Рубрики:
XMF3 CUBIC PEROVSKITES
THERMAL-PROPERTIES
HEAT-CAPACITY
TEMPERATURE DEPENDENCE
DIELECTRIC PROPERTIES
X-RAY
NH4ZNF3
NH4MNCL3
NH4COF3
NH4CDF3
XMF3 CUBIC PEROVSKITES
THERMAL-PROPERTIES
HEAT-CAPACITY
TEMPERATURE DEPENDENCE
DIELECTRIC PROPERTIES
X-RAY
NH4ZNF3
NH4MNCL3
NH4COF3
NH4CDF3
Аннотация: The pressure dependence of the structural phase transition temperature has been measured for the powder samples of NH4MgF3, NH4ZnF3, NH4MnF3, NH4CoF3, NH4CdF3, and NH4MnCl3 perovskites in the pressure range 0 to 600 MPa. It was found that the values of dT(0)/dP are negative for the Mg, Zn. Co. Mn trifluorides and positive for NH4CdF3 and NH4MnCl3. Comparison with the known data for other halide and oxide perovskites allowed to conclude that the sign of dT(0)/dP is correlated with the value of the Goldschmidt tolerance factor of the perovskite, and its value is closely related to the temperature and mechanism of the transition.
WOS
Держатели документа:
Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Zaragoza 50009, Spain
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Доп.точки доступа:
Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Bartolome, J.; Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич