Рубрики:
MAGNETO-OPTICAL PROPERTIES
FEBO3 SINGLE-CRYSTALS
FERRIC BORATE
CALCITE STRUCTURE
IRON BORATE
TEMPERATURE
FIELD
SPECTRA
FE3BO6
CRBO3
MAGNETO-OPTICAL PROPERTIES
FEBO3 SINGLE-CRYSTALS
FERRIC BORATE
CALCITE STRUCTURE
IRON BORATE
TEMPERATURE
FIELD
SPECTRA
FE3BO6
CRBO3
Аннотация: The Mossbauer effect in the Fe1 - xVxBO3 solid solutions has been measured at 130 and 300 K. The Fe0.05V0.95BO3 composition was studied in the interval 4.2-300 K. The experimental data obtained are described in terms of the model of a dilute magnetic insulator in which atoms of the first coordination sphere provide a major contribution to the hyperfine field at iron nucleus sites. It was found that, at low temperatures, the field H-hf is generated primarily by the iron ion itself and depends only weakly on substitution. The hyperfine interaction parameters in the discrete configuration series 6Fe, 5Fe1V, 4Fe2V, 3Fe3V, and 2Fe4V were determined. The magnitude of the isomer shift suggests that iron in the crystal resides in the trivalent state. (C) 2004 MAIK "Nauka/Interperiodica".
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Держатели документа:
Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Univ Cologne, Inst Phys, D-50937 Cologne, Germany
Krasnoyarsk State Tech Univ, Krasnoyarsk 660074, Russia
ИФ СО РАН
Physikalisches Institut, Universitat zu Koln, Koln, 50937, Germany
Krasnoyarsk Stt. Tech. University, Krasnoyarsk, 660074, Russian Federation
Доп.точки доступа:
Bayukov, O. A.; Баюков, Олег Артемьевич; Abd-Elmeguid, M. M.; Ivanova, N. B.; Иванова, Наталья Борисовна; Kazak, N. V.; Казак, Наталья Валерьевна; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Rudenko, V. V.; Руденко, Валерий Васильевич; Skrebtsov, G. \пер.\