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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Dementyev, Dmitry, Bolsunovsky, Alexander
Заглавие : A long-term study of radionuclide concentrations in mushrooms in the 30-km zone around the Mining-and-Chemical Combine (Russia)
Колич.характеристики :10 с
Место публикации : Isot. Environ. Health Stud.: TAYLOR & FRANCIS LTD. - ISSN 1025-6016, DOI 10.1080/10256016.2020.1718124. - ISSN 1477-2639(eISSN)
Примечания : Cited References:25
Предметные рубрики: CS-137
FOREST
RADIOCESIUM
FUNGI
ACCUMULATION
ACCIDENT
Аннотация: Cs-137 concentrations were measured in mushrooms in an area affected by radioactive discharges of the Mining-and-Chemical Combine (MCC) (Rosatom, Russia) in 2002-2017. The sources of radionuclides in the study sites were global fallouts and waterborne and airborne radioactive discharges of the MCC. The mushroom species Suillus granulatus and S. luteus showed the highest Cs-137 concentrations (140-7100 Bq kg(-1)) for this area. Over the entire monitoring period, no significant change in Cs-137 concentration was observed in the Suillus spp. samples collected from the sites with the aerial deposition of radionuclides. In the floodplain site with the radionuclide deposition from water and air, a significant decrease in the average Cs-137 concentration was observed in the period between 2004 and 2017: a three-fold decrease in Suillus spp. and a nine-fold decrease in Lactarius deliciosus. The effective half-lives of Cs-137 in fruiting bodies of the mushrooms L. deliciosus and Suillus spp. in this site were 3.6 +/- 0.6 and 9.2 +/- 2.7 years, respectively.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zotina T. A., Anishchenko, O., V, Trofimova E. A., Dementiev, D., V
Заглавие : Comparative Assessment of the Content of Transition Metals (Cu, Zn, Mn, Pb, and Cd) and Radiocesium (Cs-137) in Pike (Esox lucius) and Burbot (Lota lota) of the Yenisei River
Колич.характеристики :9 с
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-44-240003]; Government of Krasnoyarsk krai; Krasnoyarsk Regional Fund for Support of Scientific and Technical Activity [20-44-240004]
Место публикации : Contemp. Probl. Ecol.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2022. - Vol. 15, Is. 1. - С. 91-99. - ISSN 1995-4255, DOI 10.1134/S1995425522010115. - ISSN 1995-4263(eISSN)
Примечания : Cited References:36. - This work was supported by the Russian Foundation for Basic Research, grant no. 18-44-240003, and the Government of Krasnoyarsk krai, together with the Krasnoyarsk Regional Fund for Support of Scientific and Technical Activity, grant no. 20-44-240004.
Предметные рубрики: FRESH-WATER FISH
NORTHERN PIKE
HEAVY-METALS
BRAMA L.
FOOD-WEB
SIZE
Аннотация: The trophic position of fish is one of the most important factors controlling the accumulation of potentially toxic elements and compounds in fish tissues, primarily via the spectrum of fish nutrition. In this study, the content of potentially toxic transition metals (Cu, Zn, Mn, Pb, and Cd) and radiocesium (Cs-137) in the edible tissues (muscles and liver) of two representatives of the fish-eating ichthyofauna of the Yenisei River, northern pike (Esox lucius) and burbot (Lota lota), have been comparatively studied relatively to the size of the fish. A significant decrease in the content of radiocesium and zinc in the muscles of pike and zinc in the liver of pike with an increase in body size has been recorded in juvenile pikes with a body weight (W) of less than 0.35 kg. For larger sexually mature pikes, no significant size dependences of the accumulation of metals in tissues are found. A positive correlation is found between the content of Cs-137, Cu, Zn, and Mn in muscles and the size of burbot in the W range from 0.42 to 1.62 kg. The tissues of burbots and pikes of the same size significantly (p 0.05) differ in the concentration of metals in their tissues: concentrations of Zn and Mn are 1.6-2.2 times higher in the muscle of burbot; the concentration of Pb is 1.8 times higher in muscle of pike; Cu is twice as high in the liver of burbot; and Zn and Mn are 4.7 and 1.6 times higher in the liver of pike, respectively. These differences may be due to the different food spectra of pike and burbot. Concentrations of Cu, Zn, and Mn in the liver of pike are 3-7 times higher than in muscle; the concentration of Cu in the liver of burbot is 5 times higher than in muscle. Pb and Cd tend to be higher in liver than muscle for both fish species. Despite the revealed size dependences, the concentrations of potentially toxic metals and radiocesium in the muscles and liver of fish are below the permissible concentrations for food. These results can be used to assess environmental risks for the population consuming fish, as well as to plan for the long-term environmental monitoring of rivers using representatives of piscivorous fish.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Feniova, I. Yu, Sakharova E. G., Gladyshev, M., I, Sushchik N. N., Gorelysheva, Z., I, Karpowicz M.
Заглавие : EFFECTS OF FISH ON THE TRANSFER EFFICIENCY OF CARBON, PUFA AND NUTRIENTS FROM PHYTOPLANKTON TO ZOOPLANKTON UNDER EUTROPHIC CONDITIONS
Колич.характеристики :15 с
Место публикации : Zool. Zhurnal: MAIK NAUKA-INTERPERIODICA PUBL, 2021. - Vol. 100, Is. 2. - С. 194-208. - ISSN 0044-5134, DOI 10.31857/S0044513421020215
Примечания : Cited References:49
Предметные рубрики: FATTY-ACIDS
FOOD QUALITY
FRESH-WATER
ZEBRA MUSSELS
PHOSPHORUS
Аннотация: The efficiency of the transfer of carbon, polyunsaturated fatty acids (PUFA), nitrogen and phosphorus from phytoplankton to zooplankton determines the functioning of the entire ecosystem. However, this parameter depends on environmental conditions. Fish as a very important factor to regulate planktonic communities are very likely to affect the efficiency of the transfer of basic elements and substances from phytoplankton to zoo plankton. In experimental mesocosms filled with water from an eutrophic lake and containing phyto- and zooplankton, we investigated how fish affect both primary and secondary production and the efficiency of transfer of carbon, nitrogen, phosphorus, PUFA and fatty acids (FA) from phytoplankton to zooplankton. Two treatments (control and fish treatment) were repeated in three replicates. The transfer efficiency of substances from phytoplankton to zooplankton was measured as the ratio of secondary to primary production, expressed in liters and per biomass unit in percent. The efficiency expressed per liter characterizes the productivity of the water body, while the efficiency expressed per biomass unit indicates the effectiveness of aquatic species to transfer biologically valuable substances from one trophic level to another. We found that phytoplankton-zooplankton-fish interactions are determined not only by predator-prey relationships, but also are affected by the quality of both phytoplankton and zooplankton, measured as the contents of phosphorus, nitrogen, PUFA and FA in their biomass. We showed that, in the presence of fish, the transfer efficiency of carbon, phosphorus, nitrogen, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA), FA per biomass unit from phytoplankton to zooplankton was increased two-fold, 12.4-fold, 2,5-fold, 12.4-fold, 7.4-fold, and 10-fold, respectively, relative to control. This provides the sustainability of the functioning of the ecosystem under fish pressure. Such a mechanism prevents zooplankton over-exploitation by fish and enables to prolong the food chain.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Esimbekova E. N., Kalyabina V. P., Kopylova K. V., Torgashina I. G., Kratasyuk V. A.
Заглавие : Design of bioluminescent biosensors for assessing contamination of complex matrices
Место публикации : Talanta: Elsevier B.V., 2021. - Vol. 233. - Ст.122509. - ISSN 00399140 (ISSN), DOI 10.1016/j.talanta.2021.122509
Примечания : Cited By :1
Аннотация: The presence of potentially toxic xenobiotics in complex matrices has become rather the rule than the exception. Therefore, there is a need for highly sensitive inexpensive techniques for analyzing environmental and food matrices for toxicants. Enzymes are selectively sensitive to various toxic compounds, and, thus, they can be used as the basis for detection of contaminants in complex matrices. There are, however, a number of difficulties associated with the analysis of complex matrices using enzyme assays, including the necessity to take into account properties and effects of the natural components of the test media for accurate interpretation of results. The present study describes the six-stage procedure for designing new enzyme sensors intended for assessing the quality of complex matrices. This procedure should be followed both to achieve the highest possible sensitivity of the biosensor to potentially toxic substances and to minimize the effect of the uncontaminated components of complex mixtures on the activity of the biosensor. The proposed strategy has been tested in designing a bioluminescent biosensor for integrated rapid assessment of the safety of fruits and vegetables. The biosensor is based on the coupled enzyme system NAD(P)H:FMN-oxidoreductase and luciferase as the biorecognition element. The study describes methods and techniques for attaining the desired result in each stage. The proposed six-stage procedure for designing bioluminescent enzyme biosensors can be used to design the enzymatic biosensors based on other enzymes. © 2021 Elsevier B.V.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Karpowicz M., Feniova I., Gladyshev M. I., Ejsmont-Karabin J., Gorniak A., Sushchik N. N., Anishchenko O. V., Dzialowski A. R.
Заглавие : Transfer efficiency of carbon, nutrients, and polyunsaturated fatty acids in planktonic food webs under different environmental conditions
Место публикации : Ecology and Evolution: John Wiley and Sons Ltd, 2021. - Article in press. - ISSN 20457758 (ISSN), DOI 10.1002/ece3.7651
Аннотация: The trophic transfer efficiency (TTE) is an important indicator of ecosystem functioning. However, TTE data from freshwater food webs are ambiguous due to differences in time scales and methods. We investigated the transfer of essential substances (carbon, nutrients, and polyunsaturated fatty acids) through plankton communities in 30 Polish lakes with different trophic status in the middle of summer. The results of our study revealed that different essential substances were transferred from phytoplankton to zooplankton with varying efficiencies. The average TTE of C, N, P, and the sum of ?-3 PUFA were 6.55%, 9.82%, 15.82%, and 20.90%, respectively. Our results also show a large mismatch between the elemental and biochemical compositions of zooplankton and their food during the peak of the summer stagnation, which may further promote the accumulation of essential substances. There were also large differences in TTEs between trophic conditions, with the highest efficiencies in oligotrophic lakes and the lowest in dystrophic and eutrophic lakes. Therefore, our study indicates that disturbances like eutrophication and dystrophication similarly decrease the TTE of essential substances between phytoplankton and zooplankton in freshwater food webs. © 2021 The Authors. Ecology and Evolution published by John Wiley & Sons Ltd.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Karpowicz, Maciej, Feniova, Irina, Gladyshev, Michail I., Ejsmont-Karabin, Jolanta, Gorniak, Andrzej, Sushchik, Nadezhda N., Anishchenko, Olesya V., Dzialowski, Andrew R.
Заглавие : Transfer efficiency of carbon, nutrients, and polyunsaturated fatty acids in planktonic food webs under different environmental conditions
Колич.характеристики :14 с
Коллективы : Polish National Science Centre [2016/21/B/NZ8/00434]; Federal Tasks for Institute of Biophysics SB RAS [51.1.1]; Federal Tasks for Siberian Federal University [FSRG-2020-0019]
Место публикации : Ecol. Evol.: WILEY, 2021. - Article in press. - ISSN 2045-7758, DOI 10.1002/ece3.7651
Примечания : Cited References:62. - This research was supported by the Polish National Science Centre (2016/21/B/NZ8/00434). The research was also supported by Federal Tasks for Institute of Biophysics SB RAS No. 51.1.1 and Federal Tasks for Siberian Federal University No. FSRG-2020-0019. The authors are thankful to Joanna Kozowska for her help in the collection of samples.
Предметные рубрики: PHOSPHORUS STOICHIOMETRY
LIGHT-INTENSITY
ZOOPLANKTON
TEMPERATURE
Аннотация: The trophic transfer efficiency (TTE) is an important indicator of ecosystem functioning. However, TTE data from freshwater food webs are ambiguous due to differences in time scales and methods. We investigated the transfer of essential substances (carbon, nutrients, and polyunsaturated fatty acids) through plankton communities in 30 Polish lakes with different trophic status in the middle of summer. The results of our study revealed that different essential substances were transferred from phytoplankton to zooplankton with varying efficiencies. The average TTE of C, N, P, and the sum of omega-3 PUFA were 6.55%, 9.82%, 15.82%, and 20.90%, respectively. Our results also show a large mismatch between the elemental and biochemical compositions of zooplankton and their food during the peak of the summer stagnation, which may further promote the accumulation of essential substances. There were also large differences in TTEs between trophic conditions, with the highest efficiencies in oligotrophic lakes and the lowest in dystrophic and eutrophic lakes. Therefore, our study indicates that disturbances like eutrophication and dystrophication similarly decrease the TTE of essential substances between phytoplankton and zooplankton in freshwater food webs.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Schartau, Ann Kristin, Mariash, Heather L., Christoffersen, Kirsten S., Bogan, Daniel, Dubovskaya, Olga P., Fefilova, Elena B., Hayden, Brian, Ingvason, Haraldur R., Ivanova, Elena A., Kononova, Olga N., Kravchuk, Elena S., Lento, Jennifer, Majaneva, Markus, Novichkova, Anna A., Rautio, Milla, Ruhland, Kathleen M., Shaftel, Rebecca, Smol, John P., Vrede, Tobias, Kahilainen, Kimmo K.
Заглавие : First circumpolar assessment of Arctic freshwater phytoplankton and zooplankton diversity: Spatial patterns and environmental factors
Колич.характеристики :18 с
Коллективы : RFBRRussian Foundation for Basic Research (RFBR) [20-04-00145_a]
Место публикации : Freshw. Biol.: WILEY, 2021. - Article in press. - ISSN 0046-5070, DOI 10.1111/fwb.13783. - ISSN 1365-2427(eISSN)
Примечания : Cited References:78. - RFBR, Grant/Award Number: 20-04-00145_a
Предметные рубрики: HIGH-LATITUDE LAKES
CLIMATE-CHANGE
SPECIES RICHNESS
BETA DIVERSITY
Аннотация: Arctic freshwaters are facing multiple environmental pressures, including rapid climate change and increasing land-use activities. Freshwater plankton assemblages are expected to reflect the effects of these stressors through shifts in species distributions and changes to biodiversity. These changes may occur rapidly due to the short generation times and high dispersal capabilities of both phyto- and zooplankton. Spatial patterns and contemporary trends in plankton diversity throughout the circumpolar region were assessed using data from more than 300 lakes in the U.S.A. (Alaska), Canada, Greenland, Iceland, the Faroe Islands, Norway, Sweden, Finland, and Russia. The main objectives of this study were: (1) to assess spatial patterns of plankton diversity focusing on pelagic communities; (2) to assess dominant component of beta diversity (turnover or nestedness); (3) to identify which environmental factors best explain diversity; and (4) to provide recommendations for future monitoring and assessment of freshwater plankton communities across the Arctic region. Phytoplankton and crustacean zooplankton diversity varied substantially across the Arctic and was positively related to summer air temperature. However, for zooplankton, the positive correlation between summer temperature and species numbers decreased with increasing latitude. Taxonomic richness was lower in the high Arctic compared to the sub- and low Arctic for zooplankton but this pattern was less clear for phytoplankton. Fennoscandia and inland regions of Russia represented hotspots for, respectively, phytoplankton and zooplankton diversity, whereas isolated regions had lower taxonomic richness. Ecoregions with high alpha diversity generally also had high beta diversity, and turnover was the most important component of beta diversity in all ecoregions. For both phytoplankton and zooplankton, climatic variables were the most important environmental factors influencing diversity patterns, consistent with previous studies that examined shorter temperature gradients. However, barriers to dispersal may have also played a role in limiting diversity on islands. A better understanding of how diversity patterns are determined by colonisation history, environmental variables, and biotic interactions requires more monitoring data with locations dispersed evenly across the circumpolar Arctic. Furthermore, the importance of turnover in regional diversity patterns indicates that more extensive sampling is required to fully characterise the species pool of Arctic lakes.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Esimbekova E. N., Torgashina I. G., Kalyabina V. P., Kratasyuk V. A.
Заглавие : Enzymatic Biotesting: Scientific Basis and Application
Колич.характеристики :15 с
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [19-14-50238\19]
Место публикации : Contemp. Probl. Ecol.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2021. - Vol. 14, Is. 3. - С. 290-304. - ISSN 1995-4255, DOI 10.1134/S1995425521030069. - ISSN 1995-4263(eISSN)
Примечания : Cited References:128. - This study was carried out with financial support from the Russian Foundation for Basic Research, project no. 19-14-50238\19.
Предметные рубрики: ORGANOPHOSPHORUS PESTICIDES
CHRONIC EXPOSURE
BIOSENSOR
Аннотация: The paper provides a review of the current state of research in the field of biotesting, and the problems of environmental studies and ways to solve them are discussed. The basic principles and examples of using enzymes for detecting toxicants in various environmental samples are considered. Based on an analysis of numerous published data, the advantages and limitations, as well as the prospects for using enzymes for performing biotesting tasks, are assessed. A separate section of the review is devoted to bioluminescent enzymatic bioassays developed by the authors and successfully used for environmental monitoring of water, soil, and air. The necessity of developing a battery of enzymatic bioassays is substantiated. It allows one to have the most complete and accurate information about the degree of pollution of environmental objects.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Esimbekova E. N., Torgashina I. G., Kalyabina V. P., Kratasyuk V. A.
Заглавие : Enzymatic Biotesting: Scientific Basis and Application
Место публикации : Contemp. Probl. Ecol.: Pleiades journals, 2021. - Vol. 14, Is. 3. - С. 290-304. - ISSN 19954255 (ISSN), DOI 10.1134/S1995425521030069
Примечания : Cited By :1
Аннотация: Abstract: The paper provides a review of the current state of research in the field of biotesting, and the problems of environmental studies and ways to solve them are discussed. The basic principles and examples of using enzymes for detecting toxicants in various environmental samples are considered. Based on an analysis of numerous published data, the advantages and limitations, as well as the prospects for using enzymes for performing biotesting tasks, are assessed. A separate section of the review is devoted to bioluminescent enzymatic bioassays developed by the authors and successfully used for environmental monitoring of water, soil, and air. The necessity of developing a battery of enzymatic bioassays is substantiated. It allows one to have the most complete and accurate information about the degree of pollution of environmental objects. © 2021, Pleiades Publishing, Ltd.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Schartau A. K., Mariash H. L., Christoffersen K. S., Bogan D., Dubovskaya O. P., Fefilova E. B., Hayden B., Ingvason H. R., Ivanova E. A., Kononova O. N., Kravchuk E. S., Lento J., Majaneva M., Novichkova A. A., Rautio M., Ruhland K. M., Shaftel R., Smol J. P., Vrede T., Kahilainen K. K.
Заглавие : First circumpolar assessment of Arctic freshwater phytoplankton and zooplankton diversity: Spatial patterns and environmental factors
Место публикации : Freshw. Biol.: Blackwell Publishing Ltd, 2021. - Article in press. - ISSN 00465070 (ISSN), DOI 10.1111/fwb.13783
Аннотация: Arctic freshwaters are facing multiple environmental pressures, including rapid climate change and increasing land-use activities. Freshwater plankton assemblages are expected to reflect the effects of these stressors through shifts in species distributions and changes to biodiversity. These changes may occur rapidly due to the short generation times and high dispersal capabilities of both phyto- and zooplankton. Spatial patterns and contemporary trends in plankton diversity throughout the circumpolar region were assessed using data from more than 300 lakes in the U.S.A. (Alaska), Canada, Greenland, Iceland, the Faroe Islands, Norway, Sweden, Finland, and Russia. The main objectives of this study were: (1) to assess spatial patterns of plankton diversity focusing on pelagic communities; (2) to assess dominant component of ? diversity (turnover or nestedness); (3) to identify which environmental factors best explain diversity; and (4) to provide recommendations for future monitoring and assessment of freshwater plankton communities across the Arctic region. Phytoplankton and crustacean zooplankton diversity varied substantially across the Arctic and was positively related to summer air temperature. However, for zooplankton, the positive correlation between summer temperature and species numbers decreased with increasing latitude. Taxonomic richness was lower in the high Arctic compared to the sub- and low Arctic for zooplankton but this pattern was less clear for phytoplankton. Fennoscandia and inland regions of Russia represented hotspots for, respectively, phytoplankton and zooplankton diversity, whereas isolated regions had lower taxonomic richness. Ecoregions with high ? diversity generally also had high ? diversity, and turnover was the most important component of ? diversity in all ecoregions. For both phytoplankton and zooplankton, climatic variables were the most important environmental factors influencing diversity patterns, consistent with previous studies that examined shorter temperature gradients. However, barriers to dispersal may have also played a role in limiting diversity on islands. A better understanding of how diversity patterns are determined by colonisation history, environmental variables, and biotic interactions requires more monitoring data with locations dispersed evenly across the circumpolar Arctic. Furthermore, the importance of turnover in regional diversity patterns indicates that more extensive sampling is required to fully characterise the species pool of Arctic lakes. © 2021 The Authors. Freshwater Biology published by John Wiley & Sons Ltd.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boyandin A. N., Kazantseva E. A.
Заглавие : Constructing slow-release formulations of herbicide metribuzin using its co-extrusion with biodegradable polyester poly-ε-caprolactone
Место публикации : J. Environ. Sci. Health Part B Pestic. Food Contamin. Agric. Wastes: Bellwether Publishing, Ltd., 2021. - Article in press. - ISSN 03601234 (ISSN), DOI 10.1080/03601234.2021.1911206
Аннотация: Different technologies to prepare long term pesticide forms include polymer coating, preparing composites and encapsulating pesticides in nanoparticles. A simple and low-cost method was proposed to obtain slow-release formulations by co-extrusion of a pesticide with a biodegradable polymer at a temperature above the melting points of both components. A herbicide metribuzin and low-melting polyester poly-?-caprolactone were chosen for this work. Formulations containing 10%, 20%, and 40% herbicide were prepared. During 7 days of their exposition in water, it was released from 81% to 96% of initially loaded metribuzin; the highest release was detected for 40%-loaded forms. Biodegradation of the constructs and pesticide release were further studied in the model soil. Degradation rates of the specimens increased with an increase in pesticide content, from 9% to 20% over 14 weeks for the 10%/20%-loaded and the 40%-loaded specimens, respectively. The release of metribuzin reached, respectively, 37–38% and 55%. The herbicide content in soil was lower due to its partial degradation in soil; it reached 23–25% and 33%, respectively, from initially loaded into the polymer matrix. Release kinetics of metribuzin in water as in soil best fitted the First-order model. The used approach is promising for obtaining long-term release formulations for soil applications. © 2021 Taylor & Francis Group, LLC.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kratasyuk V. A., Kolosova E. M., Sutormin O. S., Lonshakova-Mukina V. I., Baygin M. M., Rimatskaya N. V., Sukovataya I. E., Shpedt A. A.
Заглавие : Software for matching standard activity enzyme biosensors for soil pollution analysis
Место публикации : Sensors: MDPI AG, 2021. - Vol. 21, Is. 3. - Ст.1017. - С. 1-10. - ISSN 14248220 (ISSN), DOI 10.3390/s21031017
Аннотация: This work is dedicated to developing enzyme biosensor software to solve problems regarding soil pollution analysis. An algorithm and specialised software have been developed which stores, analyses and visualises data using JavaScript programming language. The developed software is based on matching data of 51 non-commercial standard soil samples and their inhibitory effects on three enzyme systems of varying complexity. This approach is able to identify the influence of chemical properties soil samples, without toxic agents, on enzyme biosensors. Such software may find wide use in environmental monitoring. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kratasyuk, Valentina A., Kolosova, Elizaveta M., Sutormin, Oleg S., Lonshakova-Mukina, Viktoriya, I, Baygin, Matvey M., Rimatskaya, Nadezhda, V, Sukovataya, Irina E., Shpedt, Alexander A.
Заглавие : Software for Matching Standard Activity Enzyme Biosensors for Soil Pollution Analysis
Колич.характеристики :10 с
Коллективы : RFBRRussian Foundation for Basic Research (RFBR); Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science [20-44-243001]; Ministry of Science and Higher Education of the Russian Federation [FSRZ-2020-0006]
Место публикации : Sensors: MDPI, 2021. - Vol. 21, Is. 3. - Ст.1017. - ISSN 1424-8220(eISSN), DOI 10.3390/s21031017
Примечания : Cited References:20. - This research was funded by RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, Grant number 20-44-243001 and the Ministry of Science and Higher Education of the Russian Federation, Grant number FSRZ-2020-0006.
Аннотация: This work is dedicated to developing enzyme biosensor software to solve problems regarding soil pollution analysis. An algorithm and specialised software have been developed which stores, analyses and visualises data using JavaScript programming language. The developed software is based on matching data of 51 non-commercial standard soil samples and their inhibitory effects on three enzyme systems of varying complexity. This approach is able to identify the influence of chemical properties soil samples, without toxic agents, on enzyme biosensors. Such software may find wide use in environmental monitoring.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zotina T., Dementyev D., Alexandrova Y.
Заглавие : Long-term trends and speciation of artificial radionuclides in two submerged macrophytes of the Yenisei River: A comparative study of Potamogeton lucens and Fontinalis antipyretica
Место публикации : J. Environ. Radioact.: Elsevier Ltd, 2021. - Vol. 227. - Ст.106461. - ISSN 0265931X (ISSN), DOI 10.1016/j.jenvrad.2020.106461
Аннотация: Long-term trends of artificial radionuclides, from 2003 to 2018, in two abundant species of macrophytes, shining pondweed, Potamogeton lucens, and water moss, Fontinalis antipyretica, have been analyzed to estimate the indicative reliability of these two species as biomonitors of radioactive contamination in a river system and to quantify the decrease in the content of artificial radionuclides in the Yenisei River. Time-dependent trends of artificial radionuclides in the biomass of these species were similar, resulting in estimates of effective half-lives for 54Mn, 58Co, 60Co, 65Zn, 137Cs, and 152Eu similar for both species. Concentrations of artificial radionuclides in biomass of shining pondweed and water moss correlated with annual discharges of the radionuclides to the Yenisei at different levels of significance, and the strongest (R2 > 0.7) positive correlation (p < 0.05) was obtained for 60Co, 65Zn, and 152Eu. Concentrations of 60Co, 137Cs, and 152Eu in water moss were 2–7.5 times higher than in shining pondweed, and considerable percentages of those isotopes were recorded in extracellular particulate matter, which was largely represented by epiphytic diatoms. Higher concentrations of artificial radionuclides in the biomass of water moss can be considered as an advantage of water moss as a monitor of radioactive contamination of the Yenisei, while shining pondweed is more useful for estimation of annual deposits of radionuclides in vegetation of the Yenisei and spatial transfer of radionuclides downstream of the discharge site. Despite differences in concentrations of artificial radionuclides, both species can be considered as reliable indicators of radioactive contamination of the river on a long-term scale. © 2020 Elsevier Ltd
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zotina, Tatiana, Dementyev, Dmitry, Alexandrova, Yuliyana
Заглавие : Long-term trends and speciation of artificial radionuclides in two submerged macrophytes of the Yenisei River: A comparative study of Potamogeton lucens and Fontinalis antipyretica
Колич.характеристики :15 с
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Krasnoyarsk Regional Scientific Foundation [18-44-240003]
Место публикации : J. Environ. Radioact.: ELSEVIER SCI LTD, 2021. - Vol. 227. - Ст.106461. - ISSN 0265-931X, DOI 10.1016/j.jenvrad.2020.106461. - ISSN 1879-1700(eISSN)
Примечания : Cited References:37. - The authors are grateful to the staff of the Radioecology Laboratory and the head of the Laboratory, Dr. Alexander Bolsunovsky, to the staff of Analytical Laboratory (Institute of Biophysics SB RAS) for their help in sample collection and measurement and to Elena Krasova for linguistic check and improvements. We also appreciate comments of anonymous reviewers, which allowed us to improve our manuscript. The research was supported partly (in 2018-2020) by the grant of Russian Foundation for Basic Research and Krasnoyarsk Regional Scientific Foundation No.18-44-240003.
Предметные рубрики: HEAVY-METALS
BRYOPHYTES
CONTAMINATION
BIOMASS
PLANTS
CS-137
TOOL
Аннотация: Long-term trends of artificial radionuclides, from 2003 to 2018, in two abundant species of macrophytes, shining pondweed, Potamogeton lucens, and water moss, Fontinalis antipyretica, have been analyzed to estimate the indicative reliability of these two species as biomonitors of radioactive contamination in a river system and to quantify the decrease in the content of artificial radionuclides in the Yenisei River. Time-dependent trends of artificial radionuclides in the biomass of these species were similar, resulting in estimates of effective half-lives for Mn-54, Co-58, Co-60, Zn-65, Cs-137, and Eu-152 similar for both species. Concentrations of artificial radionuclides in biomass of shining pondweed and water moss correlated with annual discharges of the radionuclides to the Yenisei at different levels of significance, and the strongest (R-2 0.7) positive correlation (p 0.05) was obtained for Co-60, Zn-65, and Eu-152. Concentrations of Co-60, Cs-137, and Eu-152 in water moss were 2-7.5 times higher than in shining pondweed, and considerable percentages of those isotopes were recorded in extracellular particulate matter, which was largely represented by epiphytic diatoms. Higher concentrations of artificial radionuclides in the biomass of water moss can be considered as an advantage of water moss as a monitor of radioactive contamination of the Yenisei, while shining pondweed is more useful for estimation of annual deposits of radionuclides in vegetation of the Yenisei and spatial transfer of radionuclides downstream of the discharge site. Despite differences in concentrations of artificial radionuclides, both species can be considered as reliable indicators of radioactive contamination of the river on a long-term scale.
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16.

Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Kiselev E. G., Zhila N. O., Volova T. G.
Заглавие : Biodegradable polymers - Perspectives and applications in agriculture
Место публикации : IOP Conference Series: Earth and Environmental Science: IOP Publishing Ltd, 2021. - Vol. 689: 2020 International Conference on Germany and Russia: Ecosystems Without Borders, EcoSystConfKlgtu 2020 (5 October 2020 through 10 October 2020, ) Conference code: 167944, Is. 1. - Ст.012036. - , DOI 10.1088/1755-1315/689/1/012036
Аннотация: The paper presents a brief overview of the results of the implementation of the project "Agropreparations of the new generation: a strategy of construction and realization". The first part contains the analysis of the growth of the wild-type strain Cupriavidus necator B-10646 (formerly eutrophus) and the synthesis of polyhydroxyalkanoates by this strain on various substrates: glycerol, palm oil, Siberian oil seed, sunflower seed oils, and oleic acid. On refined glycerin, a highly productive process is implemented when scaling up, allowing to obtain 128 ± 11 g / L PHA. Evaluation of oils has shown that palm oil is the best carbon substrate. The second part presents the results of the development of environmentally friendly slow-release pesticide formulations. They are a degradable matrix of poly-3-hydroxybutyrate mixed with natural materials (peat, clay, wood flour), into which a pesticide (metribuzin, tribenuron-methyl, fenoxaprop-P-ethyl, azoxystrobin, epoxiconazole, and tebuconazole) has been. The developed preparations showed high activity against pathogenic fungi and weeds and had a much weaker negative effect on the soil microflora. Studies of the degradation of the developed preparations and the release of pesticides into the soil confirm their effectiveness over a long period of time, up to 90 days. © Published under licence by IOP Publishing Ltd.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boyandin, Anatoly N., Kazantseva, Eugenia A.
Заглавие : Constructing slow-release formulations of herbicide metribuzin using its co-extrusion with biodegradable polyester poly-epsilon-caprolactone
Колич.характеристики :10 с
Коллективы : Project "Agropreparations of the new generation: a strategy of construction and realization" [074-02-2018-328]; Government of the Russian Federation [220]
Место публикации : J. Environ. Sci. Health Part B-Pestic. Contam. Agric. Wastes: TAYLOR & FRANCIS INC, 2021. - Article in press. - ISSN 0360-1234, DOI 10.1080/03601234.2021.1911206. - ISSN 1532-4109(eISSN)
Примечания : Cited References:43. - This study was financially supported by Project "Agropreparations of the new generation: a strategy of construction and realization" (Agreement No 074-02-2018-328) in accordance with Resolution No 220 of the Government of the Russian Federation of April 9, 2010, "On measures designed to attract leading scientists to the Russian institutions of higher learning".
Аннотация: Different technologies to prepare long term pesticide forms include polymer coating, preparing composites and encapsulating pesticides in nanoparticles. A simple and low-cost method was proposed to obtain slow-release formulations by co-extrusion of a pesticide with a biodegradable polymer at a temperature above the melting points of both components. A herbicide metribuzin and low-melting polyester poly-epsilon-caprolactone were chosen for this work. Formulations containing 10%, 20%, and 40% herbicide were prepared. During 7 days of their exposition in water, it was released from 81% to 96% of initially loaded metribuzin; the highest release was detected for 40%-loaded forms. Biodegradation of the constructs and pesticide release were further studied in the model soil. Degradation rates of the specimens increased with an increase in pesticide content, from 9% to 20% over 14 weeks for the 10%/20%-loaded and the 40%-loaded specimens, respectively. The release of metribuzin reached, respectively, 37-38% and 55%. The herbicide content in soil was lower due to its partial degradation in soil; it reached 23-25% and 33%, respectively, from initially loaded into the polymer matrix. Release kinetics of metribuzin in water as in soil best fitted the First-order model. The used approach is promising for obtaining long-term release formulations for soil applications.
