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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gladyshev M.I., Anishchenko O.V., Sushchnik N.N., Kalacheva G.S., Gribovskaya I.V., Ageev A.V.
Заглавие : Influence of anthropogenic pollution on content of essential polyunsaturated fatty acids in links of food chain of river ecosystem
Место публикации : Contemporary Problems of Ecology. - 2012. - Vol. 5, Is. 4. - С. 376-385. - ISSN 19954255 (ISSN) , DOI 10.1134/S1995425512040051
Ключевые слова (''Своб.индексиров.''): gammarus--grayling--heavy metals--polyunsaturated fatty acids--amphipod--anthropogenic effect--anthropogenic source--fatty acid--food chain--heavy metal--littoral environment--oil pollution--phenol--river system--salmonid--sampling--krasnoyarsk [russian federation]--russian federation--yenisei river--gammarus
Аннотация: In the course of monthly sampling in 2008-2010, two regions of the littoral of the Yenisei river were compared. One of these regions (conventionally pure) was situated upstream of Krasnoyarsk, while the other (conventionally polluted) was downstream of Krasnoyarsk. The concentrations of heavy metals, oil products, phenols, biogenic elements and essential polyunsaturated fatty acids (PUFAs) in various components of the river ecosystem were determined. It was discovered that the anthropogenic pollution causes a decrease in the resources of essential PUFA in the biomass of the upper links of the food chain of the river ecosystem. В© 2012 Pleiades Publishing, Ltd.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gladyshev M.I., Sushchik N.N., Kalachova G.S., Shchur L.A.
Заглавие : The effect of algal blooms on the disappearance of phenol in a small forest pond
Место публикации : Water Research. - 1998. - Vol. 32, Is. 9. - С. 2769-2775. - ISSN 00431354 (ISSN) , DOI 10.1016/S0043-1354(98)00009-8
Ключевые слова (''Своб.индексиров.''): algal blooms--phenol--seasonal dynamics of biodegradation--self-purification--algae--biodegradation--ecosystems--phenols--purification--reaction kinetics--reservoirs (water)--surface waters--experimental microecosystems--forest pond waters--green algae volvox aureus--inorganic nutrients--krasnoyarsk reservoir--water pollution--lake water--phenol--article--ecosystem--forest--green alga--priority journal--russian federation--water pollutant--water temperature
Аннотация: Using experimental microecosystems the kinetics of phenol disappearance in small forest pond waters (Siberia, Russia) in the summer of 1995-96 were investigated. Despite of high variability of components of the ecosystem (plankton biomass and species composition) and two pronounced 'blooms' of green algae Volvox aureus the same kinetics of the disappearance took place over the investigated period. Half-lives of the pollutant depended on water temperature only. A comparison of the self-purification of the pond with that of the Krasnoyarsk reservoir, 'blooming' with blue-greens was carried out. Half-lives in the pond were significantly lower than that in the reservoir. During the periods of 'blooms' of the green algae in the pond the concentrations of inorganic nutrients were comparatively high and the phenol-degrading bacteria likely were not limited by these nutrients, in contrast to the periods of 'bloom' of the blue-green algae in the reservoir.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stom D.I., Geel T.A., Balayan A.E., Shachova G.I., Kuznetsov A.M., Medvedeva S.E.
Заглавие : Bioluminescent method in studying the complex effect of sewage components
Место публикации : Archives of Environmental Contamination and Toxicology. - 1992. - Vol. 22, Is. 2. - С. 203-208. - ISSN 00904341 (ISSN)
Ключевые слова (''Своб.индексиров.''): heavy metal--phenol derivative--quinone derivative--article--bacterium--bioluminescence--cell membrane--nonhuman--priority journal--sludge--ultrastructure--benzoquinones--catechin--hydroquinones--luminescent measurements--metals--phenol--phenols--photobacterium--sewage--vibrio--water pollutants, chemical--bacteria (microorganisms)
Аннотация: The inhibition of bacterial luminescence has been used in testing industrial enterprises sewage. The toxicity of the sewage is less than the total toxicity of separate components due to neutralization of quinone products of polyphenol oxidation in the reactions with the other phenol components of sewage. Toxicity increase is due to their influence on the cell membrane. Studies of cell ultrastructure confirm this fact. The studied mechanism of the complex effect allowed a more accurate forecast of the ecological situation during the discharge of phenol compounds and metals. It also showed the necessity of taking into account the complex effect of sewage components on contaminant discharge into water reservoirs.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Semenov D.A., Sudachkova N.E., Khlebopros R.G.
Заглавие : A new scheme of lignin biosynthesis and the mechanism of its regulation of functional properties.
Место публикации : Doklady. Biochemistry and biophysics. - 2002. - Vol. 382. - С. 50-52. - ISSN 16076729 (ISSN)
Ключевые слова (''Своб.индексиров.''): lignin--peroxidase--phenol derivative--polymer--article--biosynthesis--cell wall--chemistry--metabolism--oxidation reduction reaction--physiology--plant--cell wall--lignin--oxidation-reduction--peroxidase--phenols--plants--polymers
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Voinova O..., Gladyshev M.I., Volova T.G.
Заглавие : Comparative study of PHA degradation in natural reservoirs having various types of ecosystems
Место публикации : Macromol. Symp.: WILEY-V C H VERLAG GMBH, 2008. - Vol. 269: 4th European Symposium on Biopolymers (OCT 02-04, 2007, Kusadasi, TURKEY). - С. 34-37. - 4. - ISSN 1022-1360, DOI 10.1002/masy.zoo850906
Примечания : Cited References: 15
Предметные рубрики: POLYHYDROXYALKANOATES
BIODEGRADATION
DISAPPEARANCE
POLYESTERS
PHENOL
Ключевые слова (''Своб.индексиров.''): biodegradable polyesters--ecosystem--natural environment--pha--water reservoir
Аннотация: The kinetics of polyhydroxyalkanoate (PHA) degradation in natural environment in two water reservoirs having various ecological characteristics was studied. It was shown that biodegradation of polymer essentially depends on the environment temperature and inorganic composition of water. The processes of polymer degradation under aerobic and anaerobic conditions were compared. The polymer degradation was slower under anaerobic conditions.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vysotski E.S., Liu Z.J., Markova S.V., Blinks J.R., Deng L..., Frank L.A., Herko M..., Malikova N.P., Rose J.P., Wang B.C., Lee J...
Заглавие : Violet bioluminescence and fast kinetics from W92F obelin: Structure-based proposals for the bioluminescence triggering and the identification of the emitting species
Колич.характеристики :12 с
Место публикации : Biochemistry: AMER CHEMICAL SOC, 2003. - Vol. 42, Is. 20. - С. 6013-6024. - ISSN 0006-2960, DOI 10.1021/bi027258h
Примечания : Cited References: 45
Предметные рубрики: RAY CRYSTALLOGRAPHIC ANALYSIS
PHOTOPROTEIN AEQUORIN
ANGSTROM RESOLUTION
RECOMBINANT OBELIN
CALCIUM
LUMINESCENCE
LONGISSIMA
EVOLUTION
PROTEINS
COELENTERAZINE
Аннотация: Obelin from the hydroid Obelia longissima and aequorin are members of a subfamily of Ca2+-regulated photoproteins that is a part of the larger EF-hand calcium binding protein family. On the addition of Ca2+, obelin generates a blue bioluminescence emission (lambda(max) = 485 nm) as the result of the oxidative decarboxylation of the bound substrate, coelenterazine. The W92F obelin mutant is noteworthy because of the unusually high speed with which it responds to sudden changes of [Ca2+] and because it emits violet light rather than blue due to a prominent band with lambda(max) = 405 nm. Increase of pH in the range from 5.5 to 8.5 and using D2O both diminish the contribution of the 405 nm band, indicating that excited state proton transfer is involved. Fluorescence model studies have suggested the origin of the 485 nm emission as the excited state of an anion of coelenteramide, the bioluminescence reaction product, and 405 nm from the excited neutral state. Assuming that the dimensions of the substrate binding cavity do not change during the excited state formation, a His22 residue within hydrogen bonding distance to the 6-(p-hydroxy)-phenyl group of the excited coelenteramide is a likely candidate for accepting the phenol proton to produce an ion-pair excited state, in support of recent suggestions for the bioluminescence emitting state. The proton transfer could be impeded by removal of the Trp92 H-bond, resulting in strong enhancement of a 405 nm band giving the violet color of bioluminescence. Comparative analysis of 3D structures of the wild-type (WT) and W92F obelins reveals that there are structural displacements of certain key Ca2+-ligating residues in the loops of the two C-terminal EF hands as well as clear differences in hydrogen bond networks in W92F. For instance, the hydrogen bond between the side-chain oxygen atom of Asp 169 and the main-chain nitrogen of Arg112 binds together the incoming alpha-helix of loop III and the exiting cc-helix of loop IV in WT, providing probably concerted changes in these EF hands on calcium binding. But this linkage is not found in W92F obelin. These differences apparently do not change the overall affinity to calcium of W92F obelin but may account for the kinetic differences between the WT and mutant obelins. From analysis of the hydrogen bond network in the coelenterazine binding cavity, it is proposed that the trigger for bioluminescence reaction in these Ca2+-regulated photoproteins may be a shift of the hydrogen bond donor-acceptor separations around the coelenterazine-2-hydroperoxy substrate, initiated by small spatial adjustment of the exiting a-helix of loop IV.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : GLADYSHEV M.I., GRIBOVSKAYA I.V., ADAMOVICH V.V.
