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    The influence of deuteration on the phase transitions in (NH4)(3)Me3+F6 cryolites (Me3+ = Sc and Ga)
/ I. N. Flerov [et al.] // Phys. Solid State. - 2002. - Vol. 44, Is. 10. - P. 1961-1966, DOI 10.1134/1.1514788. - Cited References: 11 . - ISSN 1063-7834
РУБ Physics, Condensed Matter
Рубрики:
(NH4)(3)SCF6

Аннотация: The heat capacity of partially deuterated crystals with a cryolite structure, namely, (NH4)(3)ScF6 and (NH4)(3)GaF6, is measured in the temperature range from 80 to 370 K. The p-T phase diagrams of these compounds are investigated at pressures up to p = 0.6 GPa. It is revealed that the deuteration does not affect the sequences of phase transitions observed in the proton-containing ammonium cryolites studied earlier. The isotope effect most clearly manifests itself in significant changes in the thermodynamic parameters of the I12/m1-P (1) over bar low-temperature transformation in scandium cryolite. (C) 2002 MAIK "Nauka/Interperiodica".

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Держатели документа:
Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Afanas'ev, M. L.; Ushakova, T. V.