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Каталог книг и продолжающихся изданий библиотеки Института биофизики СО РАН
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1.


   
    Photosynthetic apparatus of cucumber and pea plants grown under red light with discrete or continuous spectra / E. N. Zavorueva [et al.] // Russian Journal of Plant Physiology. - 1996. - Vol. 43, Is. 2. - P191-199 . - ISSN 1021-4437
Кл.слова (ненормированные):
And thermoinduced changes in fluorescence yield -- Cucumis sativum -- Photo -- Photophosphorylation -- Pigments -- Pisum sativum
Аннотация: The effect of light sources with discrete or continuous spectra of red light (50 W/m2, 600-700 nm) on the structural and functional characteristics of chloroplasts were studied in leaves of cucumber (Cucumis sativum L.) plants, which die under strong red light, and pea (Pisum sativum L.) plants, which tolerate red light under the same conditions. Leaf condition was assessed by measuring thermo-and photoinduced changes in the chlorophyll fluorescence yield and the photochemical and photophosphorylating activities of the chloroplasts. Different responses of the pigment apparatus of pea and cucumber plants to red light with continuous or line spectra were revealed. Pea plants responded to discrete-spectrum light by changing P700 content, the ratio of antenna chlorophyll to P700, and the position of the low-temperature peak of the temperature-induced chlorophyll fluorescence yield. In cucumber plants, disturbances in the energy transfer from the short-wavelength pigments to chlorophyll a were observed. In both plants, the effects of line spectrum light on the pigment apparatus were reversible; the ratio of cyclic to noncyclic photophosphorylation, photosynthetic control, and the extent of the coupling of photosynthetic electron transport to photophosphorylation did not change compared to the control light. The need for examining the line spectra of light sources for growing plants under moderate intensities of artificial light (about 50 W/m2 of photosynthetically active radiation) is discussed.

Scopus
Держатели документа:
Institute of Biophysics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation : 660036, Красноярск, Академгородок, д. 50, стр. 50

Доп.точки доступа:
Zavorueva, E.N.; Nesterenko, T.V.; Volkova, E.K.; Tikhomirov, A.A.

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2.


   
    Bioluminescence of bacteria: a rhythmic process / L. Y. Berzhanzkaya, I. I. Gitel'zon, A. M. Fish // BIOPHYSICS. - 1973. - Vol. 18, Is. 2. - P293-301 . - ISSN 0006-3509
Кл.слова (ненормированные):
bacterium -- computer -- in vitro study -- methodology -- microorganism -- theoretical study
Аннотация: New results obtained in the detection of rhythms in the low frequency range in the light signal of a small number of photo bacteria are reported. The luminescence of a small number of bacteria was recorded with an apparatus the sensitivity of which was 12 quanta/pulse. To check the possible rhythms in the luminescence of the bacteria, correlation analysis was made of the interpulse intervals of the detection of the signal with a computer. This revealed a definite rhythm in the bacterial luminescence the fundamental frequency of which lies in the region 8 c/s. Profound modulation of a bioluminescent signal at this and multiple frequencies was demonstrated. The harmonic components found in the spectrum of the signal refute the existing view of the continuous character of bacterial luminescence.

Scopus
Держатели документа:
Kirenskii Inst. Phys., USSR Acad. Sci., Siberian Div., Krasnoyarsk, Russia : 660036, Красноярск, Академгородок, д. 50, стр. 50

Доп.точки доступа:
Berzhanzkaya, L.Y.; Gitel'zon, I.I.; Fish, A.M.

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3.


   
    Structure of the Ca2+-regulated photoprotein obelin at 1.7 angstrom resolution determined directly from its sulfur substructure [Text] / Z. J. Liu [et al.] // Protein Sci. - 2000. - Vol. 9, Is. 11. - P2085-2093. - Cited References: 41 . - ISSN 0961-8368
РУБ Biochemistry & Molecular Biology
Рубрики:
CALCIUM-MODULATED PROTEINS
   AMINO-ACID SEQUENCE
   CA-2+-BINDING PHOTOPROTEIN
   CA2+-BINDING PHOTOPROTEIN
   MACROMOLECULAR STRUCTURES
   3-DIMENSIONAL STRUCTURE
   ANOMALOUS SCATTERING
   CRYSTAL-STRUCTURES
   DIFFRACTION DATA
   BINDING SITE
Кл.слова (ненормированные):
bioluminescence -- crystallography -- obelin -- photoprotein -- single wavelength anomalous scattering -- solvent flattening -- sulfur phasing
Аннотация: The crystal structure of the photoprotein obelin (22.2 kDa) from Obelia longissima has been determined and refined to 1.7 Angstrom resolution. Contrary to the prediction of a peroxide, the noncovalently bound substrate, coelenterazine, has only a single oxygen atom bound at the C2-position. The protein-coelenterazine 2-oxy complex observed in the crystals is photo-active because, in the presence of calcium ion, bioluminescence emission within the crystal is observed. This structure represents only the second de novo protein structure determined using the anomalous scattering signal of the sulfur substructure in the crystal. The method used here is theoretically different from that used for crambin in 1981 (4.72 kDa) and represents a significant advancement in protein crystal structure determination.

Держатели документа:
Univ Georgia, Dept Biochem & Mol Biol, Athens, GA 30602 USA
Russian Acad Sci, Inst Biophys, Krasnoyarsk 660036, Russia
ИБФ СО РАН : 660036, Красноярск, Академгородок, д. 50, стр. 50

Доп.точки доступа:
Liu, Z.J.; Vysotski, E.S.; Chen, C.J.; Rose, J.P.; Lee, J...; Wang, B.C.

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4.


   
    LIGHT SCATTERING BY ENSEMBLE OF NONSPHERICAL PARTICLES INTO SOLID ANGLES [Text] / L. E. PARAMONOV ; ed. Optic // PASSIVE INFRARED REMOTE SENSING OF CLOUDS AND THE ATMOSPHERE II. Ser. PROCEEDINGS OF THE SOCIETY OF PHOTO-OPTICAL INSTRUMENTATION ENGINEERS (SPIE) : SPIE - INT SOC OPTICAL ENGINEERING, 1994. - Vol. 2309: Conference on Passive Infrared Remote Sensing of Clouds and the Atmosphere II (SEP 26-28, 1994, ROME, ITALY). - P. 349-357. - Cited References: 0 . - ISBN 0-8194-1639-8
РУБ Remote Sensing


WOS
Держатели документа:
RUSSIAN ACAD SCI,SIBERIAN BRNACH,INST BIOPHYS,KRASNOYARSK 660036,RUSSIA
ИБФ СО РАН : 660036, Красноярск, Академгородок, д. 50, стр. 50
Доп.точки доступа:
PARAMONOV, L.E.; Optic \ed.\

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5.


   
    ON OPTICAL EQUIVALENCE OF THE RANDOMLY ORIENTED ELLIPSOIDAL AND POLYDISPERSE SPHERICAL PARTICLES - EXTINCTION, SCATTERING AND ABSORPTION CROSS SECTIONS [Text] / L. E. PARAMONOV ; ed. Optic // PASSIVE INFRARED REMOTE SENSING OF CLOUDS AND THE ATMOSPHERE II. Ser. PROCEEDINGS OF THE SOCIETY OF PHOTO-OPTICAL INSTRUMENTATION ENGINEERS (SPIE) : SPIE - INT SOC OPTICAL ENGINEERING, 1994. - Vol. 2309: Conference on Passive Infrared Remote Sensing of Clouds and the Atmosphere II (SEP 26-28, 1994, ROME, ITALY). - P. 358-360. - Cited References: 0 . - ISBN 0-8194-1639-8
РУБ Remote Sensing


WOS
Держатели документа:
RUSSIAN ACAD SCI,SIBERIAN BRANCH,INST BIOPHYS,KRASNOYARSK 660036,RUSSIA
ИБФ СО РАН : 660036, Красноярск, Академгородок, д. 50, стр. 50
Доп.точки доступа:
PARAMONOV, L.E.; Optic \ed.\

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6.


