/ K. S. Aleksandrov [et al.]> // Phys. Solid State. - 2009. -
Vol. 51,
Is. 4. - P. 810-816,
DOI 10.1134/S1063783409040295. - Cited References: 22. - The authors are grateful to V.I. Zinenko for helpful discussion of the results.This work was conducted in the framework of Integration Project (no. 3.7) of the Russian Academy of Sciences (Siberian Branch).
. - ISSN 1063-7834
Аннотация: Pressure-induced phase transitions in the ScF3 crystal were studied using synchrotron radiation diffraction, polarization microscopy, and Raman spectroscopy. The phase existing in the range 0.6-3.0 GPa is optically anisotropic; its structure is described by space group R (3) c (Z = 2), and the transition is due to rotation of ScF6 octahedra around a threefold axis. The pressure dependence of the structural parameters and angle of rotation are determined. The number of Raman spectral lines corresponds to that expected for this structure; above the phase transition point, a recovery of soft modes takes place. At a pressure of 3.0 GPa, a transition occurs to a new phase, which remains metastable as the pressure decreases. The results are interpreted using an ab initio method based on the Gordon-Kim approach.
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Держатели документа: [Aleksandrov, K. S.
Voronov, V. N.
Vtyurin, A. N.
Krylov, A. S.
Molokeev, M. S.
Pavlovskii, M. S.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Goryainov, S. V.
Likhacheva, A. Yu.] Russian Acad Sci, Siberian Branch, Inst Geol & Mineral, Novosibirsk 630090, Russia
[Ancharov, A. I.] Russian Acad Sci, Siberian Branch, Inst Solid State Chem, Novosibirsk 630091, Russia
ИФ СО РАН
Доп.точки доступа: Aleksandrov, K. S.; Александров, Кирилл
Сергеевич; Voronov, V. N.; Воронов, Владимир Николаевич; Vtyurin, A. N.; Втюрин, Александр Николаевич; Krylov, A. S.; Крылов, Александр
Сергеевич; Molokeev, M. S.; Молокеев,
Максим Сергеевич; Pavlovskii, M. S.;
Павловский,
Максим Сергеевич; Goryainov, S. V.; Likhacheva, A. Y.; Ancharov, A. I.; Russian Academy of Sciences (Siberian Branch)