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1.

Вид документа : Однотомное издание
Шифр издания : Е572/L71
Заглавие : Lignin biodegradation: microbiology, chemistry, and potential applications : Proceedings of an international seminar, organized under the auspices of the United States-Japan Cooperative Science Program, held May 9-11, 1978 at the U.S. Forest Products Laboratory, Madison, Wis. Vol. I
Выходные данные : Boca Raton, Fla. : CRC Press, 1980
Колич.характеристики :241 pp.: il + 26 cm.
Коллективы : United States-Japan Cooperative Science Program.
Примечания : Bibliogr. at the end of the chapters. - Subject ind.: p. 231-235.- Chemical ind.: p. 237-241
ISBN, Цена 0-8493-5459-5 : $55.00 per vol., 48.00, р.
ББК : Е572
Предметные рубрики: Лигнин-- биодеградация
Ключевые слова (''Своб.индексиров.''): лигнин--биодеградация
Экземпляры :КФ(1)
Свободны : КФ(1)
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Volova T.G., Shishatskaya E.I., Nikolaeva E.D., Sinskey A.J.
Заглавие : In vivo study of 2D PHA matrices of different chemical compositions: Tissue reactions and biodegradations
Место публикации : Mater. Sci. Technol. - 2014. - Vol. 30, Is. 5. - С. 549-557. - ISSN 17432847 (ISSN) , DOI 10.1179/1743284713Y.0000000470
Ключевые слова (''Своб.индексиров.''): biocompatibility--biodegradation--implantation--pha--polyhydroxyalkanoates--tissue response--biocompatibility--biodegradable polymers--copolymers--degradation--ion implantation--microbiology--tissue--chemical compositions--foreign body giant cells--hydroxybutyric acids--maximum thickness--pha--polyhydroxyalkanoates--polymer matrices--tissue response--biodegradation
Аннотация: Matrices based on resorbable polyhydroxyalkanoates (PHAs) of five types {a homopolymer of 3- hydroxybutyric acid, copolymers of 3-hydroxybutyric and 4-hydroxybutyric acids [P(3HB/4HB)], 3-hydroxybutyric and 3-hydroxyvaleric acids [P(3HB/3HV)], 3-hydroxybutyric and 3-hydroxyhexanoic acids [P(3HB/3HHx)]} have been constructed and characterised. No significant differences have been found in tissue response to implantation of these PHAs. Non-coarse fibrous capsules that formed around PHA matrices reached their maximum thickness (60-90 ?m) 90 days after implantation; by day 180, the average thickness of the capsules had decreased by 1·5-2·3 times. The number of foreign body giant cells, resorbing PHAs, remained high. In vivo biodegradation behaviour of polymer matrices is related to the chemical composition of the PHA. Matrices prepared from copolymers P(3HB/4HB) and P(3HB/3HHx) exhibited the fastest degradation rates. P3HB/3HV matrices were degraded more slowly, and P3HB matrices were the most durable. In the PHA matrices that were degraded more slowly, giant cell reaction developed later. © 2014 Institute of Materials, Minerals and Mining.
Scopus
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bondar V.S., Boersma M.G., Golovlev E.L., Vervoort J..., Van Berkel WJH, Finkelstein Z.I., Solyanikova I.P., Golovleva L.A., Rietjens IMCM
Заглавие : (19)F NMR study on the biodegradation of fluorophenols by various Rhodococcus species
Колич.характеристики :12 с
Место публикации : Biodegradation: SPRINGER, 1998. - Vol. 9: NMR in Environmental Sciences Symposium (OCT 24, 1997, EDE, NETHERLANDS), Is. 6. - С. 475-486. - ISSN 0923-9820, DOI 10.1023/A:1008391906885
Примечания : Cited References: 37
Предметные рубрики: NUCLEAR-MAGNETIC-RESONANCE
PSEUDOMONAS-PUTIDA MT-2
PHENOL HYDROXYLASE
BACTERIAL-DEGRADATION
3-OXOADIPATE PATHWAY
FLUOROBENZOIC ACID
CONVERSION
METABOLISM
CYCLOISOMERASES
2-CHLORO-CIS,CIS-MUCONATE
Ключевые слова (''Своб.индексиров.''): biodegradation--fluorophenols--(19)f nmr--oxidative defluorination--rhodococcus species
Аннотация: Of all NMR observable isotopes (19)F is the one perhaps most convenient for studies on biodegradation of environmental pollutants. The reasons underlying this potential of (19)F NMR are discussed and illustrated on the basis of a study on the biodegradation of fluorophenols by four Rhodococcus strains. The results indicate marked differences between the biodegradation pathways of fluorophenols among the various Rhodococcus species. This holds not only for the level and nature of the fluorinated biodegradation pathway intermediates that accumulate, but also for the regioselectivity of the initial hydroxylation step. Several of the Rhodococcus species contain a phenol hydroxylase that catalyses the oxidative defluorination of ortho-fluorinated di- and trifluorophenols. Furthermore, it is illustrated how the (19)F NMR technique can be used as a tool in the process of identification of an accumulated unknown metabolite, in this case most likely 5-fluoromaleylacetate. Altogether, the (19)F NMR technique proved valid to obtain detailed information on the microbial biodegradation pathways of fluorinated organics, but also to provide information on the specificity of enzymes generally considered unstable and, for this reason, not much studied so far.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Volova T.G., Shishatskaya E.I., Nikolaeva E.D., Sinskey A.J.
Заглавие : In vivo study of 2D PHA matrices of different chemical compositions: tissue reactions and biodegradations
Колич.характеристики :9 с
Коллективы : Government of the Russian Federation
Место публикации : Mater. Sci. Technol.: MANEY PUBLISHING, 2014. - Vol. 30, Is. 5. - С. 549-557. - ISSN 0267-0836, DOI 10.1179/1743284713Y.0000000470. - ISSN 1743-2847
Примечания : Cited References: 31. - The study was supported by the project initiated by the Government of the Russian Federation (decree no. 220 of 09.04.2010) for governmental support of scientific research conducted under the guidance of leading scientists at Russian institutions of higher learning (agreement no. 11.G34.31.0013) and the Program of Integrated Research of the Presidium of SB RAS (project no. 96).
Предметные рубрики: BIOMEDICAL INVESTIGATIONS
POLYHYDROXYALKANOATES
VITRO
BIOCOMPATIBILITY
DEGRADATION
SCAFFOLDS
CONDUITS
POLYMERS
Ключевые слова (''Своб.индексиров.''): pha--polyhydroxyalkanoates--biocompatibility--implantation--tissue response--biodegradation
Аннотация: Matrices based on resorbable polyhydroxyalkanoates (PHAs) of five types {a homopolymer of 3-hydroxybutyric acid, copolymers of 3-hydroxybutyric and 4-hydroxybutyric acids [P(3HB/4HB)], 3-hydroxybutyric and 3-hydroxyvaleric acids [P(3HB/3HV)], 3-hydroxybutyric and 3-hydroxyhexanoic acids [P(3HB/3HHx)]} have been constructed and characterised. No significant differences have been found in tissue response to implantation of these PHAs. Non-coarse fibrous capsules that formed around PHA matrices reached their maximum thickness (60-90 mm) 90 days after implantation; by day 180, the average thickness of the capsules had decreased by 1.5- 2.3 times. The number of foreign body giant cells, resorbing PHAs, remained high. In vivo biodegradation behaviour of polymer matrices is related to the chemical composition of the PHA. Matrices prepared from copolymers P(3HB/4HB) and P(3HB/3HHx) exhibited the fastest degradation rates. P3HB/3HV matrices were degraded more slowly, and P3HB matrices were the most durable. In the PHA matrices that were degraded more slowly, giant cell reaction developed later.
WOS
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Lesnyak D.V., Popova L.Y.
Заглавие : A conflict: Induction-inhibition of luminescence in the expression of lux-genes in transgenic bacteria
Колич.характеристики :5 с
Место публикации : Biofizika: MEZHDUNARODNAYA KNIGA, 2002. - Vol. 47, Is. 6. - P1059-1063. - ISSN 0006-3029
Примечания : Cited References: 12
Ключевые слова (''Своб.индексиров.''): salicylate, naphtalene concentration--bacterial bioluminescence, biodegradation
Аннотация: The relationship between the induction of the luminescent operon of lux-genes fused with the naphthalene and salicylate degradation genes and the inhibition of light emission caused by these compounds was studied. The quantitative correlations between these processes manifest themselves in the fact that light intensity linearly increased in a narrow concentration range of the inductor and then decreased due to the inhibition of the luminescence reaction itself, which is not related to the regulation of expression of lux-genes.
