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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Naumkin N. S., Shestakov N. P., Ivanenko A. A., Kargin V. F., Shestakov A. B.
Заглавие : A thermospectral setup for evaluating the content of unbound components in microscopic samples of an epoxy polymer
Место публикации : Instrum. Exp. Tech.: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 55, Is. 2. - P.294-297. - ISSN 0020-4412, DOI 10.1134/S0020441212010198
Примечания : Cited References: 5. - This study was supported by the Center of Collective Use of the Krasnoyarsk Scientific Center (Siberian Branch, Russian Academy of Sciences), the Presidium of the Russian Academy of Sciences (project no. 27.1), the Department of Physical Sciences, Russian Academy of Sciences, (project no. 9.1), and the Siberian Branch, Russian Academy of Sciences (integration project no. 5).
Аннотация: A setup and a technique for optical measurements intended for evaluating the content of unbound compounds in an epoxy polymer are described. The principle of operation of the setup is based on measurements of the spectra of absorption of infrared (IR) radiation by condensed products of evaporation of unbound components. The needed mass of a sample is about 0.01 g. The results of measurements of the IR radiation absorption as a function of the concentrations of the mixture components-ED-22 epoxy resin, isomethyltetrahydrophthalic anhydride (hardener), and a cure promoter (N integral D-606/2)-are presented. The relative content of chemically unbound components in the structure of a polymer matrix is evaluated as a function of the hardener concentration, thus allowing determination of the stoichiometric ratio of the initial components of an epoxy mixture. The obtained results are compared to those obtained by the extraction method.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Belousov A. L., Patrusheva T. N., Karacharov A. A., Ivanenko A. A., Kirik S. D., Khol'kin A. I.
Заглавие : Amorphous and Crystalline Nickel Oxide Films Obtained by the Extraction-Pyrolysis Method for Electrochromic Cells
Коллективы : program "Research and Development for the Priority Areas of the Russian Science-and-Technology Sector for 2014-2020" [075-15-2019-1843]; [RFMEFI60719X0307]
Место публикации : Theor. Found. Chem. Eng. - 2020. - Vol. 54, Is. 4. - P.699-705. - ISSN 0040-5795, DOI 10.1134/S0040579520040041. - ISSN 1608-3431(eISSN)
Примечания : Cited References: 8. - This work was performed as part of the program "Research and Development for the Priority Areas of the Russian Science-and-Technology Sector for 2014-2020"; Grant Agreement no. 075-15-2019-1843; the Project Unique Identifier RFMEFI60719X0307
Предметные рубрики: NIO THIN-FILMS
Аннотация: This paper reports studies of thin films of nickel oxide obtained by the extraction–pyrolysis method on glass and quartz substrates at temperatures of 380–600°C. The films have been characterized by atomic force microscopy and X-ray diffraction. It is shown that amorphous and crystalline nickel oxide films are formed on the glass. The grain size depends on the annealing temperature, while increased annealing temperatures lead to recrystallization and a decrease in the grain size in NiO films from 130 to 35 nm.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Nemtsev I. V., Tambasov I. A., Ivanenko A. A., Zyryanov V. Ya.
Заглавие : Angle-resolved reflection spectroscopy of high-quality PMMA opal crystal
Место публикации : Photonics Nanostruc. Fundam. Appl. - 2018. - Vol. 28. - P.37-44. - ISSN 15694410 (ISSN), DOI 10.1016/j.photonics.2017.11.007
Примечания : Cited References: 72. - This study was supported by the Russian Foundation for Basic Research (Grant No. 16-32-00302 мол_а ), by the Council for Grants of the President of the Russian Federation ( SP-317.2015.1 ), by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project No. 16-42-243059 р_мол_а and No. 16-48-242092 р_офи_м, and by the Program of Foundation for Promotion of Small Enterprises in Science and Technology (No.6662ГУ2015) (“УМНИК” program). We acknowledge the support of Krasnoyarsk Regional Center for Collective Use of SB of RAS for equipment and technique. We thank A. V. Shabanov and O. V. Shabanova for assistance in dispersion preparation. We also thank V. G. Myagkov for useful discussion of the results.
Ключевые слова (''Своб.индексиров.''): pmma opal--photonic crystal--electron microscopy--angular resolved reflective spectroscopy
Аннотация: PMMA opal crystal was prepared by a simple hybrid method, which includes sedimentation, meniscus formation and evaporation. We investigated three surfaces of this crystal by angle-resolved reflective light spectroscopy and SEM study. The angle-resolved reflective measurements were carried out in the 400–1100 nm range. We have determined the high-quality ordered surface of the crystal region. Narrow particle size distribution of the surface has been revealed. The average particle diameter obtained with SEM was nearly 361 nm. The most interesting result was that reflectivity of the surface turned out up to 98% at normal light incidence. Using a fit of dependences of the maximum reflectivity wavelength from an angle based on the Bragg–Snell law, the wavelength of maximum 0° reflectivity, the particle diameter and the fill factor have been determined. For the best surface maximum reflectivity wavelength of a 0° angle was estimated to be 869 nm. The particle diameter and fill factor were calculated as 372 nm and 0.8715, respectively. The diameter obtained by fitting is in excellent agreement with the particle diameter obtained with SEM. The reflectivity maximum is assumed to increase significantly when increasing the fill factor. We believe that using our simple approach to manufacture PMMA opal crystals will significantly increase the fabrication of high-quality photonic crystal templates and thin films
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krylov A. S., Molokeev M. S., Misyul S. V., Krylova S. N., Oreshonkov A. S., Ivanenko A. A., Zykova V. A., Ivanov Y. N., Sukhovsky A. A., Voronov V. N., Safonov I. N., Vtyurin A. N.
Заглавие : Crystal structure and phase transitions of a layered perovskite-like CsScF4 crystal
Коллективы : Russian Foundation for Basic Research [16-02-00102]
Место публикации : CrystEngComm: Royal Society of Chemistry, 2016. - Vol. 18, Is. 43. - P.8472-8486. - ISSN 1466-8033, DOI 10.1039/c6ce01144f
Примечания : Cited References:47. - The authors are grateful to Prof. I. N. Flerov for valuable support and useful discussions. This work was partly supported by the Russian Foundation for Basic Research, Project 16-02-00102. The research is partially conducted within the framework of the state task of the Ministry of Education and Science of the Russian Federation for Siberian Federal University on R&D performance in 2014 (Task 3.2534.2014/K). X-ray data from powders, Raman NMR, and IR spectra were obtained with use the analytical equipment of Krasnoyarsk Center of collective use SB RAS.
Предметные рубрики: NEGATIVE THERMAL-EXPANSION
RAMAN-SCATTERING
LATTICE-DYNAMICS
Аннотация: This work is devoted to the complex research on temperature phase transitions in a CsScF4 crystal. The crystal structure was solved and refined at different temperatures by using the Rietveld method. Structural phase transitions were investigated by using the following spectroscopic methods, some of them for the first time: Brillouin spectroscopy, Raman spectroscopy, IR absorption spectroscopy and NMR. The symmetry analysis of the Brillouin zone center of all phases is presented. The vibrational spectra of the crystal in three phases have been calculated. The structural phase transition mechanism was determined. The transitions at T-1 = 475 K and T-2 = 317.5 K are of displacement type. The Raman soft modes have been associated with rotations of the ScF6 octahedral group.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Tambasov I. A., Myagkov V. G., Ivanenko A. A., Bykova L. E., Yozhikova E. V., Maksimov I. A., Ivanov V. V.
Заглавие : Effect of exposure to optical radiation and temperature on the electrical and optical properties of In2O3 films produced by autowave oxidation
Коллективы : Ministry of Education and Science of the Russian Federation [14.513.11.0023]
Место публикации : Semiconductors: MAIK Nauka-Interperiodica / Springer, 2014. - Vol. 48, Is. 2. - P.207-211. - ISSN 1063-7826, DOI 10.1134/S1063782614020286. - ISSN 1090-6479
Примечания : Cited References: 42. - This study was supported by the Ministry of Education and Science of the Russian Federation, Federal Targeted Program "Research and Development in Priority Fields of Development of the Science and Technology Complex of Russia for 2007-2013", state contract no. 14.513.11.0023.
