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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Thomas, Sabu, Shumilova A. A., Kiselev E. G., Baranovsky, S., V, Vasiliev A. D., Nemtsev, I., V, Kuzmin, Andrei Petrovich, Sukovatyi A. G., Avinash, R. Pai, Volova T. G.
Заглавие : Thermal, mechanical and biodegradation studies of biofiller based poly-3-hydroxybutyrate biocomposites
Колич.характеристики :12 с
Коллективы : Government of the Russian Federation [220]; Project "Agropreparations of the new generation: a strategy of construction and realization" [074-02-2018-328]
Место публикации : Int. J. Biol. Macromol.: ELSEVIER, 2020. - Vol. 155. - С. 1373-1384. - ISSN 0141-8130, DOI 10.1016/j.ijbiomac.2019.11.112. - ISSN 1879-0003(eISSN)
Примечания : Cited References:38. - This studywas financially supported by Project "Agropreparations of the new generation: a strategy of construction and realization" (Agreement No 074-02-2018-328) in accordance with Resolution No 220 of the Government of the Russian Federation of April 9, 2010, "On measures designed to attract leading scientists to the Russian institutions of higher learning".; The surface of the samples was investigated using a scanning electron microscope Hitachi TM-3000 in the Joint Instrument Use Center at the Krasnoyarsk Scientific Center of Siberian Branch of Russian Academy of Sciences.
Предметные рубрики: FORMULATIONS
POLYHYDROXYALKANOATES
POLYHYDROXYBUTYRATE
SOIL
Аннотация: Biodegradable poly-3-hydroxybutyrate [P(3HB)] and natural fillers - clay, peat, and birch wood flour - were used to prepare powdered composites to form pellets and granules. Pellets were produced by cold pressing of polymer and filler powder whereas granules were produced from the powders wetted with ethanol. Characterization techniques like IR spectroscopy, differential scanning calorimetry, X-ray analysis, mechanical analysis and electron microscopy were employed to study the properties of the initial P(3HB) and fillers and the composites. Analysis of the IR spectra of the composites showed the absence of chemical bonds between the components, i.e. the composites were physical mixtures. Young's moduli of the pellets prepared from initial materials varied considerably, and the highest value was obtained for P(3HB) pellets (350 MPa). Studies of biodegradation of composite pellets and granules in the soil for 35 days showed that the residual mass of the pellets had decreased to 68% for P (3HB); 56.4% for P(3HB)/peat; 67% for P(3HB)/wood flour, and 64% for P(3HB)/clay; granules exhibited a similar mass loss, residual mass of the granules of P(3HB) was 68.4%, P(3HB)/peat 46.4%; P(3HB)/wood flour 77%, and P (3HB)/clay 74%. This shows the significance of the material as an eco-friendly composite without sacrificing its mechanical properties. (C) 2019 Published by Elsevier B.V.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Joseph, Blessy, Sam, Rubie Mavelil, Balakrishnan, Preetha, Maria, Hanna J., Gopi, Sreeraj, Volova, Tatiana, Fernandes, Susana C. M., Thomas, Sabu
Заглавие : Extraction of Nanochitin from Marine Resources and Fabrication of Polymer Nanocomposites: Recent Advances
Колич.характеристики :37 с
Коллективы : Government of the Russian Federation [074-02-2018-328, 220]; "Investissements d'Avenir" French programFrench National Research Agency (ANR) [ANR-16-IDEX-0002]; Region Nouvelle-AquitaineRegion Nouvelle-Aquitaine; Communaute d'Agglomeration du Pays Basque, France
Место публикации : Polymers: MDPI, 2020. - Vol. 12, Is. 8. - Ст.1664. - ISSN 2073-4360(eISSN), DOI 10.3390/polym12081664
Примечания : Cited References:128. - This study was financially supported by project "Agro preparations of the new generation: a strategy of construction and realization" (agreement number 074-02-2018-328) in accordance with resolution number 220 of the Government of the Russian Federation of 9 April 2010, "On measures designed to attract leading scientists to the Russian institutions of higher learning." S.C.M.F. is the recipient of an E2S UPPA Research Partnership Chair (MANTA: Marine Materials) supported by the "Investissements d'Avenir" French program managed by ANR (ANR-16-IDEX-0002), the Region Nouvelle-Aquitaine and the Communaute d'Agglomeration du Pays Basque, France.
Предметные рубрики: NATURAL-RUBBER NANOCOMPOSITES
ELECTROSPUN PVDF MEMBRANE
ALPHA-CHITIN
Аннотация: Industrial sea food residues, mainly crab and shrimp shells, are considered to be the most promising and abundant source of chitin. In-depth understanding of the biological properties of chitin and scientific advancements in the field of nanotechnology have enabled the development of high-performance chitin nanomaterials. Nanoscale chitin is of great economic value as an efficient functional and reinforcement material for a wide range of applications ranging from water purification to tissue engineering. The use of polymers and nanochitin to produce (bio) nanocomposites offers a good opportunity to prepare bioplastic materials with enhanced functional and structural properties. Most processes for nanochitin isolation rely on the use of chemical, physical or mechanical methods. Chitin-based nanocomposites are fabricated by various methods, involving electrospinning, freeze drying, etc. This review discusses the progress and new developments in the isolation and physico-chemical characterization of chitin; it also highlights the processing of nanochitin in various composite and functional materials.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Prudnikova S., Streltsova N., Volova T.