Заглавие : DISAPPEARANCE OF PHENOL IN WATER SAMPLES TAKEN FROM THE YENISEI RIVER AND THE KRASNOYARSK RESERVOIR
Место публикации : Water Res.: PERGAMON-ELSEVIER SCIENCE LTD, 1993. - Vol. 27, Is. 6. - С. 1063-1070. - 8. - ISSN 0043-1354, DOI 10.1016/0043-1354(93)90071-O
Примечания : Cited References: 20
Предметные рубрики: ORGANIC-COMPOUNDS
LAKE WATER
MINERALIZATION
BIODEGRADATION
KINETICS
MODELS
Ключевые слова (''Своб.индексиров.''): biodegradation--phenol
Аннотация: Using experimental microecosystems the kinetics of phenol disappearance in river and reservoir water were investigated. In river water the disappearance kinetics could be described by A first-order equation, the same kinetics took place in reservoir water before and after the period of ''bloom'' of blue-green algae. During the ''bloom'', the phenol seemed to be mineralized by bacteria which grew at the expense of another compound, and the model of best fit was the model of exponential growth and low concentration of the test substrate. In the river, two sections differed according to the difference between the mean values of the specific disappearance rates. In the reservoir these rates were lower than those in the river. In general the specific disappearance rate values did not correlate with the values of initial bacterioplankton density, the concentrations of inorganic nutrients nor the chemical oxygen demand. Conclusions about the integral influence of ecosystems on the disappearance rates and dependence of self-purification kinetics on the type of aquatic ecosystem were made.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bondar V.S., Boersma M.G., van Berkel WJH, Finkelstein Z.I., Golovlev E.L., Baskunov B.P., Vervoort J..., Golovleva L.A., Rietjens IMCM
Заглавие : Preferential oxidative dehalogenation upon conversion of 2-halophenols by Rhodococcus opacus 1G
Колич.характеристики :10 с
Место публикации : FEMS Microbiol. Lett.: ELSEVIER SCIENCE BV, 1999. - Vol. 181, Is. 1. - С. 73-82. - ISSN 0378-1097, DOI 10.1111/j.1574-6968.1999.tb08828.x
Примечания : Cited References: 30
Предметные рубрики: PHENOL HYDROXYLASE
POLYCHLORINATED PHENOLS
MICROBIAL-DEGRADATION
TRICHOSPORON-CUTANEUM
METABOLISM
PURIFICATION
REGIOSELECTIVITY
CHLOROAROMATICS
COMPONENT
BENZOATE
Ключевые слова (''Своб.индексиров.''): phenol hydroxylase--oxidative dehalogenation--2-halophenol--f-19 nmr--rhodococcus opacus
Аннотация: The regiospecificity of hydroxylation of C2-halogenated phenols by Rhodococcus opacus 1G was investigated. Oxidative defluorination at the C2 position ortho with respect to the hydroxyl moiety was preferred over hydroxylation at the non fluorinated C6 position for all 2-fluorophenol compounds studied. Initial hydroxylation of 2,3,5-trichlorophenol resulted in the exclusive formation of 3,5-dichlorocatechol. These results indicate that, in contrast to all other phenol ortho-hydroxylases studied so far, phenol hydroxylase from R. opacus 1G is capable of catalyzing preferential oxidative defluorination but also oxidative dechlorination. (C) 1999 Federation of European Microbiological Societies. Published by Elsevier Science B.V. All rights reserved.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bondar V.S., Boersma M.G., Golovlev E.L., Vervoort J..., Van Berkel WJH, Finkelstein Z.I., Solyanikova I.P., Golovleva L.A., Rietjens IMCM
Заглавие : (19)F NMR study on the biodegradation of fluorophenols by various Rhodococcus species
Колич.характеристики :12 с
Место публикации : Biodegradation: SPRINGER, 1998. - Vol. 9: NMR in Environmental Sciences Symposium (OCT 24, 1997, EDE, NETHERLANDS), Is. 6. - С. 475-486. - ISSN 0923-9820, DOI 10.1023/A:1008391906885
Примечания : Cited References: 37
Предметные рубрики: NUCLEAR-MAGNETIC-RESONANCE
PSEUDOMONAS-PUTIDA MT-2
PHENOL HYDROXYLASE
BACTERIAL-DEGRADATION
3-OXOADIPATE PATHWAY
FLUOROBENZOIC ACID
CONVERSION
METABOLISM
CYCLOISOMERASES
2-CHLORO-CIS,CIS-MUCONATE
Ключевые слова (''Своб.индексиров.''): biodegradation--fluorophenols--(19)f nmr--oxidative defluorination--rhodococcus species
Аннотация: Of all NMR observable isotopes (19)F is the one perhaps most convenient for studies on biodegradation of environmental pollutants. The reasons underlying this potential of (19)F NMR are discussed and illustrated on the basis of a study on the biodegradation of fluorophenols by four Rhodococcus strains. The results indicate marked differences between the biodegradation pathways of fluorophenols among the various Rhodococcus species. This holds not only for the level and nature of the fluorinated biodegradation pathway intermediates that accumulate, but also for the regioselectivity of the initial hydroxylation step. Several of the Rhodococcus species contain a phenol hydroxylase that catalyses the oxidative defluorination of ortho-fluorinated di- and trifluorophenols. Furthermore, it is illustrated how the (19)F NMR technique can be used as a tool in the process of identification of an accumulated unknown metabolite, in this case most likely 5-fluoromaleylacetate. Altogether, the (19)F NMR technique proved valid to obtain detailed information on the microbial biodegradation pathways of fluorinated organics, but also to provide information on the specificity of enzymes generally considered unstable and, for this reason, not much studied so far.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gladyshev M.I., Sushchik N.N., Kalacheva G.S., Shchur L.A.
Заглавие : Composition of free fatty acids of the surface film of water and kinetic of self-purification from phenol in forest pond at ''bloom'' of Volvox aureus
Колич.характеристики :4 с
Место публикации : Dokl. Akad. Nauk: MEZHDUNARODNAYA KNIGA, 1996. - Vol. 349, Is. 6. - С. 840-843. - ISSN 0869-5652
Примечания : Cited References: 5
Предметные рубрики: KRASNOYARSK RESERVOIR
MODELS
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gealageas R..., Malikova N.P., Picaud S..., Borgdorff A.J., Burakova L.P., Brulet P..., Vysotski E.S., Dodd R.H.
Заглавие : Bioluminescent properties of obelin and aequorin with novel coelenterazine analogues
Колич.характеристики :13 с
Коллективы : ICSN; CNRS Physics, Chemistry and Biology interface grant; RFBR [12-04-00131]; Government of Russian Federation [11.G34.31.0058]; ANR
Место публикации : Anal. Bioanal. Chem.: SPRINGER HEIDELBERG, 2014. - Vol. 406, Is. 11. - С. 2695-2707. - ISSN 1618-2642, DOI 10.1007/s00216-014-7656-4. - ISSN 1618-2650
Примечания : Cited References: 57. - R.G. acknowledges the ICSN for a fellowship. We are grateful for the ANR grant to P.B. and a CNRS Physics, Chemistry and Biology interface grant to R.H.D. and P.B.; N.P.M, L.P.B., and E.S.V. acknowledge the RFBR grant 12-04-00131 and the Program of the Government of Russian Federation "Measures to attract leading scientists to Russian educational institutions" (grant 11.G34.31.0058). P.B. and A.J.B. are indebted to Eric Karplus from Science Wares Inc. for helping with single-photon imaging software.
Предметные рубрики: PHOTOPROTEIN OBELIN
CRYSTAL-STRUCTURE
CA2+-REGULATED PHOTOPROTEINS
CA2+-ACTIVATED PHOTOPROTEIN
SEMISYNTHETIC AEQUORINS
ANGSTROM RESOLUTION
RECOMBINANT OBELIN
BINDING PROTEIN
CALCIUM-BINDING
CA2+ DYNAMICS
Ключевые слова (''Своб.индексиров.''): bioluminescence--luciferase--photoprotein--coelenterazine
Аннотация: The main analytical use of Ca2+-regulated photoproteins from luminous coelenterates is for real-time non-invasive visualization of intracellular calcium concentration ([Ca2+](i)) dynamics in cells and whole organisms. A limitation of this approach for in vivo deep tissue imaging is the fact that blue light emitted by the photoprotein is highly absorbed by tissue. Seven novel coelenterazine analogues were synthesized and their effects on the bioluminescent properties of recombinant obelin from Obelia longissima and aequorin from Aequorea victoria were evaluated. Only analogues having electron-donating groups (m-OCH3 and m-OH) on the C6 phenol moiety or an extended resonance system at the C8 position (1-naphthyl and alpha-styryl analogues) showed a significant red shift of light emission. Of these, only the alpha-styryl analogue displayed a sufficiently high light intensity to allow eventual tissue penetration. The possible suitability of this compound for in vivo assays was corroborated by studies with aequorin which allowed the monitoring of [Ca2+](i) dynamics in cultured CHO cells and in hippocampal brain slices. Thus, the alpha-styryl coelenterazine analogue might be potentially useful for non-invasive, in vivo bioluminescence imaging in deep tissues of small animals.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Manukovski N.S., Teremova M.I., Gurevich Y.L., Pan'Kova I.M.
Заглавие : Phenol and Naphthalene degradation by mixed culture of microorganisms
Место публикации : Studies in Environmental Science. - 1991. - Vol. 42, Is. C. - P155-163. - ISSN 01661116 (ISSN) , DOI 10.1016/S0166-1116(08)70323-6
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : GLADYSHEV M.I., GRIBOVSKAIA I.V., SHCHUR L.A.
Заглавие : SEASONAL DYNAMICS OF THE KINETICS OF NATURAL PHENOL DECONTAMINATION IN THE SYDIN BAY OF THE KRASNOYARSK WATER RESERVOIR
Колич.характеристики :3 с
Место публикации : DOKLADY AKADEMII NAUK SSSR: MEZHDUNARODNAYA KNIGA, 1990. - Vol. 313, Is. 6. - P1512-1514. - ISSN 0002-3264
Примечания : Cited References: 4
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14.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : GLADYSHEV M.I., GRIBOVSKAYA I.V.
Заглавие : PHENOL BIODEGRADATION IN THE YENISEI RIVER AND THE KRASNOYARSK RESERVOIR, RUSSIA
Колич.характеристики :5 с
Место публикации : HYDROLOGICAL, CHEMICAL AND BIOLOGICAL PROCESSES OF TRANSFORMATION AND TRANSPORT OF CONTAMINANTS IN AQUATIC ENVIRONMENTS. Ser. IAHS PUBLICATIONS: INT ASSOC HYDROLOGICAL SCIENCES, 1994. - Hydrochemistry 1993 Symposium on Hydrological, Chemical and Biological Processes of Transformation and Transport of Contaminants in Aquatic Environments (MAY 24-28, 1993, ROSTOV NA DONU, RUSSIA), Is. 219. - P217-221. - ISBN 0144-7815. - ISBN 0-947571-88-4
Примечания : Cited References: 0
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gurevich Y.L., Teremova M.I., Latyntseva A.V.