WOS
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6.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : GLADYSHEV M.I., GRIBOVSKAYA I.V.
Заглавие : PHENOL BIODEGRADATION IN THE YENISEI RIVER AND THE KRASNOYARSK RESERVOIR, RUSSIA
Колич.характеристики :5 с
Место публикации : HYDROLOGICAL, CHEMICAL AND BIOLOGICAL PROCESSES OF TRANSFORMATION AND TRANSPORT OF CONTAMINANTS IN AQUATIC ENVIRONMENTS. Ser. IAHS PUBLICATIONS: INT ASSOC HYDROLOGICAL SCIENCES, 1994. - Hydrochemistry 1993 Symposium on Hydrological, Chemical and Biological Processes of Transformation and Transport of Contaminants in Aquatic Environments (MAY 24-28, 1993, ROSTOV NA DONU, RUSSIA), Is. 219. - P217-221. - ISBN 0144-7815. - ISBN 0-947571-88-4
Примечания : Cited References: 0
WOS
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : GLADYSHEV M.I., GRIBOVSKAYA I.V., ADAMOVICH V.V.
Заглавие : DISAPPEARANCE OF PHENOL IN WATER SAMPLES TAKEN FROM THE YENISEI RIVER AND THE KRASNOYARSK RESERVOIR
Место публикации : Water Res.: PERGAMON-ELSEVIER SCIENCE LTD, 1993. - Vol. 27, Is. 6. - С. 1063-1070. - 8. - ISSN 0043-1354, DOI 10.1016/0043-1354(93)90071-O
Примечания : Cited References: 20
Предметные рубрики: ORGANIC-COMPOUNDS
LAKE WATER
MINERALIZATION
BIODEGRADATION
KINETICS
MODELS
Ключевые слова (''Своб.индексиров.''): biodegradation--phenol
Аннотация: Using experimental microecosystems the kinetics of phenol disappearance in river and reservoir water were investigated. In river water the disappearance kinetics could be described by A first-order equation, the same kinetics took place in reservoir water before and after the period of ''bloom'' of blue-green algae. During the ''bloom'', the phenol seemed to be mineralized by bacteria which grew at the expense of another compound, and the model of best fit was the model of exponential growth and low concentration of the test substrate. In the river, two sections differed according to the difference between the mean values of the specific disappearance rates. In the reservoir these rates were lower than those in the river. In general the specific disappearance rate values did not correlate with the values of initial bacterioplankton density, the concentrations of inorganic nutrients nor the chemical oxygen demand. Conclusions about the integral influence of ecosystems on the disappearance rates and dependence of self-purification kinetics on the type of aquatic ecosystem were made.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boyandin A.N., Prudnikova S.V., Karpov V.A., Ivonin V.N., Do N.L., Nguyen T.H., Le TMH, Filichev N.L., Levin A.L., Filipenko M.L., Volova T.G., Gitelson I.I.
Заглавие : Microbial degradation of polyhydroxyalkanoates in tropical soils
Место публикации : Int. Biodeterior. Biodegrad.: ELSEVIER SCI LTD, 2013. - Vol. 83. - С. 77-84. - 8. - ISSN 0964-8305, DOI 10.1016/j.ibiod.2013.04.014
Примечания : Cited References: 74. - This study was financially supported by Project "Biotechnologies of novel biomaterials" (Agreement No. 11.G34.31.0013) in accordance with Resolution No. 220 of the Government of the Russian Federation of April 9, 2010, "On measures designed to attract leading scientists to the Russian institutions of higher learning".
