Рубрики:
(NH4)3VO2F4
(NH4)3VO2F4
Аннотация: (NH4)(3)VO2F4 crystals were grown, and polarization-optical studies and measurements of birefringence were conducted on crystal plates of various cuts over a wide temperature range. Phase transitions were detected at temperatures T-1 up arrow = 417 K, T-3 up arrow = 211 K, and T-4 up arrow = 205 K (on heating) and at T-1 down arrow = 413 K, T-3 down arrow = 210 K, and T-4 down arrow = 200 K (on cooling). The transitions are accompanied by anomalies of the birefringence and by twinning. The sequence of changes in the phase symmetry is assumed to be as follows: cubic Fm (3) over barm↔ orthorhombic Immm (I222(1)) monoclinic 112/m)↔ triclinic P (1) over bar. Near temperatures T-2 approximate to 240-250 K, an additional anomaly of the birefringence is observed, with the crystal retaining the orthorhombic symmetry.
WOS,
Scopus,
Для получение полного текста обратитесь в библиотеку
Держатели документа:
[Mel'nikova, S. V.
Kocharova, A. G.] Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Доп.точки доступа:
Kocharova, A. G.; Кочарова, Алла Георгиевна; Мельникова, Светлана Владимировна; Russian Federation [NSh-1011.2008.2]; Russian Foundation for Basic Research [06-02-16 102]