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    Preparation and structural properties of nonlinear optical borates K 2(1-x)Rb 2xAl 2B 2O 7, 0 ˂ x ˂ 0.75
/ V. V. Atuchin [и др.] // J. Alloys Compd. - 2012. - Vol. 515. - P. 119-122, DOI 10.1016/j.jallcom.2011.11.115. - Cited References: 30. - This study was supported by SB RAS (Grant 34) and RFBR Grants 11-02-90706-mob_st and 11-03-00867a. . - ISSN 0925-8388
   Перевод заглавия: Получение и структурные свойства нелинейных оптических боратов K 2(1-x)Rb 2xAl 2B 2O 7, 0 ˂ x ˂ 0.75
РУБ Chemistry, Physical + Materials Science, Multidisciplinary + Metallurgy & Metallurgical Engineering + Aluminum + Crystal structure + Nonlinear optics + Rietveld analysis + Rubidium + Solid solutions + Structural properties + X ray powder diffraction

Аннотация: The structures of K 2(1-x)Rb 2xAl 2B 2O 7, x = 0.25, 0.5, 0.75, have been determined in space group P321 through Rietveld analysis of X-ray powder diffraction data. The solubility limit in K 2(1-x)Rb 2xAl 2B 2O 7 crystals has been estimated as x similar to 0.83-0.9. Nonlinear optical properties of KRbAl 2B 2O 7 have been verified by powder Kurtz-Perry method. Mechanisms of structural parameter variation in K 2Al 2B 2O 7 crystal family have been discussed.

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Доп.точки доступа:
Atuchin, V. V.; Bazarov, B. G.; Gavrilova, T. A.; Grossman, V. G.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bazarova, Zh. G.

    Quality of the rare earth aluminum borate crystals for laser applications, probed by high-resolution spectroscopy of the Yb3+ ion
/ K. N. Boldyrev [et al.] // Opt. Mater. - 2012. - Vol. 34, Is. 11. - P. 1885-1889, DOI 10.1016/j.optmat.2012.05.021. - Cited References: 20. - This work was supported by the Russian Academy of Sciences under the Programs for Basic Research, the Russian Foundation for Basic research under Grants No 10-02-01071-a and No 09-02-00171-a, and by the Ministry of Education and Science under Grant HIII-4828.2012.2. . - ISSN 0925-3467
РУБ Materials Science, Multidisciplinary + Optics

Аннотация: A comparative study was performed of the low-temperature high-resolution absorption spectra of the Yb3+ probe in R1−xYbxAl3(BO3)4 (R = Y, Tm, Lu) crystals grown by flux technique independently in four different laboratories using different solvents. We show that the incorporation of solvent components into the crystal in the course of crystallization gives rise to spectral satellites of the Yb3+ 0(2F7/2) → 0′(2F5/2) absorption lines and assign particular satellites to the Yb3+ centers near the bismuth and molybdenum impurities (which decrease the transparency of YAB in the UV spectral range). We suggest this spectroscopic method for a rapid analysis of the quality of UV laser crystals and for improvement of growth technologies.

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Держатели документа:
[Boldyrev, K. N.
Popova, M. N.] RAS, Inst Spect, Troitsk 142190, Moscow Region, Russia
[Bettinelli, M.] Univ Verona, Dept Biotechnol, I-37134 Verona, Italy
[Bettinelli, M.] UdR Verona, INSTM, I-37134 Verona, Italy
[Temerov, V. L.
Gudim, I. A.
Bezmaternykh, L. N.] RAS, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Loiseau, P.
Aka, G.] ENSCP, CNRS, LCMCP, UMR 7574, F-75005 Paris, France
[Leonyuk, N. I.] Moscow MV Lomonosov State Univ, Fac Geol, Moscow 119899, Russia

Доп.точки доступа:
Boldyrev, K. N.; Popova, M. N.; Bettinelli, M.; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, Irina A.; Гудим, Ирина Анатольевна; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Loiseau, P.; Aka, G.; Leonyuk, N. I.

    Coupled R and Fe magnetic excitations in RFe 3(BO 3) 4 multiferroics
/ A. M. Kuzmenko [et al.] // Diffusion and Defect Data Pt.B: Solid State Phenomena. - 2012. - Vol. 190. - P. 269-272, DOI 10.4028/www.scientific.net/SSP.190.269 . - ISBN 9783037854365
Аннотация: Various resonance modes were observed in the transmission spectra of rare-earth iron borates RFe 3(BO 3) 4 (R = Nd 3+, Sm 3+, Gd 3+) at the frequency range 100-600 GHz, which were attributed to collective magnetic excitations in the exchange coupled Fe- and R-subsystems, i.e. antiferromagnetic (Fe) resonance and electron transitions in the R-ions. Strong interaction of the Fe and R oscillations was revealed and theoretically analyzed taking into account feature of the R-ion ground state. Intensities of the coupled modes (contributions to magnetic permeability) strongly depend on a difference of Fe and R ions g-factors that allows defining the sign of the latter. In particular, an appreciable intensity of exchange (Nd) modes in NdFe 3(BO 3) 4 is caused by g Nd?,|| < 0 whereas in GdFe 3(BO 3) 4 with gGd ? gFe ? 2 the exchange (Gd) modes were hided due to compensation of Fe and Gd contributions. In SmFe 3(BO 3) 4, despite a negligible Sm g-factor, the Sm modes were clear observed due to their excitation via coupling with the Fe-subsystem. В© (2012) Trans Tech Publications.

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Доп.точки доступа:
Kuzmenko, A. M.; Кузьменко А.М.; Mukhin, A. A.; Ivanov, V.Yu.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Moscow International Symposium on Magnetism(5 ; 2011 ; Aug. ; 21-25 ; Moscow)

    Preparation, structural and electronic properties of nonlinear optical borates K2(1-x)Rb2xAl2B2O7
/ V. Atuchin [et al.] // Abstract of the 2th Int. Symp. on Laser Interaction with Matter. - 2012. - P. 184



Доп.точки доступа:
Atuchin, V. V.; Атучин, Виктор Валерьевич; Grossman, V. G.; Гроссман В.Г.; Lin, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bazarov, B. G.; Базаров Б.Г.; Bazarova, Zh.G.; Базарова Ж.Г.; International Symposium on Laser Interaction with Matter (LIMIS 2014) (2 ; 2012; сент. ; 9-12 ; Xi`an, China)

    Synthesis, crystal and valence band structure of nonlinear optical borates K2(1-x)Rb2xAl2B2O7
/ V. V. Atuchin [et al.] // VI Сессия Научного совета РАН по механике : материалы всероссийской конференции. - Барнаул, 2012. - P. 91 . - ISBN 5756809376


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Доп.точки доступа:
Atuchin, V. V.; Атучин, Виктор Валерьевич; Bazarov, B. G.; Базаров Б.Г.; Grossman, V. G.; Lin, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bazarova, Zh.G.; Базарова Ж.Г.; Российский национальный комитет по теоретической и прикладной механике; Объединенный Научный совет РАН по комплексной проблеме "Механика"; Научный совет по механике деформируемого твердого тела РАН; Институт проблем механики им. А.Ю. Ишлинского РАН; Институт проблем машиноведения РАН; Алтайский государственный технический университет им. И.И. Ползунова; Российский фонд фундаментальных исследований; "Сессия Научного совета РАН по механике", Всероссийская конференция (6 ; 26-31 июля 2012 ; Барнаул / Белокуриха, Россия)

    Solid state synthesis and band structure of nonlinear borates K2(1-x)Rb2xAl2B2O7
/ B. G. Bazarov [et al.] // XVI Международная конференция "Опто-, наноэлектроника, нанотехнологии и микросистемы" : Труды. - Ульяновск, 2012. - P. 122



Доп.точки доступа:
Bazarov, B. G.; Базаров Б.Г.; Grossman, V. G.; Lin, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Atuchin, V. V.; Атучин, Виктор Валерьевич; Bazarova, Zh.G.; Базарова Ж.Г.; Институт нанотехнологий микроэлектроники РАН; Ульяновский государственный университет; Российский фонд фундаментальных исследований; Академия наук Татарстана; "Opto-, nanoelectronics, nanotechnology, and microsystems", International Conference (2012 ; sept. ; 4-7 ; Ulyanovsk, Russia); "Опто-, наноэлектроника, нанотехнологии и микросистемы", международная конференция (2013 ; июль.; 26-30 ; Ульяновск)

    Determination of the magnetic structure of SmFe3(BO3)4 by neutron diffraction: comparison with other RFe3(BO3)4 iron borates
/ C. Ritter [et al.] // J. Phys.: Condens. Matter. - 2012. - Vol. 24, Is. 38. - Ст. 386002, DOI 10.1088/0953-8984/24/38/386002. - Cited References: 40. - This work was supported by RFBR, grant No. 10-02-00765. . - ISSN 0953-8984
РУБ Physics, Condensed Matter

