00079 mol_a, 3.5743.2017/6.7]

/ A. Krylov, I. Yushina, E. Slyusareva [et al.] // Phys. Chem. Chem. Phys. - 2022. - Vol. 24, Is. 6. - P. 3788-3798, DOI 10.1039/d1cp05021d. - Cited References: 57. - This work was financially supported by the RFBR (Russian Foundation for Basic Research, project number: 21-52-12018) and DFG (Deutsche Forschungsgemeinschaft, project number: 448809307). The Raman and high hydrostatic pressure experiments were performed in the Center for Common Use of the Krasnoyarsk Scientific Center SB RAS. The authors thank M. Maliuta for sample synthesis and characterisation . - ISSN 1463-9076. - ISSN 1463-9084РУБ Chemistry, Physical + Physics, Atomic, Molecular & Chemical

Аннотация: The behaviours of the open pore (op) and closed pore (cp) phases of the flexible Ni2(ndc)2(dabco) (ndc – 2,6-naphthalene dicarboxylate, dabco – 1,4-diazabicyclo[2.2.2]octane, DUT-8(Ni)) metal–organic framework under high hydrostatic pressures up to 10 GPa in isopropanol and silicone oil were studied by Raman spectroscopy. Ab initio simulations of vibrational spectra were performed for the open and closed pore phases, which allowed us to disclose the characteristic vibrational modes affected by the structural transitions under pressure. Analysis of theoretical and experimental Raman data suggests that the op–cp transition involves gateway vibrations at 25 and 67 cm−1, corresponding to trampoline/rotational motions of aromatic linkers. The experiments reveal the formation of new distorted cp phases at pressures higher than 2 GPa, which are formed without amorphisation. The transition between the cp phase and the distorted cp phase is reversible. The experiments also reveal the pivotal role of the pressure transmitting medium on the phase transition behaviour.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
South Ural State Univ, SEC Nahenotechnol, Lenin Ave 76, Chelyabinsk 454080, Russia.
Siberian Fed Univ, Svobodny Prospect 79, Krasnoyarsk 660041, Russia.
Tech Univ Dresden, Chair Inorgan Chem 1, Bergstr 66, D-01062 Dresden, Germany.

Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Yushina, Irina; Slyusareva, Evgenia; Krylova, S. N.; Крылова, Светлана Николаевна; Vtyurin, A. N.; Втюрин, Александр Николаевич; Kaskel, Stefan; Senkovska, Irena; RFBR (Russian Foundation for Basic Research)Russian Foundation for Basic Research (RFBR) [21-52-12018]; DFG (Deutsche Forschungsgemeinschaft)German Research Foundation (DFG) [448809307]