Заглавие : The effect of the pesticide delivery method on the microbial community of field soil
Место публикации : Environ. Sci. Pollut. Res.: Springer Science and Business Media Deutschland GmbH, 2020. - Article in press. - ISSN 09441344 (ISSN), DOI 10.1007/s11356-020-11228-7
Аннотация: The study deals with the effects of herbicides (metribuzin, tribenuron-methyl, fenoxaprop-P-ethyl) and fungicides (tebuconazole, epoxiconazole, azoxystrobin) applied to soil as free pesticides or as slow release formulations embedded in a biodegradable composite matrix on the structure of the soil microbial community. The matrix consisted of a natural biopolymer poly-3-hydroxybutyrate [P(3HB)] and a filler—one of the natural materials (peat, clay, and wood flour). The soil microbial community was characterized, including the major eco-trophic groups of bacteria, dominant taxa of bacteria and fungi, and primary P(3HB)-degrading microorganisms, such as Pseudomonas, Bacillus, Pseudarthrobacter, Streptomyces, Penicillium, and Talaromyces. The addition of free pesticides adversely affected the abundance of soil microorganisms; the decrease varied from 1.4 to 56.0 times for different types of pesticides. The slow release pesticide formulations, in contrast to the free pesticides, exerted a much weaker effect on soil microorganisms, no significant inhibition in the abundance of saprotrophic bacteria was observed, partly due to the positive effects of the composite matrix (polymer/natural material), which was a supplementary substrate for microorganisms. The slow release fungicide formulations, like the free fungicides, reduced the total abundance of fungi and inhibited the development of the phytopathogens Fusarium and Alternaria. Thus, slow release formulations of pesticides preserve the bioremediation potential of soil microorganisms, which are the main factor of removing xenobiotics from the biosphere. © 2020, Springer-Verlag GmbH Germany, part of Springer Nature.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ronzhin N. O., Posokhina E. D., Mikhlina E. V., Simunin M. M., Nemtsev I. V., Ryzhkov I. I., Bondar V. S.
Заглавие : Production of a Composite Based on Alumina Nanofibers and Detonation Nanodiamonds for Creating Phenol Indication Systems
Место публикации : Dokl. Chem.: Pleiades Publishing, 2019. - Vol. 489, Is. 1. - С. 267-271. - ISSN 00125008 (ISSN), DOI 10.1134/S001250081911003X
Аннотация: Abstract: A composite of alumina nanofibers (ANF) and modified detonation nanodiamonds (MDND) was produced by mixing aqueous suspensions of the components in a weight ratio of 5 : 1 with subsequent incubation of the mixture for 15 min at 32°C. It was assumed that the formation of the composite is ensured by the difference of the zeta potentials of the components, which is negative for MDND and positive for ANF. Vacuum filtration of the mixture through a fluoroplastic filter (pore diameter 0.6 ?m) formed disks 40 mm in diameter, which were then heat-treated at 300°C to impart structural stability to the composite. Scanning electron microscopy detected that the obtained composite has a network structure, in which MDND particles are distributed over the surface of ANF. It was determined that the MDND particles incorporated in the composite catalyze the phenol–4-aminoantipyrine–H2O2 oxidative azo coupling reaction to form a colored product (quinoneimine). The applicability of the composite to repeated phenol detection in aqueous samples was demonstrated. © 2019, Pleiades Publishing, Ltd.
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Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Stolyar S. V., Chekanova L. A., Yaroslavtsev R. N., Ladygina V. P., Tirranen L. S.
Заглавие : Effect of nanoparticles in growth of test - Bacteria
Место публикации : Journal of Physics: Conference Series: Institute of Physics Publishing, 2019. - Vol. 1399: International Scientific Conference on Applied Physics, Information Technologies and Engineering 2019, APITECH 2019 (25 September 2019 through 27 September 2019, ) Conference code: 156053, Is. 2. - Ст.022029. - , DOI 10.1088/1742-6596/1399/2/022029
Аннотация: Confident effect of five magnetic composite nanoparticles (FeP@Ag, FeP@Pd, CoP, NiP, Fe2O3@A) on growth of test bacteria colonies (Acinetobacter baumannii, scherichia coli, Klebsiella pneumoniae, Pseudomonas aeruginosa, Staphylococcus aureus) in five replicates each is considered. Reliable inhibitors of colonies of all five test bacteria were nanoparticles FeP@Ag. CoP nanoparticles are reliable inhibitors of growth of 4 test bacteria (except for test bacteria Escherichia oli). NiP nanoparticles are reliable inhibitors of growth of 2 test bacteria: Escherichia oli and Klebsiella pneumoniae. Bacteria Escherichia oli were most sensitive to the effect of magnetic nanoparticles; and bacteria Pseudomonas aeruginosa and Staphylococcus aureus were most resistant to the effect of magnetic nanoparticles. The prospects of the method are in the possibility of multiple reuse of the magnetic particles with antimicrobial properties for bacterial decontamination of the studied sources of water and removal of magnetic nanoparticles from the treated liquids by electromagnet. The method can find use in water treatment facilities for household, Industrial and medical wastes. © Published under licence by IOP Publishing Ltd.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ronzhin N. O., Posokhina E. D., Mikhlina E. V., Simunin M. M., Nemtsev I. V., Ryzhkov I. I., Bondar V. S.