   
    Adaptive simulation of atmospheric phenomena [Text] / J. P. Lankin ; ed. GA Zherebtsov [et al.] // EIGHTH INTERNATIONAL SYMPOSIUM ON ATMOSPHERIC AND OCEAN OPTICS: ATMOSPHERIC PHYSICS. Ser. PROCEEDINGS OF THE SOCIETY OF PHOTO-OPTICAL INSTRUMENTATION ENGINEERS (SPIE) : SPIE-INT SOC OPTICAL ENGINEERING, 2002. - Vol. 4678: 8th International Symposium on Atmospheric and Ocean Optics - Atmospheric Physics (JUN 25-29, 2001, IRKUTSK, RUSSIA). - P. 668-679, DOI 10.1117/12.458507. - Cited References: 46 . - ISBN 0277-786X. - ISBN 0-8194-4433-2
РУБ Meteorology & Atmospheric Sciences + Optics + Spectroscopy

Кл.слова (ненормированные):
atmosphere -- system -- adaptation -- self-adaptation -- neuroinformatics
Аннотация: The paper describes scientific methodology of developing complex nonlinear dynamic models which form the basis of a new scientific trend called Stikhioniks(1) and are a efficient tool to devise atmosphere models. The model is aimed to develop complexly organized hierarchical non-equilibrium adaptive systems with a wide range of connections and elements and is a new step as related to the now dominant mechanical-statistical paradigm.

WOS
Держатели документа:
Russian Acad Sci, Siberian Branch, Inst Biophys, Krasnoyarsk 660036, Russia
ИБФ СО РАН : 660036, Красноярск, Академгородок, д. 50, стр. 50

Доп.точки доступа:
Lankin, J.P.; Zherebtsov, GA \ed.\; Matvienko, GG \ed.\; Banakh, VA \ed.\; Banakh, \ed.\

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7.


   
    Algorithms of self-adaptation for atmospheric model designing [Text] / J. P. Lankin, T. F. Baskanova ; ed.: GG Matvienko, o, GG Matvie // TENTH JOINT INTERNATIONAL SYMPOSIUM ON ATMOSPHERIC AND OCEAN OPTICS/ATMOSPHERIC PHYSICS, PT 2: LASER SENSING AND ATMOSPHERIC PHYSICS. Ser. PROCEEDINGS OF THE SOCIETY OF PHOTO-OPTICAL INSTRUMENTATION ENGINEERS (SPIE) : SPIE-INT SOC OPTICAL ENGINEERING, 2004. - Vol. 5397: 10th Joint International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics (JUN 24-28, 2003, Tomsk, RUSSIA). - P. 260-270, DOI 10.1117/12.548609. - Cited References: 23 . - ISBN 0277-786X. - ISBN 0-8194-5316-1
РУБ Environmental Sciences + Meteorology & Atmospheric Sciences + Optics

Аннотация: The paper describes the principal limitations of the traditional methods used to construct atmospheric models. These limitations would not allow any fundamental improvement of atmospheric modeling. Ways are proposed to overcome the current limitations, based oil the methodology of constructing adaptive models and neuroinformatics. Algorithms of self-adaptation for neural networks intended for the construction of atmospheric models are given. Essentially, the developed algorithms are adaptive shells and can be easily transferred to other models.

WOS
Держатели документа:
RAS, SB, Inst Biophys, Krasnoyarsk 660036, Russia
ИБФ СО РАН : 660036, Красноярск, Академгородок, д. 50, стр. 50

Доп.точки доступа:
Lankin, J.P.; Baskanova, T.F.; Matvienko, GG \ed.\; Matvie, o, GG \ed.\

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8.


   
    Pre-biotic stage of life origin under non-photo synthetic conditions [Text] / S. I. Bartsev, V. V. Mezhevikin ; ed. SI Bartse // SPACE LIFE SCIENCES: CLOSED ECOLOGICAL SYSTEMS: EARTH AND SPACE APPLICATIONS. Ser. ADVANCES IN SPACE RESEARCH : PERGAMON-ELSEVIER SCIENCE LTD, 2005. - Vol. 35: Workshop on Closed Ecological Systems (JUL, 2004, Paris, FRANCE), Is. 9. - P. 1643-1647, DOI 10.1016/j.asr.2005.04.072. - Cited References: 14 . - ISBN 0273-1177
РУБ Engineering, Aerospace + Astronomy & Astrophysics + Ecology + Geosciences, Multidisciplinary + Meteorology & Atmospheric Sciences

