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Найдено документов в текущей БД: 18

    Optodynamic phenomena in aggregates of polydisperse plasmonic nanoparticles
[Text] / A. E. Ershov [et al.] // Appl. Phys. B-Lasers Opt. - 2014. - Vol. 115, Is. 4. - P. 547-560, DOI 10.1007/s00340-013-5636-6. - Cited References: 48. - Authors are thankful to Prof. V. A. Markel (University of Pennsylvania) for supplying program codes for realization of the coupled dipole method for polydisperse metal nanoparticle aggregates. This research was supported by the Russian Academy of Sciences under the Grants 24.29, 24.31, III.9.5, 43, SB RAS-SFU (101); Ministry of Education and Science of Russian Federation under Contract 14.B37.21.0457. . - ISSN 0946-2171. - ISSN 1432-0649
РУБ Optics + Physics, Applied

Аннотация: We propose an optodynamical model of interaction of pulsed laser radiation with aggregates of spherical metallic nanoparticles embedded into host media. The model takes into account polydispersity of particles, pair interactions between the particles, dissipation of absorbed energy, heating and melting of the metallic core of particles and of their polymer adsorption layers, and heat exchange between electron and ion components of the particle material as well as heat exchange with the interparticle medium. Temperature dependence of the electron relaxation constant of the particle material and the effect of this dependence on interaction of nanoparticles with laser radiation are first taken into consideration. We study in detail light-induced processes in the simplest resonant domains of multiparticle aggregates consisting of two particles of an arbitrary size in aqueous medium. Optical interparticle forces are realized due to the light-induced dipole interaction. The dipole moment of each particle is calculated by the coupled dipole method (with correction for the effect of higher multipoles). We determined the role of various interrelated factors leading to photomodification of resonant domains and found an essential difference in the photomodification mechanisms between polydisperse and monodisperse nanostructures.

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Держатели документа:
[Ershov, A. E.
Karpov, S. V.
Semina, P. N.] Russian Acad Sci, LV Kirenski Inst Phys, Krasnoyarsk 660036, Russia
[Gavrilyuk, A. P.] Russian Acad Sci, Inst Computat Modeling, Krasnoyarsk 660036, Russia
[Gavrilyuk, A. P.
Karpov, S. V.] Siberian Fed Univ, Krasnoyarsk 660028, Russia
ИФ СО РАН
ИВМ СО РАН

Доп.точки доступа:
Ershov, A.E.; Gavrilyuk, A.P.; Гаврилюк, Анатолий Петрович; Karpov, S.V.; Semina, P.N.; Russian Academy of Sciences [24.29, 24.31, III.9.5, 43, SB RAS-SFU (101)]; Ministry of Education and Science of Russian Federation [14.B37.21.0457]

    Effect of local environment in resonant domains of polydisperse plasmonic nanoparticle aggregates on optodynamic processes in pulsed laser fields
[Text] / A. E. Ershov [et al.] // Chin. Phys. B. - 2015. - Vol. 24, Is. 4. - Ст. 047804, DOI 10.1088/1674-1056/24/4/047804. - Cited References:25. - Project supported by the Russian Academy of Sciences (Grant Nos. 24.29, 24.31, III.9.5, 43, SB RAS-SFU (101), and 3-9-5). . - ISSN 1674-1056. - ISSN 1741-4199
РУБ Physics, Multidisciplinary
Рубрики:
METAL NANOPARTICLES
   GOLD NANOPARTICLES

   OPTICAL-PROPERTIES

Кл.слова (ненормированные):
nanoparticle -- surface plasmon -- colloid aggregate -- optodynamics

Аннотация: Interactions of pulsed laser radiation with resonance domains of multiparticle colloidal aggregates having an increasingly complex local environment are studied via an optodynamic model. The model is applied to the simplest configurations, such as single particles, dimers, and trimers consisting of mono- and polydisperse Ag nanoparticles. We analyze how the local environment and the associated local field enhancement by surrounding particles affect the optodynamic processes in domains, including their photomodification and optical properties.

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Держатели документа:
Russian Acad Sci, LV Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Russian Acad Sci, Inst Computat Modeling, Krasnoyarsk 660036, Russia
Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
Siberian Fed Univ, Krasnoyarsk 660028, Russia

Доп.точки доступа:
Ershov, A.E.; Gavrilyuk, A.P.; Гаврилюк, Анатолий Петрович; Karpov, S.V.; Semina, P.N.; Russian Academy of Sciences [24.29, 24.31, III.9.5, 43, SB RAS-SFU (101), 3-9-5]

    Возможности построения радиосвязи с помощью орбитальных отражателей и магнитных антенн вращающейся поляризации
[Текст] : статья / Н. А. Тестоедов [и др.] // Вестник Сибирского государственного аэрокосмического университета им. академика М.Ф. Решетнева. - 2015. - Т. 16, № 2. - С. 364-367 . - ISSN 1816-9724
   Перевод заглавия: The possibility of constructing a radio communication using orbital reflectors and magnetic antennas polarization rotating

Кл.слова (ненормированные):
radio -- microsatellites -- magnetic antennas -- радиосвязь -- микроспутники -- магнитные антенны

Аннотация: Применение космоса для традиционных радиолюбительских приложений возможно с помощью относительно дешевых маложивущих микроспутников, которые выводятся на низкие орбиты экипажем космической станции. Радиосвязь может быть построена на базе отражателей и частотно-независимых малых магнитных антенн с вращающейся поляризацией, которые должны выполнять специальную функцию - связывать излученную в пространстве электромагнитную энергию с электронными компонентами аппаратуры, и поэтому они являются одними из основных элементов, определяющих построение радиотехнических систем. Поскольку в природе нет магнитных зарядов и, следовательно, нет магнитного тока, понимаемого как движение этих зарядов, то магнитный излучатель как элемент магнитного тока не может быть осуществлен, однако если антенный излучатель изначально создает переменное вращающееся вихревое магнитное поле, создать антенну возможно, реализовав в ней свойства магнитоэлектрической индукции. Первая телефонная спутниковая связь между Америкой и Великобританией была налажена через массивный экспериментальный американский спутник Echo1, запущенный на низкую околоземную орбиту, который представлял собой шар диаметром около 30 м, изготовленный из радиоотражающего материала. Тип такого спутника связи можно применить и в предлагаемой радиосвязи. Однако поскольку приемные и передающие антенны являются узконаправленными, то космический аппарат должен иметь на орбите такую ориентацию, чтобы он принял сигнал и отразил его. Диаметр сферы при этом может быть значительно меньших размеров, а положение на орбите можно удерживать корректирующей двигательной установкой, расположенной в центре масс. Радиоотражающая поверхность может быть выполнена из надувной пленки или сетеполотна, изготовленного, например, из позолоченной вольфрамовой проволоки диаметром порядка 30 мкм, разворачиваемого в сферу в трансформируемой конструкции. Возможен вариант выполнения сетеполотна из магнитно-мягкого материала типа сталей Э8, Э10, железа «Армко» или пермаллоя, которые являются идеальными проводниками магнитных потоков и не требуют охлаждения до криогенных температур.
The use of space for traditional Amateur radio applications is possible using relatively cheap only briefly long microsatellites, which are displayed on a low orbit of the space station crew. The radio can be built on the basis of reflectors and frequency-independent small magnetic antenna with circular polarization, which must fulfill a special function: to associate radiated into space electromagnetic energy with electronic components of the apparatus, and therefore are one of the main defining elements of the building radio systems. Since there are no magnetic charges, and therefore, no magnetic current, understood as the movement of these charges, a magnetic emitter, a magnetic current element, cannot be accomplished, however, if the antenna radiator initially creates an alternating rotating vortex magnetic field, it is possible to create the antenna having in it the properties of magneto-electric induction. The first satellite phone communication between America and Britain was established through a massive experimental American satellite Echo1, launched into low earth orbit, which represented a ball with a diameter of about 30 m, made of radiotracer material. The type of such a communication satellite can be used in the proposed radio communications. However, since the receiving and transmitting antennas are highly directional, the spacecraft must be in the orbit of such an orientation that it took the signal and reflected it. The diameter of the sphere can be much smaller, and the position in orbit to keep a corrective propulsion system, located in the center of mass. Radioreflective surface may be made of an inflatable film or setpolicy made, for example, of gold-plated tungsten wire with a diameter of about 30 ?m deployed in the field in transformable structures. Possible embodiment of setpolicy of magnetically soft material type steel A, E, iron “Armco” or permalloy, which are perfect conductors of magnetic flux and do not require cooling to cryogenic temperatures.

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Держатели документа:
АО «Информационные спутниковые системы» имени академика М. Ф. Решетнёва»
Институт вычислительного моделирования СО РАН

Доп.точки доступа:
Тестоедов, Н.А.; Testoedov N.A.; Двирный, В.В.; Dvirnyi V.V.; Крушенко, Генрих Гаврилович; Krushenko G.G.; Двирный, Г.В.; Dvirnyi G.V.
577.29
Ф 94

    Функционализированные аптамерами магнитные нанодиски для нанохирургии опухолей
[Текст] : статья / С. С. Замай [и др.] // Сибирское медицинское обозрение. - 2015. - № 6. - С. 48-54 . - ISSN 1819-9496
   Перевод заглавия: Functionalized by the aptamers magnetic nanodiscs for nanosurgery of the tumors
УДК

Аннотация: Цель исследования. Определение перспектив использования функционализированных ДНК-аптамерами магнитных никелевых нанодисков с золотым покрытием для адресной клеточной хирургии онкологических заболеваний. Матери алы и методы. В качестве модели опухоли была использована асцитная карцинома Эрлиха. Теоретически и экспериментально исследованы структуры магнитного поля пермаллоевых и кобальтовых дисков Au-Fe(20)Ni(80)-Au и Au-Co-Au. Результаты. Выполнены оценки механического воздействия нанодисков на клеточную мембрану в переменном магнитном поле. Определены оптимальные состав, геометрия и структура остаточной намагниченности нанодисков. Экспериментально in vitro и in vivo для асцитной карциномы Эрлиха показана возможность использования функционализированных ДНК-аптамерами трехслойных Au-Ni-Au нанодисков с дипольной структурой остаточной намагниченности для адресного разрушения клеток-мишеней. 3аключе-ие. На основании теоретических расчетов и экспериментальных данных сделано заключение о том, что нанодиски Au-Ni-Au, обладающие магнитными свойствами, могут быть использованы для разработки новых методов и препаратов для малоинвазивной клеточной нанохирургии, которая позволяет адресно и дозировано уничтожать только клетки опухоли, в том числе, и метастазы.
The aim of the research. Determination of the prospects of application the functionalized by DNA-aptamers magnetic nickel nanodiscs with gold coating for targeted cell cancer surgery. Materials and methods. As tumor model was used Ehrlich ascites carcinoma. Theoretically and experimentally were investigated the structures of the magnetic field of permalloy and cobalt disks Au-Fe (20) Ni (80) -Au and Au-Co-Au. Results. It were executed the estimation of the mechanical impact of nanodiscs to the cell membrane in an alternating magnetic field. It was determined the optimum composition, geometry and structure of the residual magnetization of nanodiscs. Experimentally in vitro and in vivo for Ehrlich ascites carcinoma was showed the use of functionalized DNA-aptamers three layer Au-Ni-Au nanodisks with dipole structure of the residual magnetization for address destruction of the target cells. Conclusion. On the basis of theoretical calculations and experimental data, it was concluded that nanodiscs Au-Ni-Au, with magnetic properties, can be used to develop new methods and products for minimally invasive cellular nanosurgery that allows targeted and dosed destroy only tumor cells, including metastasis.

РИНЦ

Держатели документа:
ГАОУ ВПО Сибирский федеральный университет
ГБОУ ВПО Красноярский государственный медицинский университет имени проф. В. Ф. Войно-Ясенецкого Министерства здравоохранения РФ
ГБОУ ВПО Красноярский государственный педагогический университет им. В. П. Астафьева Министерства образования и науки РФ
Институт вычислительного моделирования СО РАН
Красноярский научный центр СО РАН

Доп.точки доступа:
Замай, Сергей Сергеевич; Zamay Sergey Sergeevich; Прокопенко, Владимир Семенович; Prokopenko Vladimir Semenovich; Замай, Анна Сергеевна; Zamay Anna Sergeevna; Денисенко, Валерий Васильевич; Denisenko V.V.; Ким, Петр Дементьевич; Kim Petr Dementievich; Орлов, Виталий Александрович; Orlov Vitaly Alerksandrovich; Замай, Галина Сергеевна; Zamay Galina Sergeevna; Иванченко, Татьяна Ивановна; Ivanchenko Tatiana Ivanovna; Замай, Татьяна Николаевна; Zamay Tatiana Nikolaevna

    Optimization of photothermal methods for laser hyperthermia of malignant cells using bioconjugates of gold nanoparticles
/ V. S. Gerasimov [et al.] // Colloid J. - 2016. - Vol. 78, Is. 4. - P435-442, DOI 10.1134/S1061933X16040050 . - ISSN 1061-933X
Аннотация: Selective action of laser radiation on membranes of malignant cells has been studied in different regimes using conjugates of gold nanoparticles with oligonucleotides by the example of DNA aptamers. Under the conditions of a contact between a bioconjugate and a cell surface and the development of substantial and rapidly relaxing temperature gradients near a nanoparticle, the membranes of malignant cells alone are efficiently damaged due to the local hyperthermia of a cellular membrane. It has been shown that employment of pulsed instead of continuous wave laser radiation provides the localization of the damaging action, which does not involve healthy cells. © 2016, Pleiades Publishing, Ltd.

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Держатели документа:
Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk, Russian Federation
Institute of Computational Modeling, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50/44, Krasnoyarsk, Russian Federation
Kirenskii Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50/38, Krasnoyarsk, Russian Federation
Reshetnev State Siberian State Aerospace University, pr. Gazety “Krasnoyarskii rabochii” 31, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Gerasimov, V. S.; Ershov, A. E.; Karpov, S. V.; Polyutov, S. P.; Semina, P. N.

    Suppression of surface plasmon resonance in Au nanoparticles upon transition to the liquid state
/ V. S. Gerasimov [et al.] // Opt. Express. - 2016. - Vol. 24, Is. 23. - P26851-26856, DOI 10.1364/OE.24.026851 . - ISSN 1094-4087
Аннотация: Significant suppression of resonant properties of single gold nanoparticles at the surface plasmon frequency during heating and subsequent transition to the liquid state has been demonstrated experimentally and explained for the first time. The results for plasmonic absorption of the nanoparticles have been analyzed by means of Mie theory using experimental values of the optical constants for the liquid and solid metal. The good qualitative agreement between calculated and experimental spectra support the idea that the process of melting is accompanied by an abrupt increase of the relaxation constants, which depends, beside electronphonon coupling, on electron scattering at a rising number of lattice defects in a particle upon growth of its temperature, and subsequent melting as a major cause for the observed plasmonic suppression. It is emphasized that observed effect is fully reversible and may underlie nonlinear optical responses of nanocolloids and composite materials containing plasmonic nanoparticles and their aggregates in conditions of local heating and in general, manifest itself in a wide range of plasmonics phenomena associated with strong heating of nanoparticles. © 2016 Optical Society of America.

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Держатели документа:
Siberian Federal University, Krasnoyarsk, Russian Federation
Institute of Computational Modeling, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian State Aerospace University, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarskz, Russian Federation
Division of Theoretical Chemistry and Biology, Royal Institute of Technology, Stockholm, Sweden

Доп.точки доступа:
Gerasimov, V. S.; Ershov, A. E.; Gavrilyuk, A. P.; Karpov, S. V.; Agren, H.; Polyutov, S. P.

    Thermal effects in systems of colloidal plasmonic nanoparticles in high-intensity pulsed laser fields [Invited]
/ V. S. Gerasimov [et al.] // Opt. Mater. Express. - 2017. - Vol. 7, Is. 2. - P555-568, DOI 10.1364/OME.7.000555 . - ISSN 2159-3930
Аннотация: We have studied light induced processes in nanocolloids and composite materials containing ordered and disordered aggregates of plasmonic nanoparticles accompanied by their strong heating. A universal comprehensive physical model that combines mechanical, electrodynamical, and thermal interactions at nanoscale has been developed as a tool for investigations. This model was used to gain deep insight on phenomena that take place in nanoparticle aggregates under high-intensity pulsed laser radiation resulting in the suppression of nanoparticle resonant properties. Verification of the model was carried out with single colloidal Au and Ag nanoparticles and their aggregates. © 2017 Optical Society of America.

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Держатели документа:
Siberian Federal University, Krasnoyarsk, Russian Federation
Institute of Computational Modeling, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian State Aerospace University, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Royal Institute of Technology, Stockholm, Sweden
The Beckman Institute for Advanced Science and Technology, University of Illinois at Urbana-Champaign, Urbana, IL, United States

Доп.точки доступа:
Gerasimov, V. S.; Ershov, A.E.; Ершов, Александр Евгеньевич; Karpov, S. V.; Gavrilyuk, A.P.; Гаврилюк, Анатолий Петрович; Zakomirnyi, V. I.; Rasskazov, I. L.; Agren, H.; Polyutov, S. P.

    Surface plasmon resonances in liquid metal nanoparticles
/ A. E. Ershov [et al.] // Appl Phys B. - 2017. - Vol. 123, Is. 6, DOI 10.1007/s00340-017-6755-2 . - ISSN 0946-2171
Аннотация: We have shown significant suppression of resonant properties of metallic nanoparticles at the surface plasmon frequency during the phase transition “solid–liquid” in the basic materials of nanoplasmonics (Ag, Au). Using experimental values of the optical constants of liquid and solid metals, we have calculated nanoparticle plasmonic absorption spectra. The effect was demonstrated for single particles, dimers and trimers, as well as for the large multiparticle colloidal aggregates. Experimental verification was performed for single Au nanoparticles heated to the melting temperature and above up to full suppression of the surface plasmon resonance. It is emphasized that this effect may underlie the nonlinear optical response of composite materials containing plasmonic nanoparticles and their aggregates. © 2017, Springer-Verlag Berlin Heidelberg.

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Держатели документа:
Institute of Computational Modeling, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, Russian Federation
Siberian State University of Science and Technologies, Krasnoyarsk, Russian Federation
L.V. Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Ershov, A. E.; Gerasimov, V. S.; Gavrilyuk, A. P.; Karpov, S. V.

    Titanium nitride as light trapping plasmonic material in silicon solar cell
/ N. Venugopal [et al.] // Opt Mater. - 2017. - Vol. 72. - P397-402, DOI 10.1016/j.optmat.2017.06.035 . - ISSN 0925-3467

Кл.слова (ненормированные):
Photovoltaics -- Plasmonics -- Titanium nitride -- Absorption spectroscopy -- CMOS integrated circuits -- Efficiency -- Gold -- Metals -- MOS devices -- Nanoparticles -- Nanostructured materials -- Nitrides -- Optoelectronic devices -- Plasmons -- Semiconductor devices -- Silicon -- Silver -- Solar cells -- Solar power generation -- Thin film solar cells -- Thin films -- Time domain analysis -- Tin oxides -- Titanium -- Titanium compounds -- Titanium nitride -- Absorption enhancement -- Complementary metal oxide semiconductors -- Nanoparticle diameter -- Other opto-electronic devices -- Photovoltaics -- Plasmonic nanoparticle -- Plasmonics -- Thin-film silicon solar cells -- Silicon solar cells

Аннотация: Light trapping is a crucial prominence to improve the efficiency in thin film solar cells. However, last few years, plasmonic based thin film solar cells shows potential structure to improve efficiency in photovoltaics. In order to achieve the high efficiency in plasmonic based thin film solar cells, traditionally noble metals like Silver (Ag) and Gold (Au) are extensively used due to their ability to localize the light in nanoscale structures. In this paper, we numerically demonstrated the absorption enhancement due to the incorporation of novel plasmonic TiN nanoparticles on thin film Silicon Solar cells. Absorption enhancement significantly affected by TiN plasmonic nanoparticles on thin film silicon was studied using Finite-Difference-Time-Domain Method (FDTD). The optimal absorption enhancement 1.2 was achieved for TiN nanoparticles with the diameter of 100 nm. The results show that the plasmonic effect significantly dominant to achieve maximum absorption enhancement g(?) at longer wavelengths (red and near infrared) and as comparable with Au nanoparticle on thin film Silicon. The absorption enhancement can be tuned to the desired position of solar spectrum by adjusting the size of TiN nanoparticles. Effect of nanoparticle diameters on the absorption enhancement was also thoroughly analyzed. The numerically simulated results show that TiN can play the similar role as gold nanoparticles on thin film silicon solar cells. Furthermore, TiN plasmonic material is cheap, abundant and more Complementary Metal Oxide Semiconductor (CMOS) compatible material than traditional plasmonic metals like Ag and Au, which can be easy integration with other optoelectronic devices. © 2017 Elsevier B.V.