Заглавие : Production of a Composite Based on Alumina Nanofibers and Detonation Nanodiamonds for Creating Phenol Indication Systems
Колич.характеристики :5 с
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-29-19078 mk]
Место публикации : Dokl. Chem.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2019. - Vol. 489. - С. 267-271. - ISSN 0012-5008, DOI 10.1134/S001250081911003X. - ISSN 1608-3113(eISSN)
Примечания : Cited References:13. - This work was supported by the Russian Foundation for Basic Research (project no. 18-29-19078 mk).
Предметные рубрики: NANOPARTICLES
GRAPHENE
Аннотация: A composite of alumina nanofibers (ANF) and modified detonation nanodiamonds (MDND) was produced by mixing aqueous suspensions of the components in a weight ratio of 5 : 1 with subsequent incubation of the mixture for 15 min at 32 degrees C. It was assumed that the formation of the composite is ensured by the difference of the zeta potentials of the components, which is negative for MDND and positive for ANF. Vacuum filtration of the mixture through a fluoroplastic filter (pore diameter 0.6 mu m) formed disks 40 mm in diameter, which were then heat-treated at 300 degrees C to impart structural stability to the composite. Scanning electron microscopy detected that the obtained composite has a network structure, in which MDND particles are distributed over the surface of ANF. It was determined that the MDND particles incorporated in the composite catalyze the phenol-4-aminoantipyrine-H2O2 oxidative azo coupling reaction to form a colored product (quinoneimine). The applicability of the composite to repeated phenol detection in aqueous samples was demonstrated.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Prudnikova, Svetlana, Streltsova, Nadezhda, Volova, Tatiana
Заглавие : The effect of the pesticide delivery method on the microbial community of field soil
Колич.характеристики :17 с
Коллективы : Ministry of Science and Higher Education of the Russian Federation, project "Agropreparations of the new generation: a strategy of construction and realization" [074-02-2018-328]
Место публикации : Environ. Sci. Pollut. Res.: SPRINGER HEIDELBERG, 2020. - Article in press. - ISSN 0944-1344, DOI 10.1007/s11356-020-11228-7. - ISSN 1614-7499(eISSN)
Примечания : Cited References:119. - This study was financially supported by the Ministry of Science and Higher Education of the Russian Federation, project "Agropreparations of the new generation: a strategy of construction and realization" (Agreement No 074-02-2018-328).
Предметные рубрики: CONTROLLED-RELEASE
2,4-DICHLOROPHENOXYACETIC ACID
DEGRADATION
Аннотация: The study deals with the effects of herbicides (metribuzin, tribenuron-methyl, fenoxaprop-P-ethyl) and fungicides (tebuconazole, epoxiconazole, azoxystrobin) applied to soil as free pesticides or as slow release formulations embedded in a biodegradable composite matrix on the structure of the soil microbial community. The matrix consisted of a natural biopolymer poly-3-hydroxybutyrate [P(3HB)] and a filler-one of the natural materials (peat, clay, and wood flour). The soil microbial community was characterized, including the major eco-trophic groups of bacteria, dominant taxa of bacteria and fungi, and primary P(3HB)-degrading microorganisms, such asPseudomonas,Bacillus,Pseudarthrobacter,Streptomyces,Penicillium, andTalaromyces. The addition of free pesticides adversely affected the abundance of soil microorganisms; the decrease varied from 1.4 to 56.0 times for different types of pesticides. The slow release pesticide formulations, in contrast to the free pesticides, exerted a much weaker effect on soil microorganisms, no significant inhibition in the abundance of saprotrophic bacteria was observed, partly due to the positive effects of the composite matrix (polymer/natural material), which was a supplementary substrate for microorganisms. The slow release fungicide formulations, like the free fungicides, reduced the total abundance of fungi and inhibited the development of the phytopathogensFusariumandAlternaria. Thus, slow release formulations of pesticides preserve the bioremediation potential of soil microorganisms, which are the main factor of removing xenobiotics from the biosphere.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Jose C., Chan C. H., Winie T., Joseph B., Tharayil A., Maria H. J., Volova T., Mantia F. P.L., Rouxel D., Morreale M., Laroze D., Mathew L., Thomas S.