Предметные рубрики: POLY-BETA-HYDROXYBUTYRATE
CHAIN-LENGTH POLYHYDROXYALKANOATES
POLY(3-HYDROXYBUTYRATE) DEPOLYMERASE
COASTAL WATERS
PHA FILMS
BIODEGRADATION
BACTERIA
IDENTIFICATION
POLYESTERS
POLY(3-HYDROXYBUTYRATE-CO-3-HYDROXYVALERATE)
Ключевые слова (''Своб.индексиров.''): polyhydroxyalkanoates (phas)--biopolymers--biopolymer properties--soil biodegradation--pha degrading microorganisms
Аннотация: The integrated study addressing biodegradation of microbial linear polyesters of hydroxyalkanoic acids (polyhydroxyalkanoates, PHAs) in tropical conditions by microbial communities of Vietnamese soils was performed in locations close to Hanoi and Nha Trang, which differed in their weather conditions and microbial communities. It shows that PHA degradation in tropical soils is influenced by polymer chemical composition, specimen shape, and microbial characteristics. The homopolymer of 3-hydroxybutyric acid is degraded at higher rates than the copolymer of 3-hydroxybutyric and 3-hydroxyvaleric acids. The average rates of mass loss were 0.04-0.33% per day for films and 0.02-0.18% for compact pellets. PHA degradation was accompanied by a decrease in the polymer molecular mass and, usually, an increase in the degree of crystallinity, suggesting preferential degradation of the amorphous phase. Under the study conditions, representatives of the bacterial genera Burkholderia, Bacillus, Cupriavidus, Mycobacterium, and Nocardiopsis and such micromycetes as Acremonium, Gongronella, Paecilomyces, and Penicillium, Trichoderma have been identified as major PHA degraders. (C) 2013 Elsevier Ltd. All rights reserved.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Volova T.G., Belyaeva O.G., Plotnikov V.F., Puzyr' A.P.
Заглавие : Studies of biodegradation of microbial polyhydroxyalkanoates
Место публикации : Applied Biochemistry and Microbiology. - 1998. - Vol. 34, Is. 5. - С. 488-492. - ISSN 00036838 (ISSN)
Аннотация: Biodegradation of polyhydroxyalkanoates (PHA) - polymers of hydroxylated fatty acids - differing in chemical composition, crystallinity, melting temperature, and molecular weight was studied in soil and water environments under conditions of varying ambient temperature and pH. Under similar conditions, homogeneous films of polyhydroxybutyrate (PHB) with different initial properties were degraded at virtually equal rates. Hydroxybutyrate-hydroxyvalerate copolymers with a lower crystallinity and different microstructure in comparison to PHB were degraded at a 20 to 30% higher rate on average. The ambient temperature significantly influenced the rate of PHA biodegradation.
Scopus
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Volova T.G., Belyaeva O.G., Plotnikov V.F., Puzyr' A.P.
Заглавие : Studies of Biodegradation of Microbial Polyhydroxyalkanoates
Место публикации : Prikladnaya Biokhimiya i Mikrobiologiya. - 1998. - Vol. 34, Is. 5. - С. 543. - ISSN 05551099 (ISSN)
Аннотация: Biodegradation of polyhydroxyalkanoates (PHA) - polymers of hydroxylated fatty acids - differing in chemical composition, crystallinity, melting temperature, and molecular weight was studied in soil and water environments under conditions of varying ambient temperature and pH. Under similar conditions, homogeneous films of polyhydroxybutyrate (PHB) with different initial properties were degraded at virtually equal rates. Hydroxybutyrate-hydroxyvalerate copolymers with a lower crystallinity and different microstructure in comparison to PHB were degraded at a 20 to 30% higher rate on average. The ambient temperature significantly influenced the rate of PHA biodegradation.
Scopus
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boyandin A. N., Prudnikova S.V., Filipenko M.L., Khrapov E.A., Vasiliev A. D., Volova, Tatiana G.
Заглавие : Biodegradation of polyhydroxyalkanoates by soil microbial communities of different structures and detection of PHA degrading microorganisms
Коллективы : Government of the Russian Federation [11.G34.31.0013]; Presidium of the Siberian Branch of Russian Academy of Sciences [96]
Место публикации : Appl. Biochem. Microbiol.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2012. - Vol. 48, Is. 1. - С. 28-36. - 9. - ISSN 0003-6838, DOI 10.1134/S0003683812010024
Примечания : Cited References: 39. - The work was supported by the project initiated by the Government of the Russian Federation for governmental support of scientific research conducted under the guidance of leading scientists at Russian institutions of higher learning (Agreement No. 11.G34.31.0013) and the Program of Integrated Research of the Presidium of the Siberian Branch of Russian Academy of Sciences (project no. 96).
