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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ruseikina A. V., Grigoriev M. V., Solovyov L. A., Chernyshev V. A., Aleksandrovsky A. S., Krylov A. S., Krylova S. N., Shestakov N. P., Velikanov D. A., Garmonov A. A., Matigorov A. V., Eberle M. A., Schleid T., Safin D. A.
Заглавие : A Challenge toward novel quaternary sulfides SrLnCuS3 (Ln = La, Nd, Tm): Unraveling synthetic pathways, structures and properties
Место публикации : Int. J. Mol. Sci. - 2022. - Vol. 23, Is. 20. - Ст.12438. - ISSN 14220067 (ISSN), DOI 10.3390/ijms232012438
Примечания : Cited References: 62. - The research was funded by the Tyumen Oblast Government, as part of the West-Siberian Interregional Science and Education Center’s project No. 89-DON (3). This work was supported by state assignment of the Ministry of Science and Higher Education of the Russian Federation (Project Reg. No. 720000Φ.99.1.Б385AA13000)
Аннотация: We report on the novel heterometallic quaternary sulfides SrLnCuS3 (Ln = La, Nd, Tm), obtained as both single crystals and powdered samples. The structures of both the single crystal and powdered samples of SrLaCuS3 and SrNdCuS3 belong to the orthorhombic space group Pnma but are of different structural types, while both samples of SrTmCuS3 crystallize in the orthorhombic space group Cmcm with the structural type KZrCuS3. Three-dimensional crystal structures of SrLaCuS3 and SrNdCuS3 are formed from the (Sr/Ln)S7 capped trigonal prisms and CuS4 tetrahedra. In SrLaCuS3, alternating 2D layers are stacked, while the main backbone of the structure of SrNdCuS3 is a polymeric 3D framework [(Sr/Ln)S7]n, strengthened by 1D polymeric chains (CuS4)n with 1D channels, filled by the other Sr2+/Ln3+ cations, which, in turn, form 1D dimeric ribbons. A 3D crystal structure of SrTmCuS3 is constructed from the SrS6 trigonal prisms, TmS6 octahedra and CuS4 tetrahedra. The latter two polyhedra are packed together into 2D layers, which are separated by 1D chains (SrS6)n and 1D free channels. In both crystal structures of SrLaCuS3 obtained in this work, the crystallographic positions of strontium and lanthanum were partially mixed, while only in the structure of SrNdCuS3, solved from the powder X-ray diffraction data, were the crystallographic positions of strontium and neodymium partially mixed. Band gaps of SrLnCuS3 (Ln = La, Nd, Tm) were found to be 1.86, 1.94 and 2.57 eV, respectively. Both SrNdCuS3 and SrTmCuS3 were found to be paramagnetic at 20-300 K, with the experimental magnetic characteristics being in good agreement with the corresponding calculated parameters.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Belyaev B. A., Serzhantov A. M., Leksikov An. A., Bal'va Ya. F., Aleksandrovsky A. S., Galeev R. G
Заглавие : A high-selectivity waveguide bandpass filter with interference suppression by more than 120 dB in rejection band
Колич.характеристики :5 с
Место публикации : Tech. Phys. Lett. - 2023. - Vol. 49, Is. 5. - P.72-76. - ISSN 10637850 (ISSN), DOI 10.21883/TPL.2023.05.56034.19541. - ISSN 10906533 (eISSN)
Примечания : Cited References: 10. - This study was carried out under agreement No. 470 dated August 30, 2022, between the Kirensky Institute of Physics (Siberian Branch, Russian Academy of Sciences), the Regional Science Foundation, and ”AO ”NPP ”Radiosvyaz“ as part of a competitive tender of research-andengineering and innovative projects for the first climatological research and education center ”Yenisey Siberia“
Аннотация: The design of a 10th-order waveguide bandpass filter with an additional inductive cross-coupling between non-adjacent resonators has been proposed and studied. An inductive coupling is formed by a U-shaped conductor structure with grounded ends that is formed in the filter cover. This method of cross-coupling organization ensures not only the temperature stability of the characteristics, but also the manufacturability of the structure. The high selectivity of the device is achieved by both the attenuation poles located near the passband, as well as the level of suppression in the stopbands, exceeding 120 dB. The passband loss of the fabricated filter is ~ 0.8 dB at its central frequency f0=18.2 GHz and relative bandwidth Δf/f0=1.5%. The small dimensions (135 x 30 x 10 mm) and the weight of about 200 g of the device, with simultaneously high electrical characteristics show the promise of its use, for example, in on-board and ground-based space communication systems.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Ershov A. A., Oreshonkov A. S., Shestakov N. P., Aleksandrovsky A. S., Vtyurin A. N.
