/ A. S. Krylov // J. Raman Spectrosc. - 2013. - Vol. 44, Is. 5. - P. 763-769DOI 10.1002/jrs.4263
. -
Аннотация: This paper reports Raman spectroscopy investigation of phase transitions in Rb2NaYF6 crystal. The experimental spectra were compared with the calculated one. The spectra were obtained in temperature range from 8 to 300 K. The Raman spectra shows anomalous temperature-dependent behavior at T1 = 154 and T2 = 122 K. Soft mode restoration has been found, which allows us to attribute first transition at 154 K to displacive type. Detailed analysis temperature dependencies of the line positions and widths have been performed. We found no effects of possible lattice disorder anywhere, except narrow (about 20 K) range above the T1 temperature. The Raman spectra of Rb2NaYF6 crystal have been obtained and analyzed under hydrostatic pressure up to 4.33 GPa (at T = 295 K). The high pressure experiment up to 4.33 GPa did not disclose any effects associated with phase transitions. The lattice vibration spectra were calculated up to 10 GPa. The calculation has been demonstrated that the Rb2NaYF6 does not undergo high pressure phase transition.
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Krylov, A. S.; Крылов, Александр Сергеевич; Vtyurin, A. N.; Втюрин, Александр Николаевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Voronov, V. N.; Воронов, Владимир Николаевич; Krylova, S. N.; Крылова, Светлана Николаевна
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Formation of ferromagnetic germanides by solid-state reactions in 20Ge/80Mn films
/ V. G. Myagkov [et al.] // Thin Solid Films. - 2014. - Vol. 552. - P. 86-91, DOI 10.1016/j.tsf.2013.12.029. - Cited References: 53
. - ISSN 0040-6090
РУБ Materials Science, Multidisciplinary + Materials Science, Coatings & Films + Physics, Applied + Physics, Condensed Matter
Аннотация: Solid state reactions between Ge and Mn films are systematically examined using X-ray diffraction, photoelectron spectroscopy, and magnetic and electrical measurements. The films have a nominal atomic ratio Ge:Mn = 20:80 and are investigated at temperatures from 50 to 500 °C. It is established that after annealing at ~ 120°C, the ferromagnetic Mn5Ge3 phase is the first phase to form at the 20Ge/80Mn interface. As the annealing temperature increases to 300°C, the weak magnetic Mn5Ge 2 + Mn3Ge phases simultaneously begin to grow and they become dominant at 400°C. Increasing the annealing temperature to 500°C leads to the formation of the ferromagnetic phase with a Curie temperature TC ~ 350-360 K and magnetization 14-25 kA/m at room temperature. The X-ray diffraction study of the samples shows the reflections from the Mn 5Ge3 phase, and the photoelectron spectra contain the oxygen and carbon peaks. The homogeneous distribution of oxygen and carbon over the sample thickness suggests that the increased Curie temperature and magnetization are related to the migration of C and O atoms into the Mn 5Ge3 lattice and the formation of the Nowotny phase Mn5Ge3CxOy. The initiation temperature (~ 120 C) is the same in the Mn5Ge3 phase with the solid-state reactions in the Ge/Mn films as well as in the phase separation in the GexMn1 - x diluted semiconductors. Thus, we conclude that the synthesis of the Mn5Ge3 phase is the moving force for the spinodal decomposition of the GexMn 1 - x diluted semiconductors.
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
Reshetnev Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660049, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Доп.точки доступа:
Myagkov, V. G.; Мягков, Виктор Григорьевич; Zhigalov, V. S.; Жигалов, Виктор Степанович; Matsynin, A. A.; Мацынин, Алексей Александрович; Bykova, L. E.; Быкова, Людмила Евгеньевна; Mikhlin, Y. L.; Bondarenko, G. N.; Бондаренко, Галина Николаевна; Patrin, G. S.; Патрин, Геннадий Семёнович; Yurkin, G. Yu.; Юркин, Глеб Юрьевич
Рубрики:
PHASE-FORMATION
MAGNETIC-PROPERTIES
Mn5Ge3 FILMS
X-RAY
Ge(111)
TRANSFORMATIONS
DIFFUSION
SPECTRA
SYSTEM
LAYERS
Кл.слова (ненормированные):
Manganite-germanium -- Solid state reaction -- First phase -- Mn5Ge3 alloy -- Carbon impurity -- Oxygen impurity -- Annealing -- Magnetic anisotropy
PHASE-FORMATION
MAGNETIC-PROPERTIES
Mn5Ge3 FILMS
X-RAY
Ge(111)
TRANSFORMATIONS
DIFFUSION
SPECTRA
SYSTEM
LAYERS
Кл.слова (ненормированные):
Manganite-germanium -- Solid state reaction -- First phase -- Mn5Ge3 alloy -- Carbon impurity -- Oxygen impurity -- Annealing -- Magnetic anisotropy
Аннотация: Solid state reactions between Ge and Mn films are systematically examined using X-ray diffraction, photoelectron spectroscopy, and magnetic and electrical measurements. The films have a nominal atomic ratio Ge:Mn = 20:80 and are investigated at temperatures from 50 to 500 °C. It is established that after annealing at ~ 120°C, the ferromagnetic Mn5Ge3 phase is the first phase to form at the 20Ge/80Mn interface. As the annealing temperature increases to 300°C, the weak magnetic Mn5Ge 2 + Mn3Ge phases simultaneously begin to grow and they become dominant at 400°C. Increasing the annealing temperature to 500°C leads to the formation of the ferromagnetic phase with a Curie temperature TC ~ 350-360 K and magnetization 14-25 kA/m at room temperature. The X-ray diffraction study of the samples shows the reflections from the Mn 5Ge3 phase, and the photoelectron spectra contain the oxygen and carbon peaks. The homogeneous distribution of oxygen and carbon over the sample thickness suggests that the increased Curie temperature and magnetization are related to the migration of C and O atoms into the Mn 5Ge3 lattice and the formation of the Nowotny phase Mn5Ge3CxOy. The initiation temperature (~ 120 C) is the same in the Mn5Ge3 phase with the solid-state reactions in the Ge/Mn films as well as in the phase separation in the GexMn1 - x diluted semiconductors. Thus, we conclude that the synthesis of the Mn5Ge3 phase is the moving force for the spinodal decomposition of the GexMn 1 - x diluted semiconductors.
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
Reshetnev Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660049, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Доп.точки доступа:
Myagkov, V. G.; Мягков, Виктор Григорьевич; Zhigalov, V. S.; Жигалов, Виктор Степанович; Matsynin, A. A.; Мацынин, Алексей Александрович; Bykova, L. E.; Быкова, Людмила Евгеньевна; Mikhlin, Y. L.; Bondarenko, G. N.; Бондаренко, Галина Николаевна; Patrin, G. S.; Патрин, Геннадий Семёнович; Yurkin, G. Yu.; Юркин, Глеб Юрьевич
Pseudo-proper ferroelectric phase transitions in oxyfluoride K3WO3F3
/ M. P. Ivliev [и др.] // Phase Transit. - 2014. - Vol. 87, Is. 6. - P. 592-602, DOI 10.1080/01411594.2013.878026. - Cited References: 14. - This study was supported by the of the President of the Russian Federation for the Support of Leading Scientific Schools [Grant NSh-924.2014.2].
. - ISSN 0141-1594. - ISSN 1029-0338
Перевод заглавия: "Псевдособственный" сегнетоэлектрический фазовый переход в оксифториде K3WO3F3
Рубрики:
TRANSFORMATIONS
(NH4)(3)MOO3F3
(NH4)(3)WO3F3
CS
Кл.слова (ненормированные):
phase transition -- statistical mechanics -- order-disorder -- ferroelectric -- TRANSFORMATIONS -- (NH4)(3)MOO3F3 -- (NH4)(3)WO3F3 -- CS
Аннотация: Based on the structural data on the phases of cryolite (ordered perovskite) K3WO3F3, we develop a statistical model, which allows to describe the sequence of phase transitions observed in this compound using a unified approach. According to the model, the crystal possesses two structural subsystems: the K cations located in the octahedral positions and the WO3F3 octahedra in positions alternating with K cations. In the symmetric (cubic) phase, each subsystem can be found in one of the eight states. At decreasing temperature, an orientational phase transition in the subsystem of octahedra occurs first, followed by a phase transition to the low-temperature phase, caused by the loss of stability with respect to the ordering in the K cation subsystem. We find that the electric polarization occurs as pseudoproper and discuss the mechanisms of formation of the phase states.
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Держатели документа:
Southern Fed Univ, Inst Phys Res, Rostov Na Donu, Russia
Siberian Fed Univ, Inst Phys Engn & Radioelect, Krasnoyarsk, Russia
Siberian Dept RAS, Kirensky Inst Phys, Krasnoyarsk, Russia
Доп.точки доступа:
Ivliev, M. P.; Misyul, S. V.; Мисюль, Сергей Валентинович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Sakhnenko, V. P.