Аннотация: Temperature dependent neutron diffraction studies were performed on SmFe3(BO3)4. The crystallographic structure was determined to stay as R32 over the whole studied temperature range of 2 K ‹ T ‹ 300 K. A magnetic phase transition characterized by the magnetic propagation vector κ = [0 0 3/2] takes place at TN = 34 K. The magnetic structure sees an easy-plane arrangement within the trigonal basal a–b-plane of ferromagnetic layers of iron and samarium having a canting angle of about 70° relative to each other. Neighbouring layers in the c-direction are antiferromagnetically coupled; at 2 K the magnetic moment values amount to μFe = 4.2(1) μB and μSm = 0.8(2) μB. The non-Brillouin type increase of the iron magnetic moment below TN points to a strong Fe–Sm exchange and to the simultaneous appearance of long range magnetic order on both sublattices.

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Держатели документа:
[Ritter, C.] Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France
[Pankrats, A.
Gudim, I.
Vorotynov, A.] RAS, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Ritter, C.; Pankrats, A.I.; Панкрац, Анатолий Иванович; Gudim, I. A.; Гудим, Ирина Анатольевна; Vorotynov, A.M.; Воротынов, Александр Михайлович

    The Faraday effect in TbFe3(BO3)4 and TbAl3(BO3)4 borates
/ V. A. Bedarev [et al.] // J. Magn. Magn. Mater. - 2014. - Vol. 362. - P. 150-153, DOI 10.1016/j.jmmm.2014.03.034. - Cited References: 16 . - ISSN 0304-8853. - ISSN 1873-4766
РУБ Materials Science, Multidisciplinary + Physics, Condensed Matter

Кл.слова (ненормированные):
Antiferromagnet -- Faraday rotation -- Magnetization

Аннотация: The magnetic field dependences of the Faraday rotation of light and the magnetization of antiferromagnet TbFe3(BO3)(4) and paramagnet TbAl3(BO3)(4) compounds have been investigated. It is established that the main contribution to the Faraday rotation in the TbFe3(BO3)(4) is associated with the Tb3+ subsystem at low temperatures. The antiferromagnetic ordering effects on this contribution is shown. (C) 2014 Elsevier B.V. All rights reserved.

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Держатели документа:
Natl Acad Sci Ukraine, B Verkin Inst Low Temperature Phys & Engn, UA-61103 Kharkov, Ukraine
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Bedarev, V. A.; Pashchenko, M. I.; Merenkov, D. N.; Savina, Y. O.; Pashchenko, V. O.; Gnatchenko, S. L.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Temerov, V. L.; Темеров, Владислав Леонидович

    Morphology of the polar twin structure in Czochralski grown α-SrB4O7 crystals
/ A. I. Zaitsev [et al.] // J. Cryst. Growth. - 2015. - Vol. 416. - P. 17-20, DOI 10.1016/j.jcrysgro.2015.01.004. - Cited References:15. - This study is supported by Grant of the President of the Russian Federation for the support of leading scientific schools SS-924.2014.2. . - ISSN 0022. - ISSN 1873-5002. -
РУБ Crystallography + Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
TETRABORATE
   STRONTIUM

   SRB4O7

Кл.слова (ненормированные):
Optical microscopy -- Czochralski method -- Borates -- Growth twins -- Nonlinear -- optic materials

Аннотация: The arrangement of a polar twin structure in Czochralski grown α-SrB4O7 crystals has been investigated. The transversal twin boundaries are stretched along [ 1 0 1 ] and [ 1 0 0 ] directions. The lateral twin boundaries are parallel to ( 0 1 0 ) plane. The twin structures have an extension up to centimeter size in all directions. Supposedly, they originate from polysynthetic polar microtwins revealed to form in ( 1 0 1 ¯ ) and ( 1 ¯ 0 1 ¯ ) growth pyramids. The dimensions, planarity and thickness stability of each individual twin are favorable for organizing quasi-phase matching conditions for nonlinear optical doubling of high-aperture beams.

