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Найдено документов в текущей БД: 19

    Simulation of conditions for fabrication of optical nanowaveguides in the form of chains of spherical metal nanoparticles by electrostatic functionalization of the process substrate
/ S. V. Karpov, I. L. Rasskazov // Colloid J. - 2013. - Vol. 75, Is. 3. - P. 279-288, DOI 10.1134/S1061933X13030083 . - ISSN 1061-933X
Аннотация: A method is proposed for electrostatic functionalization of substrates used to prepare ordered structures composed of closely spaced plasmon-resonant nanoparticles. The method ensures selective deposition of nanoparticles from the bulk of a colloidal system onto the substrates. This method is based on placing a metal nanotemplate of a required configuration at the opposite side of a substrate, with an electric potential being applied to the template. A mathematical model is developed to ensure that the system parameters responsible for the deposition of metal nanoparticles into ordered single-domain structures on the substrate from a bulk sol in a nonuniform electric field generated by the nanotemplate correspond to the real experimental conditions. Since the degree of imperfection of the synthesized chains governs the applicability of these structures to transmission of the optical excitation at the frequency of the surface plasmon of the particles, the dependence of the degree of imperfection on the physicochemical and electrical parameters of the system is studied using the Brownian-dynamics model. The calculations of the spectral and transmission properties of nanowaveguides of this type are exemplified. В© 2013 Pleiades Publishing, Ltd.

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Держатели документа:
Russian Acad Sci, Siberian Branch, Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660028, Russia;

Доп.точки доступа:
Рассказов, Илья Леонидович; Rasskazov, I. L.; Карпов, Сергей Васильевич

    Crystal structure and luminescence property of a novel blue-emitting Cs2xCa2xGd2(1−x)(PO4)2:Eu2+ (x = 0.36) phosphor
/ K. Geng, Z. G. Xia, M. S. Molokeev // Dalton Trans. - 2014. - Vol. 43, Is. 37. - P. 14092-14098, DOI 10.1039/c4dt01578a. - Cited References: 29. - This present work was supported by the National Natural Science Foundation of China (grant no. 51002146, no. 51272242), Natural Science Foundation of Beijing (2132050), the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950), the Fundamental Research Funds for the Central Universities (2011YYL131), Beijing Nova Program (Z131103000413047) and Beijing Youth Excellent Talent Program (YETP0635) and the Funds of the State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University (KF201306). . - ISSN 1477-9226. - ISSN 1477-9234
   Перевод заглавия: Кристаллическая структура и люминесцентные свойства нового синего люминофора Cs2xCa2xGd2(1-x)(PO4)2:Eu2+ (x = 0.36)
РУБ Chemistry, Inorganic & Nuclear

Аннотация: A novel blue-emitting double-phosphate phosphor Cs0.72Ca0.72Gd1.28(PO4)(2):Eu2+ was synthesized by the sol-gel method, and the structure and luminescence properties were investigated in detail. The crystal structure and chemical composition of Cs0.72Ca0.72Gd1.28(PO4)(2) matrix was analyzed and determined based on Rietveld refinements and phase and chemical composition analysis. The composition-optimized Cs0.72Ca0.72Gd1.28(PO4)(2):Eu2+ exhibited strong blue light, peaking at 462 nm upon excitation at 365 nm with the CIE coordinates of (0.139, 0.091). The quenching concentration of Eu2+ in the Cs0.72Ca0.72Gd1.28(PO4)(2) phase was about 0.01 and attributed to the dipole-quadrupole interaction. The thermally stable luminescence properties, fluorescence decay curves and diffuse reflectance spectra of Cs0.72Ca0.72Gd1.28(PO4)(2):Eu2+ phosphors are also discussed, all of which indicate that the Cs0.72Ca0.72Gd1.28(PO4)(2):Eu2+ phosphor is a promising phosphor for application in white-light UV LEDs.

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Держатели документа:
China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China
Univ Sci & Technol, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Xia, Zhiguo; Molokeev, M. S.; Молокеев, Максим Сергеевич

    A study of the hysteresis property of the current voltage characteristic in high-temperature superconductors
/ М. И. Петров [et al.] // Solid State Commun. - 1992. - Vol. 82, Is. 6. - P. 453-456, DOI 10.1016/0038-1098(92)90748-X. - Cited References: 21 . - ISSN 0038-1098
РУБ Physics, Condensed Matter

Аннотация: Temperature measurements of current-voltage characteristics (CVC) of the (Y, Lu)1Ba2Cu3O7-delta high-temperature superconductor have been performed. Analysis of the data shows that CVC of HTSC is mainly formed by two mechanisms: the creep of the Abrikosov vortices inside the crystallites and the Andreev reflection of the carriers within the metal character boundary between the crystallites.

