Труды сотрудников института физики

/ A. A. Lundin, V. E. Zobov // J. Exp. Theor. Phys. - 2015. - Vol. 120, Is. 5. - P. 762-771, DOI 10.1134/S1063776115040093. - Cited References:62 . - ISSN 1063. - ISSN 1090-6509. - РУБ Physics, Multidisciplinary

Аннотация: A modification of the widespread phenomenological model theory of multiple-quantum (MQ) nuclear magnetic resonance spectra of a single cluster of correlated spins has been developed. In contrast to the mentioned theory, the size distribution of such clusters has been consistently taken into account. To obtain the distribution, solutions for the amplitudes of the expansion in the complete set of orthogonal operators are used. Expressions specifying the dependence of the profile of the intensities of MQ coherences on their number n (order) have been obtained. The total form of the dependence has been evaluated by means of the numerical implementation of the resulting expressions. The asymptotic expressions for large n values (wings of the spectrum) have been obtained analytically by the saddle-point method. It has been shown that the dependence under study has a Gaussian central part and exponential wings. The results obtained are in agreement with the previous calculations for some model systems and existing experimental data.

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Держатели документа:
Russian Acad Sci, Semenov Inst Chem Phys, Moscow 117977, Russia.
Russian Acad Sci, Akademgorodok, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Zobov, V. E.; Зобов, Владимир Евгеньевич

/ V. E. Zobov, A. A. Lundin // Theor. Math. Phys. - 2004. - Vol. 141, Is. 3. - P. 1737-1749, DOI 10.1023/B:TAMP.0000049765.41265.dd. - Cited References: 24 . - ISSN 0040-5779РУБ Physics, Multidisciplinary + Physics, Mathematical

Аннотация: Using the exactly solvable model known in statistical physics as the infinite-range interaction model (the van der Waals model), we obtain expressions for the hierarchy of multispin multiquantum time correlation functions for a solid-state paramagnetic nuclear spin system with magnetic dipole-dipole interaction between nuclei. These functions are observed experimentally using contemporary multiquantum NMR spectroscopy methods. We write the complete set of orthogonal multispin operators explicitly and find the time dependence for amplitudes of multiparticle time correlation functions. The proposed model describes the behavior of multiparticle correlation functions well, at least for not very large numbers n of expansion harmonics. The theoretical results agree well with the experimental data obtained for hexamethylbenzol.

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Держатели документа:
RAS, Siberian Branch, Kirenskii Inst Phys, Krasnoyarsk, Russia
RAS, NN Semenov Chem Phys Inst, Moscow, Russia
ИФ СО РАН
Kirenskii Institute for Physics, Siberian Branch, RAS, Krasnoyarsk, Russia, Russian Federation
Semenov Inst. for Chemical Physics, RAS, Moscow, Russia, Russian Federation

Доп.точки доступа:
Lundin, A. A.; Зобов, Владимир Евгеньевич

/ V. E. Zobov, M. A. Popov // J. Exp. Theor. Phys. - 2003. - Vol. 97, Is. 1. - P. 78-84, DOI 10.1134/1.1600799. - Cited References: 22 . - ISSN 1063-7761РУБ Physics, Multidisciplinary

Аннотация: The hypothesis concerning the existence of singular points on the imaginary time axis for a correlation function of a system with the dipole-dipole interaction of nuclear spins of a crystal is verified. Within the framework of the self-consistent fluctuating field theory taking into account the principal corrections related to the correlation of local fields, a result for this coordinate is obtained in terms of the ratios of lattice sums. Experimental values of this coordinate are calculated from the wings of the nuclear magnetic resonance absorption spectrum of a BaF2 crystal for the magnetic field directions along the three crystallographic axes. Good agreement of the theoretical and experimental results justifies this hypothesis. (C) 2003 MAIK "Nauka / Interperiodica".

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Держатели документа:
Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Krasnoyarsk State Univ, Krasnoyarsk 660041, Russia
ИФ СО РАН
Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Krasnoyarsk State University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Popov, M. A.; Зобов, Владимир Евгеньевич