Заглавие : Absorption spectra of PrF3 crystal
Коллективы : Russia-China workshop on dielectric and ferroelectric materials, Российская академия наук, Воронежский государственный технический университет
Место публикации : The Second Rus.-China Workshop on Dielectic and Ferroel. Mater.: program. - 2015. - Ст.P6.3. - P.82: abstract book
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Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Tsipotan A., Aleksandrovsky A. S., Slabko V.
Заглавие : Alteration of the aggregation stability of quantum dots by irradiation
Коллективы : International Conference on Metamaterials and Nanophotonics
Место публикации : AIP Conf. Proc. - 2017. - Vol. 1874. - Ст.040053. - , DOI 10.1063/1.4998126
Примечания : Cited References: 11
Аннотация: The influence of weak irradiation on the aggregation stability of quantum dots is considered. It was shown that under combined UV and visible light irradiation, a gradual increase in spontaneous aggregation takes place, testifying decrease in stabilizing potential barrier height. Thereby, the laser-induced controllable self-assembly of CdTe QDs is recommended to be performed over a time period between 80 and 100 min after the beginning of low intensity irradiation under conditions equivalent to those applied in this study.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Dubynina A. V., Semina P. N., Sokolov A. E., Zabluda V. N., Aleksandrovskii A. S., Karacharov A., Zamay G. S., Kolovskaya O. S., Ivanchenko T., Govorina Y., Zamay A. S., Zamay T. S.
Заглавие : Aptamer-mediated targeted hyperthermia caused by gold nanoparticles
Коллективы : Annual Meeting of the Oligonucleotide Therapeutics Society
Место публикации : 11th Annual Meet. of the Oligonucleotide Therapeutics Soc. (OTS). - 2015. - P.127
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kolovskaya O. S., Zamay T. N., Belyanina I. V., Karlova E. A., Garanzha I. V., Aleksandrovsky A. S., Kirichenko A. K., Dubinina A. V., Sokolov A. Е., Zamay G. S., Glazyrin Y. E., Zamay S. S., Ivanchenko T. I., Chanchikova N. G., Tokarev N. A., Shepelevich N. V., Ozerskaya A.V., Bardin E., Belugin K., Belkin S. A., Zabluda V. N., Gargaun A., Berezovski M. V., Kichkailo A.S.
Заглавие : Aptamer-targeted plasmonic photothermal therapy of cancer
Место публикации : Mol. Ther. Nucl. Acids. - 2017. - Vol. 9. - P.12-21. - ISSN 2162-2131 Electronic, DOI 10.1016/j.omtn.2017.08.007
Примечания : Cited References: 8. - We thank Mr. Yousef Risha for improving the use of English in the manuscript and Mr. George Y. Vorogeikin, Mr. Yuri I. Vorogeikin, and “OKB ART” for the infrared imaging. This research is supported by Ministry of Education and Science Federal Target Program #14.607.21.0104 (RFMEFI60714X0104).
Аннотация: Novel nanoscale bioconjugates combining unique plasmonic photothermal properties of gold nanoparticles (AuNPs) with targeted delivery using cell-specific DNA aptamers have a tremendous potential for medical diagnostics and therapy of many cell-based diseases. In this study, we demonstrate the high anti-cancer activity of aptamer-conjugated, 37-nm spherical gold nanoparticles toward Ehrlich carcinoma in tumor-bearing mice after photothermal treatment. The synthetic anti-tumor aptamers bring the nanoparticles precisely to the desired cells and selectively eliminate cancer cells after the subsequent laser treatment. To prove tumor eradication, we used positron emission tomography (PET) utilizing radioactive glucose and computer tomography, followed by histological analysis of cancer tissue. Three injections of aptamer-conjugated AuNPs and 5 min of laser irradiations are enough to make the tumor undetectable by PET. Histological analysis proves PET results and shows lower damage of healthy tissue in addition to a higher treatment efficiency and selectivity of the gold nanoparticles functionalized with aptamers in comparison to control experiments using free unconjugated nanoparticles.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Aleksandrovsky A. S., Vyunishev A. M., Zaitsev A. I., Pospelov G. I., Rovsky V. E., Slabko V. V.
Заглавие : Broadband frequency conversion in random nonlinear photonic crystals
Коллективы : "Laser Optics", International conference (15; 2012 ; June ; 25-29; St. Petersburg), "Оптика лазеров", Международная конференция (15; 2012 ; июнь ; 25-29; Санкт-Петербург)
Место публикации : Laser Optics 2012. - 2012. - Ст.WeR1-p69. - P.42
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Vyunishev A. M., Aleksandrovsky A. S., Zaitsev A. I., Slabko V. V.
Заглавие : Broadband pulse conversion in 1d disordered nonlinear photonic crystals
Коллективы : "Light in Disordered Photonic Media", 546. WE-Heraeus-Seminar (546; 2013 ; 2-4 dec; Bad Honnef, Germany)
Место публикации : WE-Heraeus-Seminar: "Light in Disordered Photonic Media", 546. - 2013
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kornienko V. S., Tsipotan A. S., Aleksandrovsky A. S., Slabko V. V.
Заглавие : Brownian dynamics of the self-assembly of complex nanostructures in the field of quasi-resonant laser radiation
Место публикации : Photonics Nanostruc. Fundam. Appl. - 2019. - Vol. 35. - Ст.100707. - ISSN 15694410 (ISSN), DOI 10.1016/j.photonics.2019.100707
Примечания : Cited References: 32. - The reported study was funded by Russian Science Foundation (Grant 18-72-00003 ). V.V. Slabko is grateful for the support from the Ministry of Education and Science of the Russian Federation (Grant 3.6341.2017/VU ).
Аннотация: Self-assembly of nanoparticles under the action of laser field can be an universal method for the formation of nanostructures with specific properties for application in sensorics and nanophotonics. For prognosis of the self-assembly processes, the model of movement of an ensemble of nanoparticles in a viscous media under the action of laser radiation with the account for interaction of laser-induced polarizations and Brownian dynamics is developed. This model is applied to the investigation of the self-assembly process of a triple of nanoparticles into three-particle structure with a predetermined geometry.Two specific cases of formation of nanostructure from a preliminarily formed pair of particles are studied: either for the pair fixed in space or from the unfixed pair of nanoparticles. The geometry of resulting nanostructures is shown to be determined by the polarization direction of laser radiation and the laser wavelength. Under proper choice of these parameters the formation of structures is shown to be highly efficient. E. g., maximum probability of structures formation is as hig as 36–46% per single laser pulse of 10 ns duration. © 2019 Elsevier B.V.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vyunishev A. M., Aleksandrovsky A. S., Zaitsev A. I., Slabko V. V.
Заглавие : Cerenkov nonlinear diffraction of femtosecond pulses
Место публикации : J. Opt. Soc. Am. B: Optical Society of America, 2013. - Vol. 30, Is. 7. - P.2014-2021. - ISSN 0740-3224, DOI 10.1364/JOSAB.30.002014
Примечания : Cited References: 43. - The work was partially supported by the Grant of the President of the Russian Federation MK-250.2013.2, by RFBR through Grant No. 12-02-31167, by the Ministry of Education and Science of the Russian Federation (Contract No. 14.B37.21.0730), by Krasnoyarsk Regional Fund of Science and Technical Activity Support, by PSB RAS Project 2.5.2, and by SFU Grant F12.
Предметные рубрики: STRONTIUM BARIUM NIOBATE
2ND-HARMONIC GENERATION
PHOTONIC CRYSTAL
DOMAIN-WALLS
MODULATION
Аннотация: Cerenkov nonlinear diffraction of femtosecond pulses in one-dimensional nonlinear photonic crystal of strontium tetraborate was studied theoretically and experimentally in both frequency and time domains. Spectral features of second harmonic radiation were measured in the course of mapping the nonlinear photonic crystal structure. The local second harmonic spectrum demonstrates complex angular behavior within the beam cross section. The spectral width of the second harmonic radiation is found to be fundamental beam size-dependent, and optimal focusing should be used for exact conversion of the fundamental spectrum into the second harmonic one. Experimental results are in excellent agreement with calculations. Maximum second harmonic generation efficiency was up to 2.1% at pumping by a femtosecond oscillator. (C) 2013 Optical Society of America
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11.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Vyunishev A. M., Aleksandrovsky A. S., Zaitsev A. I., Slabko V. V.
Заглавие : Cerenkov nonlinear diffraction of femtosecond pulses in random nonlinear photonic crystal
Коллективы : Russia-Taiwan School-Seminar on Nonlinear Optics and Photonics (3; 2013 ; Jun. ; 14-18; Владимир/ Суздаль)
Место публикации : Third Russia-Taiwan School-Seminar on Nonlinear Optics and Photonics : Program and Book of Abstracts. - 2013. - Ст.S1-11-O30. - P.20
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Tsipotan, Aleksey S., Gerasimova M. A., Polyutov, Sergey P., Aleksandrovsky A. S., Slabko, Vitaliy V.
Заглавие : Comparative analysis of methods for enhancement of the photostability of CdTe@TGA QD colloid solutions
Коллективы : RFBR; Government of Krasnoyarsk Territory of SB RAS Program [16-42-240410r_a, 0356-2015-0412, II.2P]; Ministry of Education and Science of the Russian Federation [3.6341.2017/VU]
Место публикации : J. Phys. Chem. B: American Chemical Society, 2017. - Vol. 121, Is. 23. - P.5876-5881. - ISSN 1520-6106, DOI 10.1021/acs.jpcb.7b03166
Примечания : Cited References:41. - This research was supported by RFBR and Government of Krasnoyarsk Territory by Research Project No. 16-42-240410r_a and by Project No. 0356-2015-0412 of SB RAS Program No. II.2P. V.V.S. is grateful for the support from the Ministry of Education and Science of the Russian Federation (Grant No. 3.6341.2017/VU).
Предметные рубрики: BOVINE SERUM-ALBUMIN
SENSITIZED SOLAR-CELLS
QUANTUM DOTS
Аннотация: The employment of colloid quantum dots in a number of applications is limited by their instability under light irradiation. Additional methods of photostability enhancement of UV+visible-irradiated TGA-stabilized CdTe quantum dots are investigated. Photostability enhancement was observed via either addition of sodium sulphite in the role of chemical oxygen absorber or addition of 1% gelatin, or, finally, by additional stabilization by bovine serum albumine (BSA). The latter method is the most promising, since it not only enhances the quantum dots' photostability but also makes them more biocompatible and extends the possibilities of their biological applications.
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13.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Aleksandrovsky A. S., Vyunishev A. M., Slabko V.V., Zaitsev A. I., Zamkov A. V.
Заглавие : Conversion of radiation in nonlinear photonic crystals of strontium tetraborate
Коллективы : European Conference on Lasers and Electro-Optics and the European Quantum Electronics Conference
Место публикации : CLEO/Europe - EQEC 2009 - European Conference on Lasers and Electro-Optics and the European Quantum Electronics Conference. - 2009. - ISBN 9781424440801 (ISBN), DOI 10.1109/CLEOE-EQEC.2009.5196562. - ISBN 21622701
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisenko Y. G., Sedykh A. E., Molokeev M. S., Oreshonkov A. S., Aleksandrovsky A. S., Krylov A. S., Khritokhin N. A., Sal'nikova E. I., Andreev O. V., Muller-Buschbaum K.
Заглавие : Crystal and electronic structure, thermochemical and photophysical properties of europium-silver sulfate monohydrate AgEu(SO4)2·H2O
Место публикации : J. Solid State Chem. - 2021. - Vol. 294. - Ст.121898. - ISSN 00224596 (ISSN), DOI 10.1016/j.jssc.2020.121898
Примечания : Cited References: 54. - This work was partially supported by the Russian Foundation for Basic Research (Grant 19-33-90258∖19 ). Use of equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center « Krasnoyarsk Science Center SB RAS» is acknowledged
Аннотация: In order to synthesize single crystals of europium-silver double sulfate monohydrate, a hydrothermal reaction route was used. It was found that the crystallization cannot be performed under standard conditions. The compound AgEu(SO4)2·H2O crystallizes in the trigonal crystal system, space group P3221 (a = 6.917(1), c = 12.996(2) Å, V = 538.53(17) Å3). The structure consists of triple-capped trigonal prisms [EuO9], in which one oxygen atom belongs to crystalline water, silver octahedra [AgO6], and sulfate tetrahedra [SO4]. The hydrogen bonds in the system additionally stabilize the structure. The electronic band structure wasstudied by density functional theory calculations which show that AgEu(SO4)2·H2O is an indirect band gap dielectric. Temperature dependent photoluminescence spectroscopy shows emission bands of transitions from the 5D0 state to the spin-orbit components of the 7FJmultiplet (J = 0–6).The ultranarrow transition 5D0 - 7F0 shows a red shift with respect to other europium-containing water-free sulfates that is ascribed to the presence of OH group in the crystal structure in the close vicinity of the Eu3+ ion. An effect of abnormal sensitivity of the Ω4 intensity factor to minor distortions of the local environment is detected for the observed low local symmetry of C2.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sofronova S. N., Moshkina E. M., Chernyshev A., Vasil'ev A. D., Maximov N., Aleksandrovsky A. S., Andryushchenko T., Shabanov A. V.
Заглавие : Crystal growth and cation order of Ni3-xCoxB2O6 oxyborates
Колич.характеристики :15 с
Место публикации : CrystEngComm. - 2024. - Article in press. - ISSN 14668033 (eISSN), DOI 10.1039/D4CE00091A
Примечания : Cited References: 28. - The research was funded by Russian Science Foundation and Krasnoyarsk Regional Fund of Science, project № 23-12-20012 (https://rscf.ru/en/project/23-12-20012/)
Аннотация: A series of single crystals of Ni3-xCoxB2O6 compounds with the kotoite structure and with different concentrations of transition metal ions (x = 0; 0,19; 0,6; 0,93; 2) were obtained. The lattice parameters and atomic coordinates were determined using X-ray diffraction. The theoretical calculations using the WIEN2k package predict that nickel ions tend to occupy the 4f crystallographic position, while cobalt ions tend to occupy the 2a crystallographic positions. The study of the diffuse scattering spectra and comparison of the Racah parameters for the compounds Ni3B2O6 and Co2NiB2O6 provides experimental evidence that the nickel ions occupy crystallographic position 4f.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova L. T., Molokeev M. S., Aleksandrovskii A. S., Kargin Y. F., Golubeva E. O., Denisov V. M.
Заглавие : Crystal structure, luminescence, and thermodynamic properties of Pb10–xEux(GeO4)2+x(VO4)4–x (x = 0.1, 0.2, 0.3) substituted apatites
Место публикации : Inorg. Mater. - 2021. - Vol. 57, Is. 11. - P.1158-1166. - ISSN 00201685 (ISSN), DOI 10.1134/S0020168521110030
Примечания : Cited References: 26. - This work was supported in part by the Russian Federation Ministry of Science and Higher Education as part of the state research target for the Siberian Federal University federal state autonomous educational institution of higher education, project no. FSRZ-2020-0013
Аннотация: Pb10 – xEux(GeO4)2 + x(VO4)4 – x (x = 0.1, 0.2, 0.3) Eu-substituted lead germanatovanadates with the apatite structure have been prepared by solid-state reactions, via firing in air in the temperature range 773–1073 K, using oxides (PbO, Eu2O3, GeO2, and V2O5) as starting materials. Using X-ray diffraction, we have determined the hexagonal cell parameters (sp. gr. P63/m) of the synthesized phases and refined their crystal structure (the atomic position coordinates, isotropic thermal parameters, and principal bond lengths in their structure are presented). We have measured the luminescence spectra of the Pb10 – xEux(GeO4)2 + x(VO4)4 – x (x = 0.1, 0.2, 0.3) apatites and shown that europium concentration has little effect on the shape of the luminescence spectra. Using experimental heat capacity data obtained for polycrystalline samples by differential scanning calorimetry in the temperature range 350–1050 K, we calculated the main thermodynamic functions of the Eu-substituted lead germanatovanadates.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisenko Y. G., Molokeev M. S., Oreshonkov A. S., Krylov A. S., Aleksandrovsky A. S., Azarapin N. O., Andreev O. V., Razumkova I. A., Atuchin V. V.