Предметные рубрики: GAS SENSOR RESPONSE
INDIUM OXIDE-FILMS
THIN-FILMS
HIGH-PERFORMANCE
TIN OXIDE
TRANSPARENT CONDUCTORS
SUBSTRATE-TEMPERATURE
ROOM-TEMPERATURE
TRANSISTORS
PHOTOREDUCTION
Аннотация: Indium-oxide films are synthesized by the autowave-oxidation reaction. It is shown that, upon exposure to optical radiation, the resistance of the films sharply decreases and the maximal relative change in the resistance is 52% at room temperature. Two resistance relaxation rates after termination of the irradiation, 15 Omega s(-1) during the first 30 s and 7 Omega s(-1) over the remaining time, are determined. The data of infrared spectroscopy of the films show that exposure to optical radiation induces a 2.4% decrease in the transmittance at a wavelength of 6.3 mu m. It is found that, after termination of the irradiation, the transmittance gradually increases with a rate of 0.006% s(-1). It is suggested that photoreduction is the dominant mechanism responsible for changes in the electrical and optical properties of the In2O3 films.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krylov A. S., Sofronova S. N., Kolesnikova E. M., Ivanov Y. N., Sukhovsky A. A., Goryainov S. V., Ivanenko A. A., Shestakov N. P., Kocharova A. G., Vtyurin A. N.
Заглавие : Experimental and theoretical methods to study structural phase transition mechanisms in K3WO3F3 oxyfluoride
Коллективы : Russian Foundation for Basic Research [4828.2012.2, 12-02-31205]; Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" [8379]
Место публикации : J. Solid State Chem. - 2014. - Vol. 218. - P.32-37. - ISSN 0022-4596, DOI 10.1016/j.jssc.2014.05.028. - ISSN 1095-726X
Примечания : Cited References: 21. - The Authors are grateful to Prof. Zinenko V.I. for constructive discussion of the results. The work has been done with financial support of the Russian Foundation for Basic Research projects nos. 4828.2012.2, 12-02-31205; Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" project no. 8379.
Предметные рубрики: LATTICE-DYNAMICS
RAMAN-SCATTERING
ELPASOLITE
(NH4)3WO3F3
SPECTROSCOPY
CRYSTALS
Ключевые слова (''Своб.индексиров.''): raman spectroscopy--ir spectroscopy--nmr spectroscopy--high hydrostatic pressure--oxyfluorides--lattice dynamics calculations
Аннотация: The results of structural phase transitions mechanisms study in K3WO3F3oxyfluoride are represented by different experimental and theoretical methods. The structural phase transition anomalies at T1=452 K and T2=414 K of Raman and IR spectra have been analyzed. Using vibrational spectroscopy methods, the NMR-experiment has been done to clarify the nature of found phase transitions: displacive types or order-disorder types. The model of “disordered” crystal was proposed, and the results of lattice dynamics calculation in frameworks of the generalized Gordon–Kim method of ordered (R3) and “disordered” crystals were compared. The high pressure phases were studied by the Raman technique too.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanenko A. A., Tambasov I. A., Pshenichnaia A. A., Shestakov N. P.
Заглавие : Flexible film broadband absorber based on diamond-graphite mixture and polyethylene
Место публикации : Opt. Mater.: Elsevier Science, 2017. - Vol. 73. - P.388-392. - ISSN 09253467 (ISSN), DOI 10.1016/j.optmat.2017.08.041
Примечания : Cited References: 54. - This study was supported by the Russian Foundation for Basic Research (Grants No. 16-32-00302 мол_а), by the Council for Grants of the President of the Russian Federation (SP-317.2015.1), by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project No. 16-42-243059 р_мол_а and No. 16-48-242092 р_офи_м.
Ключевые слова (''Своб.индексиров.''): flexible film broadband absorption--diamond-graphite mixture--polyethylene--reflectivity--transmittance
Аннотация: Flexible film broadband absorber based on diamond-graphite mixture and polyethylene was fabricated by hot pressing. The film thickness of the absorber was 90 μm. We have measured angular reflectivity, diffusional reflectivity and transmittance in the range 85–8000 cm−1 (117–1.25 μm) in order to determine the absorption. It was shown that room temperature pressing of mesh print with 250 μm step significantly reduces reflectivity of the absorber. The absorption was over 0.85 in the range 85–320 cm−1 (117–31.25 μm) and 0.98 in the range 320–8000 cm−1 (31.25–1.25 μm). We believe that the designed and manufactured absorber might become a promising material for optical devices where high broadband absorption and flexibility are required.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vtyurin A. N., Gerasimova Y. V., Shestakov N. P., Ivanenko A. A.