Перевод заглавия: "Псевдособственный" сегнетоэлектрический фазовый переход в оксифториде K3WO3F3
Рубрики:
TRANSFORMATIONS
(NH4)(3)MOO3F3
(NH4)(3)WO3F3
CS
Кл.слова (ненормированные):
phase transition -- statistical mechanics -- order-disorder -- ferroelectric -- TRANSFORMATIONS -- (NH4)(3)MOO3F3 -- (NH4)(3)WO3F3 -- CS
Аннотация: Based on the structural data on the phases of cryolite (ordered perovskite) K3WO3F3, we develop a statistical model, which allows to describe the sequence of phase transitions observed in this compound using a unified approach. According to the model, the crystal possesses two structural subsystems: the K cations located in the octahedral positions and the WO3F3 octahedra in positions alternating with K cations. In the symmetric (cubic) phase, each subsystem can be found in one of the eight states. At decreasing temperature, an orientational phase transition in the subsystem of octahedra occurs first, followed by a phase transition to the low-temperature phase, caused by the loss of stability with respect to the ordering in the K cation subsystem. We find that the electric polarization occurs as pseudoproper and discuss the mechanisms of formation of the phase states.
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Держатели документа:
Southern Fed Univ, Inst Phys Res, Rostov Na Donu, Russia
Siberian Fed Univ, Inst Phys Engn & Radioelect, Krasnoyarsk, Russia
Siberian Dept RAS, Kirensky Inst Phys, Krasnoyarsk, Russia
Доп.точки доступа:
Ivliev, M. P.; Misyul, S. V.; Мисюль, Сергей Валентинович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Sakhnenko, V. P.
Spin crossovers in Mott-Hubbard insulators at high pressures
/ I. S. Lyubutin, S. G. Ovchinnikov // J. Magn. Magn. Mater. - 2012. - Vol. 324, Is. 21. - P. 3538-3541, DOI 10.1016/j.jmmm.2012.02.084. - Cited References: 16. - We acknowledge the help and discussions with Drs. A.G. Gavriliuk, V.V. Struzkin and J.F. Lin. Supports by RFBR (Grants # 09-02-00171, 10-02-00251, # 11-02-00636, # 11-02-00291, # 11-02-12089) and by the RAS Program "Strongly correlated electronic systems" are acknowledged.
. - ISSN 0304-8853
РУБ Materials Science, Multidisciplinary + Physics, Condensed Matter
Аннотация: The high-pressure induced phase transitions initiated by electronic transition in 3d ions from the high-spin (HS) to the low-spin (LS) state (HS-LS spin-crossover) are considered. Behavior of the system with d(6) electronic configuration is investigated in the ground state of zero temperature and critical pressure P-c. Magnetic properties of the Mott-Hubbard insulator (Mg1-xFex)O are studied in the vicinity of the quantum critical point (T=0, P-c). At the critical pressure of spin crossover P-c, the spin gap energy epsilon(S) between HS and LS states is zero. The quantum spins fluctuations HS double left right arrow LS do not require any energy, and the antiferromagnetism is destroyed in the quantum critical point by the first order transition. (C) 2012 Published by Elsevier B.V.
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Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Moscow International Symposium on Magnetism(5 ; 2011 ; Aug. ; 21-25 ; Moscow)
Рубрики:
ELECTRONIC-TRANSITION
MAGNETIC COLLAPSE
PHASE-TRANSFORMATIONS
BIFEO3 CRYSTAL
METAL-OXIDES
METALLIZATION
Кл.слова (ненормированные):
Electronic structure -- Spin crossover -- High pressure -- Magnetic transition
ELECTRONIC-TRANSITION
MAGNETIC COLLAPSE
PHASE-TRANSFORMATIONS
BIFEO3 CRYSTAL
METAL-OXIDES
METALLIZATION
Кл.слова (ненормированные):
Electronic structure -- Spin crossover -- High pressure -- Magnetic transition
Аннотация: The high-pressure induced phase transitions initiated by electronic transition in 3d ions from the high-spin (HS) to the low-spin (LS) state (HS-LS spin-crossover) are considered. Behavior of the system with d(6) electronic configuration is investigated in the ground state of zero temperature and critical pressure P-c. Magnetic properties of the Mott-Hubbard insulator (Mg1-xFex)O are studied in the vicinity of the quantum critical point (T=0, P-c). At the critical pressure of spin crossover P-c, the spin gap energy epsilon(S) between HS and LS states is zero. The quantum spins fluctuations HS double left right arrow LS do not require any energy, and the antiferromagnetism is destroyed in the quantum critical point by the first order transition. (C) 2012 Published by Elsevier B.V.
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Доп.точки доступа:
Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Moscow International Symposium on Magnetism(5 ; 2011 ; Aug. ; 21-25 ; Moscow)
Electrical and dielectrical propeties of gas-sensor resistive type Bi2Sn2O7
/ L. V. Udod [et al.] // Solid State Phenom. : Selected, peer reviewed papers. - 2014. - Vol. 215: Trends in Magnetism: Nanomagnetism (EASTMAG-2013). - P. 503-506, DOI 10.4028/www.scientific.net/SSP.215.503. - Cited References: 14. - This work was supported by the Russian Foundation for Basic Research projects no. 12-02-00125-а
. - ISSN 978-30383. - ISSN 1662-9779
Перевод заглавия: Электрические и диэлектрические свойства резистивного типа газовых сенсоров на основе Bi2Sn2O7
Кл.слова (ненормированные):
crystallographic structure -- polymorphic transformations -- electrical resistivity -- dielectric permeability
Аннотация: Polycrystalline samples of Bi2Sn2O7 have been synthesized by conventional solid-state reaction method. According to the X-ray powder diffraction research, our sample co-existing of two polymorphs phases: cubic and rhombic, concurrently. The real dielectric permeability Re (ε) monotonic grows versus temperature and the imaginary dielectric permeability Im (ε) nonmonotonic is increased at the heating. There are maxima at Т=450 K on both temperature dependences Im (ε) and Re (ε) reveal. Anomalies in the temperature dependence of electrical resistivity at temperatures are found and to be correlated with the α → β structural phase transition temperature.
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Доп.точки доступа:
Ovchinnikov, S. G. \ed.\; Овчинников, Сергей Геннадьевич; Samardak, A. \ed.\; Udod, L. V.; Удод, Любовь Викторовна; Sitnicov, M. N.; Aplesnin, S. S.; Аплеснин, Сергей Степанович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism(5 ; 2013 ; sept. ; 15-21 ; Vladivostok)
Перевод заглавия: Электрические и диэлектрические свойства резистивного типа газовых сенсоров на основе Bi2Sn2O7
Кл.слова (ненормированные):
crystallographic structure -- polymorphic transformations -- electrical resistivity -- dielectric permeability
Аннотация: Polycrystalline samples of Bi2Sn2O7 have been synthesized by conventional solid-state reaction method. According to the X-ray powder diffraction research, our sample co-existing of two polymorphs phases: cubic and rhombic, concurrently. The real dielectric permeability Re (ε) monotonic grows versus temperature and the imaginary dielectric permeability Im (ε) nonmonotonic is increased at the heating. There are maxima at Т=450 K on both temperature dependences Im (ε) and Re (ε) reveal. Anomalies in the temperature dependence of electrical resistivity at temperatures are found and to be correlated with the α → β structural phase transition temperature.
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Доп.точки доступа:
Ovchinnikov, S. G. \ed.\; Овчинников, Сергей Геннадьевич; Samardak, A. \ed.\; Udod, L. V.; Удод, Любовь Викторовна; Sitnicov, M. N.; Aplesnin, S. S.; Аплеснин, Сергей Степанович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism(5 ; 2013 ; sept. ; 15-21 ; Vladivostok)
Phase transformations in the Mn-Ge system and in Ge x Mn1-x diluted semiconductors
/ V. G. Myagkov [et al.] // JETP Letters. - 2012. - Vol. 96, Is. 1. - P. 40-43, DOI 10.1134/S0021364012130097. - Cited References: 36
. - ISSN 0021-3640
РУБ Physics, Multidisciplinary
Аннотация: Results of an X-ray diffraction study as well as magnetic and electrical measurements of the solid-state reactions in Ge/Mn polycrystalline films of an 80/20 atomic composition have been presented. It has been shown that the ferromagnetic Mn5Ge3 phase is formed first on the Ge/Mn interface after annealing at similar to 120A degrees C. The further increase in the annealing temperature to 300A degrees C leads to the beginning of the synthesis of the Mn11Ge8 phase, which becomes dominating at 400A degrees C. The existence of new structural transitions in the Mn-Ge system in the region of similar to 120 and similar to 300A degrees C has been predicted on the basis of the presented results and results obtained earlier when studying solid-state reactions in different film structures. The supposition about the general chemical mechanisms of the synthesis of the Mn5Ge3 and Mn11Ge8 phases during the solid-state reactions in the Ge/Mn films of the 80/20 atomic composition and the phase separation in Ge (x) Mn1 - x (x 0.95) diluted semiconductors has been substantiated.
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Держатели документа:
[Myagkov, V. G.
Zhigalov, V. S.
Matsynin, A. A.
Bykova, L. E.
Bondarenko, G. V.
Patrin, G. S.
Velikanov, D. A.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Myagkov, V. G.
Zhigalov, V. S.
Matsynin, A. A.] Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
[Bondarenko, G. N.] Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia
[Patrin, G. S.