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Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Петров, Михаил Иванович; Petrov, M. I.; Krivomazov, S. N.; Khrustalev, B. P.; Хрусталев, Борис Петрович; Aleksandrov, K. S.; Александров, Кирилл Сергеевич

    Comparative investigations of the crystal structure and photoluminescence property of eulytite-type Ba3Eu(PO4)3 and Sr3Eu(PO4)3
/ H. P. Ji [et al.] // Dalton Trans. - 2015. - Vol. 44, Is. 16. - P. 7679-7686, DOI 10.1039/c4dt03887h. - Cited References:65. - This work was supported by the National Natural Science Foundations of China (grant no. 51032007, no. 51002146, no. 51272242), the Research Fund for the Doctoral Program of Higher Education of China (grant no. 20130022110006), Natural Science Foundations of Beijing (2132050), and the Program for New Century Excellent Talents in the University of the Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047) and Beijing Youth Excellent Talent Program (YETP0635). VVA is partly supported by the Ministry of Education and Science of the Russian Federation. . - ISSN 1477. - ISSN 1477-9234
   Перевод заглавия: Сравнительный анализ кристаллических структур и люминесцентных свойств Ba3Eu(PO4)3 и Sr3Eu(PO4)3. со структурой эвлитина
РУБ Chemistry, Inorganic & Nuclear

Аннотация: In this study, the Ba3Eu(PO4)3 and Sr3Eu(PO4)3 compounds were synthesized and the crystal structures were determined for the first time by Rietveld refinement using powder X-ray diffraction (XRD) patterns. Ba3Eu(PO4)3 crystallizes in cubic space group I3d, with cell parameters of a = 10.47996(9) Å, V = 1151.01(3) Å3 and Z = 4; Ba2+ and Eu3+ occupy the same site with partial occupancies of 3/4 and 1/4, respectively. Besides, in this structure, there exists two distorted kinds of the PO4 polyhedra orientation. Sr3Eu(PO4)3 is isostructural to Ba3Eu(PO4)3 and has much smaller cell parameters of a = 10.1203(2) Å, V = 1036.52(5) Å3. The bandgaps of Ba3Eu(PO4)3 and Sr3Eu(PO4)3 are determined to be 4.091 eV and 3.987 eV, respectively, based on the UV–Vis diffuse reflectance spectra. The photoluminescence measurements reveal that, upon 396 nm n-UV light excitation, Ba3Eu(PO4)3 and Sr3Eu(PO4)3 exhibit orange-red emission with two main peaks at 596 nm and prevailing 613 nm, corresponding to the 5D0 → 7F1 and 5D0 → 7F2 transitions of Eu3+, respectively. The dynamic disordering in the crystal structures contributes to the broadening of the luminescence spectra. The electronic structure of the phosphates was calculated by the first-principles method. The analysis elucidats that the band structures are mainly governed by the orbits of phosphorus, oxygen and europium, and the sharp peaks of the europium f-orbit occur at the top of the valence bands.

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Держатели документа:
China Univ Geosci, Sch Mat Sci & Technol, Natl Lab Mineral Mat, Beijing Key Lab Mat Utilizat Nonmetall Minerals &, Beijing 100083, Peoples R China.
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China.
SB RAS, LV Kirensky Phys Inst, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
Chinese Acad Sci, Tech Inst Phys & Chem, Beijing Ctr Crystal R&D, Key Lab Funct Crystals & Laser Technol, Beijing 100190, Peoples R China.
Univ Chinese Acad Sci, Beijing 100049, Peoples R China.
Russian Acad Sci, Inst Semicond Phys, SB RAS, Lab Opt Mat & Struct, Novosibirsk 630090, Russia.
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia.
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia.

Доп.точки доступа:
Ji, Haipeng; Huang, Zhaohui; Xia, Zhiguo; Molokeev, M. S.; Молокеев, Максим Сергеевич; Jiang, Xingxing; Lin, Zheshuai; Atuchin, V. V.

    Cyan-emitting LiBaBO3:Eu2+ phosphor: Crystal structure and luminescence property comparison with LiSrBO3:Eu2+
/ Z. H. Huang [et al.] // Chem. Phys. Lett. - 2015. - Vol. 628. - P. 21-24, DOI 10.1016/j.cplett.2015.04.004. - Cited References:19. - This work was supported by the National Natural Science Foundations of China (Grant No. 51032007) and the Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20130022110006). . - ISSN 0009. - ISSN 1873-4448
   Перевод заглавия: Голубой люминофор LiBaBO3:Eu2+: сравнение кристаллической структуры и люминесценции с LiSrBO3:Eu2+
РУБ Chemistry, Physical + Physics, Atomic, Molecular & Chemical

Аннотация: Cyan-emitting LiBaBO3:Eu2+ phosphor was synthesized by solid-state reaction at 800 °C. Structure refinement by Rietveld method reveals that LiBaBO3 crystallizes in a monoclinic cell, space groups P21/c or P21/n. Upon 365 nm excitation, LiBaBO3:Eu2+ shows a symmetric emission band peaking at 496 nm with full-width at half-maximum of 80 nm; when monitoring at 496 nm, a broad excitation band in the UV region (250–420 nm) is observed. The luminescence property of LiBaBO3:Eu2+ is considerably different from LiSrBO3:Eu2+ which holds the same space group. The local structures of the two hosts are compared to explain the different behaviors of Eu2+.

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Держатели документа:
China Univ Geosci, Beijing Key Lab Mat Utilizat Nonmetall Minerals &, Natl Lab Mineral Mat, Sch Mat Sci & Technol, Beijing 100083, Peoples R China.
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.

Доп.точки доступа:
Huang, Zhaohui; Ji, Haipeng; Fang, Minghao; Molokeev, M. S.; Молокеев, Максим Сергеевич; Liu, Shuyue; Liu, Yan'gai; Wu, Xiaowen

    Facile solution-precipitation assisted synthesis and luminescence property of greenish-yellow emitting Ca6Ba(PO4)4O:Eu2+ phosphor
/ H. Ji [et al.] // Mater. Res. Bull. - 2016. - Vol. 75. - P. 233-238, DOI 10.1016/j.materresbull.2015.11.055. - Cited References: 22. - This work was partly supported by the National Natural Science Foundations of China (grant nos. 51272242, 51472222, 51511130035), the Research Fund for the Doctoral Program of Higher Education of China (grant no. 20130022110006), and the Russian Foundation for Basic Research (grant no. 15-52-53080 GFEN_a). VVA was partly supported by the Ministry of Education and Science of the Russian Federation . - ISSN 0025-5408
   Перевод заглавия: Легкий синтез с помощью осаждения раствора и люминесцентные свойства люминофора Ca6Ba(PO4)4O:Eu2+ излучающего зеленовато-желтый свет.
РУБ Materials Science, Multidisciplinary

Аннотация: Greenish-yellow emitting microcrystalline Ca6Ba(PO4)4O:Eu2+ phosphor was successfully prepared by a solution-precipitation assisted high temperature reaction method. Phase structure, morphology and/or luminescence properties of the precursor and the as-prepared phosphors were characterized. The phase-pure Ca6Ba(PO4)4O:Eu2+ phosphors were obtained with smooth grain surface and particle size of 2–8 μm. Ca6Ba(PO4)4O:Eu2+ exhibits bright greenish-yellow color emission with its maximum at 540 nm upon UV-blue light excitation. The maximum position of the broad emission band is independent on the calcination temperature. The emission intensity increases with increasing calcination temperature due to improved crystallinity. Besides, the presence of two Eu2+ emission centers in the Ca6Ba(PO4)4O crystal lattice was confirmed and the coordination effects are considered concerning the roles of isolated O atoms and those from the PO4 tetrahedra.

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Держатели документа:
School of Materials Science and Technology, Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, China University of Geosciences, Beijing, China
Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, Russian Federation
Functional Electronics Laboratory, Tomsk State University, Tomsk, Russian Federation
Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk, Russian Federation

Доп.точки доступа:
Ji, H.; Huang, Z.; Xia, Z.; Xie, Y; Molokeev, M. S.; Молокеев, Максим Сергеевич; Atuchin, V. V.
Свободных экз. нет

    Effect of cobalt impurity ions on the magnetic and electrical properties of iron monosilicide crystals
/ G. S. Patrin [et al.] // J. Exp. Theor. Phys. - 2011. - Vol. 112, Is. 2. - P. 303-309, DOI 10.1134/S1063776111010146. - Cited References: 23 . - ISSN 1063-7761
РУБ Physics, Multidisciplinary

Аннотация: The results of experimental investigations of Fe1 - x Co (x) Si crystals in the impurity limit with x = 0.001, 0.005, and 0.01 are reported. The temperature and field dependences of the magnetic susceptibility have been studied. According to the experimental data, the introduction of cobalt impurity leads to a change in the energy structure, which is most pronounced in a change in the electrical properties. The temperature, field, and concentration dependences of the resistivity have been measured. The results have been interpreted in the framework of the Kondo model.

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Держатели документа:
[Patrin, G. S.
Velikanov, D. A.
Volkov, N. V.
Yurkin, G. Yu.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Patrin, G. S.
Beletskii, V. V.] Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660041, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk 660036, Russian Federation
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk 660041, Russian Federation

Доп.точки доступа:
Patrin, G. S.; Патрин, Геннадий Семёнович; Beletskii, V. V.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Volkov, N. V.; Волков, Никита Валентинович; Yurkin, G. Yu.

    Surface bonding states of nano-crystalline diamond balls
/ J. L. Peng [et al.] // Int. J. Mod. Phys. B. - 2001. - Vol. 15, Is. 31. - P. 4071-4085, DOI 10.1142/S0217979201007865. - Cited References: 20 . - ISSN 0217-9792
РУБ Physics, Applied + Physics, Condensed Matter + Physics, Mathematical

Аннотация: The rough surface of nano-crystalline diamond spheres induces surface electronic states which appear as a broadened pre-peak over approx. 15 eV at the C K-edge energy threshold for carbon in the parallel electron energy loss spectrum (PEELS). This appears to be at least partially due to 1s-pi* transitions, although typically the latter occupy a range of only 4 eV for the sp(2) edge of highly-oriented pyrollytic graphite (HOPG). No pi* electrons appear in the conduction band inside the diamond particles, where all electrons are sp(3) hybridized. PEELS data were also obtained from a chemical vapour deposited diamond film (CVDF) and gem-quality diamond for comparison with the spectra of nano-diamonds. The density of sp(2) and sp(3) states on the surface of diamond nano-crystals is calculated for simple structural models of the diamond balls, including some conjecture about surface structures. The results are used to interpret the sp(2)/sp(3) ratios measured from the PEELS spectra recorded as scans across the particles. Surface roughness at the atomic scale was also examined using high-resolution transmission electron microscopy (HRTEM) and electron nano-diffraction patterns were used to confirm the crystal structures.

