Рубрики:
LIGANDS
Кл.слова (ненормированные):
Rhenium -- Copper -- Vinylidene complexes -- Heterometallic complexes -- X-ray structure -- Cyclic voltammetry
LIGANDS
Кл.слова (ненормированные):
Rhenium -- Copper -- Vinylidene complexes -- Heterometallic complexes -- X-ray structure -- Cyclic voltammetry
Аннотация: The interaction between Cp(CO)2ReCCHPh (1) and CuCl results in the new heterometallic μ-vinylidene complex [Cp(CO)2ReCu(μ2-CCHPh)(μ2-Cl)]2 (2) characterized earlier by IR and 1H, 13C NMR spectra. The molecular structure of compound 2 has been determined by X-ray diffraction analysis, revealing a dimer structure with two binuclear fragments linked to each other by asymmetric chloride bridges. The electrochemical behavior of 2 in acetonitrile was studied by cyclic voltammetry at a Pt-electrode.
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Держатели документа:
Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia
Russian Acad Sci, Siberian Branch, Inst Phys, Krasnoyarsk 660036, Russia
RAS, Siberian Branch, Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia;КНЦ СО РАНИХХТ СО РАН;
Доп.точки доступа:
Chudin, O. S.; Verpekin, V. V.; Burmakina, G. V.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Pavlenko, N. I.; Rubaylo, A. I.; Presidium of the Russian Academy of Sciences [8.15]