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Держатели документа:
SB RAS, LV Kirensky Inst Phys, Akademgorodok 660036, Krasnoyarsk, Russia.
Siberian Fed Univ, Svobodny Prospect, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Zaitsev, A. I.; Зайцев, Александр Иванович; Radionov, N. V.; Радионов, Никита Вячеславович; Cherepakhin, A. V.; Черепахин, Александр Владимирович; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Zamkov, A. V.; Замков, Анатолий Васильевич; Grant of the President of the Russian Federation for the support of leading scientific schools [SS-924.2014.2]

    Spectral signatures of spin-phonon and electron-phonon interactions in multiferroic iron borates
/ M. N. Popova [et al.] // J. Magn. Magn. Mater. - 2015. - Vol. 383. - P. 250-254, DOI 10.1016/j.jmmm.2014.10.095. - Cited References:32. - This work was supported by the Russian Science Foundation (Grant no. 14-12-01033). Experiments at U4-IR beamline NSLS-BNL (T.N.S. and A.A.S.) were performed under Contract no. DE-FG02-07ER46382 from the U.S. Department of Energy. The National Synchrotron Light Source is operated as a User Facility for the U.S. Department of Energy under Contract no. DE-AC02-98CH10886. M.N.P. thanks B.Z. Malkin for helpful discussions. . - ISSN 0304-8853. - ISSN 1873-4766
РУБ Materials Science, Multidisciplinary + Physics, Condensed Matter

Аннотация: High-resolution far-infrared reflection and polarized ellipsometry, as well as Raman scattering temperature-dependent measurements are used to study spin-phonon and electron-phonon interactions in rare-earth (RE) iron borates with the R32 structure of a natural mineral huntite, namely, in RFe3(BO3)4 with R=Pr, Nd, and Sm. Pronounced peculiarities in the ω(T) dependences at the Néel temperature TN≈32 K are observed for all the compounds studied and the origin of these peculiarities is discussed. A coupling between lattice phonons and crystal-field excitations of a RE ion manifests itself by a renormalization of frequencies and intensities of coupled modes. Modeling of the spectra has revealed the value of about 15 cm−1 for the electron–phonon coupling constant in PrFe3(BO3)4.
Высокоразрешающая эллипсометрия дальнего инфракрасного отражения и поляризованный света, а также температурнозависимые измерения комбинационного рассеяния используются для изучения спин-фононных и электрон-фононных взаимодействий в редкоземельных (RE) боратах железа со структурой R32 природного минерала хантита , а именно, в RFe3 (BO3) 4 с R = Pr, Nd, и Sm. Выраженные особенности ω (T) зависимостей при температуре Нееля TN ≈32 K наблюдаются для всех исследованных соединений и происхождение этих особенностей обсуждается.Связь между фононами решетки и возбуждениями кристаллического поля РЗ иона проявляется себя перенормализации частоты и интенсивности связанных мод. Моделирование спектров показал значение около 15cm-1 для константы электрон-фононной связи в PrFe3 (BO3) 4.

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Доп.точки доступа:
Popova, M. N.; Boldyrev, K. N.; Klimin, S. A.; Stanislavchuk, T. N.; Sirenko, A. A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Russian Science Foundation [14-12-01033]; U.S. Department of Energy [DE-FG02-07ER46382, DE-AC02-98CH10886]; Moscow International Symposium on Magnetism(6 ; 2014 ; June-July ; Moscow)

    Magnetoelectric and magnetic properties of aluminum borates Ho1 − x Nd x Al3(BO3)4
/ N. V. Volkov [et al.] // JETP Letters. - 2015. - Vol. 101, Is. 5. - P. 318-324, DOI 10.1134/S002136401505015X. - Cited References:26. - This work was supported by the Russian Foundation for Basic Research (project no. 13-02-12442 ofi_m2). . - ISSN 0021. - ISSN 1090-6487. -
РУБ Physics, Multidisciplinary
Рубрики:
HoAl3(BO3)4

Аннотация: The magnetoelectric and magnetic properties of substituted aluminum borates Ho1 − x Nd x Al3(BO3)4 have been studied experimentally and theoretically. A large magnetoelectric effect exceeding all known values in isostructural compounds except for HoAl3(BO3)4 has been found. The magnetoelectric polarization of Ho0.8Nd0.2Al3(BO3)4 and Ho0.5Nd0.5Al3(BO3)4 at T = 5 K in a field of 9 T is ΔP ab (B b ) ≈ −2630 and 1380 μC/m2, respectively. A theoretical consideration based on the crystal field model for the rare-earth ion made it possible to interpret all measured properties within the unified approach. The crystal field parameters have been determined. The temperature (3–300 K) and field (up to 9 T) dependences of the magnetization and the temperature (5–100 K) and field (up to 9 T) dependences of the polarization have been described. The studied properties of Ho1 − x Nd x Al3(BO3)4 have been compared with those of HoAl3(BO3)4 demonstrating record-high polarization values.