Velikanov, D. A.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
Доп.точки доступа:
Myagkov, V. G.; Мягков, Виктор Григорьевич; Zhigalov, V. S.; Жигалов, Виктор Степанович; Matsynin, A. A.; Мацынин, Алексей Александрович; Bykova, L. E.; Быкова, Людмила Евгеньевна; Bondarenko, G. V.; Бондаренко, Геннадий Васильевич; Bondarenko, G. N.; Бондаренко, Галина Николаевна; Patrin, G. S.; Патрин, Геннадий Семёнович; Velikanov, D. A.; Великанов, Дмитрий Анатольевич
Аннотация: Results of an X-ray diffraction study as well as magnetic and electrical measurements of the solid-state reactions in Ge/Mn polycrystalline films of an 80/20 atomic composition have been presented. It has been shown that the ferromagnetic Mn5Ge3 phase is formed first on the Ge/Mn interface after annealing at similar to 120A degrees C. The further increase in the annealing temperature to 300A degrees C leads to the beginning of the synthesis of the Mn11Ge8 phase, which becomes dominating at 400A degrees C. The existence of new structural transitions in the Mn-Ge system in the region of similar to 120 and similar to 300A degrees C has been predicted on the basis of the presented results and results obtained earlier when studying solid-state reactions in different film structures. The supposition about the general chemical mechanisms of the synthesis of the Mn5Ge3 and Mn11Ge8 phases during the solid-state reactions in the Ge/Mn films of the 80/20 atomic composition and the phase separation in Ge (x) Mn1 - x (x 0.95) diluted semiconductors has been substantiated.
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Держатели документа:
[Myagkov, V. G.
Zhigalov, V. S.
Matsynin, A. A.
Bykova, L. E.
Bondarenko, G. V.
Patrin, G. S.
Velikanov, D. A.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Myagkov, V. G.
Zhigalov, V. S.
Matsynin, A. A.] Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
[Bondarenko, G. N.] Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia
[Patrin, G. S.
Velikanov, D. A.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
Доп.точки доступа:
Myagkov, V. G.; Мягков, Виктор Григорьевич; Zhigalov, V. S.; Жигалов, Виктор Степанович; Matsynin, A. A.; Мацынин, Алексей Александрович; Bykova, L. E.; Быкова, Людмила Евгеньевна; Bondarenko, G. V.; Бондаренко, Геннадий Васильевич; Bondarenko, G. N.; Бондаренко, Галина Николаевна; Patrin, G. S.; Патрин, Геннадий Семёнович; Velikanov, D. A.; Великанов, Дмитрий Анатольевич
Processes of ordering of structural elements, critical and noncritical parameters of phase transitions in the (NH4)3WO3F3 crystal
/ M. S. Molokeev, S. V. Misyul' // Phys. Solid State. - 2012. - Vol. 54, Is. 1. - P. 155-165, DOI 10.1134/S1063783412010222. - Cited References: 18. - This study was supported by the Russian Foundation for Basic Research (project no. 09-02-00062) and the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation (grant no. NSh-4645.2010.2).
. - ISSN 1063-7834. - ISSN 1090-6460
РУБ Physics, Condensed Matter
Аннотация: The structure of the low-temperature triclinic phase of the (NH4)3WO3F3 crystal has been determined and the structure of the cubic phase of this crystal has been refined from data of an X-ray diffraction experiment performed for a powder sample. The profile and structural parameters have been refined according to the procedure implemented in the DDM program. The results obtained have been discussed with invoking the group-theoretical analysis of the complete order parameter condensate, which takes into account the critical and noncritical atomic orderings and allows one to interpret the obtained experimental data. It has been found that the symmetry transformation in the crystal can be schematically represented in the following form: Fm3¯m(Z=4)→P1¯(Z=1)→P1¯(Z=6)Fm\bar 3m(Z = 4) \to P\bar 1(Z = 1) \to P\bar 1(Z = 6) . This transformation is accompanied by the complete ordering of WO3F3 polyhedra and the displacement of NH4 ions.
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Держатели документа:
[Molokeev, M. S.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Misyul', S. V.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
Доп.точки доступа:
Misyul', S. V.; Мисюль, Сергей Валентинович; Молокеев, Максим Сергеевич
Аннотация: The structure of the low-temperature triclinic phase of the (NH4)3WO3F3 crystal has been determined and the structure of the cubic phase of this crystal has been refined from data of an X-ray diffraction experiment performed for a powder sample. The profile and structural parameters have been refined according to the procedure implemented in the DDM program. The results obtained have been discussed with invoking the group-theoretical analysis of the complete order parameter condensate, which takes into account the critical and noncritical atomic orderings and allows one to interpret the obtained experimental data. It has been found that the symmetry transformation in the crystal can be schematically represented in the following form: Fm3¯m(Z=4)→P1¯(Z=1)→P1¯(Z=6)Fm\bar 3m(Z = 4) \to P\bar 1(Z = 1) \to P\bar 1(Z = 6) . This transformation is accompanied by the complete ordering of WO3F3 polyhedra and the displacement of NH4 ions.
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Держатели документа:
[Molokeev, M. S.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Misyul', S. V.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
Доп.точки доступа:
Misyul', S. V.; Мисюль, Сергей Валентинович; Молокеев, Максим Сергеевич
Structural changes during phase transitions and the critical and noncritical order parameters in the (NH4)3Nb(O2)2F4 crystal
/ M. S. Molokeev, S. V. Misyul' // Phys. Solid State. - 2012. - Vol. 54, Is. 1. - P. 143-154, DOI 10.1134/S1063783412010234. - Cited References: 17. - This study was supported by the Russian Foundation for Basic Research (project no. 09-02-00062) and the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation (grant no. NSh-4645.2010.2).
. - ISSN 1063-7834. - ISSN 1090-6460
РУБ Physics, Condensed Matter
Аннотация: The structures of two phases of the (NH4)3Nb(O2)2F4 crystal, namely, the parent cubic phase and the most distorted low-temperature phase, have been determined from data of an X-ray diffraction experiment performed for a powder sample. The profile and structural parameters have been refined according to the procedure implemented in the DDM program. The results obtained have been discussed with invoking the group-theoretical analysis of the complete order parameter condensate, which takes into account the critical and noncritical atomic displacements and allows the interpretation of the obtained experimental data. It has been found that the most probable sequence of structural transformations occurring in the crystal can be schematically represented in the following form: Fm3¯m−→−−−−(η1,η1,η)Γ+5(11−7)C2/m−→−−−−−−−−−−−−−−−−(η1,η1,η)(0,0,0,0,0,ξ,0−ξ,0,0,0,0)Γ+5(11−7)⊗Σ2(4−2)P21/m−→−−−−−−−−−−−−−−−−−−−−−−−−−−−−(η1,η1,η)(0,0,0,0,0,ξ,0−ξ,0,0,0,0)(0,0,0,0,0,ε,0,ε,0,0,0,0)Γ+5(11−7)⊗Σ2(4−2)⊗Σ3(4−3)P21/n.\begin{gathered} Fm\bar 3m\xrightarrow[{(\eta 1,\eta 1,\eta )}]{{\Gamma _5. + (11 - 7)}}C2/m\xrightarrow[{(\eta 1,\eta 1,\eta )(0,0,0,0,0,\xi ,0 - \xi ,0,0,0,0)}]{{\Gamma _5. + (11 - 7) \otimes \Sigma _2 (4 - 2)}}P2_1 /m \hfill \\ \xrightarrow[{(\eta 1,\eta 1,\eta )(0,0,0,0,0,\xi ,0 - \xi ,0,0,0,0)(0,0,0,0,0,\varepsilon ,0,\varepsilon ,0,0,0,0)}]{{\Gamma _5. + (11 - 7) \otimes \Sigma _2 (4 - 2) \otimes \Sigma _3 (4 - 3)}}P2_1 /n. \hfill \\ \end{gathered}
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[Molokeev, M. S.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Misyul', S. V.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
Доп.точки доступа:
Misyul', S. V.; Мисюль, Сергей Валентинович; Молокеев, Максим Сергеевич
Аннотация: The structures of two phases of the (NH4)3Nb(O2)2F4 crystal, namely, the parent cubic phase and the most distorted low-temperature phase, have been determined from data of an X-ray diffraction experiment performed for a powder sample. The profile and structural parameters have been refined according to the procedure implemented in the DDM program. The results obtained have been discussed with invoking the group-theoretical analysis of the complete order parameter condensate, which takes into account the critical and noncritical atomic displacements and allows the interpretation of the obtained experimental data. It has been found that the most probable sequence of structural transformations occurring in the crystal can be schematically represented in the following form: Fm3¯m−→−−−−(η1,η1,η)Γ+5(11−7)C2/m−→−−−−−−−−−−−−−−−−(η1,η1,η)(0,0,0,0,0,ξ,0−ξ,0,0,0,0)Γ+5(11−7)⊗Σ2(4−2)P21/m−→−−−−−−−−−−−−−−−−−−−−−−−−−−−−(η1,η1,η)(0,0,0,0,0,ξ,0−ξ,0,0,0,0)(0,0,0,0,0,ε,0,ε,0,0,0,0)Γ+5(11−7)⊗Σ2(4−2)⊗Σ3(4−3)P21/n.\begin{gathered} Fm\bar 3m\xrightarrow[{(\eta 1,\eta 1,\eta )}]{{\Gamma _5. + (11 - 7)}}C2/m\xrightarrow[{(\eta 1,\eta 1,\eta )(0,0,0,0,0,\xi ,0 - \xi ,0,0,0,0)}]{{\Gamma _5. + (11 - 7) \otimes \Sigma _2 (4 - 2)}}P2_1 /m \hfill \\ \xrightarrow[{(\eta 1,\eta 1,\eta )(0,0,0,0,0,\xi ,0 - \xi ,0,0,0,0)(0,0,0,0,0,\varepsilon ,0,\varepsilon ,0,0,0,0)}]{{\Gamma _5. + (11 - 7) \otimes \Sigma _2 (4 - 2) \otimes \Sigma _3 (4 - 3)}}P2_1 /n. \hfill \\ \end{gathered}
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[Molokeev, M. S.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Misyul', S. V.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
Доп.точки доступа:
Misyul', S. V.; Мисюль, Сергей Валентинович; Молокеев, Максим Сергеевич
Phase transformations of Fe3N-Fe4N iron nitrides at pressures up to 30 GPa studied by in situ X-ray diffractometry
/ K. D. Litasov [et al.] // JETP Letters. - 2014. - Vol. 98, Is. 12. - P. 805-808, DOI 10.1134/S0021364013250140. - Cited References: 23. - This work was supported by the Ministry of Education and Science of the Russian Federation (project nos. 14.B37.21.1261 and 14.B25.31.0032) and, in part, by the Siberian Branch, Russian Academy of Sciences (integration project no. 97 for 2012-2014). The experiments were performed in cooperation between the Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, and Tohoku University (Global Center of Excellence program "Advanced Science and Technology Center for the Dynamic Earth").