Заглавие : Thermomechanical analysis of isora nanofibril incorporated polyethylene nanocomposites
Место публикации : Polym.: MDPI AG, 2021. - Vol. 13, Is. 2. - Ст.299. - С. 1-15. - ISSN 20734360 (ISSN), DOI 10.3390/polym13020299
Аннотация: The research on cellulose fiber-reinforced nanocomposites has increased by an unprecedented magnitude over the past few years due to its wide application range and low production cost. However, the incompatibility between cellulose and most thermoplastics has raised significant challenges in composite fabrication. This paper addresses the behavior of plasma-modified polyethylene (PE) reinforced with cellulose nanofibers extracted from isora plants (i.e., isora nanofibrils (INFs)). The crystallization kinetics of PE–INF composites were explained using the Avrami model. The effect of cellulose nanofillers on tuning the physiochemical properties of the nanocomposite was also explored in this work. The increase in mechanical properties was due to the uniform dispersion of fillers in the PE. The investigation on viscoelastic properties confirmed good filler–matrix interactions, facilitating the stress transfer. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Jose, Cintil, Chan, Chin Han, Winie, Tan, Joseph, Blessy, Tharayil, Abhimanyu, Maria, Hanna J., Volova, Tatiana, La Mantia, Francesco Paolo, Rouxel, Didier, Morreale, Marco, Laroze, David, Mathew, Lovely, Thomas, Sabu
Заглавие : Thermomechanical Analysis of Isora Nanofibril Incorporated Polyethylene Nanocomposites
Колич.характеристики :15 с
Коллективы : project "Agro preparations of the new generation: a strategy of construction and realization" [074-02-2018-328]; Government of the Russian Federation [220]
Место публикации : Polymers: MDPI, 2021. - Vol. 13, Is. 2. - Ст.299. - ISSN 2073-4360(eISSN), DOI 10.3390/polym13020299
Примечания : Cited References:46. - This study (polymer synthesis and investigation) was financially supported by the project "Agro preparations of the new generation: a strategy of construction and realization" (Agreement No 074-02-2018-328) in accordance with Resolution No 220 of the Government of the Russian Federation on 9 April 2010, "On measures designed to attract leading scientists to the Russian institutions of higher learning".
Аннотация: The research on cellulose fiber-reinforced nanocomposites has increased by an unprecedented magnitude over the past few years due to its wide application range and low production cost. However, the incompatibility between cellulose and most thermoplastics has raised significant challenges in composite fabrication. This paper addresses the behavior of plasma-modified polyethylene (PE) reinforced with cellulose nanofibers extracted from isora plants (i.e., isora nanofibrils (INFs)). The crystallization kinetics of PE-INF composites were explained using the Avrami model. The effect of cellulose nanofillers on tuning the physiochemical properties of the nanocomposite was also explored in this work. The increase in mechanical properties was due to the uniform dispersion of fillers in the PE. The investigation on viscoelastic properties confirmed good filler-matrix interactions, facilitating the stress transfer.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ronzhin, Nikita O., Posokhina, Ekaterina D., Mikhlina, Elena, V, Mikhlin, Yuri L., Simunin, Mikhail M., Tarasova, Lyudmila S., Vorobyev, Sergey A., Bondar, Vladimir S., Ryzhkov, Ilya I.
Заглавие : A new composite material based on alumina nanofibers and detonation nanodiamonds: synthesis, characterization, and sensing application
Колич.характеристики :14 с
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-29-19078]
Место публикации : J. Nanopart. Res.: SPRINGER, 2021. - Vol. 23, Is. 9. - Ст.199. - ISSN 1388-0764, DOI 10.1007/s11051-021-05309-y. - ISSN 1572-896X(eISSN)
Примечания : Cited References:57. - This work is partially supported by the Russian Foundation for Basic Research, Project 18-29-19078 (E. V. Mikhlina, M. M. Simunin, I. Ryzhkov).
Предметные рубрики: ELECTROCHEMICAL ENERGY-STORAGE
SELECTIVE DETECTION
PHENOL DETECTION
Аннотация: The development of inexpensive, easy-to-produce, and easy-to-use analytical tools for detection of harmful and toxic substances is a relevant research problem with direct applications in environmental monitoring and protection. In this work, we propose a novel composite material based on alumina nanofibers and detonation nanodiamonds for detection of phenol in aqueous medium. The composite material was obtained by mixing an aqueous suspension of alumina nanofibers with a diameter of 10-15 nm and a length of several microns and a hydrosol of nanodiamonds with an average cluster size of 70 nm. The mechanisms underlying the interaction of these nanomaterials are clarified and the physicochemical properties of the composite are investigated. The SEM and TEM studies show that the obtained composite has a network structure, in which clusters of nanodiamonds (10-20 nm in diameter) are distributed over the surface of nanofibers. Coupling of nanomaterials occurs due to opposite signs of their zeta potentials, which results in electrostatic attraction and subsequent chemical bonding as indicated by the X-ray photoelectron spectroscopy and simultaneous thermal analysis. The bonding apparently occurs between functional groups (mainly carboxyl) on the surface of nanodiamonds and amphoteric hydroxyl groups on the surface of alumina nanofibers. The proposed composite allows an easy-to-perform colorimetric analysis for qualitative and quantitative determination of phenol in aqueous samples with linear response over a wide range of concentrations (0.5-106 mu M). Multiple tests have shown that the composite is reusable and retains its catalytic function for at least 1 year during storage at room temperature.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sukhanova A. A., Murzova A. E., Boyandin A. N., Kiselev E. G., Sukovatyi A. G., Kuzmin A. P., Shabanov A. V.
Заглавие : Poly-3-hydroxybutyrate/chitosan composite films and nonwoven mats
Место публикации : Int. J. Biol. Macromol.: Elsevier B.V., 2020. - Vol. 165. - С. 2947-2956. - ISSN 01418130 (ISSN), DOI 10.1016/j.ijbiomac.2020.10.177
Аннотация: Composite films and nonwoven mats of the poly-3-hydroxybutyrate and chitosan natural polymers were prepared and investigated. DSC and FTIR techniques were used to confirm that P(3HB) blending with chitosan resulted in a decrease in P(3HB) crystallinity to 47% and 62% in the films and nonwoven mats, respectively. Scanning electron microscopy showed that addition of chitosan induced changes in the surface morphology of the composite films and a reduction in the diameter of ultrafine fibers in the nonwoven mats from 800 nm to 460 nm. The values of water contact angle for films (53°) and nonwoven mats (50.6°) suggested that chitosan enhanced hydrophilic properties and moisture absorption capacity of the composite materials. On the other hand, P(3HB) showed its reinforcing ability and improved the physical/mechanical properties of chitosan. The work included studies of in vitro biodegradation of the composite specimens and their ability to maintain cell growth and attachment in NIH 3T3 fibroblast culture. © 2020
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12.

Вид документа : Статья из сборника (выпуск монографической серии)
Шифр издания :
Автор(ы) : Stolyar, S., V, Chekanova L. A., Yaroslavtsev R. N., Ladygina V. P., Tirranen L. S.
Заглавие : Effect of nanoparticles in growth of test - bacteria
Колич.характеристики :6 с
Место публикации : INTERNATIONAL SCIENTIFIC CONFERENCE ON APPLIED PHYSICS, INFORMATION: IOP PUBLISHING LTD, 2019. - Vol. 1399: International Scientific Conference on Applied Physics, Information (SEP 25-27, 2019, Siberian Fed Univ, Polytechn Inst, Krasnoyarsk, RUSSIA). - Ст.022029. - (Journal of Physics Conference Series). - , DOI 10.1088/1742-6596/1399/2/022029
Примечания : Cited References:10
Аннотация: Confident effect of five magnetic composite nanoparticles (FeP@Ag, FeP@Pd, CoP, NiP, Fe2O3@AF) on growth of test bacteria colonies (Acinetobacter baumannii, Escherichia coli, Klebsiella pneumoniae, Pseudomonas aeruginosa, Staphylococcus aureus) in five replicates each is considered. Reliable inhibitors of colonies of all five test bacteria were nanoparticles FeP@Ag. CoP nanoparticles are reliable inhibitors of growth of 4 test bacteria (except for test bacteria Escherichia coli). NiP nanoparticles are reliable inhibitors of growth of 2 test bacteria: Escherichia coli and Klebsiella pneumoniae. Bacteria Escherichia coli were most sensitive to the effect of magnetic nanoparticles; and bacteria Pseudomonas aeruginosa and Staphylococcus aureus were most resistant to the effect of magnetic nanoparticles. The prospects of the method are in the possibility of multiple reuse of the magnetic particles with antimicrobial properties for bacterial decontamination of the studied sources of water and removal of magnetic nanoparticles from the treated liquids by electromagnet. The method can find use in water treatment facilities for household, Industrial and medical wastes.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sukhanova A. A., Murzova A. E., Boyandin A. N., Kiselev E. G., Sukovatyi A. G., Kuzmin A. P., Shabanov, A., V
Заглавие : Poly-3-hydroxybutyrate/chitosan composite films and nonwoven mats
Колич.характеристики :10 с
Коллективы : Ministry of Education and Science of the Russian FederationMinistry of Education and Science, Russian Federation [FEFE-2020-0015]
Место публикации : Int. J. Biol. Macromol.: ELSEVIER, 2020. - Vol. 165. - С. 2947-2956. - ISSN 0141-8130, DOI 10.1016/j.ijbiomac.2020.10.177. - ISSN 1879-0003(eISSN)
Примечания : Cited References:54. - This study was carried out as part of the State Assignment of the Ministry of Education and Science of the Russian Federation to the team of the research laboratory "Intellectual Materials and Structures" within the project "Development of the methods for modifying polymer matrices containing particulate and fibrous fillers of various origins for creating smart multifunctional materials" (subject number FEFE-2020-0015).
Предметные рубрики: BIODEGRADABLE POLY-3-HYDROXYBUTYRATE
BIOMEDICAL APPLICATIONS
BACTERIAL
Аннотация: Composite films and nonwoven mats of the poly-3-hydroxybutyrate and chitosan natural polymers were prepared and investigated. DSC and FTIR techniques were used to confirm that P(3HB) blending with chitosan resulted in a decrease in P(3HB) crystallinity to 47% and 62% in the films and nonwoven mats, respectively. Scanning electron microscopy showed that addition of chitosan induced changes in the surface morphology of the composite films and a reduction in the diameter of ultrafine fibers in the nonwoven mats from 800 nm to 460 nm. The values of water contact angle for films (53 degrees) and nonwoven mats (50.6 degrees) suggested that chitosan enhanced hydrophilic properties and moisture absorption capacity of the composite materials. On the other hand, P(3HB) showed its reinforcing ability and improved the physical/mechanical properties of chitosan. The work included studies of in vitro biodegradation of the composite specimens and their ability to maintain cell growth and attachment in NIH 3T3 fibroblast culture. (c) 2020 Published by Elsevier B.V.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Thomas S., Shumilova A. A., Kiselev E. G., Baranovsky S. V., Vasiliev A. D., Nemtsev I. V., Kuzmin A. P., Sukovatyi A. G., Avinash R. P., Volova T. G.
Заглавие : Thermal, mechanical and biodegradation studies of biofiller based poly-3-hydroxybutyrate biocomposites
Место публикации : Int. J. Biol. Macromol.: Elsevier B.V., 2019. - Article in press. - ISSN 01418130 (ISSN) , DOI 10.1016/j.ijbiomac.2019.11.112
Аннотация: Biodegradable poly-3-hydroxybutyrate [P(3HB)] and natural fillers - clay, peat, and birch wood flour – were used to prepare powdered composites to form pellets and granules. Pellets were produced by cold pressing of polymer and filler powder whereas granules were produced from the powders wetted with ethanol. Characterization techniques like IR spectroscopy, differential scanning calorimetry, X-ray analysis, mechanical analysis and electron microscopy were employed to study the properties of the initial P(3HB) and fillers and the composites. Analysis of the IR spectra of the composites showed the absence of chemical bonds between the components, i.e. the composites were physical mixtures. Young's moduli of the pellets prepared from initial materials varied considerably, and the highest value was obtained for P(3HB) pellets (350 MPa). Studies of biodegradation of composite pellets and granules in the soil for 35 days showed that the residual mass of the pellets had decreased to 68% for P(3HB); 56.4% for P(3HB)/peat; 67% for P(3HB)/wood flour, and 64% for P(3HB)/clay; granules exhibited a similar mass loss, residual mass of the granules of P(3HB) was 68.4%, P(3HB)/peat 46.4%; P(3HB)/wood flour 77%, and P(3HB)/clay 74%. This shows the significance of the material as an eco-friendly composite without sacrificing its mechanical properties. © 2018
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Goreva A.V., Shishatskaya E.I., Volova T.G., Sinskey A.J.
Заглавие : Characterization of polymeric microparticles based on resorbable polyesters of oxyalkanoic acids as a platform for deposition and delivery of drugs
Место публикации : Polym. Sci. Ser. A: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2012. - Vol. 54, Is. 2. - С. 94-105. - 12. - ISSN 0965-545X, DOI 10.1134/S0965545X12020022
Примечания : Cited References: 33. - This work was supported by the program for Support of Leading Scientific Schools of the Russian Federation (project no. 11.G34.31.0013.2010, Biotechnology of New Biomaterials) and the program of integrated studies of the Presidium of the Siberian Branch, Russian Academy of Sciences (project no. 93).
Предметные рубрики: IN-VITRO RELEASE
POLYHYDROXYBUTYRATE MICROSPHERES
BLENDS
RIFAMPICIN
BIOCOMPATIBILITY
DEGRADATION
FORMULATION
COMPOSITE
CARRIERS
MODEL
Аннотация: The effect of the preparation technique (chemical composition of a polymer, type and method of emulsion mixing, and molecular mass of a drug) on the yield, structure, and size of microparticles obtained from resorbable polyesters of microbiological origin, polyhydroxyalkanoates, is studied. It is found that the concentration of the polymer solution and the method of emulsion mixing are the most significant factors affecting the diameter of microparticles based on polyhydroxyalkanoates; the surface structure of particles depends to a higher extent on the chemical composition of the polymer. The family of microparticles from 100-200 nm to 50-70 mu m in diameter is synthesized. It is shown that the rate of drug release from microparticles in vitro into the medium is higher in the case of 3-hydroxybutyrate copolymers with 3-hydroxyvalerate than in the case of the homopolymer of 3-hydroxybutyrate. This parameter increases with the content of 3-hydroxyvalerate units in the copolymer and the porosity and mass fraction of the drug in particles with a decrease in their sizes. For in vitro systems containing a phosphate buffer, variation in the preparation parameters makes it possible to obtain microparticles with various characteristics suitable for deposition of drugs. For microparticles obtained from polyhydroxyalkanoates and having different diameters, the mathematical description of the kinetics of drug release from the polymer matrix is provided.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gordeev S.K., Konopleva R.F., Chekanov V.A., Korchagina S.B., Belyaev S.P., Golosovskii I.V., Denisov I.A., Belobrov P.I.
Заглавие : Specific features in the change of electrical resistivity of carbon nanocomposites based on nanodiamonds under neutron irradiation
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2013. - Vol. 55, Is. 7. - С. 1480-1486. - 7. - ISSN 1063-7834, DOI 10.1134/S1063783413070147
Примечания : Cited References: 24. - This study was supported by the Ministry of Education and Science of the Russian Federation (state contract nos. 14.518.11.7028 and 16.518.11.7034) and the Russian Foundation for Basic Research (project no. 10-02-00576).
Предметные рубрики: NANOPARTICLES
Аннотация: The physical properties of bulk composite materials consisting of nanodiamond, pyrolytic carbon, and nanopores were investigated. Samples were irradiated in a channel of the reactor by fast neutrons (E 0.5MeV) in ampoules with helium and in an aqueous medium. The dependences of the electrical transport properties of materials with different compositions on the dose of irradiation with fast neutrons were studied. A nonmonotonic change in the electrical resistivity with an increase in the neutron fluence was revealed. Possible explanations were offered for the observed dependence of the electrical resistivity on the neutron fluence, in particular, those related to the physical processes occurring in surface states of the three-phase system of the nanocomposite.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shishatskaya E.I., Kamendov I.V., Starosvetsky S.I., Vinnik Y.S., Markelova N.N., Shageev A.A., Khorzhevsky V.A., Peryanova O.V., Shumilova A.A.
Заглавие : An in vivo study of osteoplastic properties of resorbable poly-3-hydroxybutyrate in models of segmental osteotomy and chronic osteomyelitis
Место публикации : Artif. Cells, Nanomed. Biotechnol. - 2014. - Vol. 42, Is. 5. - С. 344-355. - ISSN 21691401 (ISSN) , DOI 10.3109/21691401.2013.816312
Ключевые слова (''Своб.индексиров.''): 3d implants--bone substitute--histological analysis and radiography--hydroxyapatite--p3hb--polymer of 3-hydroxybutyric acid--reconstructive osteogenesis--3-hydroxybutyric acid--bone substitutes--histological analysis--osteogenesis--p3hb--hydroxyapatite
Аннотация: A series of 3D implants and filling materials prepared from powdered biodegradable polymers, polyhydroxyalkanoates (PHAs), have been designed for the purposes of reparative osteogenesis. The 3D implants are made of resorbable polymer of hydroxybutyric acid (poly-3-hydroxybutyrate, P3HB) and a composite of this polymer with hydroxyapatite (HA) (P3HB/HA). The properties of the implants were studied in vivo in a model of segmental osteotomy and compared with commercial material Bio-Oss®. All implants containing P3HB as the main component facilitate reconstructive osteogenesis. P3HB and P3HB/HA show pronounced osteoplastic properties; their in vivo degradation is slow and corresponds to the growth of a new bone tissue, facilitating normal reparative osteogenesis. Also, powdered P3HB and P3HB/tienam can be used as filling materials for osteoplasty of bone cavities infected by Staphylococcus aureus. Biodegradable 3D implants and P3HB-based filling materials show pronounced osteoplastic properties and degrade in vivo at a slow rate, enabling normal reparative osteogenesis.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shishatskaya E.I., Khlusov I.A., Volova T.G.