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Держатели документа:
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Bryansk State Tech Univ, Bryansk 241035, Russia

Доп.точки доступа:
Volkov, N. V.; Волков, Никита Валентинович; Gudim, I. A.; Гудим, Ирина Анатольевна; Demidov, A. A.; Eremin, E. V.; Еремин, Евгений Владимирович; Russian Foundation for Basic Research [13-02-12442 ofi_m2]

    Long range magnetic order in RAl3(BO3)4 (R = Dy, Tb) borates at sub-kelvin temperatures
/ T. Zajarniuk [и др.] // 27th Int. Conf. on Low Temperature Phys. (LT-27) : book of abstracts. - 2014. - Ст. P93-0136



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Доп.точки доступа:
Zajarniuk, T.; Szewczyk, A.; Gutowska, M. U.; Pashchenko, M. I.; Пащенко М.И.; Bedarev, V. A.; Бедарев В. А.; Gnatchenko, S. L.; Гнатченко С.Л.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Temerov, V. L.; Темеров, Владислав Леонидович; Prokhorov, A. M.; Прохоров А. М.; Chernysh, L. F.; Dyakonov, V. P.; Дьяконов В. П.; International Conference on Low Temperature Physics(27 ; 2014 ; 6-13 Aug. ; Buenos Aires, Argentina)

    Uncontrolled impurity of Bi3+ in rare-earth iron borates RFe3(BO3)4
/ K. N. Boldyrev [et al.] // The 4th International Conference on the Physics of Optical Materials and Devices. ICOM 2015 : book of abstracts. - 2015. - P. 262 . - ISBN 978-86-7306-134-4


Материалы конференции


Доп.точки доступа:
Boldyrev, K. N.; Popova, M. N.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; International Conference on the Physics of Optical Materials and Devices(3 ; 2015 ; 31 aug.-4 sept. ; Budva, Montenegro)

    Effects of the Interaction between R and Fe Modes of the Magnetic Resonance in RFe3(BO3)(4) Rare-Earth Iron Borates
/ A. M. Kuz'menko [et al.] // JETP Letters. - 2011. - Vol. 94, Is. 4. - P. 294-300, DOI 10.1134/S0021364011160119. - Cited References: 27. - We are grateful to A. S. Prokhorov for discussion of this work and valuable comments. This work was supported by the Russian Foundation for Basic Research, project nos. 10-02-00846 and 09-02-01355, and the Ministry of Education and Science of the Russian Federation, project no. 16.518.11.7034. . - ISSN 0021-3640
Аннотация: Resonance modes that are due to magnetic excitations in the exchange-coupled subsystems of rare-earth ions (R = Nd3+, Sm3+, and Gd3+) and Fe3+ ions have been detected in submillimeter transmission spectra (0.1-0.6 THz) of RFe3(BO3)(4) iron borate-multiferroic single crystals. The strong interaction between spin oscillations of the Fe and R subsystems has been revealed, which determines the behavior of the modes depending on the anisotropy of the exchange splitting of the ground doublet of the R ion. It has been shown that the intensities of coupled modes (contributions to the magnetic permeability) depend strongly on the difference between the g factors of Fe and R ions. This dependence makes it possible to determine the sign of the latter g factor. In particular, a noticeable intensity of exchange Nd modes in NdFe3(BO3)(4) is due to an increase in their contribution at g(perpendicular to,parallel to)(Nd) 0, while in GdFe3(BO3)(4) with g(Gd) approximate to g(Fe) approximate to 2, the Fe and Gd contributions compensate each other and the exchange (Gd) mode is not observed. In spite of the weak interaction of Sm ions with the magnetic field, SmFe3(BO3)(4) exhibits resonance modes, which are attributed to the excitation of Sm ions through the Fe subsystem. DOI: 10.1134/S0021364011160119

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Держатели документа:
[Kuz'menko, A. M.
Mukhin, A. A.
Ivanov, V. Yu.] Russian Acad Sci, Prokhorov Gen Phys Inst, Moscow 119991, Russia
[Kadomtseva, A. M.] Moscow MV Lomonosov State Univ, Moscow 119992, Russia
[Bezmaternykh, L. N.] Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
ИФ СО РАН
Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow 119991, Russian Federation
Moscow State University, Moscow 119992, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Kuz'menko, A. M.; Mukhin, A. A.; Ivanov, V. Y.; Kadomtseva, A. M.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич

    Nonresonant x-ray magnetic scattering on rare-earth iron borates RFe3(BO3)(4)
/ J. E. Hamann-Borrero [et al.] // Phys. Rev. B. - 2010. - Vol. 82, Is. 9. - Ст. 94411, DOI 10.1103/PhysRevB.82.094411. - Cited References: 38. - This work was supported by the Deustche Forschungsgemeinschaft, through the Forschergruppe FOR520 (Grant No. HE3439/6) and HASYLAB at the Feyerherm from HMI Berlin and specially to Jorg Strempfer from HASYLAB at DESY in Hamburg for valuable discussions. . - ISSN 1098-0121
РУБ Physics, Condensed Matter

