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/ E.M. Aver'yanov // Russ. J. Phys. Chem. A. - 2012. - Vol. 86, Is. 5. - P. 720-728, DOI 10.1134/S0036024412050044. - Cited References: 37 . - ISSN 0036-0244РУБ Chemistry, Physical + Anisotropy + Molecules + Phase transitions + Tensors

Аннотация: Experimental values of the mean polarizability of molecules, (gamma) over bar, and components of the Lorentz tensor, L-j, in the nematic and smectic A phases are obtained for a homologous series of n-alkyl-p-(4-ethoxybenzylideneamino)-alpha-methylcinnamates. Dependences of the (gamma) over bar and L-j values on the mesophase temperature, the orientational order parameter S of molecules, and the number n in the homologous series are revealed. The quadratic dependence of (gamma) over bar (S) in the nematic and smectic phases is established that is invariant with respect to the nematic-smectic A transition. Polarizability densities of the molecular core and the alkyl chain are found from the monotone decreasing dependence (gamma) over bar (n)/v (where v is volume per one molecule) in the smectic phase. The presence (or absence) of the odd-even alternation of L-j(n) in the nematic (smectic) phase is shown. A monotone decrease in the Lorentz tensor anisotropy L with an increase in n is revealed in the smectic phase, and limiting values L-j(n -> infinity) are determined.

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Аверьянов, Евгений Михайлович

/ E. M. Aver'yanov // JETP Letters. - 2014. - Vol. 99, Is. 10. - P. 590-593, DOI 10.1134/S0021364014100026. - Cited References: 12 . - ISSN 0021-3640. - ISSN 1090-6487РУБ Physics, Multidisciplinary

Аннотация: The Lorentz tensor components L (j) for poly(vinylidene fluoride-trifluoroethylene, 70/30) Langmuir-Blodgett films in the ferroelectric phase are determined experimentally. The results indicate that intralayer dipole-dipole interaction between the segments of the polymer is stronger than interlayer interaction. This conclusion agrees with the absence of the critical film thickness below which ferroelectricity would cease to exist.

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Аверьянов, Евгений Михайлович

/ E. M. Aver’yanov // JETP Letters. - 2015. - Vol. 101, Is. 10. - P. 685-689, DOI 10.1134/S0021364015100033. - Cited References: 28 . - ISSN 0021-3640РУБ Physics, Multidisciplinary

Аннотация: A relation of the effective refractive index of a two-dimensional polycrystalline dielectric film in the transparency region to the refractive indices n1 and n2 of crystallites at the positions of axes 1 and 2, respectively, of refraction ellipsoids of the crystallites in the plane of the film has been obtained. This relation and the relation L* = (L1 + L2)/2 between the components of the Lorentz tensors for the film and crystallites have been confirmed by comparison with experimental data for conjugate-polymer films with uniaxial domains.

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Аверьянов, Евгений Михайлович

/ E. M. Aver’yanov // Phys. Solid State. - 2016. - Vol. 58, Is. 1. - P. 160-163, DOI 10.1134/S1063783416010042. - Cited References: 20 . - ISSN 1063-7834РУБ Physics, Condensed Matter

Аннотация: The relation between the effective ordinary refractive index n* = (n o n e )1/2 of a quasi-two-dimensional polydomain uniaxial film of a conjugated polymer F8BT in the visible transparency region and the refractive indices (n o,e ) of uniaxial domains with the optical axes randomly oriented in the plane of the film has been confirmed experimentally. The permissible interval of variations in n* has been established and a strong spectral dispersion of this interval near the long-wavelength electronic absorption band of the film has been demonstrated.

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Аверьянов, Евгений Михайлович

/ E. M. Aver’yanov // Phys. Solid State. - 2016. - Vol. 58, Is. 8. - P. 1634-1641, DOI 10.1134/S1063783416080035. - Cited References: 41 . - ISSN 1063-7834РУБ Physics, Condensed Matter

Аннотация: The dimension D of a polycrystalline film and the optical anisotropy m = εz/εx of uniaxial crystallites with the principal components εx = εy and εz of the tensor of the dielectric constant have been shown to produce a strong influence on the effective dielectric constant εD* and the effective refractive index nD* = (εD*)1/2 of the film in the optical transparency region, as well as on the boundaries of the intervals BDl ≤ εD* ≤ BDu. The intervals Δ2(m) = B2l–B2u and Δ3(m) = B3l–B3u are separated by a gap for m in the range 1 m 2, whereas the theoretical dependence ε2*(m) is separated by a gap from the interval Δ3(m) for m in the range 1 m 4. This is confirmed by a comparison of the experimental (noP) and theoretical (nD*) ordinary refractive indices for uniaxial polycrystalline films of the conjugated polymer poly(p-phenylene vinylene) (PPV) with uniaxial crystallites and appropriate values of m. In the visible transparency region of the PPV films with a change in m(λ) in the range 2 m(λ) 3 due to the dependence of the components εx,z(λ) on the light wavelength λ, the refractive indices noP2(λ) 3 near the electronic absorption band of the crystallites, the values of εoP(λ) lie in the region of the overlap of the intervals Δ2(m) and Δ3(m). The boundaries mc of the range 1 m mc are determined, for which the interval Δ2(m) is separated by a gap from the dependences ε3*(m) corresponding to the effective medium theory with spherical crystallites and hierarchical models of a polycrystal, as well as from the proposed new dependence ε3*(m).

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Доп.точки доступа:
Аверьянов, Евгений Михайлович