. - ISSN 0021-3640. - ISSN 1090-6487
РУБ Physics, Multidisciplinary
Аннотация: The parameters of the equation of state of the stable epsilon-Fe3Nx (where x = 0.8) nitride in the Fe-N system have been determined at pressures up to 30 GPa and temperatures up to 1273 K. The parameters V-0 = 81.48(2) angstrom(3), K-T = 162(3) GPa, K-T = 4.0 = 1.66(2), gamma(0) = 555 K, and q = 1 have been determined for epsilon-Fe3N0.8 by the approximation of the P V T data with the Vinet equation of state and the thermal parameters within the formalism. No anomalous change in the volume of the cell owing to possible magnetic transitions has been revealed. The instability of Fe4N at high pressures and Fe3N in the presence of a deficit of nitrogen in the system has been established. The stable phase in the temperature range of 300-673 K and the pressure range of 20-30 GPa is epsilon-Fe3N rather than epsilon-Fe3N0.8.
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Russian Acad Sci, Siberian Branch, Sobolev Inst Geol & Mineral, Novosibirsk 630090, Russia
Novosibirsk State Univ, Novosibirsk 630090, Russia
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Tohoku Univ, Grad Sch Sci, Dept Earth & Planetary Mat Sci, Sendai, Miyagi 9808578, Japan
Доп.точки доступа:
Litasov, K. D.; Shatskiy, A. F.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Popov, Z. I.; Попов, Захар Иванович; Ponomarev, D. S.; Ohtani, E.; Ministry of Education and Science of the Russian Federation [14.B37.21.1261, 14.B25.31.0032]; Siberian Branch, Russian Academy of Sciences [97]
Рубрики:
EQUATION-OF-STATE
MAGNETIC-PROPERTIES
EPSILON-Fe3N1+X
1ST-PRINCIPLES
DIFFRACTION
GAMMA-Fe4N
TRANSITION
Fe4N
EQUATION-OF-STATE
MAGNETIC-PROPERTIES
EPSILON-Fe3N1+X
1ST-PRINCIPLES
DIFFRACTION
GAMMA-Fe4N
TRANSITION
Fe4N
Аннотация: The parameters of the equation of state of the stable epsilon-Fe3Nx (where x = 0.8) nitride in the Fe-N system have been determined at pressures up to 30 GPa and temperatures up to 1273 K. The parameters V-0 = 81.48(2) angstrom(3), K-T = 162(3) GPa, K-T = 4.0 = 1.66(2), gamma(0) = 555 K, and q = 1 have been determined for epsilon-Fe3N0.8 by the approximation of the P V T data with the Vinet equation of state and the thermal parameters within the formalism. No anomalous change in the volume of the cell owing to possible magnetic transitions has been revealed. The instability of Fe4N at high pressures and Fe3N in the presence of a deficit of nitrogen in the system has been established. The stable phase in the temperature range of 300-673 K and the pressure range of 20-30 GPa is epsilon-Fe3N rather than epsilon-Fe3N0.8.
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Держатели документа:
Russian Acad Sci, Siberian Branch, Sobolev Inst Geol & Mineral, Novosibirsk 630090, Russia
Novosibirsk State Univ, Novosibirsk 630090, Russia
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Tohoku Univ, Grad Sch Sci, Dept Earth & Planetary Mat Sci, Sendai, Miyagi 9808578, Japan
Доп.точки доступа:
Litasov, K. D.; Shatskiy, A. F.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Popov, Z. I.; Попов, Захар Иванович; Ponomarev, D. S.; Ohtani, E.; Ministry of Education and Science of the Russian Federation [14.B37.21.1261, 14.B25.31.0032]; Siberian Branch, Russian Academy of Sciences [97]
Oxidation of Ag nanoparticles in aqueous media: Effect of particle size and capping
/ Y. L. Mikhlin [et al.] // Appl. Surf. Sci. - 2014. - Vol. 297. - P. 75-83, DOI 10.1016/j.apsusc.2014.01.081. - Cited References: 58. - This work was partially financially supported by the Ministry of Education and Science of RF (Grant 8580) and RFBR (12-03-31178).
. - ISSN 0169-4332. - ISSN 1873-5584
Перевод заглавия: Окисление наночастиц Ag в водной среде: Влияние размера частиц и оболочки.
РУБ Chemistry, Physical + Materials Science, Coatings & Films + Physics, Applied + Physics, Condensed Matter
Аннотация: Many applications and environmental impact of silver-bearing nanomaterials critically depend upon their specific reactivity, which is still poorly understood. Here, silver nanoparticles (Ag NPs) of about 3-5 nm and 10-12 nm in diameter, uncapped and capped with l-glucose or citrate, were prepared, characterized using UV-vis absorption spectroscopy, SAXS, TEM, and their (electro) chemical oxidation was examined in comparison with each other and bulk metal applying scanning tunneling microscopy and spectroscopy, cyclic voltammetry, and XPS. A resistive switching effect was found in the tunneling spectra measured in air at the smaller uncapped Ag NPs deposited on HOPG and was interpreted in terms of Ag transfer between the particle and the probe. The anodic oxidation of these Ag NPs in 1 M NaOH yielded 3D Ag2O, while only a layer of "primary"Ag(I) oxide emerged on larger uncapped nanoparticles during the potential sweep. The formation of AgO at higher potentials proceeded readily at the "primary"oxide but was retarded at the smaller NPs. The citrate- and glucose-capping substantially impeded the formation both of Ag2O and AgO. The findings highlighted, particularly, a non-trivial effect of particle size and transient mobilization of Ag species on the reactions of silver nanoparticles. (c) 2014 Elsevier B.V. All rights reserved.
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Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Доп.точки доступа:
Mikhlin, Y. L.; Vishnyakova, E. A.; Romanchenko, A. S.; Saikova, S. V.; Сайкова, С. В.; Likhatski, M. N.; Larichev, Y. V.; Tuzikov, F. V.; Zaikovskii, V. I.; Zharkov, S. M.; Жарков, Сергей Михайлович
Перевод заглавия: Окисление наночастиц Ag в водной среде: Влияние размера частиц и оболочки.
Рубрики:
EX-SITU XPS
POLYCRYSTALLINE SILVER ELECTRODES
RAY PHOTOELECTRON-SPECTROSCOPY
METAL NANOPARTICLES
ELECTROCHEMICAL OXIDATION
ABSORPTION SPECTROSCOPY
PYROLYTIC-GRAPHITE
OXYGEN-ADSORPTION
TRANSFORMATIONS
DISSOLUTION
Кл.слова (ненормированные):
Silver nanoparticles -- Oxidation -- Resistive switching effect -- X-ray photoelectron spectroscopy
EX-SITU XPS
POLYCRYSTALLINE SILVER ELECTRODES
RAY PHOTOELECTRON-SPECTROSCOPY
METAL NANOPARTICLES
ELECTROCHEMICAL OXIDATION
ABSORPTION SPECTROSCOPY
PYROLYTIC-GRAPHITE
OXYGEN-ADSORPTION
TRANSFORMATIONS
DISSOLUTION
Кл.слова (ненормированные):
Silver nanoparticles -- Oxidation -- Resistive switching effect -- X-ray photoelectron spectroscopy
Аннотация: Many applications and environmental impact of silver-bearing nanomaterials critically depend upon their specific reactivity, which is still poorly understood. Here, silver nanoparticles (Ag NPs) of about 3-5 nm and 10-12 nm in diameter, uncapped and capped with l-glucose or citrate, were prepared, characterized using UV-vis absorption spectroscopy, SAXS, TEM, and their (electro) chemical oxidation was examined in comparison with each other and bulk metal applying scanning tunneling microscopy and spectroscopy, cyclic voltammetry, and XPS. A resistive switching effect was found in the tunneling spectra measured in air at the smaller uncapped Ag NPs deposited on HOPG and was interpreted in terms of Ag transfer between the particle and the probe. The anodic oxidation of these Ag NPs in 1 M NaOH yielded 3D Ag2O, while only a layer of "primary"Ag(I) oxide emerged on larger uncapped nanoparticles during the potential sweep. The formation of AgO at higher potentials proceeded readily at the "primary"oxide but was retarded at the smaller NPs. The citrate- and glucose-capping substantially impeded the formation both of Ag2O and AgO. The findings highlighted, particularly, a non-trivial effect of particle size and transient mobilization of Ag species on the reactions of silver nanoparticles. (c) 2014 Elsevier B.V. All rights reserved.
