/ L. Ma [et al.]> // Phys. Chem. Chem. Phys. - 2015. -
Vol. 17,
Is. 46. - P. 31188-31194,
DOI 10.1039/c5cp05130d. - Cited References: 28. - The present work was supported by the National Natural Science Foundations of China (Grant No. 51572023, 51272242 and 51511130035), and Fundamental Research Funds for the Central Universities (FRF-TP-15-005A1). The author A. H. Reshak would like to acknowledge the CENTEM project, reg. no. CZ.1.05/2.1.00/03.0088, cofunded by the ERDF as part of the Ministry of Education, Youth and Sports OP RDI programme and, in the follow-up sustainability stage, supported through CENTEM PLUS (LO1402) by financial means from the Ministry of Education, Youth and Sports under the National Sustainability Programme I. Computational resources were provided by MetaCentrum (LM2010005) and CERIT-SC (CZ.1.05/3.2.00/08.0144) infrastructures. SA would like to thank CSIR-NPL and Physics Department IIT Delhi for financial support. This work was partly supported by the Russian Foundation for Basic Research (Grant No. 15-52-53080 GFEN_a). VVA was partly supported by the Ministry of Education and Science of the Russian Federation.
. - ISSN 1463-9076
Перевод заглавия: Разработка кислородных вакансий для самоактивируемых люминесцентных материалов BaLuAlxZn4-xO7-(1-x)/2: экспериментальный и теоретический анализ
РУБ Chemistry, Physical + Physics, Atomic, Molecular & Chemical
Аннотация: Novel self-activated yellow-emitting BaLuAlxZn4-xO7-(1-x)/2 photoluminescent materials were investigated by a combined experimental and theoretical analysis. The effects of Al/Zn composition modulation, calcination atmosphere and temperature on the crystal structure and photoluminescence properties have been studied via engineering oxygen
vacancies. Accordingly, BaLuAl0.91Zn3.09O7 prepared in an air atmosphere was found to be the stable crystalline phase with optimal oxygen content and gave a broad yellow emission band with a maximum at 528 nm. The self-activated luminescence mechanism is ascribed to the O-
vacancies based on the density functional theory (DFT) calculation. A theoretical model originating from the designed oxygen
vacancies has been proposed in order to determine the influence of O-
vacancies on the band structure and self-activated luminescence. Therefore, the appearance of a new local energy level in the band gap will cause the wide-band optical transitions in the studied BaLuAlxZn4-xO7-(1-x)/2 materials.
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Держатели документа: School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, China
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, Russian Federation
Functional Electronics Laboratory, Tomsk State University, Tomsk, Russian Federation
Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Council of Scientific and Industrial Research-National Physical Laboratory Dr K S Krishnan Marg, New Delhi, India
Department of Physics, Indian Institute of Technology, Hauz Khas, New Delhi, India
New Technologies-Research Centre, University of West Bohemia, Univerzitni 8, Pilsen, Czech Republic
Center of Excellence Geopolymer and Green Technology, School of Material Engineering, University Malaysia Perlis, Kangar, Perlis, Malaysia
Доп.точки доступа: Ma, L.; Xia, Z.; Atuchin, V. V.; Атучин, Виктор Валерьевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Auluck, S.; Reshak, A. H.; Liu, Q.