Предметные рубрики: POLY-BETA-HYDROXYBUTYRATE
CHAIN-LENGTH POLYHYDROXYALKANOATES
DEGRADATION
FILMS
POLY(3-HYDROXYBUTYRATE-CO-3-HYDROXYVALERATE)
BACTERIA
ACID
Аннотация: Biodegradation of microbial linear polymers of hydroxyalkanoic acids (polyhydroxyalkanoates, PHAs) by soil microbial communities of different structures has been studied during two field seasons in different weather conditions. This process was shown to be influenced by the polymer chemical composition, temperature, humidity, and the microbial soil component. The PHA degradation was accompanied by a decrease in the polymer molecular weight and an increase in the degree of crystallinity, indicating the preferential destruction of the amorphous phase compared to the crystalline one. The quantity of the true PHA destructors developing at the surface of the polymer samples was lower than the quantity of accompanying bacteria. The dominant PHA degrading microorganisms under the test conditions were identified as bacteria of the genera Variovorax, Stenotrophomonas, Acinetobacter, Pseudomonas, Bacillus, and Xanthomonas and as micromycetes from Penicillium, Paecilomyces, Acremonium, Verticillium, and Zygosporium.
WOS,
SCOPUS,
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Prudnikova S.V., Boyandin A.N., Kalacheva G.S., Sinskey A.J.
Заглавие : Degradable Polyhydroxyalkanoates as Herbicide Carriers
Коллективы : Government of the Russian Federation [11.G34.31.0013]
Место публикации : J. Polym. Environ.: SPRINGER/PLENUM PUBLISHERS, 2013. - Vol. 21, Is. 3. - С. 675-682. - 8. - ISSN 1566-2543, DOI 10.1007/s10924-012-0561-z
Примечания : Cited References: 31. - We thank Dr. Christopher Brigham for critical review of the manuscript prior to submission. The study was supported by the project initiated by the Government of the Russian Federation for governmental support of scientific research conducted under the guidance of leading scientists at Russian institutions of higher learning (Agreement No. 11.G34.31.0013).
Предметные рубрики: CONTROLLED-RELEASE
SOIL
BIODEGRADATION
POLYESTERS
PESTICIDE
POLY(3-HYDROXYBUTYRATE-CO-3-HYDROXYVALERATE)
MICROSPHERES
BACTERIA
Ключевые слова (''Своб.индексиров.''): herbicide--haloxyfop-p-methyl--zellek super--sustained-release formulations--polyhydroxyalkanoates--plant growth suppression
Аннотация: The biodegradable polymer poly(3-hydroxybutyrate-co-3-hydroxyvalerate) has been used to design experimental sustained-release formulations of the herbicide Zellek Super in the form of films and microgranules. The kinetics of polymer degradation and the dynamics of herbicide release show that the rate and extent of herbicide release from the polymer matrix into the soil depends on the geometry of the carrier and the proportion of the pesticide loaded into it (polymer/pesticide mass ratio). Experiments with the creeping bentgrass (Agrostis stolonifera L.) show that the formulations of the herbicide Zellek Super constructed as microgranules and films can be successfully used to suppress the growth of grasses. This study is the first to demonstrate that biodegradable polyhydroxyalkanoates can be used effectively to construct environmentally friendly sustained-release PHA-herbicide systems that can be placed into the soil together with seeds.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Voinova O..., Gladyshev M.I., Volova T.G.
Заглавие : Comparative study of PHA degradation in natural reservoirs having various types of ecosystems
Место публикации : Macromol. Symp.: WILEY-V C H VERLAG GMBH, 2008. - Vol. 269: 4th European Symposium on Biopolymers (OCT 02-04, 2007, Kusadasi, TURKEY). - С. 34-37. - 4. - ISSN 1022-1360, DOI 10.1002/masy.zoo850906
Примечания : Cited References: 15
Предметные рубрики: POLYHYDROXYALKANOATES
BIODEGRADATION
DISAPPEARANCE
POLYESTERS
PHENOL
Ключевые слова (''Своб.индексиров.''): biodegradable polyesters--ecosystem--natural environment--pha--water reservoir
Аннотация: The kinetics of polyhydroxyalkanoate (PHA) degradation in natural environment in two water reservoirs having various ecological characteristics was studied. It was shown that biodegradation of polymer essentially depends on the environment temperature and inorganic composition of water. The processes of polymer degradation under aerobic and anaerobic conditions were compared. The polymer degradation was slower under anaerobic conditions.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bartsev S. I., Gitelson J. I.
Заглавие : A mathematical model of the global processes of plastic degradation in the World Ocean with account for the surface temperature distribution
Колич.характеристики :4 с
Коллективы : State Assignment for fundamental research of RAS [01201351502]
Место публикации : Dokl. Earth Sci.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2016. - Vol. 466, Is. 2. - С. 153-156. - ISSN 1028-334X, DOI 10.1134/S1028334X16020033. - ISSN 1531-8354(eISSN)
Примечания : Cited References:12. - This work was financially supported in part by the State Assignment for fundamental research of RAS (project no. 01201351502).
Предметные рубрики: BIODEGRADATION
POLYMERS
SOIL
Аннотация: The suggested model of plastic garbage degradation allows us to obtain an estimate of the stationary density of their distribution over the surface of the World Ocean with account for the temperature dependence on the degradation rate. The model also allows us to estimate the characteristic time periods of degradation of plastic garbage and the dynamics of the mean density variation as the mean rate of plastic garbage entry into the ocean varies.
WOS,
Scopus
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boyandin A. N., Kazantseva E. A.
Заглавие : Constructing Slow-Release Metribuzin Formulations by Co-extrusion of the Pesticide with Poly-?-Caprolactone
Место публикации : Macromol. Sympos.: Wiley-VCH Verlag, 2021. - Vol. 395, Is. 1. - Ст.2000283. - ISSN 10221360 (ISSN), DOI 10.1002/masy.202000283
Аннотация: A simple and low-cost method of obtaining slow-release pesticide formulations is proposed by co-extrusion of a herbicide metribuzin with a low-melting biodegradable polyester poly-?-caprolactone, at a temperature above the melting points of both components. Formulations containing 10%, 20%, and 40% herbicide are prepared. Metribuzin release in water during 7 days of exposition reached 81% from the formulations with the 10% loading and 96% from the specimens with the 40% herbicide loading. Biodegradation and pesticide release from the polymer constructs are studied in the model soil for 14 weeks. Degradation rates of the specimens increased with an increase in pesticide content: between 9% for the 10%-loaded specimen and 20% for the 40%-loaded specimen over 14 weeks. The release of metribuzin from the specimens with the 10–20% and 40% loadings reached 37–38% and 55%, respectively; thus, taking into account soil degradation of the herbicide, the herbicide content in soil reached 23–25% and 33%, respectively, of the initially loaded into the polymer matrix. The used approach is promising to obtain long-term release formulations for soil application. © 2021 Wiley-VCH GmbH
Scopus
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sukhanova A. A., Murzova A. E., Boyandin A. N., Kiselev E. G., Sukovatyi A. G., Kuzmin A. P., Shabanov, A., V
Заглавие : Poly-3-hydroxybutyrate/chitosan composite films and nonwoven mats
Колич.характеристики :10 с
Коллективы : Ministry of Education and Science of the Russian FederationMinistry of Education and Science, Russian Federation [FEFE-2020-0015]
Место публикации : Int. J. Biol. Macromol.: ELSEVIER, 2020. - Vol. 165. - С. 2947-2956. - ISSN 0141-8130, DOI 10.1016/j.ijbiomac.2020.10.177. - ISSN 1879-0003(eISSN)
Примечания : Cited References:54. - This study was carried out as part of the State Assignment of the Ministry of Education and Science of the Russian Federation to the team of the research laboratory "Intellectual Materials and Structures" within the project "Development of the methods for modifying polymer matrices containing particulate and fibrous fillers of various origins for creating smart multifunctional materials" (subject number FEFE-2020-0015).
Предметные рубрики: BIODEGRADABLE POLY-3-HYDROXYBUTYRATE
BIOMEDICAL APPLICATIONS
BACTERIAL
Аннотация: Composite films and nonwoven mats of the poly-3-hydroxybutyrate and chitosan natural polymers were prepared and investigated. DSC and FTIR techniques were used to confirm that P(3HB) blending with chitosan resulted in a decrease in P(3HB) crystallinity to 47% and 62% in the films and nonwoven mats, respectively. Scanning electron microscopy showed that addition of chitosan induced changes in the surface morphology of the composite films and a reduction in the diameter of ultrafine fibers in the nonwoven mats from 800 nm to 460 nm. The values of water contact angle for films (53 degrees) and nonwoven mats (50.6 degrees) suggested that chitosan enhanced hydrophilic properties and moisture absorption capacity of the composite materials. On the other hand, P(3HB) showed its reinforcing ability and improved the physical/mechanical properties of chitosan. The work included studies of in vitro biodegradation of the composite specimens and their ability to maintain cell growth and attachment in NIH 3T3 fibroblast culture. (c) 2020 Published by Elsevier B.V.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Prudnikova, Svetlana, V, Evgrafova, Svetlana Yu, Volova, Tatiana G.
Заглавие : Metabolic activity of cryogenic soils in the subarctic zone of Siberia towards "green" bioplastics
Колич.характеристики :12 с
Коллективы : Project "Agropreparations of the new generation: a strategy of construction and realization" [074-02-2018-328]; Government of the Russian Federation [220]; Ministry of Science and Higher Education of the Russian Federation [FSRZ-2020-0006]
Место публикации : Chemosphere: PERGAMON-ELSEVIER SCIENCE LTD, 2021. - Vol. 263. - Ст.128180. - ISSN 0045-6535, DOI 10.1016/j.chemosphere.2020.128180. - ISSN 1879-1298(eISSN)
Примечания : Cited References:101. - This study (polymer synthesis and investigation) was financially supported by Project "Agropreparations of the new generation: a strategy of construction and realization" (Agreement No 074-02-2018-328) in accordance with Resolution No 220 of the Government of the Russian Federation of April 9, 2010, "On measures designed to attract leading scientists to the Russian institutions of higher learning", and by the State assignment of the Ministry of Science and Higher Education of the Russian Federation No. FSRZ-2020-0006 (investigation of polymer degradation in soils of Evenkia).
Аннотация: The present study investigates, for the first time, the structure of the microbial community of cryogenic soils in the subarctic region of Siberia and the ability of the soil microbial community to metabolize degradable microbial bioplastic - poly-3-hydroxybutyrate [P(3HB)]. When the soil thawed, with the soil temperature between 5-7 and 9-11 degrees C, the total biomass of microorganisms at a 10-20-cm depth was 226-234 mg g(-1) soil and CO2 production was 20-46 mg g(-1)W day(-1). The total abundance of microscopic fungi varied between (7.4 +/- 2.3) x 10(3) and (18.3 +/- 2.2) x 10(3) CFU/g soil depending on temperature; the abundance of bacteria was several orders of magnitude greater: (1.6 +/- 0.1) x 10(6) CFU g(-1) soil. The microbial community in the biofilm formed on the surface of P(3HB) films differed from the background soil in concentrations and composition of microorganisms. The activity of microorganisms caused changes in the surface microstructure of polymer films, a decrease in molecular weight, and an increase in the degree of crystallinity of P(3HB), indicating polymer biodegradation due to metabolic activity of microorganisms. The clear-zone technique e plating of isolates on the mineral agar with polymer as sole carbon source e was used to identify P(3HB)-degrading microorganisms inhabiting cryogenic soil in Evenkia. Analysis of nucleotide sequences of rRNA genes was performed to identify the following P(3HB)degrading species: Bacillus pumilus, Paraburkholderia sp., Pseudomonas sp., Rhodococcus sp., Stenotrophomonas rhizophila, Streptomyces prunicolor, and Variovorax paradoxus bacteria and the Penicillium thomii, P. arenicola, P. lanosum, Aspergillus fumigatus, and A. niger fungi. (C) 2020 Elsevier Ltd. All rights reserved.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boyandin A. N., Kazantseva E. A.
Заглавие : Constructing slow-release formulations of herbicide metribuzin using its co-extrusion with biodegradable polyester poly-ε-caprolactone
Место публикации : J. Environ. Sci. Health Part B Pestic. Food Contamin. Agric. Wastes: Bellwether Publishing, Ltd., 2021. - Article in press. - ISSN 03601234 (ISSN), DOI 10.1080/03601234.2021.1911206
Аннотация: Different technologies to prepare long term pesticide forms include polymer coating, preparing composites and encapsulating pesticides in nanoparticles. A simple and low-cost method was proposed to obtain slow-release formulations by co-extrusion of a pesticide with a biodegradable polymer at a temperature above the melting points of both components. A herbicide metribuzin and low-melting polyester poly-?-caprolactone were chosen for this work. Formulations containing 10%, 20%, and 40% herbicide were prepared. During 7 days of their exposition in water, it was released from 81% to 96% of initially loaded metribuzin; the highest release was detected for 40%-loaded forms. Biodegradation of the constructs and pesticide release were further studied in the model soil. Degradation rates of the specimens increased with an increase in pesticide content, from 9% to 20% over 14 weeks for the 10%/20%-loaded and the 40%-loaded specimens, respectively. The release of metribuzin reached, respectively, 37–38% and 55%. The herbicide content in soil was lower due to its partial degradation in soil; it reached 23–25% and 33%, respectively, from initially loaded into the polymer matrix. Release kinetics of metribuzin in water as in soil best fitted the First-order model. The used approach is promising for obtaining long-term release formulations for soil applications. © 2021 Taylor & Francis Group, LLC.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boyandin, Anatoly N., Kazantseva, Eugenia A.
