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    Kinetic Path Summation, Multi-Sheeted Extension of Master Equation, and Evaluation of Ergodicity Coefficient
[Text] : статья / A. N. Gorban // Physica A. - 2011. - Vol. 390. - p. 1009-1025DOI 10.1016/j.physa.2010.11.030 . -

Кл.слова (ненормированные):
Path summation -- Master Equation -- ergodicity coefficient -- transition graph -- reaction network -- kinetics -- relaxation time -- replica

Аннотация: We study the Master equation with time--dependent coefficients, a linear kinetic equation for the Markov chains or for the monomolecular chemical kinetics. For the solution of this equation a path summation formula is proved. This formula represents the solution as a sum of solutions for simple kinetic schemes (kinetic paths), which are available in explicit analytical form. The relaxation rate is studied and a family of estimates for the relaxation time and the ergodicity coefficient is developed. To calculate the estimates we introduce the multi--sheeted extensions of the initial kinetics. This approach allows us to exploit the internal ("micro")structure of the extended kinetics without perturbation of the base kinetics.

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Доп.точки доступа:
Горбань, Александр Николаевич