Аннотация: Hard x-ray scattering experiments with a photon energy of 100 keV were performed as a function of temperature and applied magnetic field on selected compounds of the RFe3(BO3)4 family. The results show the presence of several diffraction features, in particular, nonresonant magnetic reflections in the magnetically ordered phase and structural reflections that violate the diffraction conditions for the low-temperature phase P3(1)21 of the rare-earth iron borates. The temperature and field dependence of the magnetic superlattice reflections corroborate the magnetic structures of the borate compounds obtained by neutron diffraction. The detailed analysis of the intensity and scattering cross section of the magnetic reflection reveals details of the magnetic structure of these materials such as the spin domain structure of NdFe3(BO3)(4) and GdFe3(BO3)(4). Furthermore we find that the correlation length of the magnetic domains is around 100 angstrom for all the compounds and that the Fe moments are rotated 53 degrees +/- 3 degrees off from the hexagonal basal plane in GdFe3(BO3)(4).

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Держатели документа:
[Hamann-Borrero, J. E.
Philipp, M.
Kataeva, O.
Geck, J.
Klingeler, R.
Buechner, B.
Hess, C.] IFW Dresden, Leibniz Inst Solid State & Mat Res, D-01171 Dresden, Germany
[Kataeva, O.] Russian Acad Sci, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia
[Zimmermann, M. V.] Deutsch Elektronen Synchrotron DESY, Hamburger Synchrotronstrahlungslabor HASYLAB, D-22603 Hamburg, Germany
[Klingeler, R.] Univ Heidelberg, Kirchhoff Inst Phys, D-69120 Heidelberg, Germany
[Vasiliev, A.] Moscow MV Lomonosov State Univ, Fac Phys, Low Temp Phys Dept, Moscow 119992, Russia
[Bezmaternykh, L.] Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Leibniz Institute for Solid State and Materials Research, IFW Dresden, 01171 Dresden, Germany
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, Kazan 420088, Russian Federation
Hamburger Synchrotronstrahlungslabor (HASYLAB), Deutsches Elektronen-Synchrotron (DESY), Notkestr. 85, 22603 Hamburg, Germany
Kirchhoff Institute for Physics, University of Heidelberg, Im Neuenheimer Feld 227, D-69120 Heidelberg, Germany
Low Temperature Physics Department, Faculty of Physics, Moscow State University, Moscow 119992, Russian Federation
L. V. Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk 660,0,36, Russian Federation

Доп.точки доступа:
Hamann-Borrero, J. E.; Philipp, M.; Kataeva, O.; Zimmermann, M. V.; Geck, J.; Klingeler, R.; Vasiliev, A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Buchner, B.; Hess, C.

    Magnetic structure in iron borates RFe3(BO3)(4) (R = Er, Pr): a neutron diffraction and magnetization study
/ C. . Ritter [et al.] // J. Phys.: Condens. Matter. - 2010. - Vol. 22, Is. 20. - Ст. 206002, DOI 10.1088/0953-8984/22/20/206002. - Cited References: 22. - This work was supported by RFBR, grant no. 10-02-00765, and by the Physical Sciences Department of RAS, project no. 1.1.1.1. . - ISSN 0953-8984
РУБ Physics, Condensed Matter

Аннотация: Neutron diffraction, susceptibility and magnetization measurements (for R = Er only) were performed on iron borates RFe3(BO3)(4) (R = Pr, Er) to investigate details of the crystallographic structure, the low temperature magnetic structures and transitions and to study the role of the rare earth anisotropy. PrFe3(BO3)(4), which crystallizes in the spacegroup R32, becomes antiferromagnetic at T-N = 32 K, with t = [0 0 3/2], while ErFe3(BO3)(4), which keeps the P3(1)21 symmetry over the whole studied temperature range 1.5 K < T < 520 K, becomes antiferromagnetic below T-N = 40 K, with tau = [0 0 1/2]. Both magnetic propagation vectors lead to a doubling of the crystallographic unit cell in the c-direction. Due to the strong polarization of the Fe-sublattice, the magnetic ordering of the rare earth sublattices appears simultaneously at T-N. The moment directions are determined by the rare earth anisotropy: easy-axis along c for PrFe3(BO3)(4) and easy-plane a-b for ErFe3(BO3)(4). There are no spin reorientations present in either of the two compounds but there is the appearance below 10 K of a minority phase in the Er-compound adopting a 120 degrees arrangement of the Er-moments.