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Держатели документа:
RMIT Univ, Dept Appl Phys, Melbourne, Vic 3051, Australia
Univ Sydney, Electron Microscope Unit, Sydney, NSW 2006, Australia
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Mol Architecture Grp, Krasnoyarsk 660036, Russia
Russian Acad Sci, Siberian Branch, Inst Biophys, Krasnoyarsk 660036, Russia
Univ Melbourne, Sch Phys, Parkville, Vic 3052, Australia
ИФ СО РАН
ИБФ СО РАН
Department of Applied Physics, RMIT University, Swanston Street, Melbourne, Vic. 3051, Australia
Electron Microscope Unit, University of Sydney, NSW 2006, Australia
Molecular Architecture Group, Kirensky Institute of Physics, Institute of Biophysics, 660036 Krasnoyarsk, Russian Federation
School of Physics, University of Melbourne, Parkville, Vic. 3010, Australia

Доп.точки доступа:
Peng, J. L.; Bulcock, S.; Belobrov, P. I.; Белобров, Петр Иванович; Bursill, L. A.

    Triple molybdate scheelite-type upconversion phosphor NaCaLa(MoO4)3:Er3+/Yb3+: Structural and spectroscopic properties
/ C. S. Lim [et al.] // Dalton Trans. - 2016. - Vol. 45, Is. 39. - P. 15541-15551, DOI 10.1039/c6dt02378a. - Cited References: 71 . - ISSN 1477-9226
   Перевод заглавия: Тройной молибдат со структурой шеелита NaCaLa(MoO4)3:Er3+/Yb3+: структурные и спектроскопические свойства
Аннотация: Triple molybdate NaCaLa(1-x-y)(MoO4)3:xEr3+,yYb3+ (x = y = 0, x = 0.05 and y = 0.45, x = 0.1 and y = 0.2, x = 0.2 and y = 0) phosphors were successfully synthesized for the first time by the microwave sol-gel method. Well-crystallized particles formed after heat treatment at 900 °C for 16 h showed a fine and homogeneous morphology with particle sizes of 2-3 ?m. The structures were refined by the Rietveld method in the space group I41/a. The optical properties were examined comparatively using photoluminescence emission and Raman spectroscopy. Under excitation at 980 nm, the NaCaLa0.7(MoO4)3:0.1Er3+,0.2Yb3+ and NaCaLa0.5(MoO4)3:0.05Er3+,0.45Yb3+ particles exhibited a strong 525 nm emission band, a weaker 550 nm emission band in the green region, and three weak 655 nm, 490 nm and 410 nm emission bands in the red, blue and violet regions. The pump power dependence and Commission Internationale de L'Eclairage chromaticity of the upconversion emission intensity were evaluated in detail. © 2016 The Royal Society of Chemistry.

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Держатели документа:
Department of Advanced Materials Science and Engineering, Hanseo University, Seosan, South Korea
Laboratory of Coherent Optics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Laboratory for Nonlinear Optics and Spectroscopy, Siberian Federal University, Krasnoyarsk, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Department of Photonics and Laser Technologies, Siberian Federal University, Krasnoyarsk, Russian Federation
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, Russian Federation
Functional Electronics Laboratory, Tomsk State University, Tomsk, Russian Federation
Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk, Russian Federation
Institute of Chemistry, Tyumen State University, Tyumen, Russian Federation

Доп.точки доступа:
Lim, C. S.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Ikonnikov, D. A.; Atuchin, V. V.

    The anisotropic thermal expansion of non-linear optical crystal BaAlBO3F2 below room temperature
/ X. X. Jiang [et al.] // Front. Chem. - 2018. - Vol. 6. - Ст. 252, DOI 10.3389/fchem.2018.00252. - Cited References: 31. - This work was supported by the National Scientific Foundations of China (Grants 11474292, 51702330, 11611530680, 91622118, and 91622124), Russian Foundation for Basic Research (Grant 17-52-53031), the Special Foundation of the Director of Technical Institute of Physics and Chemistry (TIPC) and the Youth Innovation Promotion Association, CAS (outstanding member for ZL and Grant 2017035 for XJ). . - ISSN 2296-2646
   Перевод заглавия: Анизотропное тепловое расширение ниже комнатной температуры нелинейнооптического кристалла BaAlBO3F2
РУБ Chemistry, Multidisciplinary

Аннотация: Thermal expansion is a crucial factor for the performance of laser devices, since the induced thermal stress by laser irradiation would strongly affect the optical beam quality. For BaAlBO3F2 (BABF), a good non-linear optical (NLO) crystal, due to the highly anisotropic thermal expansion its practical applications are strongly affected by the “tearing” stress with the presence of local overheating area around the laser spot. Recently, the strategy to place the optical crystals in low-temperature environment to alleviate the influence of the thermal effect has been proposed. In order to understand the prospect of BABF for this application, in this work, we investigated its thermal expansion behavior below room temperature. The variable-temperature XRD showed that the ratio of thermal expansion coefficient between along c- and along a(b)- axis is high as 4.5:1 in BABF. The Raman spectrum combined with first-principles phonon analysis revealed that this high thermal expansion anisotropy mainly ascribe to progressive stimulation of the respective vibration phonon modes related with the thermal expansion along a(b)- and c-axis. The good NLO performance in BABF can be kept below room temperature. The work presented in this paper provides an in-depth sight into the thermal expansion behavior in BABF, which, we believe, would has significant implication to the manipulation in atomic scale on the thermal expansion of the materials adopted in strong-field optical facility.