Заглавие : Crystal structure, vibrational, spectroscopic and thermochemical properties of double sulfate crystalline hydrate [CsEu(H2O)3(SO4)2]·H2O and its thermal dehydration product CsEu(SO4)2
Место публикации : Crystals. - 2021. - Vol. 11, Is. 9. - Ст.1027. - ISSN 20734352 (ISSN), DOI 10.3390/cryst11091027
Примечания : Cited References: 103. - This work was partially supported by the Russian Foundation for Basic Research (grant 19-33-90258\19)
Аннотация: Crystalline hydrate of double cesium europium sulfate [CsEu(H2O)3(SO4)2]·H2O was synthesized by the crystallization from an aqueous solution containing equimolar amounts of 1Cs+:1Eu3+:2SO42− ions. Anhydrous salt CsEu(SO4)2 was formed as a result of the thermal dehydration of the crystallohydrate. The unusual effects observed during the thermal dehydration were attributed to the specific coordination of water molecules in the [CsEu(H2O)3(SO4)2]·H2O structure. The crystal structure of [CsEu(H2O)3(SO4)2]·H2O was determined by a single crystal X-ray diffraction analysis, and the crystal structure of CsEu(SO4)2 was obtained by the Rietveld method. [CsEu(H2O)3(SO4)2]·H2O crystallizes in the monoclinic system, space group P21/c (a = 6.5574(1) Å, b = 19.0733(3) Å, c = 8.8364(2) Å, β = 93.931(1)°, V = 1102.58(3) Å3). The anhydrous sulfate CsEu(SO4)2 formed as a result of the thermal destruction crystallizes in the monoclinic system, space group C2/c (a = 14.327(1) Å, b = 5.3838(4) Å, c = 9.5104(6) Å, β = 101.979(3) °, V = 717.58(9) Å3). The vibration properties of the compounds are fully consistent with the structural models and are mainly determined by the deformation of non-rigid structural elements, such as H2O and SO42−. As shown by the diffused reflection spectra measurements and DFT calculations, the structural transformation from [CsEu(H2O)3(SO4)2]·H2O to CsEu(SO4)2 induced a significant band gap reduction. A noticeable difference of the luminescence spectra between cesium europium sulfate and cesium europium sulfate hydrate is detected and explained by the variation of the extent of local symmetry violation at the crystallographic sites occupied by Eu3+ ions, namely, by the increase in inversion asymmetry in [CsEu(H2O)3(SO4)2]·H2O and the increase in mirror asymmetry in CsEu(SO4)2. The chemical shift of the 5D0 energy level in cesium europium sulfate hydrate, with respect to cesium europium sulfate, is associated with the presence of H2O molecules in the vicinity of Eu3+ ion.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zos’ko, Nikolay A., Aleksandrovsky A. S., Kenova, Tatyana, Gerasimova, Marina A., Maksimov, Nikolay G., Taran, Oxana P.