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Держатели документа:
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, Russian Federation
Institute of Computational Modeling, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
L.V. Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Venugopal, N.; Gerasimov, V. S.; Ershov, A. E.; Karpov, S. V.; Polyutov, S. P.

    In Vivo Cancer Cells Elimination Guided by Aptamer-Functionalized Gold-Coated Magnetic Nanoparticles and Controlled with Low Frequency Alternating Magnetic Field
/ I. V. Belyanina [et al.] // Theranostics. - 2017. - Vol. 7, Is. 13. - P3326-3337, DOI 10.7150/thno.17089. - Cited References:35. - The authors are grateful to George Y. Vorogeikin, Yuri I. Vorogeikin and "OKB ART". Andrey Barinov and "OPTEC Group" for help with 3D laser scanning imaging. Microscopic analyses using Carl Zeiss LSM 800 were done in the "Center for bioassay, nanotechnology and nanomaterials safety" ("Biotest-Nano") (Multiple-Access Center, Tomsk State University, Tomsk, Russia). Toxicity studies have been performed in Multiple-Access Center, Central Scientific Research Laboratory in Krasnoyarsk State Medical University named after prof. V.F. Voino-Yasenecky. This work was supported by the Russian Scientific Fund (grant #14-15-00805). . - ISSN 1838-7640
РУБ Medicine, Research & Experimental

Аннотация: Biomedical applications of magnetic nanoparticles under the influence of a magnetic field have been proved useful beyond expectations in cancer therapy. Magnetic nanoparticles are effective heat mediators, drug nanocarriers, and contrast agents; various strategies have been suggested to selectively target tumor cancer cells. Our study presents magnetodynamic nanotherapy using DNA aptamer-functionalized 50 nm gold-coated magnetic nanoparticles exposed to a low frequency alternating magnetic field for selective elimination of tumor cells in vivo. The cell specific DNA aptamer AS-14 binds to the fibronectin protein in Ehrlich carcinoma hence helps deliver the gold-coated magnetic nanoparticles to the mouse tumor. Applying an alternating magnetic field of 50 Hz at the tumor site causes the nanoparticles to oscillate and pull the fibronectin proteins and integrins to the surface of the cell membrane. This results in apoptosis followed by necrosis of tumor cells without heating the tumor, adjacent healthy cells and tissues. The aptamer-guided nanoparticles and the low frequency alternating magnetic field demonstrates a unique non-invasive nanoscalpel technology for precise cancer surgery at the single cell level.

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Держатели документа:
Krasnoyarsk State Med Univ, Krasnoyarsk, Russia.
Russian Acad Sci, KSC Siberian Branch, Fed Res Ctr, Krasnoyarsk, Russia.
Siberian Fed Univ, Krasnoyarsk, Russia.
Univ Ottawa, Dept Chem & Biomol Sci, Ottawa, ON, Canada.
Inst Computat Modeling RAS SB, Krasnoyarsk, Russia.

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Belyanina, Irina V.; Zamay, Tatiana N.; Zamay, Galina S.; Zamay, Sergey S.; Kolovskaya, Olga S.; Ivanchenko, Tatiana I.; Denisenko, Valery V.; Kirichenko, Andrey K.; Glazyrin, Yury E.; Garanzha, Irina V.; Grigorieva, Valentina V.; Shabanov, Alexandr V.; Veprintsev, Dmitry V.; Sokolov, Alexey E.; Sadovskii, Vladimir M.; Gargaun, Ana; Berezovski, Maxim V.; Kichkailo, Anna S.; Russian Scientific Fund [14-15-00805]

    Carbon Coated Alumina Nanofiber Membranes for Selective Ion Transport
/ V. S. Solodovnichenko [et al.] // Adv. Eng. Mater. - 2017. - Vol. 19, Is. 11. - Ст. 1700244, DOI 10.1002/adem.201700244. - Cited References:60. - This work is supported by the Russian Science Foundation, Project 15-19-10017. The physicochemical analysis of materials was carried out on equipment of Krasnoyarsk Scientific Center of Shared Facilities SB RAS. . - ISSN 1438-1656. - ISSN 1527-2648
РУБ Materials Science, Multidisciplinary

Аннотация: The authors propose a novel type of ion-selective membranes, which combine the advantages of ceramic nanofibrous media with good electrical conductivity. The membranes are produced from Nafen alumina nanofibers (diameter around 10nm) by filtration of nanofiber suspension through a porous support followed by drying and sintering. Electrical conductivity is achieved by depositing a thin carbon layer on the nanofibers by chemical vapor deposition (CVD). Raman and FTIR spectroscopy, X-ray fluorescence analysis, and TEM are used to confirm the carbon structure formation. The deposition of carbon leads to decreasing porosity (from 75 to 62%) and specific surface area (from 146 to 107m(2) g(-1)) of membranes, while the pore size distribution maximum shifts from 28 to 16nm. Measurements of membrane potential in an electrochemical cell show that the carbon coated membranes acquire high ionic selectivity (transference numbers 0.94 for anion and 0.06 for cation in aqueous KCl). Fitting the membrane potential data by the Teorell-Meyer-Sievers model shows that the fixed membrane charge increases proportionally with increasing electrolyte concentration. The carbon coated membranes are ideally polarizable for applied voltages from -0.5 to +0.8V. The potential applications of produced membranes include nano- and ultrafiltration, separation of charged species, and switchable ion-transport selectivity.

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Держатели документа:
Inst Computat Modeling SB RAS, Akademgorodok 50-44, Krasnoyarsk, Russia.
Fed Res Ctr KSC SB RAS, Akademgorodok 50, Krasnoyarsk, Russia.
Natl Res Univ Elect Technol MIET, Shokin Sq 1, Moscow, Russia.
Inst Chem & Chem Technol SB RAS, Akademgorodok 50-24, Krasnoyarsk, Russia.

Доп.точки доступа:
Solodovnichenko, Vera S.; Lebedev, Denis V.; Bykanova, Victoria V.; Shiverskiy, Alexey V.; Simunin, Mikhail M.; Parfenov, Vladimir A.; Ryzhkov, Ilya I.; Russian Science Foundation [15-19-10017]

    Induced-Charge Enhancement of the Diffusion Potential in Membranes with Polarizable Nanopores
/ I. I. Ryzhkov [et al.] // Phys. Rev. Lett. - 2017. - Vol. 119, Is. 22. - Ст. 226001, DOI 10.1103/PhysRevLett.119.226001. - Cited References:31. - This work is supported by the Russian Science Foundation, Project No. 15-19-10017. . - ISSN 0031-9007. - ISSN 1079-7114
РУБ Physics, Multidisciplinary

Аннотация: When a charged membrane separates two salt solutions of different concentrations, a potential difference appears due to interfacial Donnan equilibrium and the diffusion junction. Here, we report a new mechanism for the generation of a membrane potential in polarizable conductive membranes via an induced surface charge. It results from an electric field generated by the diffusion of ions with different mobilities. For uncharged membranes, this effect strongly enhances the diffusion potential and makes it highly sensitive to the ion mobilities ratio, electrolyte concentration, and pore size. Theoretical predictions on the basis of the space charge model extended to polarizable nanopores fully agree with experimental measurements in KCl and NaCl aqueous solutions.

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Держатели документа:
Inst Computat Modelling SB RAS, Fed Res Ctr KSC SB RAS, Akademgorodok 50, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Svobodny 79, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Ryzhkov, I. I.; Lebedev, D. V.; Solodovnichenko, V. S.; Shiverskiy, A. V.; Simunin, M. M.; Russian Science Foundation [15-19-10017]

    On the origin of membrane potential in membranes with polarizable nanopores
/ I. I. Ryzhkov [et al.] // J. Membr. Sci. - 2018. - Vol. 549. - P616-630, DOI 10.1016/j.memsci.2017.11.073. - Cited References:69. - This work is supported the Russian Science Foundation, Project 15-19-10017. The physicochemical analysis of materials was carried out on the equipment of Krasnoyarsk Scientific Center of Shared Facilities SB RAS. . - ISSN 0376-7388. - ISSN 1873-3123
РУБ Engineering, Chemical + Polymer Science

Аннотация: We report a new mechanism for the generation of membrane potential in polarizable nanoporous membranes separating electrolytes with different concentrations. The electric field generated by diffusion of ions with different mobilities induces a non-uniform surface charge, which results in charge separation inside the nanopore. The corresponding Donnan potentials appear at the pore entrance and exit leading to a dramatic enhancement of membrane potential in comparison with an uncharged non-polarizable membrane. At high concentration contrast, the interaction between electric field and uncompensated charge at a low concentration side results in the development of electrokinetic vortices. The theoretical predictions are based on the Space-Charge model, which is extended to nanopores with polarizable conductive surface for the first time. This model is validated against full Navier-Stokes, Nernst-Planck, and Poisson equations, which are solved in a high aspect ratio nanopore connecting two reservoirs. The experimental measurements of membrane potential of dielectric and conductive membranes in KCl and NaCl aqueous solutions confirm the theoretical results. The membranes are prepared from Nafen nanofibers with similar to 10 nm in diameter and modified by depositing a conductive carbon layer. It is shown theoretically that the membrane potential enhancement becomes greater with decreasing the electrolyte concentration and pore radius. A high sensitivity of membrane potential to the ratio of ion diffusion coefficients is demonstrated. The described phenomenon may find applications in precise determination of ion mobilities, electrochemical and bio-sensing, as well as design of nanofluidic and bioelectronic devices.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Inst Computat Modelling SB RAS, Akademgorodok 50-44, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Svobodny 79, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Ryzhkov, Ilya I.; Lebedev, Denis V.; Solodovnichenko, Vera S.; Minakov, Andrey V.; Simunin, Mikhail M.; Russian Science Foundation [15-19-10017]

    Titanium nitride nanoparticles as an alternative platform for plasmonic waveguides in the visible and telecommunication wavelength ranges
/ V. I. Zakomirnyi [et al.] // Photonics Nanostruc. Fundam. Appl. - 2018. - Vol. 30. - P50-56, DOI 10.1016/j.photonics.2018.04.005 . - ISSN 1569-4410
Аннотация: We propose to utilize titanium nitride (TiN) as an alternative material for linear periodic chains (LPCs) of nanoparticles (NPs) which support surface plasmon polariton (SPP) propagation. Dispersion and transmission properties of LPCs have been examined within the framework of the dipole approximation for NPs with various shapes: spheres, prolate and oblate spheroids. It is shown that LPCs of TiN NPs support high-Q eigenmodes for an SPP attenuation that is comparable with LPCs from conventional plasmonic materials such as Au or Ag, with the advantage that the refractory properties and cheap fabrication of TiN nanostructures are more preferable in practical implementations compared to Au and Ag. We show that the SPP decay in TiN LPCs remains almost the same even at extremely high temperatures which is impossible to reach with conventional plasmonic materials. Finally, we show that the bandwidth of TiN LPCs from non-spherical particles can be tuned from the visible to the telecommunication wavelength range by switching the SPP polarization, which is an attractive feature for integrating these structures into modern photonic devices. © 2018 Elsevier B.V.

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Держатели документа:
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, Russian Federation
School of Engineering Sciences in Chemistry, Biotechnology and Health, KTH Royal Institute of Technology, Stockholm, Sweden
The Beckman Institute for Advanced Science and Technology, University of Illinois at Urbana-Champaign, Urbana, IL, United States
Institute of Computational Modeling, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian State University of Science and Technology, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Zakomirnyi, V. I.; Rasskazov, I. L.; Gerasimov, V. S.; Ershov, A. E.; Polyutov, S. P.; Karpov, S. V.; Agren, H.

    Effect of Electric Field on Ion Transport in Nanoporous Membranes with Conductive Surface
/ D. V. Lebedev [et al.] // Pet. Chem. - 2018. - Vol. 58, Is. 6. - P474-481, DOI 10.1134/S0965544118060075. - Cited References:32. - This work was supported by the Russian Science Foundation, project no. 15-19-10017. The instrumental analysis of the materials was conducted at the Center for collective use of the Federal Research Center Krasnoyarsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences. . - ISSN 0965-5441. - ISSN 1555-6239
РУБ Chemistry, Organic + Chemistry, Physical + Energy & Fuels + Engineering,

Аннотация: The effect of an external electric field on the ionic conductivity and selective properties of ceramic membranes based on alumina nanofibers coated with a conductive carbon layer has been studied. It has been shown that the membranes are ideally polarizable in the polarizing voltage range of -500 to +500 mV and, therefore, can be used for implementing switchable ionic selectivity. Experiments have revealed that the membrane resistance decreases with a change in the applied potential from 0 to +/- 500 mV. It has been shown that the membrane selectivity can be switched from anion to cation by varying the external potential. The surface charge density of the membranes has been determined in terms of the Teorell-Meyer-Sievers model according to the experimental measurements of the membrane potential.

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Держатели документа:
Russian Acad Sci, Siberian Branch, Krasnoyarsk Sci Ctr, Inst Computat Modeling, Krasnoyarsk 660036, Russia.
St Petersburg State Univ, Inst Chem, St Petersburg 198504, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Lebedev, D. V.; Solodovnichenko, V. S.; Simunin, M. M.; Ryzhkov, I. I.; Russian Science Foundation [15-19-10017]

    Super-efficient laser hyperthermia of malignant cells with core-shell nanoparticles based on alternative plasmonic materials
/ A. S. Kostyukov [et al.] // J. Quant. Spectrosc. Radiat. Transf. - 2019. - Vol. 236. - Ст. 106599, DOI 10.1016/j.jqsrt.2019.106599 . - ISSN 0022-4073

Кл.слова (ненормированные):
Conducting oxides -- Nanoparticle -- Nanoshell -- Plasmonic photothermal therapy -- Aluminum oxide -- Core shell nanoparticles -- Efficiency -- Gallium compounds -- II-VI semiconductors -- Nanoparticles -- Nanoshells -- Nanostructured materials -- Optical films -- Plasmonics -- Pulsed lasers -- Shells (structures) -- Silica -- Specific heat -- Transparent conducting oxides -- Zinc oxide -- Aluminum-doped zinc oxide -- Comparative studies -- Conducting oxides -- Gallium doped zinc oxides -- Nanoshell -- Orders of magnitude -- Photothermal therapy -- Spatial localization -- Plasmonic nanoparticles -- aluminum -- cell -- comparative study -- gold -- nanoparticle -- oxide -- zinc

Аннотация: New type of highly absorbing core-shell AZO/Au (aluminum doped zinc oxide/gold) and GZO/Au (gallium doped zinc oxide/gold) nanoparticles have been proposed for hyperthermia of malignant cells purposes. Comparative studies of pulsed laser hyperthermia were performed for Au nanoshells with AZO core and traditional SiO2 (quartz) core. We show that under the same conditions, the hyperthermia efficiency in the case of AZO increases by several orders of magnitude compared to SiO2 due to low heat capacity of AZO. Similar results have been obtained for GZO core which has same heat capacity. Calculations for pico-, nano- and sub-microsecond pulses demonstrate that reduced pulse duration results in strong spatial localization of overheated areas around nanoparticles, which ensures the absence of negative effects to the normal tissue. Moreover, we propose new alternative way for the optimization of hyperthermia efficiency: instead of maximizing the absorption of nanoparticles, we enhance the thermal damage effect on the membrane of malignant cell. This strategy allows to find the parameters of nanoparticle and the incident radiation for the most effective therapy. © 2019 Elsevier Ltd

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Держатели документа:
Siberian Federal UniversityKrasnoyarsk, Russian Federation
Institute of Computational Modeling SB RASKrasnoyarsk, Russian Federation
Siberian State University of Science and TechnologyKrasnoyarsk, Russian Federation
The Institute of Optics, University of RochesterNY, United States
Kirensky Institute of Physics, Federal Research Center KSC SB RASKrasnoyarsk, Russian Federation

Доп.точки доступа:
Kostyukov, A. S.; Ershov, A. E.; Gerasimov, V. S.; Filimonov, S. A.; Rasskazov, I. L.; Karpov, S. V.

    Engineering novel tunable optical high-Q nanoparticle array filters for a wide range of wavelengths
/ A. D. Utyushev, I. L. Isaev, V. S. Gerasimov [et al.] // Opt. Express. - 2020. - Vol. 28, Is. 2. - P1426-1438, DOI 10.1364/OE.28.001426 . - ISSN 1094-4087
Аннотация: The interaction of non-monochromatic radiation with arrays comprising plasmonic and dielectric nanoparticles has been studied using the finite-difference time-domain electrodynamics method. It is shown that LiNbO3, TiO2, GaAs, Si, and Ge all-dielectric nanoparticle arrays can provide a complete selective reflection of an incident plane wave within a narrow spectral line of collective lattice resonance with a Q-factor of 103 or larger at various spectral ranges, while plasmonic refractory TiN and chemically stable Au nanoparticle arrays provide high-Q resonances with moderate reflectivity. Arrays with fixed dimensional parameters make it possible to fine-tune the position of a selected resonant spectral line by tilting the array relative to the direction of the incident radiation. These effects provide grounds for engineering novel selective tunable optical high-Q filters in a wide range of wavelengths, from visible to middle-IR. © 2020 Optical Society of America under the terms of the OSA Open Access Publishing Agreement

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Держатели документа:
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Siberian State University of Science and Technology, Krasnoyarsk, 660014, Russian Federation
Institute of Computational Modeling, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Federal Siberian Research Clinical Center under FMBA of Russia, Krasnoyarsk, 660037, Russian Federation
Division of Theoretical Chemistry and Biology, Royal Institute of Technology, Stockholm, SE-100 44, Sweden
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Optics, University of Rochester, Rochester, NY 14627, United States

Доп.точки доступа:
Utyushev, A. D.; Isaev, I. L.; Gerasimov, V. S.; Ershov, A. E.; Zakomirnyi, V. I.; Rasskazov, I. L.; Polyutov, S. P.; Agren, H.; Karpov, S. V.

    Glass/Au Composite Membranes with Gold Nanoparticles Synthesized inside Pores for Selective Ion Transport
/ D. Lebedev, M. Novomlinsky, V. Kochemirovsky [et al.] // Materials. - 2020. - Vol. 13, Is. 7, DOI 10.3390/ma13071767. - Cited References:60. - This research was funded by the Russian Science Foundation, grant No 19-79-00095. . - ISSN 1996-1944
РУБ Materials Science, Multidisciplinary
Рубрики:
LASER-INDUCED SYNTHESIS
   OF-THE-ART

   POROUS GLASSES

Кл.слова (ненормированные):
porous glass -- membrane -- gold nanoparticles -- laser synthesis -- ion -- transport -- modelling

Аннотация: Nanocomposite membranes have been actively developed in the last decade. The involvement of nanostructures can improve the permeability, selectivity, and anti-fouling properties of a membrane for improved filtration processes. In this work, we propose a novel type of ion-selective Glass/Au composite membrane based on porous glass (PG), which combines the advantages of porous media and promising selective properties. The latter are achieved by depositing gold nanoparticles into the membrane pores by the laser-induced liquid phase chemical deposition technique. Inside the pores, gold nanoparticles with an average diameter 25 nm were formed, which was confirmed by optical and microscopic studies. To study the transport and selective properties of the PG/Au composite membrane, the potentiometric method was applied. The uniform potential model was used to determine the surface charge from the experimental data. It was found that the formation of gold nanoparticles inside membrane pores leads to an increase in the surface charge from -2.75 mC/m(2) to -5.42 mC/m(2). The methods proposed in this work allow the creation of a whole family of composite materials based on porous glasses. In this case, conceptually, the synthesis of these materials will differ only in the selection of initial precursors.

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Держатели документа:
St Petersburg State Univ, 13B Univ Skaya Emb, St Petersburg 199034, Russia.
RAS, SB, Inst Computat Modelling, Akademgorodok 50-44, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Svobodny 79, Krasnoyarsk 660041, Russia.
RAS, Grebenshchikov Inst Silicate Chem ISCh, 2 Adm Makarova Emb, St Petersburg 199155, Russia.

Доп.точки доступа:
Lebedev, Denis; Novomlinsky, Maxim; Kochemirovsky, Vladimir; Ryzhkov, Ilya; Anfimova, Irina; Panov, Maxim; Antropova, Tatyana; Russian Science FoundationRussian Science Foundation (RSF) [19-79-00095]