Кл.слова (ненормированные):
life origin -- pre-biotic autocatalytic system -- phase-separated autocatalytic particles -- multivariate oligomeric autocatalyst
Аннотация: Spontaneous assembling of a simplest bacterial cell even if all necessary molecules are present in a solution seems to be extremely rare event and from the scientific standpoint has to be considered as impossible. Therefore, a predecessor of a living cell has to be very simple for providing its self-assembling and at the same time it should be able of progressive increase in complexity. Now phase-separated particles, first of all micelles, are put forward as possible predecessors of living cell. According to the offered working concept only phase-separated particles possessing autocatalytic properties can be considered as predecessors of living cells. The first stage of evolution of these phase-separated autocatalytic systems is the appearance of pre-biotic metabolism providing synthesis of amphiphiles for formation of capsules of these systems. This synthesis is maintained by the energy of a base reaction being a component of a planet-chemical cycle. Catalytic system providing functioning of pre-biotic metabolism is based on multivariate oligomeric autocatalyst, which reproduces itself from monomers, penetrating the particles from the outside. Since the autocatalyst realizes random polymerization then a collection of other oligomers possessing different catalytic functions is produced. In the paper the functioning of multivariate oligomeric autocatalyst in flow reactor is analyzed. (c) 2005 Published by Elsevier Ltd on behalf of COSPAR.

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Держатели документа:
Russian Acad Sci, Siberian Branch, Inst Biophys, Lab Theoret Biophys, Krasnoyarsk 660036, Russia
ИБФ СО РАН : 660036, Красноярск, Академгородок, д. 50, стр. 50

Доп.точки доступа:
Bartsev, S.I.; Mezhevikin, V.V.; Bartse, SI \ed.\

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9.


   
    Evolution and present status of experimental manned ecological systems for long-term human life support - Bios, developed by the institute of biophysics of Russian academy of sciences in Krasnoyarsk (Siberia) / J. I. Gitelson, A. G. Degermendzhy // Proceedings of the International Astronautical Congress, IAC : International Astronautical Federation, IAF, 2015. - Vol. 1: 66th International Astronautical Congress 2015: Space - The Gateway for Mankind's Future, IAC 2015 (12 October 2015 through 16 October 2015, ) Conference code: 122921. - P243-250
Кл.слова (ненормированные):
Arid regions -- Biochemistry -- Biospherics -- Plant shutdowns -- Proteins -- Reconfigurable hardware -- Closed ecological systems -- Corrective actions -- Essential proteins -- Extreme conditions -- Human intelligence -- Long-term experiments -- Physiological effects -- Russian Academy of Sciences -- Ecology
Аннотация: Closed ecological systems are of two-fold interest - as models of the Earth's biosphere explorable in experiments and as a facility for long-term autonomous human life support beyond the Earth. Theoretical analysis and experimental implementation of highly closed manned systems has been the subject of studies at the Institute of Biophysics (Russian Academy of Sciences, Siberian Branch) for many years. BIOS systems of increasing complexity with complete regeneration of atmosphere, water and partially food have been realized. In BIOS-3 experiments the system inhabited by 2-3 researchers for 4-6 months maintained its metabolic equilibrium without any negative physiological effect on the crew, which proves its sustainable condition. Specific for BIOS-3 is internal control by the people inhabiting the system. So, BIOS-3 is the first experimental implementation of V.l. Vernadsky's idea about the noosphere - habitable Biosphere controlled by human intelligence. Contrary to predictions of many environmentalists the closedness of the ecosystem is a factor that does not reduce, but increases its sustainability and makes its use for reliable life support outside the Earth realistic. The system is sustainable owing to permanent feedback between the monitoring of few key parameters of the system and automatic corrective actions on them. Main object of control is photo-biosynthesis regenerating parameters of human habitat disturbed by his vital activities. This principle has been realized in BIOS system and proved its reliability in long-term experiments. A new challenge is specified-optimal increase of trophic closedness of the system by reproduction within it essential proteins (peptides and amino acids), lipids, vitamins and other essential compounds. Alternative lines of attack on this problem by state-of-the-art biotechnological methods, GMO including, are under analysis. Reduced BIOS version - without complete closure - can be a breakthrough instrument to improve the quality of life of people living under extreme conditions on the Earth - in polar latitudes (Arctic, Antarctic), in deserts, in high mountains.

Scopus
Держатели документа:
Institute of Biophysics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Gitelson, J. I.; Degermendzhy, A. G.

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10.


   
    Optical limiting in suspension of detonation nanodiamonds in engine oil / K. G. Mikheev [et al.] // J. Nanophoton. - 2017. - Vol. 11, Is. 3. - P113258162, DOI 10.1117/1.JNP.11.032502 . - ISSN 1934-2608
Кл.слова (ненормированные):
Ambient temperature -- Detonation nanodiamonds -- Engine oil -- Optical limiting -- Optical limiting threshold -- Suspension -- Cluster analysis -- Detonation -- Engines -- Laser excitation -- Lubricating oils -- Nanoparticles -- Q switching -- Suspensions (fluids) -- Temperature -- Detonation nanodiamond -- Detonation nanodiamonds -- Engine oil -- Incident radiation -- Nanoparticle clusters -- Optical limiting -- Passive Q-switching -- Wide temperature ranges -- Nanodiamonds
Аннотация: The optical limiting (OL) of detonation nanodiamond (DND) suspensions in engine oil was studied at a temperature range of 20°C to 100°C. Oil suspensions were prepared on the basis of the DNDs with an average nanoparticle cluster size in hydrosols (Daver) of 50 and 110 nm. Raman spectroscopy was used to characterize the samples. The OL investigation was carried out by the z-scan technique. The fundamental (1064 nm) and second (532 nm) harmonic radiations of YAG:Nd3 laser with passive Q-switching as an excitation source were used. The OL thresholds for both suspensions at 532 and 1064 nm were determined. It is shown that a decrease in the average nanoparticle cluster size as well as an increase of the wavelength of the incident radiation leads to the OL threshold increase. It is established that the OL performance is not influenced by increasing the temperature from 20°C to 100°C. The results obtained show the possibility of using the DNDs suspensions in engine oil as an optical limiter in a wide temperature range. © 2017 Society of Photo-Optical Instrumentation Engineers (SPIE).

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Держатели документа:
Institute of Mechanics Ural Branch RAS, 34, T. Baramzinoy Street, Izhevsk, Russian Federation
Institute of Biophysics Siberian Branch of RAS, 50/50, Akademgorodok, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Mikheev, K. G.; Krivenkov, R. Yu.; Mogileva, T. N.; Puzyr, A. P.; Bondar, V. S.; Bulatov, D. L.; Mikheev, G. M.

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11.


   
    Saturable absorption in detonation nanodiamond dispersions / V. Vanyukov [et al.] // J. Nanophoton. - 2017. - Vol. 11, Is. 3, DOI 10.1117/1.JNP.11.032506 . - ISSN 1934-2608
Кл.слова (ненормированные):
Modelocking -- Nanodiamonds -- Nanomaterials -- Nonlinear optics -- Saturable absorption -- Carbon -- Chains -- Dispersion (waves) -- Electromagnetic wave absorption -- Laser excitation -- Laser pulses -- Light -- Light absorption -- Locks (fasteners) -- Nanostructured materials -- Nonlinear optics -- Ultrafast lasers -- Ultrashort pulses -- Yarn -- Aqueous dispersions -- Detonation nanodiamond -- Light-induced -- Modelocking -- Nano-diamond particles -- Non-linear parameters -- Saturable absorption -- Z-scan experiment -- Nanodiamonds
Аннотация: We report on a saturable absorption in aqueous dispersions of nanodiamonds with femtosecond laser pulse excitation at a wavelength of 795 nm. The open aperture Z-scan experiments reveal that in a wide range of nanodiamond particle sizes and concentrations, a lightinduced increase of transmittance occurs. The transmittance increase originates from the saturation of light absorption and is associated with a light absorption at 1.5 eV by graphite and dimer chains (Pandey dimer chains). The obtained key nonlinear parameters of nanodiamond dispersions are compared with those of graphene and carbon nanotubes, which are widely used for the mode-locking. © 2017 Society of Photo-Optical Instrumentation Engineers (SPIE).

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Держатели документа:
Institute of Photonics, University of Eastern Finland, Joensuu, Finland
Hypermemo Ltd., Joensuu, Finland
Institute of Mechanics, Russian Academy of Sciences, Izhevsk, Russian Federation
Federal research center Krasnoyarsk science Center SB RAS, Siberian Branch of RAS, Institute of Biophysics, Krasnoyarsk, Russian Federation
Texas State University, San Marcos, TX, United States
CIC nanoGUNE Consolider, Donostia-San Sebastian, Spain
G Basque Foundation for Science, Ikerbasque, Bilbao, Spain

Доп.точки доступа:
Vanyukov, V.; Mikheev, G.; Mogileva, T.; Puzyr, A.; Bondar, V.; Lyashenko, D.; Chuvilin, A.

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12.


   
    The fluorescence method for determining of photosynthetic apparatus reactivity in plant leaves / T. V. Nesterenko, V. N. Shikhov, A. A. Tikhomirov // Zhurnal Obshchei Biol. - 2019. - Vol. 80, Is. 3. - С. 187-199, DOI 10.1134/S0044459619030060. - Cited References:31 . - ISSN 0044-4596
РУБ Biology
Рубрики:
ELECTRIC-POTENTIAL DIFFERENCE
   FREQUENTLY ASKED QUESTIONS
   CHLOROPHYLL
Аннотация: Presently, the most promising way of studying, forecasting, and enhancing of organisms' tolerance to harsh environmental impacts is considered to be the estimation of initial functional state of an organism's regulatory systems. To resolve the problem of photosynthetic apparatus (PSA) tolerance to harsh impacts at the level of such a complicated functional system as a plant leaf, it is necessary to assess integral responses of the leaf's PSA to the impact. At that, simple and versatile traits may have certain advantages. At present, chlorophyll fluorescence seems to be one of the main indices of PSA activity, which can be measured relatively fast and easy. One of the possible approaches to operational integrative assessment of PSA activity may consist in usage of the parameters introduced for the curves of chlorophyll fluorescence induction (CFI) slow phase. Temporal patterns of CFI are of special interest. The simplest index T-0.5 (i.e., half-time of chlorophyll fluorescence intensity decrease during the slow phase of CFI) appears to be an integral characteristic of activation rate with regard to a number of photo-assimilation and photo-protective processes in leaves. On basis of the studies, conducted earlier, and published data, we have analyzed the behavior of T-0.5 parameter with comparison to other CFI traits (namely: qN - non-photochemical quenching coefficient, ETR - electron transport rate, Phi(PSII) - effective quantum yield of PSII photochemistry, F-p/F-T ratio) under different conditions. The influence of leaf senescence, changes in intensity of excitation light, slight dehydration of plants and their recovery from water deficiency have been examined. The pattern of T-0.5 behavior, observed in laboratory experiments, and the results of its comparison with other indices of CFI give occasion to propose the usage of T-0.5 for indirect estimation of PSA activity when operational integrative monitoring of PSA state is required. Further studies are necessary for establishing quantitative relationships between PSA activity and fluorescence parameter T-0.5 under specific stress conditions.

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Держатели документа:
RAS, Siberian Branch, Inst Biophys, Acad Gorodok 50-50, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Nesterenko, T. V.; Shikhov, V. N.; Tikhomirov, A. A.

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13.


   
    Unexpected Coelenterazine Degradation Products of Beroe abyssicola Photoprotein Photoinactivation / L. P. Burakova, M. S. Lyakhovich, K. S. Mineev [et al.] // Org. Lett. - 2021. - Vol. 23, Is. 17. - P6846-6849, DOI 10.1021/acs.orglett.1c02410. - Cited References:20. - This work was supported by grant 20-04-00085 of the Russian Foundation for Basic Research, grant 20-44-242003 of the Russian Foundation for Basic Research, Krasnoyarsk Territory, and Krasnoyarsk Regional Fund of Science in part of purification and spectral characterization of native compounds, grant 17-1401169p of the Russian Science Foundation, and the President of Russian Federation grant for Leading Scientific Schools LS-2605.2020.4 in part of structural elucidation of native products and organic synthesis. We thank Konstantin Antonov (IBCh RAS) and Igor Ivanov (IBCh RAS) for the registration of HRMS spectra. . - ISSN 1523-7060. - ISSN 1523-7052
РУБ Chemistry, Organic
Рубрики:
CRYSTAL-STRUCTURE
   BIOLUMINESCENCE
   OBELIN
   RESIDUES
   BINDING
Аннотация: Ca2+-regulated photoproteins of ctenophores lose bioluminescence activity when exposed to visible light. Little is known about the chemical nature of chromophore photo-inactivation. Using a total synthesis strategy, we have established the structures of two unusual coelenterazine products, isolated from recombinant berovin of the ctenophore Beroe abyssicola, which are Z/E isomers. We propose that during light irradiation, these derivatives are formed from 2-hydroperoxycoelenterazine via the intermediate 8a-peroxide by a mechanism reminiscent of that previously described for the auto-oxidation of green-fluorescent-protein-like chromophores.