Заглавие : Cyclic voltammetry as an activation method of TiO2 nanotube arrays for improvement of photoelectrochemical water splitting performance
Колич.характеристики :11 с
Место публикации : ChemPhotoChem. - 2023. - Vol. 7, Is. 9. - Ст.e202300100. - ISSN 23670932 (eISSN), DOI 10.1002/cptc.202300100
Примечания : Cited References: 36. - The authors express their gratitude to A. M. Zhizhaev for the microscopy and XRD analysis and V. F. Shabanov for the fruitful discussionThis work was conducted within the framework of the budget project FWES-2021-0023 for Institute of Chemistry and Chemical Technology SB RAS using the equipment of Krasnoyarsk Regional Research Equipment Centre of SB RAS
Аннотация: A facile and eco-friendly method for activating anodic TiO2 nanotubes (TNTs) by cyclic voltammetry (CV) is proposed, and photoelectrochemical properties of CV-activated TNTs are compared with those of non-activated TNTs and of TNTs activated by hydrogen-thermal reduction. EPR and luminescence studies show that the pristine samples demonstrate rather large content of paramagnetic and luminescing defects, while hydrogenation and CV-activation lead to the different type of rearrangement of defects. TNTs activated by CV-Na2SO4 demonstrate significantly improved photocurrent density (2.25 mA cm-2) in comparison with that of the hydrogen treated and pristine ones (0.93 mA cm-2 and 0.31 mA cm-2) under NUV-irradiation at 0.2 V (RHE). Enhanced photoactivity of Na2SO4-activated TNTs correlates with higher luminescence quantum yield, lowest paramagnetic defects content and larger decay time of the luminescence. Thus, a decrease in the content of defects is an important factor that reduces the non-radiative recombination of charge carriers. The activation-induced redistribution of surface and bulk defects in nanotubes explains the increased photoelectrochemical activity of TiO2-based anodes. Cyclic voltammetry has been proved to be a reliable method to increase the efficiency of TNTs in PEC water splitting.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrovsky A. S., Vyunishev A. M., Zaitsev A. I., Ikonnikov A. A., Pospelov G. I., Slabko V. V., Zhokhova A. A.
Заглавие : Deep UV generation and fs pulses characterization using strontium tetraborate
Коллективы : Nonlinear Optics and Applications (5; 2011 ; Apr. ; 19-21; Prague, Czech Republic)
Место публикации : Proc. of SPIE: SPIE-Int. Soc. Optical Engineering, 2011. - Vol. 8071. - Ст.80710K. - ISSN 0277-786X, DOI 10.1117/12.886189. - ISSN 978-0-81948-661-5
Примечания : Cited References: 12
Предметные рубрики: CRYSTAL
Ключевые слова (''Своб.индексиров.''): nonlinear photonic crystal--strontium tetraborate--second harmonic generation--random quasi phase matching--ultrafast diagnostics
Аннотация: The properties of NPC structures in strontium tetraborate are analyzed. Different types of NPC structures are revealed that possess different nonlinear properties, and their spectral dependences of frequency conversion efficiency are calculated and compared. Experimental study of these structures is reported for the process of doubling of the second harmonic of fs Ti:S laser. Tuning of generated radiation is obtained in the range 187.5 - 232.5 nm, with extreme insensitivity to the angular orientation of NPC. Behavior of tuning curve along investigated fundamental wave range is similar in all studied samples, but efficiency obtained depends on the type of structure. Conversion efficiency and spectral quality of generated radiation is experimentally shown to grow better when using NPC with improved structure. Prospects of VUV converter on a single NPC are discussed. NPCs of SBO are demonstrated to be useful for autocorrelation diagnostics both in random QPM geometry and in the geometry of nonlinear diffraction from virtual beam.
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20.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Aleksandrovsky A. S., Vyunishev A. M., Zaitsev A. I., Ikonnikov A.A., Pospelov G.I., Slabko V.V., Zhokhova A.A.
Заглавие : Deep UV generation and fs pulses characterization using strontium tetraborate
Коллективы : Nonlinear Optics and Applications
Место публикации : Nonlinear Optics and Applications V: Proceedings of the SPIE. - 2011. - С. 36. - (SPIE Optics + Optoelectronics)
Аннотация: The properties of NPC structures in strontium tetraborate are analyzed. Different types of NPC structures are revealed that possess different nonlinear properties, and their spectral dependences of frequency conversion efficiency are calculated and compared. Experimental study of these structures is reported for the process of doubling of the second harmonic of fs Ti:S laser. Tuning of generated radiation is obtained in the range 187.5 - 232.5 nm, with extreme insensitivity to the angular orientation of NPC. Behavior of tuning curve along investigated fundamental wave range is similar in all studied samples, but efficiency obtained depends on the type of structure. Conversion efficiency andspectral quality of generated radiation is experimentally shown to grow better when using NPC with improved structure. Prospects of VUV converter on a single NPC are discussed. NPCs of SBO are demonstrated to be useful for autocorrelation diagnostics both in random QPM geometry and in the geometry of nonlinear diffraction from virtual beam.
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