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Держатели документа:
Chinese Acad Sci, Tech Inst Phys & Chem, Beijing, Peoples R China.
Univ Chinese Acad Sci, Beijing, Peoples R China.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk, Russia.
Siberian Fed Univ, Dept Engn Phys & Radioelect, Krasnoyarsk, Russia.
Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Cryogen, Beijing, Peoples R China.
Tianjin Univ Technol, Inst Funct Crystals, Tianjin, Peoples R China.

Доп.точки доступа:
Jiang, Xingxing; Wang, Naizheng; Molokeev, M. S.; Молокеев, Максим Сергеевич; Wang, Wei; Guo, Shibin; Huang, Rongjin; Li, Laifeng; Hu, Zhanggui; Lin, Zheshuai

    Synthesis and magnetic property features of La-Sr-Mn-O manganite polycrystaline
/ K. P. Polyakova [et al.] // Workshop "Trends in Nanomechanics and Nanoengineering" : book of abstracts / предс. сем. K. S. Aleksandrov ; зам. предс. сем.: G. S. Patrin, S. G. Ovchinnikov ; чл. лок. ком.: N. N. Kosyrev, A. S. Fedorov [et al]. - 2009. - P. 32


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Доп.точки доступа:
Aleksandrov, K. S. \предс. сем.\; Александров, Кирилл Сергеевич; Patrin, G. S. \зам. предс. сем.\; Патрин, Геннадий Семёнович; Ovchinnikov, S. G. \зам. предс. сем.\; Овчинников, Сергей Геннадьевич; Kosyrev, N. N. \чл. лок. ком.\; Косырев, Николай Николаевич; Fedorov, A. S. \чл. лок. ком.\; Федоров, Александр Семенович; Polyakova, K. P.; Полякова, Клавдия Павловна; Patrin, G. S.; Patrusheva, T. N.; Патрушева, Тамара Николаевна; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Volkov, N. V.; Волков, Никита Валентинович; Patrin, K. G.; Klabukov, A.A.; "Trends in Nanomechanics and Nanoengineering", workshop(2009 ; Aug. ; 24-28 ; Krasnoyarsk); Сибирский федеральный университет; Институт физики им. Л.В. Киренского Сибирского отделения РАН

    Anomalous mechanical materials squeezing three-dimensional volume compressibility into one dimension
/ X. Jiang, M. S. Molokeev, L. Dong [et al.] // Nat. Commun. - 2020. - Vol. 11, Is. 1. - Ст. 5593, DOI 10.1038/s41467-020-19219-5. - Cited References: 49. - The authors acknowledge Zhuohong Yin for useful discussions and the experimental time provided by the 4W2 beam line of Beijing Synchrotron Radiation Facility (BSRF). This work was supported by the National Scientific Foundations of China (Grants 51702330, 11974360, 51872297, 51890864, 21975132, and 21991143), the Youth Innovation Promotion Association in CAS (Grant 2017035 for X.J.), Young Elite Scientist Sponsorship Program by CAST (YESS), and Fujian Institute of Innovation (FJCXY18010201) in CAS . - ISSN 2041-1723
   Перевод заглавия: Аномальные механические материалы, преобразующие трехмерную объемную сжимаемость в одномерную
Аннотация: Anomalous mechanical materials, with counterintuitive stress-strain responding behaviors, have emerged as novel type of functional materials with highly enhanced performances. Here we demonstrate that the materials with coexisting negative, zero and positive linear compressibilities can squeeze three-dimensional volume compressibility into one dimension, and provide a general and effective way to precisely stabilize the transmission processes under high pressure. We propose a “corrugated-graphite-like” structural model and discover lithium metaborate (LiBO2) to be the first material with such a mechanical behavior. The capability to keep the flux density stability under pressure in LiBO2 is at least two orders higher than that in conventional materials. Our study opens a way to the design and search of ultrastable transmission materials under extreme conditions.

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Держатели документа:
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, 660036, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Wuhan National Laboratory for Optoelectronics and School of Physics, Huazhong University of Science and Technology, Wuhan, 430074, China
Laboratory of Space Astronomy and Technology, National Astronomical Observatories, Chinese Academy of Sciences, Beijing, 100101, China
University of Chinese Academy of Sciences, Beijing, 100049, China
Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100049, China
Institute of Deep-sea Science and Engineering, Chinese Academy of Sciences, Sanya, 572000, China
Institute of Mechanics, Chinese Academy of Sciences, Beijing, 100190, China
School of Materials Science and Engineering; TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350, China

Доп.точки доступа:
Jiang, X.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Dong, L.; Dong, Z.; Wang, N.; Kang, L.; Li, X.; Li, Y.; Tian, C.; Peng, S.; Li, W.; Lin, Z.