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18.

Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Puzyr A. P., Burov A. E., Bondar V. S.
Заглавие : Detecting bioluminescence conditions in fruit bodies of two species of Armillaria basidiomycetes
Место публикации : IOP Conference Series: Earth and Environmental Science: IOP Publishing Ltd, 2021. - Vol. 677: 4th International Scientific Conference on Agribusiness, Environmental Engineering and Biotechnologies, AGRITECH-IV 2020 (18 November 2020 through 20 November 2020, ) Conference code: 167873, Is. 5. - Ст.052081. - , DOI 10.1088/1755-1315/677/5/052081
Аннотация: Mycelia of various Armillaria fungi are bioluminescent while the fruit bodies do not emit light. The presence in fruit bodies of Armillaria species of enzymes involved in the fungal bioluminescence was investigated by treating them with an exogenous analogue of the substrate for the light-emitting reaction. For this, hot extracts from nonluminous fungus Pholiota squarrosa were used. Upon spraying the pristine and transversely cut fruit bodies with the extracts, light emitting regions of different intensity were revealed. This suggests that the fruit bodies of the studied species are nonluminous due to lack of the substrate for light luminescent reaction. The prolonged incubation of the fruit bodies in water elevated the bioluminescence level. A possible mechanism which can explain this phenomenon is discussed. © 2021 Institute of Physics Publishing. All rights reserved.
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19.

Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Shevyrnogov A. P., Kononova N. A., Volkova A. I., Botvich I. Y., Pisman T. I.
Заглавие : A study of seasonal dynamics of herbaceous plant communities in Khakassia using ground-based and satellite data
Место публикации : IOP Conference Series: Earth and Environmental Science: IOP Publishing Ltd, 2021. - Vol. 677: 4th International Scientific Conference on Agribusiness, Environmental Engineering and Biotechnologies, AGRITECH-IV 2020 (18 November 2020 through 20 November 2020, ) Conference code: 167873, Is. 2. - Ст.022072. - , DOI 10.1088/1755-1315/677/2/022072
Аннотация: The present study addresses the seasonal dynamics of productivity and species composition of the meadow and steppe vegetation communities in Khakassia, determined using the ground-based and satellite data of 2017. The MODIS/Terra satellite data were used to analyze the Normalized Difference Vegetation Index (NDVI) and the Land Surface Water Index (LSWI). The NDVI and LSWI were found to be related to the productivity of the meadow and steppe vegetation. The NDVI increased as the portion of the mesophyte grasses in the grass canopy became larger. The LSWI was higher in the steppe communities, which had lower projective coverage, with spots of bare soil, than in the meadow communities, with their abundant vegetation. © Published under licence by IOP Publishing Ltd.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Chen S. -F., Vysotski E. S., Liu Y. -J.
Заглавие : H2O-Bridged Proton-Transfer Channel in Emitter Species Formation in Obelin Bioluminescence
Место публикации : J Phys Chem B: American Chemical Society, 2021. - Article in press. - ISSN 15206106 (ISSN), DOI 10.1021/acs.jpcb.1c03985
Аннотация: Bioluminescence of a number of marine organisms is conditioned by Ca2+-regulated photoprotein (CaRP) with coelenterazine as the reaction substrate. The reaction product, coelenteramide, at the first singlet excited state (S1) is the emitter of CaRP. The S1-state coelenteramide is produced via the decomposition of coelenterazine dioxetanone. Experiments suggested that the neutral S1-coelenteramide is the primary emitter species. This supposition contradicts with theoretical calculations showing that the anionic S1-coelenteramide is a primary product of the decomposition of coelenterazine dioxetanone. In this study, applying molecular dynamic (MD) simulations and the hybrid quantum mechanics/molecular mechanics (QM/MM) method, we investigated a proton-transfer (PT) process taking place in CaRP obelin from Obelia longissima for emitter formation. Our calculations demonstrate a concerted PT process with a water molecule as a bridge between anionic S1-coelenteramide and the nearest histidine residue. The low activation barrier as well as the strong hydrogen-bond network between the proton donor and the proton acceptor suggests a fast PT process comparable with that of the lifetime of excited anionic S1-coelenteramide. The existence of the PT process eliminates the discrepancy between experimental and theoretical studies. The fast PT process at emitter formation can also take place in other CaRPs. © 2021 American Chemical Society.
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