Аннотация: A new scheme of fullerene formation is proposed on the basis of the similarity between the experimentally detected carbon structures. According to experimental data, the microclusters of C(2) and C(10) are synthesized first and then either an intermediate nucleus cluster or an obtainable lower fullerene is assembled from them. A high-symmetry fullerene can be assembled with a high probability from a nucleus cluster with a "good" symmetry. The atomic and electronic structures of molecules such as C(36), C(60), C(70), and C(76) are analyzed. For C(36), the NMR spectra are calculated and compared with the experimental data. (C) 2001 MAIK "Nauka/Interperiodica".
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Держатели документа:
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Div, Krasnoyarsk 660049, Russia
Russian Acad Sci, Kirenskii Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
Krasnoyarsk State Tech Univ, Krasnoyarsk 660074, Russia
ИФ СО РАН
ИХХТ СО РАН
Inst. of Chem. and Chem. Technology, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, 660049, Russian Federation
Kirenskii Inst. of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Krasnoyarsk Stt. Tech. University, Krasnoyarsk, 660074, Russian Federation
Доп.точки доступа:
Tomilin, F. N.; Томилин, Феликс Николаевич; Avramov, P. V.; Аврамов, Павел Вениаминович; Varganov, S. A.; Kuzubov, A. A.; Кузубов, Александр Александрович; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич