Кл.слова (ненормированные):
Electron scattering -- Gold -- Lattice constants -- Liquids -- Melting -- Metal nanoparticles -- Nanoparticles -- Surface plasmon resonance -- Electron phonon couplings -- Experimental spectra -- Experimental values -- Gold Nanoparticles -- Nonlinear optical response -- Plasmonic nanoparticle -- Relaxation constants -- Surface plasmon frequency -- Plasmons
Аннотация: Significant suppression of resonant properties of single gold nanoparticles at the surface plasmon frequency during heating and subsequent transition to the liquid state has been demonstrated experimentally and explained for the first time. The results for plasmonic absorption of the nanoparticles have been analyzed by means of Mie theory using experimental values of the optical constants for the liquid and solid metal. The good qualitative agreement between calculated and experimental spectra support the idea that the process of melting is accompanied by an abrupt increase of the relaxation constants, which depends, beside electronphonon coupling, on electron scattering at a rising number of lattice defects in a particle upon growth of its temperature, and subsequent melting as a major cause for the observed plasmonic suppression. It is emphasized that observed effect is fully reversible and may underlie nonlinear optical responses of nanocolloids and composite materials containing plasmonic nanoparticles and their aggregates in conditions of local heating and in general, manifest itself in a wide range of plasmonics phenomena associated with strong heating of nanoparticles. © 2016 Optical Society of America.
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Держатели документа:
Siberian Federal University, Krasnoyarsk, Russian Federation
Institute of Computational Modeling, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian State Aerospace University, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarskz, Russian Federation
Division of Theoretical Chemistry and Biology, Royal Institute of Technology, Stockholm, Sweden
Доп.точки доступа:
Gerasimov, V. S.; Ershov, A. E.; Gavrilyuk, A. P.; Karpov, S. V.; Agren, H.; Polyutov, S. P.