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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Neubauer, Darshan, Kolmakova, Olesya, Woodhouse, Jason, Taube, Robert, Mangelsdorf, Kai, Gladyshev, Michail, Premke, Katrin, Grossart, Hans-Peter
Заглавие : Zooplankton carcasses stimulate microbial turnover of allochthonous particulate organic matter
Колич.характеристики :16 с
Коллективы : Projekt DEAL
Место публикации : ISME J.: SPRINGERNATURE, 2021. - Article in press. - ISSN 1751-7362, DOI 10.1038/s41396-020-00883-w. - ISSN 1751-7370(eISSN)
Примечания : Cited References:83. - Open Access funding enabled and organized by Projekt DEAL.
Предметные рубрики: FRESH-WATER
SEASONAL-CHANGES
CARBON
LAKE
DECOMPOSITION
DEGRADATION
Аннотация: Carbon turnover in aquatic environments is dependent on biochemical properties of organic matter (OM) and its degradability by the surrounding microbial community. Non-additive interactive effects represent a mechanism where the degradation of biochemically persistent OM is stimulated by the provision of bioavailable OM to the degrading microbial community. Whilst this is well established in terrestrial systems, whether it occurs in aquatic ecosystems remains subject to debate. We hypothesised that OM from zooplankton carcasses can stimulate the degradation of biochemically persistent leaf material, and that this effect is influenced by the daphnia:leaf OM ratio and the complexity of the degrading microbial community. Fresh Daphnia magna carcasses and C-13-labelled maize leaves (Zea mays) were incubated at different ratios (1:1, 1:3 and 1:5) alongside either a complex microbial community (50 mu m) or solely bacteria (0.8 mu m). C-13 stable-isotope measurements of CO2 analyses were combined with phospholipid fatty acids (PLFA) analysis and DNA sequencing to link metabolic activities, biomass and taxonomic composition of the microbial community. Our experiments indicated a significantly higher respiration of leaf-derived C when daphnia-derived OM was most abundant (i.e. daphnia:leaf OM ratio of 1:1). This process was stronger in a complex microbial community, including eukaryotic microorganisms, than a solely bacterial community. We concluded that non-additive interactive effects were a function of increased C-N chemodiversity and microbial complexity, with the highest net respiration to be expected when chemodiversity is high and the degrading community complex. This study indicates that identifying the interactions and processes of OM degradation is one important key for a deeper understanding of aquatic and thus global carbon cycle.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Tang K.W., Gladyshev M.I., Dubovskaya O.P., Kirillin G..., Grossart H.P.
Заглавие : Zooplankton carcasses and non-predatory mortality in freshwater and inland sea environments
Колич.характеристики :16 с
Коллективы : Humboldt Foundation; Ministry of Education and Science of Russian Federation (Siberian Federal University) [B-15]; Leibniz-Association [SAW-2011-IGB-2]; German Science foundation [KI-853/7-1, GR1540/20-1]
Место публикации : J. Plankton Res.: OXFORD UNIV PRESS, 2014. - Vol. 36, Is. 3. - С. 597-612. - ISSN 0142-7873, DOI 10.1093/plankt/fbu014. - ISSN 1464-3774
Примечания : Cited References: 168. - This work was supported by the Humboldt Foundation (Fellowship for Experienced Researchers to K. W. T.); Siberian Branch of Russian Academy of Science (Partner Project No. 8 to M. I. G. and O.P.D.); Federal Tasks of Ministry of Education and Science of Russian Federation (project B-15 of Siberian Federal University to M. I. G.); the Leibniz-Association (SAW-2011-IGB-2 to G. K.); and the German Science foundation (KI-853/7-1 to G. K., GR1540/20-1 to H. P. G.). The manuscript benefited from the constructive comments from three reviewers.
Предметные рубрики: SMALL-SCALE TURBULENCE
NON-CALANOID COPEPODS
AGGREGATES LAKE SNOW
DAPHNIA-GALEATA
MIDSUMMER DECLINE
NONCONSUMPTIVE MORTALITY
CRUSTACEAN ZOOPLANKTON
CLIMATE-CHANGE
VERTICAL-DISTRIBUTION
POPULATION-GROWTH
Ключевые слова (''Своб.индексиров.''): carbon flux--inland waters--lakes--live--dead sorting--non-predatory mortality--zooplankton carcasses
Аннотация: Zooplankton carcasses are ubiquitous in marine and freshwater systems, implicating the importance of non-predatory mortality, but both are often overlooked in ecological studies compared with predatory mortality. The development of several microscopic methods allows the distinction between live and dead zooplankton in field samples, and the reported percentages of dead zooplankton average 11.6 (minimum) to 59.8 (maximum) in marine environments, and 7.4 (minimum) to 47.6 (maximum) in fresh and inland waters. Common causes of non-predatory mortality among zooplankton include senescence, temperature change, physical and chemical stresses, parasitism and food-related factors. Carcasses resulting from non-predatory mortality may undergo decomposition leading to an increase in microbial production and a shift in microbial composition in the water column. Alternatively, sinking carcasses may contribute significantly to vertical carbon flux especially outside the phytoplankton growth seasons, and become a food source for the benthos. Global climate change is already altering freshwater ecosystems on multiple levels, and likely will have significant positive or negative effects on zooplankton non-predatory mortality. Better spatial and temporal studies of zooplankton carcasses and non-predatory mortality rates will improve our understanding of this important but under-appreciated topic.
