Аннотация: This paper reports on measurements of the specific heat of Pb2CdWO6 made at temperatures ranging from 80 to 750 K and of Pb2YbTaO6 within the 350- to 700-K temperature range. First-order phase transitions from the cubic phase at 677.3 and 581 K, respectively, were observed, and their thermodynamic characteristics were determined. The entropy change on the phase transitions is close to Rln4 for both compounds. The results obtained are discussed in terms of the model of position disordering of the lead ions. It was established that below 350 K, Pb2CdWO6 can exist in two states, stable and metastable, depending on the sample thermal prehistory. (C) 2002 MAIK "Nauka/Interperiodica".
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
CNRS, CEMEC, F-31055 Toulouse, France
ИФ СО РАН
Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Sciau, P.