    Regularities of the property changes in the compounds EuLnCuS3 (Ln = La-Lu)
/ A. V. Ruseikina, V. A. Chernyshev, D. A. Velikanov [et al.] // J. Alloys Compd. - 2021. - Vol. 874. - Ст. 159968, DOI 10.1016/j.jallcom.2021.159968. - Cited References: 102. - The work was supported by the Ministry of Science and Higher Education of the Russian Federation under Project No. FEUZ-2020-0054 ; by the " YMNIK " program research project No. 14977GY/2019; by the Ministry of Science and Higher Education of the Russian Federation under project RFMEFI59420X0019 . - ISSN 0925-8388

Кл.слова (ненормированные):
Inorganic materials -- Ab initio calculations -- Thermochemistry -- Magnetic measurements -- Microhardness -- Lattice dynamics

Аннотация: This work contains the results of complex experimental research of the compounds EuLnCuS3 (Ln = La-Lu) enhanced by the DFT calculations. It is aimed at the data replenishment with particular attention to the revelation of regularities in the property changes, in order to extend the potential applicability of the materials of the selected chemical class. The ab initio calculations of the fundamental vibrational modes of the crystal structures were in good agreement with experimental results. The wavenumbers and types of the modes were determined, and the degree of the ion participation in the modes was also estimated. The elastic properties of the compounds were calculated. The compounds were found out to be IR-transparent in the range of 4000–400 cm–1. The estimated microhardness of the compounds is in the range of 2.68–3.60 GPa. According to the DSC data, the reversible polymorphous transitions were manifested in the compounds EuLnCuS3 (Ln = Sm, Gd-Lu): for EuSmCuS3 Tα↔β = 1437 K, ΔНα↔β = 7.0 kJ·mol-1, Tβ↔γ = 1453 K, ΔНβ↔γ = 2.6 kJ·mol-1; for EuTbCuS3 Tα↔β = 1478 K, ΔНα↔β = 1.6 kJ·mol-1, Tβ↔γ = 1516 K, ΔНβ↔γ = 0.9 kJ·mol-1, Tγ↔δ = 1548 K, ΔНγ↔δ = 1.6 kJ·mol-1; for EuTmCuS3 Tα↔β = 1543 K, Tβ↔γ = 1593 K, Tγ↔δ = 1620 K; for EuYbCuS3 Tα↔β = 1513 K, Tβ↔γ = 1564 K, Tγ↔δ = 1594 K; for EuLuCuS3 Tα↔β = 1549 K, Tβ↔γ = 1601 K, Tγ↔δ = 1628 K. In the EuLnCuS3 series, the transition into either ferro- or ferrimagnetic states occurred in the narrow temperature range from 2 to 5 K. The tetrad effect in the changes of incongruent melting temperature and microhardness conditioned on rLn3+ as well as influencing of phenomenon of crystallochemical contraction were observed. For delimiting between space groups Cmcm and Pnma in the compounds ALnCuS3, the use of the tolerance factor t’ = IR(A)·IR(C) + a×IR(B)2 was verified.

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Держатели документа:
Institute of Chemistry, University of Tyumen, Tyumen, 625003, Russian Federation
Institute of Natural Sciences and Mathematics, Ural Federal University, Ekaterinburg, 620002, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660079, Russian Federation
Institute of Physics and Technology, University of Tyumen, Tyumen, 625003, Russian Federation
Engineering Centre of Composite Materials Based on Wolfram Compounds and Rare-earth Elements, University of Tyumen, Tyumen, 625003, Russian Federation
Institute of Chemistry and Chemical Technology, Federal Research Center KSC SB RAS, Krasnoyarsk, 660049, Russian Federation
University of Tyumen, Tyumen, 625003, Russian Federation

Доп.точки доступа:
Ruseikina, A. V.; Chernyshev, V. A.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Shestakov, N. P.; Шестаков, Николай Петрович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Grigoriev, M. V.; Andreev, O. V.; Garmonov, A. A.; Matigorov, A. V.; Melnikova, L. V.; Kislitsyn, A. A.; Volkova, S. S.

    Effect of crystal size on the crystalline structure and magnetic properties of cobalt films obtained via chemical deposition
/ A. V. Chzhan, S. A. Podorozhnyak, S. A. Gromilov [et al.] // Bull. Russ. Acad. Sci. Phys. - 2022. - Vol. 86, Is. 5. - P. 614-617, DOI 10.3103/S1062873822050045. - Cited References: 18 . - ISSN 1062-8738
Аннотация: A study is performed of the relationship between the sizes of cobalt crystallites and the coercive and anisotropic properties of Co–P films obtained via chemical deposition. The emergence of induced anisotropy in films obtained at low pH (7.2–8.7) is due to size effects that transform the cobalt’s crystal lattice from face-centered cubic to hexagonal close-packed as the film grows in a magnetic field.

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Держатели документа:
Krasnoyarsk State Agrarian University, Krasnoyarsk, 660049, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russian Federation
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Irkutsk State Transport University, Krasnoyarsk, 660028, Russian Federation

Доп.точки доступа:
Chzhan, A. V.; Podorozhnyak, S. A.; Gromilov, S. A.; Patrin, G. S.; Патрин, Геннадий Семёнович; Moroz, J. M.

    Degenerate bound states in the continuum in square and triangular open acoustic resonators
/ A. Sadreev, E. Bulgakov, A. Pilipchuk [et al.] // Phys. Rev. B. - 2022. - Vol. 106, Is. 8. - Ст. 085404, DOI 10.1103/PhysRevB.106.085404. - Cited References: 43 . - ISSN 2469-9950

Кл.слова (ненормированные):
Q factor measurement -- Bound-states -- Eigenstates -- Flow byes -- High Q factor -- Output flow -- Property -- Small perturbations -- Square resonators -- Triangular resonators -- Acoustic resonators

Аннотация: We consider square and equilateral triangular open acoustic resonators with the C4v and C3v symmetries, respectively. There is a unique property of square and triangular resonators of accidental number fourfold degeneracy of eigenstates that gives rise to twofold-degenerate Friedrich-Wintgen (FW) bound states in the continuum (BICs). Compared to usual FW BICs, the degenerate FW BICs maintain high Q factor in wide range of the size of resonators. That removes the fabrication difficulties of the proper choice of resonator. The presence of degenerate BICs in triangular resonators is extremely sensitive to switch output flows by small perturbations with 100% efficiency.

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Держатели документа:
Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
School of Engineering and Information Technology, University of New South Wales Canberra, Northcott Drive, AC2600, Australia

Доп.точки доступа:
Sadreev, A. F.; Садреев, Алмаз Фаттахович; Bulgakov, E. N.; Булгаков, Евгений Николаевич; Pilipchuk, A. S.; Пилипчук, Артем Сергеевич; Miroshnichenko, A.; Huang, L.

    Chemistry of vinylidene complexes—XXVII—new µ-vinylidene MnPt complexes with platinum-coordinated 1-adamantyl isocyanide ligand: spectroscopic, structural and electrochemical study
/ V. V. Verpekin, O. S. Chudin, A. A. Kondrasenko [et al.] // Transition Met. Chem. - 2022. - Vol. 47. Is. 7-8. - P. 283-292, DOI 10.1007/s11243-022-00511-w. - Cited References: 46. - This work was conducted within the framework of the budget project 0287–2021-0012 for Institute of Chemistry and Chemical Technology SB RAS . - ISSN 0340-4285
Аннотация: New binuclear MnPt µ-vinylidene complexes Cp(CO)2Mn(µ-C=CHPh)Pt(CN–Ad)(L) [L=PPh3 (1a), P(OPri)3 (2a)] bearing a terminal platinum-coordinated 1-adamantyl isocyanide ligand were prepared by the treatment of Cp(CO)2Mn(µ-C=CHPh)Pt(CO)(L) [L=PPh3 (1b), P(OPri)3 (2b)] with CN-Ad. At the same time the reaction between Cp(CO)2Mn(µ-C=CHPh)Pt(L)2 [L=PPh3 (1c), P(OPri)3 (2c)] and CN-Ad did not proceed. The new complexes were characterized by IR and 1H, 13C, 31P NMR spectroscopy. The molecular structure of Cp(CO)2Mn(µ-C=CHPh)Pt(CN–Ad)[P(OPri)3] (2a) was determined by an X-ray diffraction study. The redox properties of the new complexes and their reactions of chemical oxidation were studied. An influence of the platinum-coordinated 1-adamantyl isocyanide ligand on the properties of the synthesized µ-vinylidene compounds 1a and 2a was revealed.

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Держатели документа:
Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, Akademgorodok, 50-24, Krasnoyarsk, 660036, Russian Federation
Institute of Physics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, Akademgorodok, 50-38, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Svobodny Prospect, 79, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Verpekin, V. V.; Chudin, O. S.; Kondrasenko, A. A.; Burmakina, G. V.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Zimonin, D. V.; Rubaylo, A. I.

    Synthesis and magnetic property feature of La0.7Sr0.3MnO3 manganite polycrystalline
/ Patrin G.S., Polyakova K.P., Patrusheva T.N., Velikanov D.A., Volkov N.V., Balaev D.A., Patrin K.G., Klabukov A.A. // III Байкальская международная конференция, Иркутск, 2008, C. 79



Доп.точки доступа:
Patrin, G. S.; Патрин, Геннадий Семёнович; Polyakova, K. P.; Полякова, Клавдия Павловна; Patrusheva, T. N.; Патрушева, Тамара Николаевна; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Volkov, N. V.; Волков, Никита Валентинович; Balaev, D. A.; Балаев, Дмитрий Александрович; Patrin, K. G.; Патрин, Константин Геннадьевич; Klabukov, A. A.