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Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Доп.точки доступа:
Mikhlin, Y. L.; Vishnyakova, E. A.; Romanchenko, A. S.; Saikova, S. V.; Сайкова, С. В.; Likhatski, M. N.; Larichev, Y. V.; Tuzikov, F. V.; Zaikovskii, V. I.; Zharkov, S. M.; Жарков, Сергей Михайлович
Long-range chemical interactions in solid-state reactions: effect of an inert Ag interlayer on the formation of L10-FePd in epitaxial Pd(0 0 1)/Ag(0 0 1)/Fe(0 0 1) and Fe(0 0 1)/Ag(0 0 1)/Pd(0 0 1) trilayers
/ V. G. Myagkov [et al.] // Philos. Mag. - 2014. - Vol. 94, Is. 23. - P. 2595-2622, DOI 10.1080/14786435.2014.926037. - Cited References: 117
. - ISSN 1478-6435. - ISSN 1478-6443
РУБ Materials Science, Multidisciplinary + Mechanics + Metallurgy & Metallurgical Engineering + Physics, Applied + Physics, Condensed Matter
Аннотация: The effect of 0, 0.5, and 1 μm-thick Ag interlayers on the chemical interaction between Pd and Fe in epitaxial Pd(0 0 1)/Ag(0 0 1)/Fe(0 0 1)/MgO(0 0 1) and Fe(0 0 1)/Ag(0 0 1)/Pd(0 0 1)/MgO(0 0 1) trilayers has been studied using X-ray diffraction, 57Fe Mössbauer spectroscopy, X-ray photoelectron spectroscopy, and magnetic structural measurements. No mixing of Pd and Fe occurs via the chemically inert Ag layer at annealing temperatures up to 400 °C. As the annealing temperature is increased above 400 °C, a solid-state synthesis of an ordered L10-FePd phase begins in the Pd(0 0 1)/Ag(0 0 1)/Fe(0 0 1) and Fe(0 0 1)/Ag(0 0 1)/Pd(0 0 1) film trilayers regardless of the thickness of the buffer Ag layer. In all samples, annealing above 500 °C leads to the formation of a disordered FexPd1−x(0 0 1) phase; however, in samples lacking the Ag layer, the synthesis of FexPd1−x is preceded by the formation of an ordered L12-FePd3 phase. An analysis of the X-ray photoelectron spectroscopy results shows that Pd is the dominant moving species in the reaction between Pd and Fe. According to the preliminary results, the 2.2 μm-thick Ag film does not prevent the synthesis of the L10-FePd phase and only slightly increases the phase’s initiation temperature. Data showing the ultra-fast transport of Pd atoms via thick inert Ag layers are interpreted as direct evidence of the long-range character of the chemical interaction between Pd and Fe. Thus, in the reaction state, Pd and Fe interact chemically even though the distance between them is about 104 times greater than an ordinary chemical bond length.
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Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660049, Russia
Доп.точки доступа:
Myagkov, V. G.; Мягков, Виктор Григорьевич; Bayukov, O. A.; Баюков, Олег Артемьевич; Mikhlin, Y. L.; Михлин, Юрий Леонидович; Zhigalov, V. S.; Жигалов, Виктор Степанович; Bykova, L. E.; Быкова, Людмила Евгеньевна; Bondarenko, G. N.; Бондаренко, Галина Николаевна
Рубрики:
HIGH-TEMPERATURE SYNTHESIS
THIN-FILMS
PHASE-FORMATION
MAGNETIC-PROPERTIES
X-RAY
MARTENSITIC TRANSFORMATIONS
PHOTOELECTRON-SPECTROSCOPY
STRUCTURAL CHARACTERISTICS
CASIMIR FORCE
GOLD-FILMS
Кл.слова (ненормированные):
Fe-Pd system -- epitaxial thin film -- inert Ag buffer layer -- diffusion -- solid-state reactions -- L1(0) -- long-range chemical interactions
HIGH-TEMPERATURE SYNTHESIS
THIN-FILMS
PHASE-FORMATION
MAGNETIC-PROPERTIES
X-RAY
MARTENSITIC TRANSFORMATIONS
PHOTOELECTRON-SPECTROSCOPY
STRUCTURAL CHARACTERISTICS
CASIMIR FORCE
GOLD-FILMS
Кл.слова (ненормированные):
Fe-Pd system -- epitaxial thin film -- inert Ag buffer layer -- diffusion -- solid-state reactions -- L1(0) -- long-range chemical interactions
Аннотация: The effect of 0, 0.5, and 1 μm-thick Ag interlayers on the chemical interaction between Pd and Fe in epitaxial Pd(0 0 1)/Ag(0 0 1)/Fe(0 0 1)/MgO(0 0 1) and Fe(0 0 1)/Ag(0 0 1)/Pd(0 0 1)/MgO(0 0 1) trilayers has been studied using X-ray diffraction, 57Fe Mössbauer spectroscopy, X-ray photoelectron spectroscopy, and magnetic structural measurements. No mixing of Pd and Fe occurs via the chemically inert Ag layer at annealing temperatures up to 400 °C. As the annealing temperature is increased above 400 °C, a solid-state synthesis of an ordered L10-FePd phase begins in the Pd(0 0 1)/Ag(0 0 1)/Fe(0 0 1) and Fe(0 0 1)/Ag(0 0 1)/Pd(0 0 1) film trilayers regardless of the thickness of the buffer Ag layer. In all samples, annealing above 500 °C leads to the formation of a disordered FexPd1−x(0 0 1) phase; however, in samples lacking the Ag layer, the synthesis of FexPd1−x is preceded by the formation of an ordered L12-FePd3 phase. An analysis of the X-ray photoelectron spectroscopy results shows that Pd is the dominant moving species in the reaction between Pd and Fe. According to the preliminary results, the 2.2 μm-thick Ag film does not prevent the synthesis of the L10-FePd phase and only slightly increases the phase’s initiation temperature. Data showing the ultra-fast transport of Pd atoms via thick inert Ag layers are interpreted as direct evidence of the long-range character of the chemical interaction between Pd and Fe. Thus, in the reaction state, Pd and Fe interact chemically even though the distance between them is about 104 times greater than an ordinary chemical bond length.
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Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660049, Russia
Доп.точки доступа:
Myagkov, V. G.; Мягков, Виктор Григорьевич; Bayukov, O. A.; Баюков, Олег Артемьевич; Mikhlin, Y. L.; Михлин, Юрий Леонидович; Zhigalov, V. S.; Жигалов, Виктор Степанович; Bykova, L. E.; Быкова, Людмила Евгеньевна; Bondarenko, G. N.; Бондаренко, Галина Николаевна
Structure transformations during phase transitions in the K 3WO 3F 3 oxyfluoride
/ M. S. Molokeev [et al.] // Physics of the Solid State. - 2011. - Vol. 53, Is. 4. - P. 834-839, DOI 10.1134/S1063783411040251
. - ISSN 1063-7834
Аннотация: The structures of three phases of the K 3WO 3F 3 crystal have been determined from X-ray diffraction data obtained for a powder sample. The profile and structural parameters have been refined according to the technique implemented in the DDM program. The results obtained have been discussed using the group-theoretical analysis of the complete order parameter condensate, which takes into account the critical and noncritical atomic displacements and allows the interpretation of the experimental data. The sequence of structural transformations is found to be as follows. В© 2011 Pleiades Publishing, Ltd.
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Держатели документа:
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk 660041, Russian Federation
Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич; Misyul', S. V.; Мисюль, Сергей Валентинович; Fokina, V. D.; Фокина, Валентина Дмитриевна; Kocharova, A. G.; Кочарова, Алла Георгиевна; Aleksandrov, K. S.; Александров, Кирилл Сергеевич
Аннотация: The structures of three phases of the K 3WO 3F 3 crystal have been determined from X-ray diffraction data obtained for a powder sample. The profile and structural parameters have been refined according to the technique implemented in the DDM program. The results obtained have been discussed using the group-theoretical analysis of the complete order parameter condensate, which takes into account the critical and noncritical atomic displacements and allows the interpretation of the experimental data. The sequence of structural transformations is found to be as follows. В© 2011 Pleiades Publishing, Ltd.
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Держатели документа:
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk 660041, Russian Federation
Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич; Misyul', S. V.; Мисюль, Сергей Валентинович; Fokina, V. D.; Фокина, Валентина Дмитриевна; Kocharova, A. G.; Кочарова, Алла Георгиевна; Aleksandrov, K. S.; Александров, Кирилл Сергеевич
Structural transformations and phenomenological description of the formation of phase states in elpasolites Cs2RbDyF6 and Rb2KB′F6 (B′ = Ho, Dy, Tb)
/ I. N. Safonov [et al.] // Phys. Solid State. - 2015. - Vol. 57, Is. 3. - P. 491-498, DOI 10.1134/S1063783415030282. - Cited References:20. - This study was supported by the Ministry of Education and Science of the Russian Federation within the framework of the State Task for the Russian Siberian Federal University for Implementation of Scientific Research Work in 2014 (assignment no. 3.2534.2014/K).
. - ISSN 1063. - ISSN 1090-6460. -
РУБ Physics, Condensed Matter
Аннотация: The structures of the cubic and monoclinic phases of an Rb2KHoF6 crystal from a series of elpasolites Rb2KB′F6 (B′ = Ho, Dy, Tb), which undergoes a trigger phase transition, have been investigated using X-ray powder diffraction. The critical and noncritical displacements of atoms in the Rb2KHoF6 structure have been determined from the group-theoretical analysis of the complete condensate of order parameters. It has been reliably established that a change in the symmetry due to the phase transition in this crystal can be represented in the form Fmˉ3m11−9(Γ+4)⊕10−3(X+3)(ϕ,ϕ,ψ)P121/n1Fm\bar 3m\frac{{11 - 9(\Gamma _4. + ) \oplus 10 - 3(X_3. + )}} {{(\phi ,\phi ,\psi )}}P12_1 /n1 . A phenomenological analysis of the conditions responsible for the formation of phase states upon the phase transitions in elpasolites Cs2RbDyF6 and Rb2KB′F6 (B′ = Ho, Dy, Tb) has been carried out. Taking into account the structural data and using the phenomenological theory, it has been found that the main factor determining the formation of phase states in these and related crystals is the instability of the elpasolite structure with respect to rotational distortions of two types. It has been shown that an important role in the formation of a sequence of structural transformations in these crystals is played by the interaction of rotational order parameters and displacements of the cation from the center of a cuboctahedral hole.
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Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia.
Southern Fed Univ, Inst Phys Res, Rostov Na Donu 344090, Russia.
Доп.точки доступа:
Safonov, I. N.; Misyul', S. V.; Мисюль, Сергей Валентинович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Ivliev, M. P.; Ministry of Education and Science of the Russian Federation [3.2534.2014/K]
Аннотация: The structures of the cubic and monoclinic phases of an Rb2KHoF6 crystal from a series of elpasolites Rb2KB′F6 (B′ = Ho, Dy, Tb), which undergoes a trigger phase transition, have been investigated using X-ray powder diffraction. The critical and noncritical displacements of atoms in the Rb2KHoF6 structure have been determined from the group-theoretical analysis of the complete condensate of order parameters. It has been reliably established that a change in the symmetry due to the phase transition in this crystal can be represented in the form Fmˉ3m11−9(Γ+4)⊕10−3(X+3)(ϕ,ϕ,ψ)P121/n1Fm\bar 3m\frac{{11 - 9(\Gamma _4. + ) \oplus 10 - 3(X_3. + )}} {{(\phi ,\phi ,\psi )}}P12_1 /n1 . A phenomenological analysis of the conditions responsible for the formation of phase states upon the phase transitions in elpasolites Cs2RbDyF6 and Rb2KB′F6 (B′ = Ho, Dy, Tb) has been carried out. Taking into account the structural data and using the phenomenological theory, it has been found that the main factor determining the formation of phase states in these and related crystals is the instability of the elpasolite structure with respect to rotational distortions of two types. It has been shown that an important role in the formation of a sequence of structural transformations in these crystals is played by the interaction of rotational order parameters and displacements of the cation from the center of a cuboctahedral hole.
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Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia.
Southern Fed Univ, Inst Phys Res, Rostov Na Donu 344090, Russia.
Доп.точки доступа:
Safonov, I. N.; Misyul', S. V.; Мисюль, Сергей Валентинович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Ivliev, M. P.; Ministry of Education and Science of the Russian Federation [3.2534.2014/K]
Solid-state synthesis, structural and magnetic properties of CoPd films
/ V. G. Myagkov [et al.] // Phys. Solid State. - 2015. - Vol. 57, Is. 5. - P. 1014-1022, DOI 10.1134/S1063783415050236. - Cited References:57. - This study was supported in part by the Russian Foundation for Basic Research (project no. 15-02-00948).
. - ISSN 1063. - ISSN 1090-6460. -
РУБ Physics, Condensed Matter
Аннотация: The results of the investigation of the structural and magnetic properties of CoPd films with equiatomic composition have been presented. The films have been synthesized by vacuum annealing of polycrystalline Pd/Co and epitaxial Pd/α-Co(110) and Pd/β-Co(001) bilayer samples. It has been shown that, for all samples, the annealing to 400°C does not lead to the mixing of layers and the formation of compounds. A further increase in the annealing temperature results in the formation of a disordered CoPd phase at the Pd/Co interface, which is fully completed after annealing at 650°C. The epitaxial relationships between the disordered CoPd phase and the MgO(001) substrate are determined as follows: CoPd(110)〈1¯11|| MgO(001)〈100〉 and CoPd(001)[100] || MgO(001)[100], which are formed in the Pd/αCo(110) and Pd/βCo(001) films, respectively. According to the calculations, the first magnetocrystalline anisotropy constants of the disordered CoPd phase for Pd/αCo(110) and Pd/βCo(001) samples have close values: = –(1.6 ± 0.4) × 105 erg/cm3. A possible mechanism of the solidstate synthesis of the CoPd alloy is proposed.
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Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660036, Russia.
Доп.точки доступа:
Myagkov, V. G.; Мягков, Виктор Григорьевич; Bykova, L. E.; Быкова, Людмила Евгеньевна; Zhigalov, V. S.; Жигалов, Виктор Степанович; Tambasov, I. A.; Тамбасов, Игорь Анатольевич; Bondarenko, G. N.; Бондаренко, Галина Николаевна; Matsynin, A. A.; Мацынин, Алексей Александрович; Rybakova, A. N.; Russian Foundation for Basic Research [15-02-00948]
Рубрики:
HIGH-TEMPERATURE SYNTHESIS
EPITAXIAL THIN-FILMS
CENTERED-CUBIC CO
MARTENSITIC TRANSFORMATIONS
PHASE SYNTHESIS
SINGLE-CRYSTAL
FE FILMS
CO/PD MULTILAYERS
RECORDING MEDIA
ANISOTROPY
HIGH-TEMPERATURE SYNTHESIS
EPITAXIAL THIN-FILMS
CENTERED-CUBIC CO
MARTENSITIC TRANSFORMATIONS
PHASE SYNTHESIS
SINGLE-CRYSTAL
FE FILMS
CO/PD MULTILAYERS
RECORDING MEDIA
ANISOTROPY
Аннотация: The results of the investigation of the structural and magnetic properties of CoPd films with equiatomic composition have been presented. The films have been synthesized by vacuum annealing of polycrystalline Pd/Co and epitaxial Pd/α-Co(110) and Pd/β-Co(001) bilayer samples. It has been shown that, for all samples, the annealing to 400°C does not lead to the mixing of layers and the formation of compounds. A further increase in the annealing temperature results in the formation of a disordered CoPd phase at the Pd/Co interface, which is fully completed after annealing at 650°C. The epitaxial relationships between the disordered CoPd phase and the MgO(001) substrate are determined as follows: CoPd(110)〈1¯11|| MgO(001)〈100〉 and CoPd(001)[100] || MgO(001)[100], which are formed in the Pd/αCo(110) and Pd/βCo(001) films, respectively. According to the calculations, the first magnetocrystalline anisotropy constants of the disordered CoPd phase for Pd/αCo(110) and Pd/βCo(001) samples have close values: = –(1.6 ± 0.4) × 105 erg/cm3. A possible mechanism of the solidstate synthesis of the CoPd alloy is proposed.
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Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660036, Russia.