Заглавие : Influence of the Substitution of the Central Me Atom in Ammonium Oxyfluorides on Phase Transitions: IR Spectroscopy Study
Разночтения заглавия :авие SCOPUS: Influence of the substitution of the central Me atom in ammonium oxyfluorides on phase transitions: IR spectroscopy study
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2011. - Vol. 53, Is. 4. - P840-844. - ISSN 1063-7834, DOI 10.1134/S1063783411040330
Примечания : Cited References: 7. - This study was supported by the Russian Foundation for Basic Research (project no. 08-02-00066-a).
Предметные рубрики: (NH4)(3)WO3F3
Аннотация: Comparative investigations of infrared absorption spectra of ion-molecular crystals of the ammonium-containing oxyfluorides (NH(4))(3)WO(3)F(3) and (NH(4))(3)MoO(3)F(3) have been performed. It has been found that the parameters of the vibrational spectra exhibit anomalies in the ranges of internal vibrations of the MeO(3)F(3) octahedral groups and ammonium ions near the phase transition temperatures. A comparative analysis of the IR spectra allows us to affirm that the studied phase transition in (NH(4))(3)WO(3)F(3) is primarily associated with the ordering of octahedral groups, whereas in (NH(4))(3)MoO(3)F(3), it is mainly due to the ordering of ammonium groups and the distortion of ammonium ions by the crystal environment.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gerasimova Y. V., Oreshonkov A. S., Vtyurin A. N., Ivanenko A. A., Isaenko L. I., Ershov A. E., Pogoreltsev E. I.
Заглавие : Infrared absorption investigation of the role of octahedral groups upon the phase transition in the Rb2KMoO3F3 crystal
Коллективы : Russian Foundation for Basic Research [12-02-31205_mol_a]; Ministry of Education and Science of the Russian Federation [8379]; Interdisciplinary Integration Project of the Siberian Branch of the Russian Academy of Science [28]
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2013. - Vol. 55, Is. 11. - P.2331-2334. - ISSN 1063-7834, DOI 10.1134/S1063783413110097
Примечания : Cited References: 10. - This study was supported by the Russian Foundation for Basic Research (project no. 12-02-31205_mol_a), the Ministry of Education and Science of the Russian Federation within the framework of the Russian Federal Target Program "Scientific and Scientific-Pedagogical Human Resources for the Innovative Russia" (agreement no. 8379), and the Interdisciplinary Integration Project of the Siberian Branch of the Russian Academy of Science No. 28.
Аннотация: The infrared absorption spectra of the oxyfluoride Rb2KMoO3F3 have been measured in the frequency range corresponding to stretching vibrations of the Mo-O anion octahedron with the purpose of clarifying their role in the phase transition. A semi-empirical calculation of two possible configurations of quasioctahedral MoO3F3 groups has been performed. The results of the investigations have demonstrated that some octahedra in the crystal structure change the local symmetry from C (3v) to C (2v) due to the phase transition (T = 197 K).
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gerasimova Y. V., Sofronova S. N., Gudim, I. A., Oreshonkov A. S., Vtyurin A. N., Ivanenko A. A.
Заглавие : Infrared absorption spectra of a Nd0.5Ho0.5Fe3(BO3)4 crystal
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2016. - Vol. 58, Is. 1. - P.155-159. - ISSN 10637834 (ISSN), DOI 10.1134/S106378341601011X
Примечания : Cited References: 15. - This study was supported in part by the Russian Foundation for Basic Research (project no. 12-02-00825).
Предметные рубрики: HoFe3(BO3)4
Аннотация: Infrared absorption spectra of a Nd0.5Ho0.5Fe3(BO3)4 crystal in the spectral range of 30–1700 cm–1 have been measured at temperatures from 6 to 300 K. The experimental spectra have been analyzed based on the semiempirical calculation of the lattice dynamics and the analysis of correlation diagrams of borate complexes. No changes associated with structural phase transitions have been detected in the temperature range of measurements; the effect of magnetic ordering on the infrared absorption spectra has not been observed.
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