Заглавие : Flocculation of bacterial cells in a culture with protozoans
Колич.характеристики :5 с
Место публикации : Izv. Akad. Nauk Ser. Biol.: MEZHDUNARODNAYA KNIGA, 1998. - Is. 3. - P351-355. - ISSN 0002-3329
Примечания : Cited References: 13
Аннотация: The initial phase of formation of the biogenic suspension was studied in experimental communities of bacteria and protozoans that simulate degradation of the phenol technogenic flows. Protozoans were shown to initiate formation of bacterial aggregates and increase the size of bacterial flocules several hundred times. Factors were found by the methods of mathematical planning, which markedly affect the size and amount of flocules. Unlike natural water bodies, in the sample communites, the presence of abiogenic substrate was not essential for aggregation of the bacteria, The aggregated bacterial cells make an important contribution to degradation of organic compounds.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ronzhin N. O., Puzyr A. P., Bondar V. S.
Заглавие : On the applicability of nanodiamonds produced by detonation synthesis for phenol testing in aqueous media
Место публикации : Dokl. Chem.: Maik Nauka Publishing / Springer SBM, 2017. - Vol. 475, Is. 1. - С. 155-158. - ISSN 00125008 (ISSN) , DOI 10.1134/S0012500817070011
Аннотация: It was found that the catalytic effect of modified nanodiamonds (MND) in the H2O2–4-aminoantipyrine–phenol oxidative azo coupling reaction is due to microimpurities of iron and copper ions on the surface of nanoparticles. The efficiency of MND as a catalyst is determined by the amount of surface impurities of these ions and can be doubled by their additional adsorption on nanoparticles. Using MND for phenol indication ensures a linear yield of the colored product of the azo coupling reaction over an analyte concentration range of 0.05–10 ?g/mL. The possibility of reusing MND for phenol testing in aqueous samples was demonstrated. © 2017, Pleiades Publishing, Ltd.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ronzhin, Nikita, Puzyr, Alexey, Bondar, Vladimir
Заглавие : Detonation Nanodiamonds as a New Tool for Phenol Detection in Aqueous Medium
Колич.характеристики :6 с
Коллективы : Russian Academy of Sciences [0356-2016-0709]; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology [16-43-243027]
Место публикации : J. Nanosci. Nanotechnol.: AMER SCIENTIFIC PUBLISHERS, 2018. - Vol. 18, Is. 8. - С. 5448-5453. - ISSN 1533-4880, DOI 10.1166/jnn.2018.15382. - ISSN 1533-4899(eISSN)
Примечания : Cited References:27. - This work was supported by the state budget allocated to the fundamental research at the Russian Academy of Sciences (Project No. 0356-2016-0709) and Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research (Project No. 16-43-243027).
Предметные рубрики: ENVIRONMENTAL-POLLUTANTS
DRUG-DELIVERY
PARTICLES
CARBON
Ключевые слова (''Своб.индексиров.''): detonation nanodiamonds--catalytic activity--metal ions--azo coupling--reaction--phenol detection
Аннотация: This paper demonstrates the effectiveness of using detonation nanodiamonds (DNDs) for detecting phenol in aqueous medium. The study has shown that the catalytic effect of DNDs in the oxidative azo coupling reaction (phenol-4-aminoantipyrine-hydrogen peroxide) is produced by trace amounts of iron and copper ions adsorbed on the surface of nanoparticles. The effectiveness of DNDs as a catalyst is determined by the amounts of these adsorbates and can be enhanced by a factor of two by additional adsorption of these ions onto the nanoparticles. A rise in the temperature of the ONO-catalyzed azo coupling reaction leads to a considerable (4.5-fold) increase in the reaction product yield. DNDs used to detect phenol in aqueous medium enable a linear increase in the yield of the product of the azo coupling reaction at concentrations of the analyte of between 0.05 and 10 mu g/mlThe study demonstrates that DNDs can be reused to detect phenol in water samples.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mogilnaya O. A., Ronzhin N. O., Artemenko K. S., Bondar V. S.
Заглавие : Creation of Bifunctional Indicating Complex Based on Nanodiamonds and Extracellular Oxidases of Luminous Fungus Neonothopanus nambi
Колич.характеристики :4 с
Место публикации : Dokl. Biochem. Biophys.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2018. - Vol. 480, Is. 1. - С. 135-138. - ISSN 1607-6729, DOI 10.1134/S160767291803002X. - ISSN 1608-3091(eISSN)
Примечания : Cited References:13
Предметные рубрики: PHANEROCHAETE-CHRYSOSPORIUM
NANOPARTICLES
Аннотация: A bifunctional indicating complex was created by immobilization of extracellular oxidases (glucose oxidase and peroxidases) of luminous fungus Neonothopanus nambi onto modified nanodiamonds (MNDs) synthesized by detonation. It was found that the enzymes firmly adsorb onto MND particles and exhibit their catalytic activity. Model in vitro experiments showed that the created MND-enzymes complex is suitable for repeated use for analyte (glucose and phenol) testing and retains its activity after storage at 4 degrees C in deionized water for 1 month. The data obtained offer the prospects for developing a new class of reusable multifunctional indicating and diagnostic test systems on the basis of MNDs and higher fungal enzymes for medical and ecological analytics.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mogilnaya, Olga, Ronzhin, Nikita, Artemenko, Karina, Bondar, Vladimir
Заглавие : Nanodiamonds as an effective adsorbent for immobilization of extracellular peroxidases from luminous fungus Neonothopanus nambi to construct a phenol detection system
Колич.характеристики :9 с
Коллективы : Russian Academy of Sciences [0356-2016-0709]
Место публикации : Biocatal. Biotransform.: TAYLOR & FRANCIS LTD, 2019. - Vol. 37, Is. 2. - С. 97-105. - ISSN 1024-2422, DOI 10.1080/10242422.2018.1472586. - ISSN 1029-2446(eISSN)
Примечания : Cited References:50. - This work was supported by the state budget allocated to the fundamental research at the Russian Academy of Sciences [project no. 0356-2016-0709].
Предметные рубрики: CARBON NANOTUBES
ARMILLARIA-BOREALIS
LIGHT-EMISSION
DEGRADATION
Ключевые слова (''Своб.индексиров.''): nanodiamonds--immobilization--luminous fungus--beta-glucosidase--peroxidase--indicator system
Аннотация: Modified nanodiamonds (MNDs) produced by detonation synthesis can be used as an effective adsorbent to immobilize extracellular peroxidases of the luminous basidiomycete Neonothopanus nambi. The enzymes are firmly immobilized on MND particles and exhibit catalytic activity. The indicator system (the MND-enzyme complex) reused many times retains its ability to catalyze reaction of co-oxidation of phenol and 4-aminoantipirine in the presence of hydrogen peroxide and remains functionally active during long-term storage (for 1 month or longer) in aqueous suspensions at 4 degrees C. MNDs and enzymes of higher fungi can be effectively used to construct new reusable indicator systems for analytical applications such as monitoring contamination of aquatic environments by phenolic compounds.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ronzhin N. O., Posokhina E. D., Mikhlina E. V., Simunin M. M., Nemtsev I. V., Ryzhkov I. I., Bondar V. S.
Заглавие : Production of a Composite Based on Alumina Nanofibers and Detonation Nanodiamonds for Creating Phenol Indication Systems
Место публикации : Dokl. Chem.: Pleiades Publishing, 2019. - Vol. 489, Is. 1. - С. 267-271. - ISSN 00125008 (ISSN), DOI 10.1134/S001250081911003X
Аннотация: Abstract: A composite of alumina nanofibers (ANF) and modified detonation nanodiamonds (MDND) was produced by mixing aqueous suspensions of the components in a weight ratio of 5 : 1 with subsequent incubation of the mixture for 15 min at 32°C. It was assumed that the formation of the composite is ensured by the difference of the zeta potentials of the components, which is negative for MDND and positive for ANF. Vacuum filtration of the mixture through a fluoroplastic filter (pore diameter 0.6 ?m) formed disks 40 mm in diameter, which were then heat-treated at 300°C to impart structural stability to the composite. Scanning electron microscopy detected that the obtained composite has a network structure, in which MDND particles are distributed over the surface of ANF. It was determined that the MDND particles incorporated in the composite catalyze the phenol–4-aminoantipyrine–H2O2 oxidative azo coupling reaction to form a colored product (quinoneimine). The applicability of the composite to repeated phenol detection in aqueous samples was demonstrated. © 2019, Pleiades Publishing, Ltd.
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