Доп.точки доступа:
Myagkov, V. G.; Мягков, Виктор Григорьевич; Bykova, L. E.; Быкова, Людмила Евгеньевна; Zhigalov, V. S.; Жигалов, Виктор Степанович; Tambasov, I. A.; Тамбасов, Игорь Анатольевич; Bondarenko, G. N.; Бондаренко, Галина Николаевна; Matsynin, A. A.; Мацынин, Алексей Александрович; Rybakova, A. N.; Russian Foundation for Basic Research [15-02-00948]
Features of structural transformations in dielectrics Rb2KM3+F6, M3+ = Al, Cr, Ga, Fe, Lu, Er
/ S. G. Vasilovskiy [и др.] // Abstract book of The Fifth International Seminar on Ferroelactic Physics. - 2006. - P. 30
Доп.точки доступа:
Vasilovskiy, S. G.; Beskrovnyi, A. I.; Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Flerov, I. N.; Флёров, Игорь Николаевич; Simkin, V. G.; International Seminar on Ferroelactic Physics(5 ; 2006 ; Sept. ; 10-13 ; Voronezh)
Доп.точки доступа:
Vasilovskiy, S. G.; Beskrovnyi, A. I.; Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Flerov, I. N.; Флёров, Игорь Николаевич; Simkin, V. G.; International Seminar on Ferroelactic Physics(5 ; 2006 ; Sept. ; 10-13 ; Voronezh)
Green’s functions of spin and electromagnetic waves in the sinusoidal superlattice
/ V. A. Ignatchenko, D. S. Tsikalov // Solid State Phenom. : Selected, peer reviewed papers. - 2015. - Vol. 233-234: Achievements in Magnetism. - P. 47-50, DOI 10.4028/www.scientific.net/SSP.233-234.47
. - ISSN 1662-9779. - ISSN 978-3-038
Кл.слова (ненормированные):
Continued fractions -- Electromagnetic waves -- Green’s functions -- Magnonic crystals -- Photonic crystals -- Sinusoidal modulation -- Spin waves -- Superlattices -- Circular waveguides -- Fourier transforms -- Green's function -- Photonic crystals -- Spin waves -- Superlattices -- Analytical expressions -- Continued fraction -- Fourier transformations -- Magnonic crystals -- S function -- Sinusoidal modulation -- Spectral representations -- Electromagnetic waves
Аннотация: The problem of finding the Green's function of spin and electromagnetic waves in the sinusoidal superlattice is considered. An analytical expression for the spectral representation of the Green's function has been found in the form of ascending continued fractions, the particular denominators of which are ordinary continued fractions. The Green’s function in the r -space has been found by the numerical Fourier transformation of the Greens’s function found in the spectral representation. © (2015) Trans Tech Publications, Switzerland.
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Доп.точки доступа:
Perov, N. \ed.\; Semisalova, A. \ed.\; Tsikalov, D. S.; Цикалов, Денис Сергеевич; Игнатченко, Вальтер Алексеевич; Moscow International Symposium on Magnetism(6 ; 2014 ; June-July ; Moscow)
Кл.слова (ненормированные):
Continued fractions -- Electromagnetic waves -- Green’s functions -- Magnonic crystals -- Photonic crystals -- Sinusoidal modulation -- Spin waves -- Superlattices -- Circular waveguides -- Fourier transforms -- Green's function -- Photonic crystals -- Spin waves -- Superlattices -- Analytical expressions -- Continued fraction -- Fourier transformations -- Magnonic crystals -- S function -- Sinusoidal modulation -- Spectral representations -- Electromagnetic waves
Аннотация: The problem of finding the Green's function of spin and electromagnetic waves in the sinusoidal superlattice is considered. An analytical expression for the spectral representation of the Green's function has been found in the form of ascending continued fractions, the particular denominators of which are ordinary continued fractions. The Green’s function in the r -space has been found by the numerical Fourier transformation of the Greens’s function found in the spectral representation. © (2015) Trans Tech Publications, Switzerland.
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Доп.точки доступа:
Perov, N. \ed.\; Semisalova, A. \ed.\; Tsikalov, D. S.; Цикалов, Денис Сергеевич; Игнатченко, Вальтер Алексеевич; Moscow International Symposium on Magnetism(6 ; 2014 ; June-July ; Moscow)
Heat-induced transformations in coronene - Single-walled carbon nanotube systems
/ A. I. Chernov [et al.] ; International Workshop on Nanocarbon Photonics and Optoelectronics) // J. Nanophoton. - 2016. - Vol. 10, Is. 1 : Special Section on Nanocarbon Photonics and Optoelectronics. - Ст. 012504, DOI 10.1117/1.JNP.10.012504. - Cited References: 14
. - ISSN 1934-2608
РУБ Nanoscience & Nanotechnology + Optics
Аннотация: Coronene molecules are used as filler for single-walled carbon nanotubes. Variation of the synthesis temperature regimes leads to formation of different types of carbon nanostructures inside the nanotubes. Accurate determination of the structures by optical spectroscopy methods remains an important issue in composite materials. Clear distinction between adsorbed organic molecules on the surface of the tubes and filled structures may be accessed by Raman and photoluminescence spectroscopies. We perform additional heat treatment after the initial synthesis procedure and show the evolution of the optical spectral features corresponding to the filled structures and adsorbed materials on the surface of single-walled carbon nanotubes. © 2015 Society of Photo-Optical Instrumentation Engineers (SPIE).
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Доп.точки доступа:
Chernov, A. I.; Fedotov, P. V.; Krylov, A. S.; Крылов, Александр Сергеевич; Vtyurin, A. N.; Втюрин, Александр Николаевич; Obraztsova, E. D.; International Workshop on Nanocarbon Photonics and Optoelectronics (4th ; 28 July - 1 August, 2014 ; Polvijärvi, North Karelia, Finland)
Рубрики:
Graphene nanoribbons
Encapsulation
Reactor
Кл.слова (ненормированные):
graphene nanoribbons -- coronene molecules -- coronene stacks -- columns -- single-walled carbon nanotubes -- nanoreactor
Graphene nanoribbons
Encapsulation
Reactor
Кл.слова (ненормированные):
graphene nanoribbons -- coronene molecules -- coronene stacks -- columns -- single-walled carbon nanotubes -- nanoreactor
Аннотация: Coronene molecules are used as filler for single-walled carbon nanotubes. Variation of the synthesis temperature regimes leads to formation of different types of carbon nanostructures inside the nanotubes. Accurate determination of the structures by optical spectroscopy methods remains an important issue in composite materials. Clear distinction between adsorbed organic molecules on the surface of the tubes and filled structures may be accessed by Raman and photoluminescence spectroscopies. We perform additional heat treatment after the initial synthesis procedure and show the evolution of the optical spectral features corresponding to the filled structures and adsorbed materials on the surface of single-walled carbon nanotubes. © 2015 Society of Photo-Optical Instrumentation Engineers (SPIE).
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Chernov, A. I.; Fedotov, P. V.; Krylov, A. S.; Крылов, Александр Сергеевич; Vtyurin, A. N.; Втюрин, Александр Николаевич; Obraztsova, E. D.; International Workshop on Nanocarbon Photonics and Optoelectronics (4th ; 28 July - 1 August, 2014 ; Polvijärvi, North Karelia, Finland)
Structural and magnetic features of solid-phase transformations in Mn/Bi and Bi/Mn films
/ V. G. Myagkov [et al.] // JETP Letters. - 2016. - Vol. 103, Is. 4. - P. 254-259, DOI 10.1134/S0021364016040111. - Cited References: 47. - This work was supported by the Russian Foundation for Basic Research (project nos. 15-02-00948 and 16-03-00069), by the Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools (project no. SP-317.2015.1), and by the Foundation for Promotion of the Development of Small Scientific and Engineering Enterprises (project nos. 0011727 and 6662GU2015, program Umnik). The electron microscopy studies were performed on the equipment of the Shared Usage Center, Krasnoyarsk Research Center, Siberian Branch, Russian Academy of Sciences.
. - ISSN 0021-3640
РУБ Physics, Multidisciplinary
Аннотация: Solid-phase transformations at different annealing temperatures in Mn/Bi (Mn on Bi) and Bi/Mn (Bi on Mn) films have been studied using X-ray diffraction, electron microscopy, and magnetic measurements. It has been shown that the synthesis of the α-MnBi phase in polycrystalline Mn/Bi films begins at a temperature of ~120°C and the Mn and Bi layers react completely at 300°C. The resulting α-MnBi(001) samples have a large perpendicular magnetic anisotropy (Ku ≃ 1.5 × 107 erg/cm3) and a coercive force H HC ~ 3 kOe. In contrast to Mn/Bi, the ferromagnetic α-MnBi phase in Bi/Mn films is not formed even at annealing processes up to 400°C and Mn clusters are formed in a Bi melt. This asymmetry in phase transformations occurs because chemosorbed oxygen existing on the surface of the Mn film in Bi/Mn films suppresses a solid-phase reaction between Mn and Bi. The analysis of the results obtained implies the existence of new low-temperature (~120°C) structural transformation in the Mn–Bi system. © 2016, Pleiades Publishing, Inc.