    Amino-bridged attapulgite@perovskite nanocomposites: The role of bridge linkage to optical property and stability
/ L. Qiu, M. Guan, W. Wang [et al.] // Inorg. Chem. Front. - 2023. - Vol. 10, Is. 16. - P. 4797-4807, DOI 10.1039/D3QI00863K. - Cited References: 50. - This work was supported by the National Natural Science Foundation of China (Grant Nos. 52072349 and 52172162). Z.D. acknowledges support from the Fundamental Research Funds for the Central Universities, China University of Geosciences (Wuhan) (No. 162301202610), the Natural Science Foundation of Guangdong Province (2022A1515012145), Shenzhen Science and Technology Program (JCYJ20220530162403007), and Key Research and Development Plan of Hubei Province. G.L. acknowledges support from the Natural Science Foundation of Zhejiang Province (LR22E020004). M.S. Molokeev and S.P. Polyutov acknowledge the support by the Ministry of Science and High Education of Russian Federation (Project No. FSRZ2023-0006) . - ISSN 2052-1553
   Перевод заглавия: Аминомостиковые нанокомпозиты аттапульгит@перовскит: роль мостиковой связи в их оптических свойствах и стабильности

Аннотация: Perovskite-based nanocomposites have garnered significant interests due to their potential in interfacial engineering, optical modification, and stability enhancement. However, current understanding of the construction models between perovskites and guest materials is limited, and the design concept of perovskite-based nanocomposites remains unclear. Herein, we thoroughly investigate the effects of amino bridge linkage in attapulgite@perovskite nanocomposites on the crystallization kinetics, optical properties, and stabilities of perovskites by monitoring the difference in structural, compositional, and morphological characteristics. The attapulgite@perovskite nanocomposite with amino bridge linkage exhibited a smaller average size distribution of 23.8 ± 5.8 nm, along with enhanced thermal stability (81% relative PL intensity after a heating-cooling cycle) and photo-stability (84% relative PL intensity after 30 h ultraviolet light irradiation). These improvements can be attributed to the adequate passivation of amino bridge linkages. Our work aims to provide a deeper understanding of perovskite-based nanocomposite construction and inspire new approaches for modifying their optical properties and enhancing their stability.

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Держатели документа:
Faculty of Materials Science and Chemistry, China University of Geosciences, 388 Lumo Road, Wuhan 430074, P. R. China.
Zhejiang Institute, China University of Geosciences, Hangzhou 311305, P. R. China.
Shenzhen Institute, China University of Geosciences, Shenzhen, 518052, P. R. China.
International Research Center of Spectroscopy and Quantum Chemistry — IRC SQC, Siberian Federal University, Krasnoyarsk, 660041, Russia.
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Qiu, Lei; Guan, Mengyu; Wang, Wei; Molokeev, M. S.; Молокеев, Максим Сергеевич; Polyutov, Sergey; Dai, Zhigao; Li, Guogang

    Phase transitions and nonlinear optical property modifications in BaGa4Se7
/ L. Isaenko, L. Dong, S. V. Melnikova [et al.] // Inorg. Chem. - 2024. - Vol. 63, Is. 21. - P. 10042-10049, DOI 10.1021/acs.inorgchem.4c01341. - Cited References: 27. - This work was supported by the National Natural Science Foundation of China, grant no. 22133004 (first-principles studies), the Ministry of Education and Science of the Russian Federation, grant FSUS-2020-0036 (crystal growth, crystal structure analysis, and band gap measurement), and partly done on the state assignment of IGM SB RAS no. 122041400031-2 (composition chemical analysis and SHG coefficient measurements) . - ISSN 0020-1669. - ISSN 1520-510X

Аннотация: Phase transitions can change the crystal structure and modify the physical properties of crystals. In this work, we investigate the phase transition behavior in BaGa4Se7, an important middle infrared (mid-IR) nonlinear optical (NLO) crystal, in the temperature range from room temperature to 1173 K. Interestingly, the BaGa4Se7 crystal undergoes a reversible ferroelastic phase transition at T = 528 K, resulting in the presence of a newly discovered phase (γ-phase) at the higher temperature. The experimental temperature dependence of optical birefringence, as well as the first-principles birefringence and NLO coefficients, reveals that the γ-phase exhibits larger birefringence and better NLO properties compared with those of the low-temperature phase (α-phase). This work demonstrates that phase-transition-induced structural modification can improve the mid-IR NLO properties, which would provide an effective avenue to obtain materials with good optoelectronic performance.

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Держатели документа:
Sobolev Institute of Geology and Mineralogy SB RAS, Novosibirsk State University, Novosibirsk 630090, Russia
Functional Crystals Lab, Technical Institute of Physics and Chemistry, CAS, University of Chinese Academy of Sciences, Beijing 100190, China
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
Department of Physics, Far Eastern State Transport University, Khabarovsk 680021, Russia
Kutateladze Institute of Thermophysics SB RAS, Novosibirsk 630090, Russia

Доп.точки доступа:
Isaenko, L.; Dong, L.; Melnikova, S. V.; Мельникова, Светлана Владимировна; Molokeev, M. S.; Молокеев, Максим Сергеевич; Korzhneva, K. E.; Krinitsin, P. G.; Kurus, A. F.; Samoshkin, D. A.; Belousov, R. A.; Lin, Zh.