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3.

Вид документа : Статья из сборника (выпуск монографической серии)
Шифр издания :
Автор(ы) : Gros J.-B., Lasseur C., Tikhomirov A.A., Manukovsky N.S., Ushakova S.A., Zolotukhin I.G., Tirranen L.S., Borodina E.V., Kovalev V.S.
Заглавие : Wheat growth on neutral and soil-like substrates: Carbon dioxide exchange and microflora
Место публикации : Acta Horticulturae. - 2004. - Vol. 644. - С. 243-248
Ключевые слова (''Своб.индексиров.''): carbon dioxide--closed ecological system
Аннотация: The soil-like substrate (SLS), which is a potential candidate for employment in closed ecological systems, has been tested. CO2 exchange, composition and numbers of soil microflora have been examined in .wheat-SLS. system. The results produced have been compared to analogous characteristics of .wheat-neutral substrate. system. A hydroponic method was used under wheat growing on the neutral substrate (expanded clay aggregate). Plants for both studies were grown in closed environment from seed to physiological maturity. In the .wheat-SLS. system, the net photosynthetic rate of canopy was positive in the course of 6.55 days after planting. The net photosynthetic rate of canopy in .wheat-neutral substrate. system was positive in the entire course of vegetation. According to calculations in the course of vegetation, photosynthesis has withdrawn 3.28 kg m-2 CO2 from the .wheat-SLS. system and 3.40 kg m-2 CO2 from the .wheat-neutral substrate. system. On the SLS dominant among bacteria were the spore-forming bacteria from Bacillus genus, among fungi . from Trichoderma genus. In the hydroponic cultivation on neutral substrate dominant were bacteria from Pseudomonas genus, most commonly found fungi were species from Fusarium and Botrytis genera.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gitel'son I.I., Tikhomirov A.A., Parshina O.V., Ushakova S.A., Kalacheva G.S.
Заглавие : Volatile metabolites and external CO2 exchange of wheat cenoses under optimal conditions and thermal stress
Место публикации : Applied Biochemistry and Microbiology. - 2002. - Vol. 38, Is. 1. - С. 78-82. - ISSN 00036838 (ISSN) , DOI 10.1023/A:1013212907872
Ключевые слова (''Своб.индексиров.''): carbon dioxide--volatile agent--article--biosynthesis--carbon dioxide transport--chemical composition--concentration (parameters)--controlled study--cultivar--metabolite--nonhuman--photosynthesis--photosynthetically active radiation--plant metabolism--qualitative analysis--quantitative analysis--stress--temperature sensitivity--thermal exposure--thermostability--wheat--rickettsia sp. par--triticum--triticum aestivum
Аннотация: The effects of elevated temperature (35 and 45В°C) on photosynthesis, respiration, and both the qualitative and quantitative compositions of volatile emissions (VE) of wheat (Triticum aestuvum L. cultivar 232) cenoses at light intensities of 70, 150, or 240 W/m2 of photosynthetically available radiation (PAR) were studied. At a PAR of 240 W/m2, the thermal stabilities of photosynthesis and respiration increased at 35В°C and decreased at 45В°C. Elevated temperatures nonuniformly changed the rates and direction of VE syntheses. In this process, the highest increase in VE evolution was observed at 70 W/m2 and 35В°C; the lowest, at 240 W/m2. In addition, the concentrations and composition of VE during the repair period differed from the initial values.
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5.

Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Latysheva V., Demyanenko T., Botvich I., Emelyanov D., Khizhnyak S.
Заглавие : Use of spectral surface characteristics for mapping soil cover structure under Krasnoyarsk forest-steppe conditions
Место публикации : E3S Web of Conferences: EDP Sciences, 2020. - Vol. 223: 2020 Regional Problems of Earth Remote Sensing, RPERS 2020 (29 September 2020 through 2 October 2020, ) Conference code: 166122. - Ст.03003. - , DOI 10.1051/e3sconf/202022303003
Аннотация: The relations between the spectral surface characteristics of the elements of the soil cover structure and soil properties in the Krasnoyarsk forest-steppe of Central Siberia were investigated. It was revealed that the most informative parameters for field spectrometry are the content of humus, carbonate carbon dioxide and the prevailing particle-size fractions. A statistically significant relationship between the elements of the soil cover structure and the reflectivity of soils has been confirmed by means of multidimensional statistics. The wave lengths with the greatest coupling force are highlighted. Regression equations for remote study of soil cover structure have been obtained, which can be used if additional point studies are carried out in a wider range of test parameters. © The Authors, published by EDP Sciences, 2020.
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6.