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Держатели документа:
[Ritter, C.] Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France
[Vorotynov, A.
Pankrats, A.
Petrakovskii, G.
Temerov, V.
Gudim, I.] RAS, Siberian Branch, LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
[Petrakovskii, G.] Siberian Fed Univ, Krasnoyarsk, Russia
[Szymczak, R.] Inst Phys PAS, Warsaw, Poland
ИФ СО РАН
Institut Laue-Langevin, Boite Postale 156, F-38042 Grenoble, France
L v Kirenskii Institute of Physics, Siberian Branch of RAS, Krasnoyarsk 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Institute of Physics PAS, Warsaw, Poland

Доп.точки доступа:
Ritter, C.; Vorotynov, A. M.; Воротынов, Александр Михайлович; Pankrats, A. I.; Панкрац, Анатолий Иванович; Petrakovskii, G. A.; Петраковский, Герман Антонович; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна; Szymczak, R.

    Spectroscopic study of the magnetic ordering in SmFe3(BO3)(4)
/ E. P. Chukalina [et al.] // Phys. Lett. A. - 2010. - Vol. 374, Is. 15-16. - P. 1790-1792, DOI 10.1016/j.physleta.2010.02.018. - Cited References: 20. - The authors thank B.Z. Malkin and S.A. Klinnin for helpful discussions and K.N. Boldyrev for participating in some low-temperatures measurements. This work was supported in part by the Russian Foundation for Basic Research (grants Nos. 10-02-01071 and 10-02-00765), and by the Russian Academy of Sciences under the Programs for Basic Research. . - ISSN 0375-9601
РУБ Physics, Multidisciplinary

Аннотация: SmFe3(BO3)(4) belongs to the family of rare-earth RFe3(BO3)(4) multiferroics. We present the first measurements of the optical spectra of SmFe3(BO3)(4) (on single crystals) and report the data on the crystal-field levels and their symmetries for the ground multiplet H-6(5/2) [0 (Gamma(4)). 135 (Gamma(56)), and 220 (Gamma(4)) cm(-1)] and on the ground-state exchange splitting (13.2 cm(-1) at 1.7 K), important to interpret the magnetic, magnetoelectric, and thermodynamic properties of this compound. The observed exchange splitting of the Sm3+ Kramers doublets manifests the magnetic ordering in SmFe3(BO3)(4) at 32 +/- 1 K. From a comparison of the temperature-dependent spectra of the Sm3+ ion in SmFe3(BO3)(4) and in Nd-Gd mixed iron borate where the magnetic spin reorientation has been found earlier, we suggest the easy-plane arrangement of the Fe spins in SmFe3(BO3)(4). The samarium iron borate preserves the R32 (D-3(7)) crystal structure at all the investigated temperatures (down to 1.7 K). (C) 2010 Elsevier B.V. All rights reserved.

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Держатели документа:
[Chukalina, E. P.
Popova, M. N.] RAS, Inst Spect, Troitsk 142190, Moscow Region, Russia
[Bezmaternykh, L. N.
Gudim, I. A.] RAS, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Institute of Spectroscopy, RAS, 5, Fizicheskaya str, 142190 Troitsk, Moscow region, Russian Federation
L.V. Kirensky Institute of Physics, Siberian Branch, RAS, 660036 Krasnoyarsk, Russian Federation

Доп.точки доступа:
Chukalina, E. P.; Popova, M. N.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна

    Magnetic structure in iron borates RFe(3)(BO(3))(4)(R= Y, Ho): a neutron diffraction and magnetization study
/ C. . Ritter [et al.] // J. Phys.: Condens. Matter. - 2008. - Vol. 20, Is. 36. - Ст. 365209, DOI 10.1088/0953-8984/20/36/365209. - Cited References: 16. - This work was supported by RFBR, grant no. 06-02-16255. . - ISSN 0953-8984
РУБ Physics, Condensed Matter

Аннотация: Neutron diffraction, susceptibility and magnetization measurements were performed on iron borates RFe(3)(BO(3))(4)(R = Y, Ho) to investigate the low temperature magnetic structures and to clarify the role of the rare earth in the formation of the long-range magnetic order. Both compounds see an identical magnetic propagation vector tau = [ 0, 0, 1/2] within the P3(1)21 crystallographic space group appear at Neel temperatures of T(N) = 37 K for the Y and TN = 38 K for the Ho compound. The strong polarization effect of the Fe sublattice on the Ho(3+) ions leads to the simultaneous ordering of both sublattices while the competition between their anisotropies governs the spin-reorientation process at T(SR) = 5 K. The results obtained are discussed in the framework of the determined structural details and the specific rare-earth ions present including information on compounds investigated earlier.

