Рубрики:
TRANSITION-METAL-COMPLEXES
CATIONIC CARBYNE COMPLEXES
RAY CRYSTAL-STRUCTURE
MOLECULAR-STRUCTURE
HETEROBIMETALLIC COMPLEXES
LIGANDS
MANGANESE
CLUSTERS
DINUCLEAR
PD2CL2(MU-PH2PCH2PPH2)2
Кл.слова (ненормированные):
Rhenium -- Palladium -- Iron -- Vinylidene complexes -- Heterometallic complexes
TRANSITION-METAL-COMPLEXES
CATIONIC CARBYNE COMPLEXES
RAY CRYSTAL-STRUCTURE
MOLECULAR-STRUCTURE
HETEROBIMETALLIC COMPLEXES
LIGANDS
MANGANESE
CLUSTERS
DINUCLEAR
PD2CL2(MU-PH2PCH2PPH2)2
Кл.слова (ненормированные):
Rhenium -- Palladium -- Iron -- Vinylidene complexes -- Heterometallic complexes
Аннотация: The reaction of [Cp(CO)2ReCCHPh] (1) with [Pd(PPh3)4] followed by the treatment of resulting [Cp(CO)2RePd(μ-CCHPh)(PPh3)2] (2) with diphosphines (dppe, dppp) gave new complexes [Cp(CO)2RePd(μ-CCHPh)(dppe)] (3) and [Cp(CO)2RePd(μ-CCHPh)(dppp)] (4). Treatment of the synthesized complexes with [Fe2(CO)9] led to mixtures of [Cp(CO)2ReFe(μ-CCHPh)(CO)4] (5), [(dppe)PdFe2(CO)8] (6), [CpReFe2(μ3-CCHPh)(CO)8] (7), [CpReFePd(μ3-CCHPh)(CO)5(dppe)] (8) and of 5, [(dppp)PdFe2(CO)8] (9), [CpReFePd(μ3-CCHPh)(CO)5(dppp)] (10), respectively. The main products of both reactions were trinuclear μ3-vinylidene clusters 8 and 10. Reactions of the trinuclear μ3-vinylidene ReFePd clusters 8 and 10 with Fe2(CO)9 were also studied. New complexes were characterized by IR, 1H, 13C, 31P NMR spectroscopy and cyclic voltammetry. The structure of [CpReFe2(μ3-CCHPh)(CO)8] was determined by single-crystal X-ray diffraction.
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Держатели документа:
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660036, Russia
Russian Acad Sci, Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
RAS, Siberian Branch, Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Доп.точки доступа:
Verpekin, V. V.; Верпекин В. В.; Kondrasenko, A. A.; Кондрасенко, Александр Александрович; Chudin, O. S.; Чудин О. С.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Burmakina, G. V.; Бурмакина Г. В.; Pavlenko, N. I.; Павленко, Нина Ивановна; Rubaylo, A. I.; Рубайло, Анатолий Иосифович