Заглавие : Constructing slow-release formulations of herbicide metribuzin using its co-extrusion with biodegradable polyester poly-epsilon-caprolactone
Колич.характеристики :10 с
Коллективы : Project "Agropreparations of the new generation: a strategy of construction and realization" [074-02-2018-328]; Government of the Russian Federation [220]
Место публикации : J. Environ. Sci. Health Part B-Pestic. Contam. Agric. Wastes: TAYLOR & FRANCIS INC, 2021. - Article in press. - ISSN 0360-1234, DOI 10.1080/03601234.2021.1911206. - ISSN 1532-4109(eISSN)
Примечания : Cited References:43. - This study was financially supported by Project "Agropreparations of the new generation: a strategy of construction and realization" (Agreement No 074-02-2018-328) in accordance with Resolution No 220 of the Government of the Russian Federation of April 9, 2010, "On measures designed to attract leading scientists to the Russian institutions of higher learning".
Аннотация: Different technologies to prepare long term pesticide forms include polymer coating, preparing composites and encapsulating pesticides in nanoparticles. A simple and low-cost method was proposed to obtain slow-release formulations by co-extrusion of a pesticide with a biodegradable polymer at a temperature above the melting points of both components. A herbicide metribuzin and low-melting polyester poly-epsilon-caprolactone were chosen for this work. Formulations containing 10%, 20%, and 40% herbicide were prepared. During 7 days of their exposition in water, it was released from 81% to 96% of initially loaded metribuzin; the highest release was detected for 40%-loaded forms. Biodegradation of the constructs and pesticide release were further studied in the model soil. Degradation rates of the specimens increased with an increase in pesticide content, from 9% to 20% over 14 weeks for the 10%/20%-loaded and the 40%-loaded specimens, respectively. The release of metribuzin reached, respectively, 37-38% and 55%. The herbicide content in soil was lower due to its partial degradation in soil; it reached 23-25% and 33%, respectively, from initially loaded into the polymer matrix. Release kinetics of metribuzin in water as in soil best fitted the First-order model. The used approach is promising for obtaining long-term release formulations for soil applications.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boyandin, Anatoly Nikolayevich, Kazantseva, Eugenia Andreevna
Заглавие : Constructing Slow-Release Metribuzin Formulations by Co-extrusion of the Pesticide with Poly-epsilon-Caprolactone
Колич.характеристики :3 с
Коллективы : Government of the Russian Federation [220, 074-02-2018-328]
Место публикации : Macromol. Symp.: WILEY-V C H VERLAG GMBH, 2021. - Vol. 395: 4th International Conference on Progress on Polymers and Composites (NOV 26-28, 2020, ELECTR NETWORK), Is. 1. - Ст.2000283. - ISSN 1022-1360, DOI 10.1002/masy.202000283. - ISSN 1521-3900(eISSN)
Примечания : Cited References:6. - This study was financially supported by Project "Agropreparations of the new generation: a strategy of construction and realization" (Agreement No 074-02-2018-328) in accordance with Resolution No 220 of the Government of the Russian Federation of April 9, 2010, "On measures designed to attract leading scientists to the Russian institutions of higher learning".
Аннотация: A simple and low-cost method of obtaining slow-release pesticide formulations is proposed by co-extrusion of a herbicide metribuzin with a low-melting biodegradable polyester poly-epsilon-caprolactone, at a temperature above the melting points of both components. Formulations containing 10%, 20%, and 40% herbicide are prepared. Metribuzin release in water during 7 days of exposition reached 81% from the formulations with the 10% loading and 96% from the specimens with the 40% herbicide loading. Biodegradation and pesticide release from the polymer constructs are studied in the model soil for 14 weeks. Degradation rates of the specimens increased with an increase in pesticide content: between 9% for the 10%-loaded specimen and 20% for the 40%-loaded specimen over 14 weeks. The release of metribuzin from the specimens with the 10-20% and 40% loadings reached 37-38% and 55%, respectively; thus, taking into account soil degradation of the herbicide, the herbicide content in soil reached 23-25% and 33%, respectively, of the initially loaded into the polymer matrix. The used approach is promising to obtain long-term release formulations for soil application.
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