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Держатели документа:
Fed Res Ctr Krasnoyarsk Sci Ctr SB RAS, Inst Biophys SB RAS, Photo Biol Lab, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Shemyakin Ovchinnikov Inst Bioorgan Chem, Moscow 117997, Russia.
Moscow Inst Phys & Technol, Dolgoprudnyi 141701, Russia.
Pirogov Russian Natl Res Med Univ, Moscow 117997, Russia.

Доп.точки доступа:
Burakova, Ludmila P.; Lyakhovich, Maria S.; Mineev, Konstantin S.; Petushkov, Valentin N.; Zagitova, Renata, I; Tsarkova, Aleksandra S.; Kovalchuk, Sergey, I; Yampolsky, Ilia, V; Vysotski, Eugene S.; Kaskova, Zinaida M.; Mineev, Konstantin; Tsarkova, Aleksandra; Vysotski, Eugene; Kaskova, Zinaida; Burakova, Lyudmila; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [20-04-00085]; Russian Foundation for Basic Research, Krasnoyarsk Territory [20-44-242003]; Krasnoyarsk Regional Fund of Science in part of purification and spectral characterization of native compounds; Russian Science FoundationRussian Science Foundation (RSF) [17-1401169p]; Russian FederationRussian Federation [LS-2605.2020.4]

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14.


   
    H2O-Bridged Proton-Transfer Channel in Emitter Species Formation in Obelin Bioluminescence / S. F. Chen, E. S. Vysotski, Y. J. Liu // J. Phys. Chem. B. - 2021. - Vol. 125, Is. 37. - P10452-10458, DOI 10.1021/acs.jpcb.1c03985. - Cited References:50. - This work was supported by the Program of Shanghai Institute of Technology (no. YJ2016-42), the National Natural Science Foundation of China (21973005 and 21911530094), and the Russian Foundation for Basic Research (20-04-00085 and 19-14-53004). . - ISSN 1520-6106. - ISSN 1520-5207
РУБ Chemistry, Physical
Рубрики:
CHEMILUMINESCENT DECOMPOSITION
   FLUORESCENCE-SPECTRA
   MECHANISM
   QM/MM
Аннотация: Bioluminescence of a number of marine organisms is conditioned by Ca2+-regulated photoprotein (CaRP) with coelenterazine as the reaction substrate. The reaction product, coelenteramide, at the first singlet excited state (S-1) is the emitter of CaRP. The S-1-state coelenteramide is produced via the decomposition of coelenterazine dioxetanone. Experiments suggested that the neutral S-1-coelenteramide is the primary emitter species. This supposition contradicts with theoretical calculations showing that the anionic S-1-coelenteramide is a primary product of the decomposition of coelenterazine dioxetanone. In this study, applying molecular dynamic (MD) simulations and the hybrid quantum mechanics/molecular mechanics (QM/MM) method, we investigated a proton-transfer (PT) process taking place in CaRP obelin from Obelia longissima for emitter formation. Our calculations demonstrate a concerted PT process with a water molecule as a bridge between anionic S-1-coelenteramide and the nearest histidine residue. The low activation barrier as well as the strong hydrogen-bond network between the proton donor and the proton acceptor suggests a fast PT process comparable with that of the lifetime of excited anionic S-1-coelenteramide. The existence of the PT process eliminates the discrepancy between experimental and theoretical studies. The fast PT process at emitter formation can also take place in other CaRPs.

WOS
Держатели документа:
Shanghai Inst Technol, Sch Chem & Environm Engn, Shanghai 201418, Peoples R China.
Fed Res Ctr Krasnoyarsk Sci Ctr SB RAS, Inst Biophys SB RAS, Photo Biol Lab, Krasnoyarsk 660036, Russia.
Beijing Normal Univ Zhuhai, Ctr Adv Mat Res, Adv Inst Nat Sci, Zhuhai 519087, Peoples R China.
Beijing Normal Univ, Coll Chem, Key Lab Theoret & Computat Photochem, Minist Educ, Beijing 100875, Peoples R China.

Доп.точки доступа:
Chen, Shu-Feng; Vysotski, Eugene S.; Liu, Ya-Jun; Vysotski, Eugene; Program of Shanghai Institute of Technology [YJ2016-42]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21973005, 21911530094]; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [20-04-00085, 19-14-53004]

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