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Держатели документа:
[Ritter, C.] Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France
[Vorotynov, A.
Pankrats, A.
Petrakovskii, G.
Temerov, V.
Gudim, I.] RAS, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Szymczak, R.] Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland
ИФ СО РАН
Institute Laue-Langevin, Boite Postale 156, F-38042 Grenoble, France
L V Kirenskii Institute of Physics, Siberian Branch, RAS, Krasnoyarsk 660036, Russian Federation
Institute of Physics, Polish Academy of Sciences, PL-02668 Warsaw, Poland

Доп.точки доступа:
Ritter, C.; Vorotynov, A. M.; Воротынов, Александр Михайлович; Pankrats, A. I.; Панкрац, Анатолий Иванович; Petrakovskii, G. A.; Петраковский, Герман Антонович; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна; Szymczak, R.

    Investigation of the iron borates DyFe3(BO3)(4) and HoFe3(BO3)(4) by the method of Er3+ spectroscopic probe
/ T. N. Stanislavchuk [et al.] // Phys. Lett. A. - 2007. - Vol. 368, Is. 5. - P. 408-411, DOI 10.1016/j.physleta.2007.04.044. - Cited References: 16 . - ISSN 0375-9601
РУБ Physics, Multidisciplinary

Аннотация: Temperature-dependent high-resolution optical spectra of the Er3+ probe ion in DyFe3(BO3)(4) and HoFe3(BO3)(4) are reported. The data provide the temperature of magnetic ordering and direction of the Fe3+ magnetic moments. Both compounds order magnetically at T-N = 39 +/- 1K. The magnetic structure of DyFe3(BO3)(4) is of the easy-axis type, while that of HoFe3(BO3)(4) is of the easy-plane type. The role of anisotropic interactions between the iron and the rare-earth subsystems is discussed. (c) 2007 Elsevier B.V. All rights reserved.

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Держатели документа:
Russian Acad Sci, Inst Spect, Troitsk 142190, Moscow Region, Russia
LV Kirenskii Inst Phys, RAS, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Institute of Spectroscopy, Russian Academy of Sciences, 142190 Troitsk, Moscow region, Russian Federation
L.V. Kirensky Institute of Physics, Siberian Branch, RAS, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Stanislavchuk, T. N.; Chukalina, E. P.; Popova, M. N.; Bezmaternykh, L. N.; Gudim, I. A.; Гудим, Ирина Анатольевна

    Studies of magnetic and optic properties of rare-earth gallo-ferroborates by Mossbauer and optical spectroscopy
/ O. A. Bayukov [et al.] // Physica B. - 2005. - Vol. 359: International Conference on Strongly Correlated Electron Systems (SCES 04) (JUL 26-30, 2004, Karlsruhe, GERMANY). - P. 1321-1323, DOI 10.1016/j.physb.2005.01.397. - Cited References: 3 . - ISSN 0921-4526
РУБ Physics, Condensed Matter

Аннотация: Magnetic and optical properties of GdFe3-xGax(BO3)(4) single crystals are investigated by Mossbauer and optical spectroscopy. The GdFe3(BO3)(4) multielectron band structure model is derived. A high- and low-spin crossover of Fe3+ ion, a collapse of the magnetic moment, the suppression of Coulomb correlations, and insulator-semiconductor transition are predicted. The jump of an energy gap is measured at pressure 43 GPa. (c) 2005 Elsevier B.V. All rights reserved.

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Держатели документа:
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk, Russia
Inst High Pressure Phys, Troitsk 142190, Russia
Inst Crystallog, Moscow 117333, Russia
Univ Liverpool, Liverpool L69 3BX, Merseyside, England
ИФ СО РАН
LV Kirensky Institute of Physics, Siberian Branch of RAS, Krasnoyarsk, Russian Federation
Institute of High Pressure Physics, 142190, Troisk, Moscow region, Russian Federation
Institute of Crystallograhy, Leninsky Av. 59, 117333, Moscow, Russian Federation
The University of Liverpool, Liverpool L69 3BX, United Kingdom

Доп.точки доступа:
Bayukov, O. A.; Баюков, Олег Артемьевич; Gavrilyuk, A. M.; Zabluda, V. N.; Заблуда, Владимир Николаевич; Lyubutin, I. S.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Potseluyko, A. M.; Tomas, M.; Trojan, I. A.; Kharlamova, S. A.