Вид документа : Статья из сборника (выпуск монографической серии)
Шифр издания :
Автор(ы) : Latysheva, Valentina, Demyanenko, Tatyana, Botvich, Irina, Emelyanov, Dmitriy, Khizhnyak, Sergey
Заглавие : USE OF SPECTRAL SURFACE CHARACTERISTICS FOR MAPPING SOIL COVER STRUCTURE UNDER KRASNOYARSK FOREST-STEPPE CONDITIONS
Колич.характеристики :6 с
Место публикации : REGIONAL PROBLEMS OF EARTH REMOTE SENSING (RPERS 2020): E D P SCIENCES, 2020. - Vol. 223: Conference on Regional Problems of Earth Remote Sensing (RPERS) (SEP 29-OCT 02, 2020, Krasnoyarsk, RUSSIA). - Ст.03003. - (E3S Web of Conferences). - , DOI 10.1051/e3sconf/202022303003
Примечания : Cited References:6
Аннотация: The relations between the spectral surface characteristics of the elements of the soil cover structure and soil properties in the Krasnoyarsk forest-steppe of Central Siberia were investigated. It was revealed that the most informative parameters for field spectrometry are the content of humus, carbonate carbon dioxide and the prevailing particle-size fractions. A statistically significant relationship between the elements of the soil cover structure and the reflectivity of soils has been confirmed by means of multidimensional statistics. The wave lengths with the greatest coupling force are highlighted. Regression equations for remote study of soil cover structure have been obtained, which can be used if additional point studies are carried out in a wider range of test parameters. Keywords: soil cover structure, spectral brightness coefficient, humus, particle-size distribution, multiple regression.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Biel K.Y., Fomina I.R., Nazarova G.N., Soukhovolsky V.G., Khlebopros R.G., Nishio J.N.
Заглавие : Untangling metabolic and spatial interactions of stress tolerance in plants. 1. Patterns of carbon metabolism within leaves
Место публикации : Protoplasma. - 2010. - Vol. 245, Is. 1. - С. 49-73. - ISSN 0033183X (ISSN) , DOI 10.1007/s00709-010-0135-7
Ключевые слова (''Своб.индексиров.''): carbon metabolism--leaf anatomy--leaf form and function--maximal ecological utility--photosynthesis--stress tolerance spinacia oleracea--aspartate aminotransferase isoenzyme 1--bicarbonate--carbon--carbon dioxide--catalase--chlorophyll--malate dehydrogenase--oxygen--ribulosebisphosphate carboxylase--vegetable protein--article--enzymology--histology--light--metabolism--oxidation reduction reaction--photosynthesis--physiological stress--physiology--plant leaf--spinach--theoretical model--aspartate aminotransferase, cytoplasmic--bicarbonates--carbon--carbon dioxide--catalase--chlorophyll--light--malate dehydrogenase--models, theoretical--oxidation-reduction--oxygen--photosynthesis--plant leaves--plant proteins--ribulose-bisphosphate carboxylase--spinacia oleracea--stress, physiological--spinacia oleracea
Аннотация: The localization of the key photoreductive and oxidative processes and some stress-protective reactions within leaves of mesophytic C3 plants were investigated. The role of light in determining the profile of Rubisco, glutamate oxaloacetate transaminase, catalase, fumarase, and cytochrome-c-oxidase across spinach leaves was examined by exposing leaves to illumination on either the adaxial or abaxial leaf surfaces. Oxygen evolution in fresh paradermal leaf sections and CO2 gas exchange in whole leaves under adaxial or abaxial illumination was also examined. The results showed that the palisade mesophyll is responsible for the midday depression of photosynthesis in spinach leaves. The photosynthetic apparatus was more sensitive to the light environment than the respiratory apparatus. Additionally, examination of the paradermal leaf sections by optical microscopy allowed us to describe two new types of parenchyma in spinach-pirum mesophyll and pillow spongy mesophyll. A hypothesis that oxaloacetate may protect the upper leaf tissue from the destructive influence of active oxygen is presented. The application of mathematical modeling shows that the pattern of enzymatic distribution across leaves abides by the principle of maximal ecological utility. Light regulation of carbon metabolism across leaves is discussed. В© 2010 Springer-Verlag.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Degermendzhy A.G., Gulati R.D.
Заглавие : Understanding the mechanisms of blooming of phytoplankton in Lake Shira, a saline lake in Siberia (the Republic of Khakasia)
Место публикации : Aquatic Ecology. - 2002. - Vol. 36, Is. 2. - С. 331-340. - ISSN 13862588 (ISSN)
Ключевые слова (''Своб.индексиров.''): carbon budget--cyanobacteria--heterotrophic bacteria--hydrogen sulphide--mathematical models of stratification--meromictic lakes--microbial loop--stratification--trophic scheme--algal bloom--ecosystem modeling--limiting factor--nutrient availability--phytoplankton--saline lake--trophic interaction--russian federation--algae--bacteria (microorganisms)--cyanobacteria--lyngbya--lyngbya contorta
Аннотация: The paper summarises the results of a three-year research study (European Union Grant: INTAS 97-0519) aimed at investigating the planktonic populations and trophic organization of the Lake Shira ecosystem - a saline lake in Khakasia, Siberia. The lake exhibits a stable summer-autumn stratification of the chemical-biological components. The mechanisms responsible for the 'blooming' of phytoplankton in the deeper layers were investigated in greater detail, using data from both field and laboratory experiments. The spectra of nutrition were examined to estimate the relationships between the specific growth rates of the hydrobionts and the influence of the limiting factors: light, nutrients. The observed heterotrophic capability of a metalimnetic phytoplankton population might help explain the development in the deeper waters of Lyngbya contorta. The scheme of trophic interactions was put up, based on the assessment of the carbon pools and carbon flows in the pelagic zone of the lake. A mathematical model of the vertical structure of the lake's plankton populations was constructed, using the ecosystem description and data of vertical turbulent diffusion. The role of light and nutrient limitations and grazing mortality in forming the vertical inhomogeneities, particularly in lowering the depth of the maximal cyanobacterial biomass, has been demonstrated. The theoretical curves for the stratification of chemical and biological parameters have been brought in conformity with the field observations, e.g. for the different patterns of the peaks, and for the biomass maxima of cyanobacteria, purple and green sulphur bacteria, oxygen, and hydrogen sulphide. The calculations revealed that for an adequate assessment of the parameters for the hydrogen sulphide zone it is necessary to introduce flows of allochthonous organic matter. Based on the form of the sulphur distribution curve, the allochthonous input of organic matter and the inflow of hydrogen sulphide from the bottom have been theoretically discriminated for the first time. It has also been ascertained that irrespective of the depth the allochthonous substances limiting bacterial growth, the bacteria are uniformly distributed over depth and can serve as an indicator of the presence of limitation (the effect of autostabilisation in space). Of indisputable interest to limnology are the specific methods developed for understanding the functioning of Lake Shira ecosystem. These include the autostabilisation of the limiting factors, the on-the-spot fluorescent method of determining the three classes of microalgae, the algal mixotrophy and the planktonic population interactions and feedbacks, and development of a more sensitive, bioluminescent method for mapping the nonhomogeneities. Owing to a balanced combination of classical approaches (field observations, in situ data on production-decomposition) and the more recent ones (satellite monitoring, biophysical methods of estimating interactions of populations, mathematical models based on the field and experimental data), many of the structural-function relationships in the ecosystem can now be explained, and the models can provide 'mutual control and mutual agreement' between the data collected using different approaches.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bolsunovsky A.Y., Bondareva L.G.
Заглавие : Tritium in surface waters of the Yenisei River basin
Место публикации : Journal of Environmental Radioactivity. - 2003. - Vol. 66, Is. 3. - С. 285-294. - ISSN 0265931X (ISSN) , DOI 10.1016/S0265-931X(02)00132-7
Ключевые слова (''Своб.индексиров.''): deep-well injection of radionuclides--nuclear reactor--surface and ground waters--tritium--yenisei river basin--cooling water--nuclear reactors--sediments--surface waters--river basins--tritium--carbon 14--surface water--tritium--groundwater--nuclear power plant--radioactive pollution--surface water--tritium--article--catchment--measurement--radioactive contamination--river--sediment--environmental monitoring--geologic sediments--mining--power plants--reference values--russia--tritium--water pollutants, radioactive--russian federation--tritium
Аннотация: This paper reports an investigation of the tritium content in the surface waters of the Yenisei River basin near the Mining and Chemical Combine (MCC). In 2001 the maximum tritium concentration in the Yenisei River did not exceed 4 В± 1 Bq l-1, which is consistent with the data of 1998-99. However, it has been found that there are surface waters containing enhanced tritium as compared with the background values for the Yenisei River. For instance, in the Ploskii Stream and the Shumikha River the maximum tritium concentrations amount to 168 and 81 Bq l-1, respectively. The source of tritium in these surface waters is the last operating reactor at the MCC, which still uses the Yenisei water as coolant. In water and sediment samples of the Bolshaya Tel River (a tributary of the Yenisei River) the tritium content turned out to be at least 10 times higher than the background values for the Yenisei River. The measurements conducted at the RPA RADON (Moscow) revealed not only tritium but also the artificial radionuclide 14C in the Bolshaya Tel samples. The data obtained suggest that the Bolshaya Tel River receives the major part of tritium from sediments rather than from the water catchment area. This allows the conclusion that there is water exchange between the surface waters and the radioactively contaminated underground horizons of the "Severny" testing site. В© 2002 Elsevier Science Ltd. All rights reserved.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Karpowicz M., Feniova I., Gladyshev M. I., Ejsmont-Karabin J., Gorniak A., Sushchik N. N., Anishchenko O. V., Dzialowski A. R.
Заглавие : Transfer efficiency of carbon, nutrients, and polyunsaturated fatty acids in planktonic food webs under different environmental conditions
Место публикации : Ecology and Evolution: John Wiley and Sons Ltd, 2021. - Article in press. - ISSN 20457758 (ISSN), DOI 10.1002/ece3.7651
Аннотация: The trophic transfer efficiency (TTE) is an important indicator of ecosystem functioning. However, TTE data from freshwater food webs are ambiguous due to differences in time scales and methods. We investigated the transfer of essential substances (carbon, nutrients, and polyunsaturated fatty acids) through plankton communities in 30 Polish lakes with different trophic status in the middle of summer. The results of our study revealed that different essential substances were transferred from phytoplankton to zooplankton with varying efficiencies. The average TTE of C, N, P, and the sum of ?-3 PUFA were 6.55%, 9.82%, 15.82%, and 20.90%, respectively. Our results also show a large mismatch between the elemental and biochemical compositions of zooplankton and their food during the peak of the summer stagnation, which may further promote the accumulation of essential substances. There were also large differences in TTEs between trophic conditions, with the highest efficiencies in oligotrophic lakes and the lowest in dystrophic and eutrophic lakes. Therefore, our study indicates that disturbances like eutrophication and dystrophication similarly decrease the TTE of essential substances between phytoplankton and zooplankton in freshwater food webs. © 2021 The Authors. Ecology and Evolution published by John Wiley & Sons Ltd.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Karpowicz, Maciej, Feniova, Irina, Gladyshev, Michail I., Ejsmont-Karabin, Jolanta, Gorniak, Andrzej, Sushchik, Nadezhda N., Anishchenko, Olesya V., Dzialowski, Andrew R.
Заглавие : Transfer efficiency of carbon, nutrients, and polyunsaturated fatty acids in planktonic food webs under different environmental conditions
Колич.характеристики :14 с
Коллективы : Polish National Science Centre [2016/21/B/NZ8/00434]; Federal Tasks for Institute of Biophysics SB RAS [51.1.1]; Federal Tasks for Siberian Federal University [FSRG-2020-0019]
Место публикации : Ecol. Evol.: WILEY, 2021. - Article in press. - ISSN 2045-7758, DOI 10.1002/ece3.7651
Примечания : Cited References:62. - This research was supported by the Polish National Science Centre (2016/21/B/NZ8/00434). The research was also supported by Federal Tasks for Institute of Biophysics SB RAS No. 51.1.1 and Federal Tasks for Siberian Federal University No. FSRG-2020-0019. The authors are thankful to Joanna Kozowska for her help in the collection of samples.
Предметные рубрики: PHOSPHORUS STOICHIOMETRY
LIGHT-INTENSITY
ZOOPLANKTON
TEMPERATURE
Аннотация: The trophic transfer efficiency (TTE) is an important indicator of ecosystem functioning. However, TTE data from freshwater food webs are ambiguous due to differences in time scales and methods. We investigated the transfer of essential substances (carbon, nutrients, and polyunsaturated fatty acids) through plankton communities in 30 Polish lakes with different trophic status in the middle of summer. The results of our study revealed that different essential substances were transferred from phytoplankton to zooplankton with varying efficiencies. The average TTE of C, N, P, and the sum of omega-3 PUFA were 6.55%, 9.82%, 15.82%, and 20.90%, respectively. Our results also show a large mismatch between the elemental and biochemical compositions of zooplankton and their food during the peak of the summer stagnation, which may further promote the accumulation of essential substances. There were also large differences in TTEs between trophic conditions, with the highest efficiencies in oligotrophic lakes and the lowest in dystrophic and eutrophic lakes. Therefore, our study indicates that disturbances like eutrophication and dystrophication similarly decrease the TTE of essential substances between phytoplankton and zooplankton in freshwater food webs.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kovel E. S., Kicheeva A. G., Vnukova N. G., Churilov G. N., Stepin E. A., Kudryasheva N. S.
Заглавие : Toxicity and antioxidant activity of fullerenol c60,70 with low number of oxygen substituents
Место публикации : Int. J. Mol. Sci.: MDPI AG, 2021. - Vol. 22, Is. 12. - Ст.6382. - ISSN 16616596 (ISSN), DOI 10.3390/ijms22126382
Аннотация: Fullerene is a nanosized carbon structure with potential drug delivery applications. We studied the bioeffects of a water-soluble fullerene derivative, fullerenol, with 10-12 oxygen groups (F10-12); its structure was characterized by IR and XPS spectroscopy. A bioluminescent enzyme system was used to study toxic and antioxidant effects of F10-12 at the enzymatic level. Antioxidant characteristics of F10-12 were revealed in model solutions of organic and inorganic oxidizers. Low-concentration activation of bioluminescence was validated statistically in oxidizer solutions. Toxic and antioxidant characteristics of F10-12 were compared to those of homologous fullerenols with a higher number of oxygen groups:F24-28 and F40-42. No simple dependency was found between the toxic/antioxidant characteristics and the number of oxygen groups on the fullerene’s carbon cage. Lower toxicity and higher antioxidant activity of F24-28 were identified and presumptively attributed to its higher solubility. An active role of reactive oxygen species (ROS) in the bioeffects of F10-12 was demonstrated. Correlations between toxic/antioxidant characteristics of F10-12 and ROS content were evaluated. Toxic and antioxidant effects were related to the decrease in ROS content in the enzyme solutions. Our results reveal a complexity of ROS effects in the enzymatic assay system. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kovel, Ekaterina S., Kicheeva, Arina G., Vnukova, Natalia G., Churilov, Grigory N., Stepin, Evsei A., Kudryasheva, Nadezhda S.
Заглавие : Toxicity and Antioxidant Activity of Fullerenol C-60,C-70 with Low Number of Oxygen Substituents
Колич.характеристики :17 с
Коллективы : RFBRRussian Foundation for Basic Research (RFBR) [N18-29-19003]; RFBR, Krasnoyarsk Territory; Krasnoyarsk Regional Fund of Science [N20-44-243001]; Program of the Federal Service for Surveillance on Consumer Rights Protection and Human Wellbeing, Fundamental Study 2020-2025 (Russian Federation)
Место публикации : Int. J. Mol. Sci.: MDPI, 2021. - Vol. 22, Is. 12. - Ст.6382. - ISSN 1422-0067(eISSN), DOI 10.3390/ijms22126382
Примечания : Cited References:93. - This research was funded by RFBR, N18-29-19003; RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, N20-44-243001; and partly supported by the Program of the Federal Service for Surveillance on Consumer Rights Protection and HumanWellbeing, Fundamental Study 2020-2025 (Russian Federation).
Предметные рубрики: HUMIC SUBSTANCES
DETOXIFICATION PROCESSES
BIOLOGICAL-ACTIVITY
Аннотация: Fullerene is a nanosized carbon structure with potential drug delivery applications. We studied the bioeffects of a water-soluble fullerene derivative, fullerenol, with 10-12 oxygen groups (F10-12); its structure was characterized by IR and XPS spectroscopy. A bioluminescent enzyme system was used to study toxic and antioxidant effects of F10-12 at the enzymatic level. Antioxidant characteristics of F10-12 were revealed in model solutions of organic and inorganic oxidizers. Low-concentration activation of bioluminescence was validated statistically in oxidizer solutions. Toxic and antioxidant characteristics of F10-12 were compared to those of homologous fullerenols with a higher number of oxygen groups:F24-28 and F40-42. No simple dependency was found between the toxic/antioxidant characteristics and the number of oxygen groups on the fullerene's carbon cage. Lower toxicity and higher antioxidant activity of F24-28 were identified and presumptively attributed to its higher solubility. An active role of reactive oxygen species (ROS) in the bioeffects of F10-12 was demonstrated. Correlations between toxic/antioxidant characteristics of F10-12 and ROS content were evaluated. Toxic and antioxidant effects were related to the decrease in ROS content in the enzyme solutions. Our results reveal a complexity of ROS effects in the enzymatic assay system.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ushakova S.A., Tikhomirov A.A.
Заглавие : Tolerance of LSS plant component to elevated temperatures
Место публикации : Acta Astronautica. - 2002. - Vol. 50, Is. 12. - С. 759-764. - ISSN 00945765 (ISSN) , DOI 10.1016/S0094-5765(02)00010-3
Ключевые слова (''Своб.индексиров.''): metabolism--photosynthesis--rate constants--thermal effects--thermoanalysis--thermal tolerance--life support systems (spacecraft)--carbon dioxide--adaptation--article--brassicaceae--comparative study--heat--instrumentation--light--metabolism--microclimate--photosynthesis--physiology--plant physiology--wheat--adaptation, physiological--brassicaceae--carbon dioxide--ecological systems, closed--heat--life support systems--light--photosynthesis--plant physiology--triticum
Аннотация: Stability of LSS based on biological regeneration of water, air and food subject to damaging factors is largely dependent on the behavior of the photosynthesizing component represented, mainly, by higher plants. The purpose of this study is to evaluate the tolerance of uneven-aged wheat and radish cenoses to temperature effects different in time and value. Estimation of thermal tolerance of plants demonstrated that exposure for 20 h to the temperature increasing to 45В°C brought about irreversible damage both in photosynthetic processes (up to 80% of initial value) and the processes of growth and development. Kinetics of visible photosynthesis during exposure to elevated temperatures can be used to evaluate critical exposure time within the range of which the damage of metabolic processes is reversible. With varying light intensity and air temperature it is possible to find a time period admissible for the plants to stay under adverse conditions without considerable damage of metabolic processes. В© 2002 Elsevier Science Ltd. All rights reserved.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vlasov A., Ralchenko V., Gordeev S., Zakharov D., Vlasov I., Karabutov A., Belobrov P.
Заглавие : Thermal properties of diamond/carbon composites
Место публикации : Diamond and Related Materials. - 2000. - Vol. 9: 10th European Conference on Diamond, Diamond-like Materials, Carbon Nanotubes, Nitrides and Silicon Carbide (12 September 1999 through 17 September 1999, Prague, Czech Republic, Is. 3-6. - С. 1104-1109. - ISSN 09259635 (ISSN) , DOI 10.1016/S0925-9635(99)00256-3
Ключевые слова (''Своб.индексиров.''): diamond composites--laser flash technique--tem--thermal conductivity--grain size and shape--laser applications--nanostructured materials--phonons--thermal conductivity of solids--transmission electron microscopy--diamond composites--laser flash technique--industrial diamonds--carbon--composite--diamond--thermal conductivity
Аннотация: The thermal conductivity, k, of diamond/carbon composites with different ratios of sp 2/sp 3-bonded carbon is measured by the laser flash technique. The thermal conductivity of nanocomposites containing 6 nm diamond particles falls within the range of k=0.003-0.017 W/cmK at room temperature. The thermal conductivity increases while nanopores are gradually filled with pyrolytic carbon (pyrocarbon/diamond mass ratio variation of 0.0-0.5). Transmission electron microscopy data reveal a fairly uniform mixture of two carbon phases, the diamond and matrix having similar grain sizes. Estimates show that the phonon free path is limited by dimensions of carbon matrix layer. Thermal data for coarse-grain (1-2 ?m) composites are also given for comparison. (C) 2000 Elsevier Science S.A. All rights reserved.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vlasov A..., Ralchenko V..., Gordeev S..., Zakharov D..., Vlasov I..., Karabutov A..., Belobrov P...
Заглавие : Thermal properties of diamond/carbon composites
Колич.характеристики :6 с
Место публикации : Diam. Relat. Mat.: ELSEVIER SCIENCE SA, 2000. - Vol. 9: 10th European Conference on Diamond, Diamond-Like Materials, Nitrides and Silicon Carbide (Diamond 1999) (SEP 12-17, 1999, PRAGUE, CZECH REPUBLIC), Is. 03.06.2013. - P1104-1109. - ISSN 0925-9635, DOI 10.1016/S0925-9635(99)00256-3
Примечания : Cited References: 9
Предметные рубрики: CVD DIAMOND
CONDUCTIVITY
FILMS
RAMAN
Ключевые слова (''Своб.индексиров.''): diamond composites--laser flash technique--tem--thermal conductivity
Аннотация: The thermal conductivity, k, of diamond/carbon composites with different ratios of sp(2)/sp(3)-bonded carbon is measured by the laser flash technique. The thermal conductivity of nanocomposites containing 6 nm diamond particles falls within the range of k = 0.003-0.017 W/cmK; at room temperature. The thermal conductivity increases while nanopores are gradually filled with pyrolytic carbon (pyrocarbon/diamond mass ratio variation of 0.0-0.5). Transmission electron microscopy data reveal a fairly uniform mixture of two carbon phases, the diamond and matrix having similar grain sizes. Estimates show that the phonon free path is limited by dimensions of carbon matrix layer. Thermal data for coarse-grain (1-2 mu m) composites are also given for comparison. (C) 2000 Elsevier Science S.A. All rights reserved.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Volova T.G., Kalacheva G.S.
Заглавие : The synthesis of hydroxybutyrate and hydroxyvalerate copolymers by the bacterium Ralstonia eutropha
Место публикации : Mikrobiologiya. - 2005. - Vol. 74, Is. 1. - С. 63-69. - ISSN 00263656 (ISSN)
Ключевые слова (''Своб.индексиров.''): ?-ketothiolase--controlled synthesis--poly(hydroxybutyrate-co-hydroxyvalerate)--ralstonia eutropha--bacteria (microorganisms)--cupriavidus necator--acetoacetyl coenzyme a--acetyl coenzyme a acyltransferase--acyl coenzyme a--acyltransferase--butyric acid derivative--carbon dioxide--fructose--hydrogen--poly(3 hydroxybutyrate) co (3 hydroxyvalerate)--poly(3-hydroxyalkanoic acid) synthase--poly(3-hydroxybutyrate)-co-(3-hydroxyvalerate)--polyester--polyhydroxyalkanoate synthase--valeric acid derivative--article--chemistry--crystallization--culture medium--metabolism--wautersia eutropha--acetyl-coa c-acyltransferase--acyl coenzyme a--acyltransferases--butyrates--carbon dioxide--crystallization--culture media--cupriavidus necator--fructose--hydrogen--polyesters--valerates
Аннотация: The paper deals with the study of the synthesis of 3-hydroxybutyrate (3HB) and 3-hydroxyvalerate (3HV) copolymers by the bacterium Ralstonia eutropha B-5786 grown under different carbon nutrition conditions (growth on carbon dioxide, fructose, and CO2-valerate and fructose-valerate mixtures). The parameters to be analyzed included the yield of biomass, the yield, synthesis rate, and composition of copolymers, the activity of the key enzymes of polyhydroxyalkanoate (PHA) synthesis (?-ketothiolase, acetoacetyl-CoA reductase, and PHA synthase), the maximum tolerable concentration of valerate to the bacterium, and the conditions that govern the incorporation of hydroxyvalerate to copolymers. This allowed the relationship between cultivation conditions and the proportion of monomers in the copolymers to be deduced. We were able to synthesize a range of 3HB/3HV copolymers and found that the thermal characteristics and the degree of crystallinity of these copolymers depend on the molar fraction of 3HV.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Volova T.G., Kalacheva G.S.
Заглавие : The synthesis of hydroxybutyrate and hydroxyvalerate copolymers by the bacterium Ralstonia eutropha
Место публикации : Microbiology. - 2005. - Vol. 74, Is. 1. - С. 54-59. - ISSN 00262617 (ISSN) , DOI 10.1007/s11021-005-0028-5
Ключевые слова (''Своб.индексиров.''): ?-ketothiolase--controlled synthesis--poly(hydroxybutyrate-co-hydroxyvalerate)--ralstonia eutropha--bacteria (microorganisms)--ralstonia--wautersia eutropha
Аннотация: The paper deals with the study of the synthesis of 3-hydroxybutyrate (3HB) and 3-hydroxyvalerate (3HV) copolymers by the bacterium Ralstonia eutropha B-5786 grown under different carbon nutrition conditions (growth on carbon dioxide, fructose, and CO2-valerate and fructose-valerate mixtures). The parameters to be analyzed included the yield of biomass; the yield, synthesis rate, and composition of copolymers; the activity of the key enzymes of polyhydroxyalkanoate (PHA) synthesis ?-ketothiolase, acetoacetyl-CoA reductase, and PHA synthase); the maximum tolerable concentration of valerate to the bacterium; and the conditions that govern the incorporation of hydroxyvalerate into copolymers. This allowed the relationship between cultivation conditions and the proportion of monomers in the copolymers to be deduced. We were able to synthesize a range of 3HB/3HV copolymers and found that the thermal characteristics and the degree of crystallinity of such copolymers depend on the molar fraction of 3HV. В© 2005 Pleiades Publishing, Inc.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Barkhatov, Yu. V., Ushakova S. A., Shikhov V. N., Evgrafova, S. Yu., Tikhomirov A. A., Degermendzhi A. G.
Заглавие : The Influence of Temperature and Humidity on Greenhouse Gas Emission in Experiments on Imitation of the Full Vegetation Cycle of Tundra Ecosystems
Колич.характеристики :3 с
Коллективы : Russian Foundation for Basic Research; Krasnoyarsk Krai Government; Krasnoyarsk Regional Fund of Science [17-45-240884]; Russian Foundation for Basic Research [16-04-01677-a]; Institute of Biophysics, Siberian Branch, Russian Academy of Sciences [56.1.4.]
Место публикации : Dokl. Earth Sci.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2018. - Vol. 483, Is. 2. - С. 1539-1541. - ISSN 1028-334X, DOI 10.1134/S1028334X18120115. - ISSN 1531-8354(eISSN)
Примечания : Cited References:15. - This study was supported by the Russian Foundation for Basic Research, the Krasnoyarsk Krai Government and the Krasnoyarsk Regional Fund of Science (project no. 17-45-240884), the Russian Foundation for Basic Research (project no. 16-04-01677-a), and the Institute of Biophysics, Siberian Branch, Russian Academy of Sciences, governmental assignment, theme no. 56.1.4. for 2013-2020.
Предметные рубрики: POLYGONAL TUNDRA
METHANE EMISSION
CARBON
DELTA
LAKES
Аннотация: Laboratory experiments were conducted in a hermetically sealed growth chamber with two soil samples obtained from the arctic tundra zone with different levels of moisture. Samples were maintained at a growing season typical of the region from which they were taken, and for the sample with a high level of moisture it was made twice: with the temperature in accord with natural conditions and one increased by 2 degrees C. It has been shown that heating of the overmoistened tundra soil by 2 degrees C can increased the average carbon dioxide emissions by almost two times (from 75 to 100-150 mg m(-2) h(-1)). Upon the application of heat, no significant increase in methane emission was observed.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Churilov G.N., Weisman R.B., Bulina N.V., Vnukova N.G., Puzir A.P., Solovyov L.A., Bachilo S.M., Tsyboulski D.A., Glushenko G.A.
Заглавие : The influence of Ir and Pt addition on the synthesis of fullerenes at atmospheric pressure
Колич.характеристики :12 с
Место публикации : Fuller. Nanotub. Carbon Nanostruct.: MARCEL DEKKER INC, 2003. - Vol. 11, Is. 4. - P371-382. - ISSN 1536-383X, DOI 10.1081/FST-120025856
Примечания : Cited References: 17
Предметные рубрики: CARBON PLASMA
STRIATIONS
DISCHARGE
FLOW
Ключевые слова (''Своб.индексиров.''): fullerene synthesis--plasma--atmospheric pressure--fullerene derivatives--iridium--platinum
Аннотация: The addition of metallic Ir and Pt to a fullerene-forming, atmospheric-pressure plasma reactor was found to influence the generation of carbonaceous products. It was observed that the added metals were efficiently dispersed into the plasma and that their presence increased the yield of fullerenes. The addition of Ir led to a noticeable shift in the fullerene distribution towards C-60, whereas the addition of Pt increased the proportion Of C-60 oxides and decreased the proportion of higher fullerenes. Addition of Ir also caused a reduction of the soot particle size and the formation of a considerable quantity of carbon nanotubes.
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