Заглавие : A hybrid PHB-hydroxyapatite composite for biomedical application: Production, in vitro and in vivo investigation
Место публикации : Journal of Biomaterials Science, Polymer Edition. - 2006. - Vol. 17, Is. 5. - С. 481-498. - ISSN 09205063 (ISSN) , DOI 10.1163/156856206776986242
Ключевые слова (''Своб.индексиров.''): biocompatibility--hydroxyapatite (ha)--phb-hydroxyapatite composite--polyhydroxyalkanoate (pha)--polyhydroxybutyrate (p(3hb))--properties--biocompatibility--differential thermal analysis--electron microscopy--free energy--interfacial energy--physical properties--surface properties--x ray analysis--biomedical application--physicochemical properties--polyhydroxyalkanoate (pha)--polyhydroxybutyrate (phb)--hydroxyapatite--hydroxyapatite--poly(3 hydroxybutyric acid)--polymer--biomaterial--hydroxybutyric acid--adhesion--animal cell--animal tissue--article--biomedicine--bone marrow cell--cell differentiation--cell growth--chemical structure--composite material--controlled study--crystallization--decomposition--electron microscopy--in vitro study--in vivo study--melting point--mouse--nonhuman--ossification--osteoblast--physical chemistry--priority journal--rat--strength--structure analysis--surface property--synthesis--temperature measurement--thermal analysis--tissue engineering--wettability--animal--biomechanics--bioremediation--bone prosthesis--cattle--cell culture--chemistry--cytology--differential scanning calorimetry--drug effect--human--materials testing--prostheses and orthoses--scanning electron microscopy--standard--wistar rat--murinae--animals--biocompatible materials--biodegradation, environmental--biomechanics--bone substitutes--cattle--cells, cultured--differential thermal analysis--durapatite--humans--hydroxybutyrates--materials testing--microscopy, electron, scanning--osteoblasts--prostheses and implants--rats--rats, wistar--surface properties
Аннотация: Samples of a hybrid composite of polyhydroxybutyrate (PHB), a biodegradable polyester, and hydroxyapatite (HA), with different PHB/HA ratios, have been prepared using mechanical-physical method. Electron microscopy, X-ray structure analysis and differential thermal analysis have been used to investigate the structure and physicochemical properties of the composite, depending on the PHB/HA ratio. The properties of the surface of the HA-loaded composite are significantly different from those of the pure polymer. As the HA percentage in the composite increases, free interface energy, the cohesive force, i.e., the strength of the adhesive bond between the composite surface and the water phase, and surface wettability increase. The HA percentage of the composite does not influence its melting temperature, but affects the temperature for the onset of decomposition: as the HA content increases from 0 to 10% (w/w), Td decreases from 260В°C to 225В°C. The degree of crystallinity of PHB/HA increases from 77% to 89% with an increase in the HA fraction from 10% to 50%. Functional properties of the composites have been investigated in vitro and in vivo. The best parameters of growth and differentiation of murine marrow osteoblasts are registered on PHB/HA samples containing 10% and 20% HA. In ectopic bone formation assay it has been proven that the hybrid PHB/HA composites can function as scaffolds and that bone tissue develops on their surface and in pores. В© VSP 2006.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Karabutov A.V., Frolov V.D., Konov V.I., Ralchenko V.G., Gordeev S.K., Belobrov P.I.
Заглавие : Low-field electron emission of diamond/pyrocarbon composites
Место публикации : Journal of Vacuum Science and Technology B: Microelectronics and Nanometer Structures. - 2001. - Vol. 19: 13th International Vaccum Microelectronics Conference (14 August 2000 through 17 August 2000, Guangzhou, Is. 3. - С. 965-970. - ISSN 10711023 (ISSN) , DOI 10.1116/1.1368669
Ключевые слова (''Своб.индексиров.''): carbon nanotubes--chemical bonds--chemical vapor deposition--composite materials--diamond films--electric conductivity--electron emission--electron energy levels--hysteresis--interfaces (materials)--raman scattering--semiconducting diamonds--semiconductor quantum wells--transmission electron microscopy--x ray diffraction analysis--x ray photoelectron spectroscopy--pyrocarbon composites--nanostructured materials
Аннотация: The properties of field electron emission for diamond/pyrocarbon nanocomposites produced from diamond particles surrounded by a pyrocarbon matrix were studied. Low-threshold emissions at fields of ?1 V/?m with no activation or hysterisis in the current versus voltage (I/V) behaviour were observed for the materials. Scanning tunneling-field emission microscopy was used to study the mechanisms of low-field electron emission from the composites, and a model based on quantum well effect at the diamond/graphite interface was proposed and discussed.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vlasov A., Ralchenko V., Gordeev S., Zakharov D., Vlasov I., Karabutov A., Belobrov P.
Заглавие : Thermal properties of diamond/carbon composites
Место публикации : Diamond and Related Materials. - 2000. - Vol. 9: 10th European Conference on Diamond, Diamond-like Materials, Carbon Nanotubes, Nitrides and Silicon Carbide (12 September 1999 through 17 September 1999, Prague, Czech Republic, Is. 3-6. - С. 1104-1109. - ISSN 09259635 (ISSN) , DOI 10.1016/S0925-9635(99)00256-3
Ключевые слова (''Своб.индексиров.''): diamond composites--laser flash technique--tem--thermal conductivity--grain size and shape--laser applications--nanostructured materials--phonons--thermal conductivity of solids--transmission electron microscopy--diamond composites--laser flash technique--industrial diamonds--carbon--composite--diamond--thermal conductivity
Аннотация: The thermal conductivity, k, of diamond/carbon composites with different ratios of sp 2/sp 3-bonded carbon is measured by the laser flash technique. The thermal conductivity of nanocomposites containing 6 nm diamond particles falls within the range of k=0.003-0.017 W/cmK at room temperature. The thermal conductivity increases while nanopores are gradually filled with pyrolytic carbon (pyrocarbon/diamond mass ratio variation of 0.0-0.5). Transmission electron microscopy data reveal a fairly uniform mixture of two carbon phases, the diamond and matrix having similar grain sizes. Estimates show that the phonon free path is limited by dimensions of carbon matrix layer. Thermal data for coarse-grain (1-2 ?m) composites are also given for comparison. (C) 2000 Elsevier Science S.A. All rights reserved.
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