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Держатели документа:
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, Russian Federation
Siberian State Aerospace University, pr. Gazety Krasnoyarskii Rabochii, Krasnoyarsk, Russian Federation
Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk, Russian Federation
Доп.точки доступа:
Myagkov, V. G.; Мягков, Виктор Григорьевич; Bykova, L. E.; Быкова, Людмила Евгеньевна; Yakovchuk, V. Yu.; Яковчук, Виктор Юрьевич; Zhigalov, V. S.; Жигалов, Виктор Степанович; Volochaev, M. N.; Волочаев, Михаил Николаевич; Matsynin, A. A.; Мацынин, Алексей Александрович; Tambasov, I. A.; Тамбасов, Игорь Анатольевич; Seredkin, V. A.; Середкин, Виталий Александрович; Patrin, G. S.; Патрин, Геннадий Семёнович; Bondarenko, G. N.; Бондаренко, Галина Николаевна
Рубрики:
High-temperature synthesis
Epitaxial thin-films
State synthesis
Martensitic transformations
Vacuum depositions
MnBi filmsd
Bi
System
Anisotropy
Compound
High-temperature synthesis
Epitaxial thin-films
State synthesis
Martensitic transformations
Vacuum depositions
MnBi filmsd
Bi
System
Anisotropy
Compound
Аннотация: Solid-phase transformations at different annealing temperatures in Mn/Bi (Mn on Bi) and Bi/Mn (Bi on Mn) films have been studied using X-ray diffraction, electron microscopy, and magnetic measurements. It has been shown that the synthesis of the α-MnBi phase in polycrystalline Mn/Bi films begins at a temperature of ~120°C and the Mn and Bi layers react completely at 300°C. The resulting α-MnBi(001) samples have a large perpendicular magnetic anisotropy (Ku ≃ 1.5 × 107 erg/cm3) and a coercive force H HC ~ 3 kOe. In contrast to Mn/Bi, the ferromagnetic α-MnBi phase in Bi/Mn films is not formed even at annealing processes up to 400°C and Mn clusters are formed in a Bi melt. This asymmetry in phase transformations occurs because chemosorbed oxygen existing on the surface of the Mn film in Bi/Mn films suppresses a solid-phase reaction between Mn and Bi. The analysis of the results obtained implies the existence of new low-temperature (~120°C) structural transformation in the Mn–Bi system. © 2016, Pleiades Publishing, Inc.
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Держатели документа:
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, Russian Federation
Siberian State Aerospace University, pr. Gazety Krasnoyarskii Rabochii, Krasnoyarsk, Russian Federation
Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk, Russian Federation
Доп.точки доступа:
Myagkov, V. G.; Мягков, Виктор Григорьевич; Bykova, L. E.; Быкова, Людмила Евгеньевна; Yakovchuk, V. Yu.; Яковчук, Виктор Юрьевич; Zhigalov, V. S.; Жигалов, Виктор Степанович; Volochaev, M. N.; Волочаев, Михаил Николаевич; Matsynin, A. A.; Мацынин, Алексей Александрович; Tambasov, I. A.; Тамбасов, Игорь Анатольевич; Seredkin, V. A.; Середкин, Виталий Александрович; Patrin, G. S.; Патрин, Геннадий Семёнович; Bondarenko, G. N.; Бондаренко, Галина Николаевна
Structural transformations and the critical and noncritical parameters during the phase transition in the (NH4)(2)KWO3F3 oxyfluoride
/ M. S. Molokeev, S. V. Misyul' // Phys. Solid State. - 2011. - Vol. 53, Is. 8. - P. 1672-1679, DOI 10.1134/S1063783411080208. - Cited References: 18. - This study was supported by the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation (grant no. NSh-4645.2010.2).
. - ISSN 1063-7834
РУБ Physics, Condensed Matter
Аннотация: The structures of two phases of the (NH4)(2)KWO3F3 crystal have been determined from X-ray diffraction data obtained for a powder sample. The profile and structural parameters have been refined according to the procedure implemented in the DDM program. The results obtained have been discussed with invoking the group-theoretical analysis of the complete order parameter condensate, which takes into account the critical and noncritical atomic orderings and allows one to interpret the experimental data. It has been found that the symmetry transformation in the crystal can be schematically represented in the form Fm (3) over barm (10-10((X) over bar5)) - ((eta, 0, 0, 0, 0, 0)) Pmmn.This transformation is accompanied by the ordering of WO3F3 polyhedra and the displacement of NH4 and K ions.
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Держатели документа:
[Molokeev, M. S.] Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
[Misyul', S. V.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk 660041, Russian Federation
Доп.точки доступа:
Misyul', S. V.; Мисюль, Сергей Валентинович; Молокеев, Максим Сергеевич
Аннотация: The structures of two phases of the (NH4)(2)KWO3F3 crystal have been determined from X-ray diffraction data obtained for a powder sample. The profile and structural parameters have been refined according to the procedure implemented in the DDM program. The results obtained have been discussed with invoking the group-theoretical analysis of the complete order parameter condensate, which takes into account the critical and noncritical atomic orderings and allows one to interpret the experimental data. It has been found that the symmetry transformation in the crystal can be schematically represented in the form Fm (3) over barm (10-10((X) over bar5)) - ((eta, 0, 0, 0, 0, 0)) Pmmn.This transformation is accompanied by the ordering of WO3F3 polyhedra and the displacement of NH4 and K ions.
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Держатели документа:
[Molokeev, M. S.] Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
[Misyul', S. V.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk 660041, Russian Federation
Доп.точки доступа:
Misyul', S. V.; Мисюль, Сергей Валентинович; Молокеев, Максим Сергеевич
Mossbauer Investigation of Temperature Transformations in Bacterial Ferrihydrite
/ S. V. Stolyar [et al.] // Phys. Solid State. - 2011. - Vol. 53, Is. 1. - P. 100-104, DOI 10.1134/S1063783411010306. - Cited References: 10. - This study was supported by the Federal Agency for Science and Innovation of the Russian Federation within the framework of the Russian Federal Target Program "Scientific and Scientific-Pedagogical Personnel of the Innovative Russia" for 2009-2013 and the Russian Foundation for Basic Research (project no. 09-04-98038-r_sibir'_a).
. - ISSN 1063-7834
РУБ Physics, Condensed Matter
Аннотация: Ferrihydrite nanoparticles formed as a result of the microorganism activity have been studied using Mossbauer spectroscopy, X-ray powder diffraction analysis, and X-ray fluorescence analysis. Three positions of trivalent iron with nonoverlapping ranges of quadrupole splittings have been revealed in bacterial ferrihydrite: QS{Fe(3+)(1)} = 0.49-0.83 mm/s, QS{Fe(3+)(2)} = 0.84-1.10 mm/s, and QS{Fe(3+)(3)} = 1.25-1.73 mm/s. It has been experimentally demonstrated that the Fe(3+)(3) positions are the centers of nucleation of the hematite phase in the course of heat treatment.
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Держатели документа:
[Stolyar, S. V.
Bayukov, O. A.
Iskhakov, R. S.
Ishchenko, L. A.
Yakovchuk, V. Yu.
Piksina, O. E.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Stolyar, S. V.
Bayukov, O. A.
Iskhakov, R. S.
Ishchenko, L. A.
Yakovchuk, V. Yu.
Pozdnyakov, A. I.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Ladygina, V. P.] Russian Acad Sci, Siberian Branch, Presidium Krasnoyarsk Sci Ctr, Int Res Ctr Extreme States Organism, Krasnoyarsk 660036, Russia
[Dobretsov, K. G.] Joint Stock Co Russian Railways RZhD, Railway Clin Hosp Krasnoyarsk Stn, Krasnoyarsk 660021, Russia
ИФ СО РАН
КНЦ СО РАН
Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk 660041, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation
International Research Center for Extreme States of the Organism, Presidium of Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation
Railway Clinical Hospital at the Krasnoyarsk station, Joint Stock Company Russian Railways (RZhD), pr. Mira 154, Krasnoyarsk 660021, Russian Federation
Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Bayukov, O. A.; Баюков, Олег Артемьевич; Ladygina, V. P.; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ishchenko, L. A.; Yakovchuk, V. Y.; Dobretsov, K. G.; Pozdnyakov, A. I.; Piksina, O. E.
Аннотация: Ferrihydrite nanoparticles formed as a result of the microorganism activity have been studied using Mossbauer spectroscopy, X-ray powder diffraction analysis, and X-ray fluorescence analysis. Three positions of trivalent iron with nonoverlapping ranges of quadrupole splittings have been revealed in bacterial ferrihydrite: QS{Fe(3+)(1)} = 0.49-0.83 mm/s, QS{Fe(3+)(2)} = 0.84-1.10 mm/s, and QS{Fe(3+)(3)} = 1.25-1.73 mm/s. It has been experimentally demonstrated that the Fe(3+)(3) positions are the centers of nucleation of the hematite phase in the course of heat treatment.
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Держатели документа:
[Stolyar, S. V.
Bayukov, O. A.
Iskhakov, R. S.
Ishchenko, L. A.
Yakovchuk, V. Yu.
Piksina, O. E.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Stolyar, S. V.
Bayukov, O. A.
Iskhakov, R. S.
Ishchenko, L. A.
Yakovchuk, V. Yu.
Pozdnyakov, A. I.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Ladygina, V. P.] Russian Acad Sci, Siberian Branch, Presidium Krasnoyarsk Sci Ctr, Int Res Ctr Extreme States Organism, Krasnoyarsk 660036, Russia
[Dobretsov, K. G.] Joint Stock Co Russian Railways RZhD, Railway Clin Hosp Krasnoyarsk Stn, Krasnoyarsk 660021, Russia
ИФ СО РАН
КНЦ СО РАН
Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk 660041, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation
International Research Center for Extreme States of the Organism, Presidium of Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation
Railway Clinical Hospital at the Krasnoyarsk station, Joint Stock Company Russian Railways (RZhD), pr. Mira 154, Krasnoyarsk 660021, Russian Federation
Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Bayukov, O. A.; Баюков, Олег Артемьевич; Ladygina, V. P.; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ishchenko, L. A.; Yakovchuk, V. Y.; Dobretsov, K. G.; Pozdnyakov, A. I.; Piksina, O. E.