/ E. A. Pavlov [et al.] // Russ. Metall. - 2018. -
Is. 8. - P. 728-732,
DOI 10.1134/S0036029518080141. - Cited References: 18. - This work was performed in terms of project no. 1622/17 of the Krasnoyarsk Plant of Nonferrous Metals and the Institute of Solid State Chemistry and Mechanochemistry.
. - ISSN 0036-0295. - ISSN 1555-6255
РУБ Metallurgy & Metallurgical Engineering
Аннотация: The interaction between a solid inert metal (Ir) and an active liquid metal (Ga) during mechanical activation in a high-energy planetary mill is studied by X-ray diffraction and scanning electron microscopy with EDS-apparatus for high-resolution energy dispersive X-ray microanalysis. The influence of mechanical activation conditions on the formation of GaxIry intermetallic compounds and GaxIry/Ir composites and on their solubility in various acids is investigated. Being a surfactant for iridium, gallium propagates along the grain boundaries of polycrystalline iridium particles during mechanical activaiton and, hence, sharply decreases their strength. As a result of strong mechanical deformation during activation, the contact surface area between the solid and liquid metals, where the intermetallic compounds form intensely, increases sharply. As a result of treatment of the products of mechanical activaiton by a mixture of concentrated hydrochloric and nitric acids, iridium (>30%) from passes into an acid solution and forms HxIrCly complex compounds, which can interact with bases to form soluble complex salts.
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Держатели документа: OAO Krasnoyarsk Plant Nonferrous Met, Krasnoyarsk 660027, Russia.
Russian Acad Sci, Siberian Branch, Fed Res Ctr, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Inst Solid State Chem & Mechanochem, Novosibirsk 630128, Russia.
Russian Acad Sci, Ural Branch, Inst Met, Ekaterinburg 620016, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Доп.точки доступа: Pavlov, E. A.; Chuprov, I. V.; Nikulin, M. V.; Mal'tsev, E. V.; Pshenichnaya, A. A.; Пшеничная, Анастасия Александровна; Grigoreva, T. F.; Pastukhov, E. A.; Skuratov, A. P.; Lyakhov, N. Z.
