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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boldyrev K. N., Pisarev R. V., Bezmaternykh L. N., Popova M. N.
Заглавие : Antiferromagnetic dichroism in a complex multisublattice magnetoelectric CuB2O4
Коллективы : Russian Academy of Sciences under the Programs for Basic Research; Russian Federation [MK-3521.2015.2], Russian Foundation for Basic Research [15-32-20613, 15-02-04222], Ministry of Education and Science of the Russian Federation [14.B25.0031.25]
Место публикации : Phys. Rev. Lett.: American Physical Society, 2015. - Vol. 114, Is. 24. - Ст.247210. - ISSN 0031, DOI 10.1103/PhysRevLett.114.247210. - ISSN 10797114(eISSN)
Примечания : Cited References:40. - This study was supported by the Russian Academy of Sciences under the Programs for Basic Research, by the President of the Russian Federation (Grant No. MK-3521.2015.2, K. N. B.), by the Russian Foundation for Basic Research (Grants No. 15-32-20613, K. N. B., and No. 15-02-04222, R. V. P.), and by the Ministry of Education and Science of the Russian Federation (Grant No. 14.B25.0031.25, R. V. P.).
Предметные рубрики: MAGNETIC SOLITON LATTICE
COPPER METABORATE
GYROTROPIC BIREFRINGENCE
SPECTROSCOPY
EXCITATIONS
TRANSITIONS
CRYSTALS
Cr2O3
FIELD
Аннотация: Magnetic control of the crystal chirality was announced by Saito et al. [Phys. Rev. Lett. 101, (2008)] on the ground of experiments in CuB2O4. This claim has raised a sharp dispute in the literature because it seemed to contradict the fundamental symmetry principles. We settle this dispute on the basis of a high-resolution optical spectroscopy study of excitonic transitions in CuB2O4. We find that a large sublattice-sensitive antiferromagnetic linear dichroism (LD) emerges at the Néel temperature TN=21 K and show how it could simulate a “magnetic-field control of the crystal chirality.” We prove that the discovered LD is related microscopically to the magnetic Davydov splitting. This LD is highly sensitive to subtle changes in the spin subsystems, which allowed us to observe a splitting of the phase transition into an incommensurate magnetic phase into two transitions (T∗1=8.5 and T∗2=7.9 K) and to suggest elliptical spiral structures below T∗1, instead of a simple circular helix proposed earlier.О магнитном контроле кристаллической хиральности сообщил Сайто и др. [Phys. Rev. Lett. 101, 117402 (2008)] на основании экспериментов в CuB2O4. Это требование вызвало резкий спор в литературе, потому что это казалось, противоречат основным принципам симметрии. Мы урегулировать этот спор на основе исследования с помощью оптической спектроскопии высокого разрешения экситонных переходов в CuB2O4. Мы считаем, что большой подрешетко-чувствительный антиферромагнитный линейный дихроизм (LD) возникает при температуре Нееля TN= 21 Kи показываем, как это может имитировать "контроль магнитным полем кристаллической хиральности." Мы докажем, что обнаруженный LD связанс микроскопическим магнитным Давыдовским расщеплением. Этот Л.Д. весьма чувствителен к тонким изменениям в спиновых подсистем, которые позволили нам наблюдать расщепление фазового перехода в несоизмеримы магнитная фаза в двух переходов (T*1= 8,5 и Т*2 = 7,9 К) и предположить эллиптическую спиральную структуру ниже T*1, вместо простой круговой спирали предложенный ранее.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boldyrev K. N., Stanislavchuk T. N., Sirenko A. A., Kamenskyi D., Bezmaternykh L. N., Popova M. N.
Заглавие : Bifurcations observed in the spectra of coupled electron-phonon modes in multiferroic PrFe3(BO3)4 subjected to a magnetic field [Electronic resource]
Место публикации : ArXiv. - 2016. - Ст.1609.02125
Вид и объем ресурса: Electronic text data
Примечания : Cited References: 19. - This research was supported by the Russian Scientific Foundation under Grant No 14-12-01033, the President of Russian Federation (MK-3521-2015.2, K.N.B.), and the U.S. Department of Energy under Grant No DE-FG02-07ER46382 (experiments at U4-IR beamline NSLS-BNL, T.N.S. and A.A.S.). The National Synchrotron Light Source is operated as a User Facility for he U.S. Department of Energy under Contract No. DE-AC02-98CH10886. Part of this work was supported by EMFL (contract No. 26211). M.N.P. thanks B.Z. Malkin helpful discussions.
Аннотация: We report on bifurcations effect mediated by the electron-phonon coupling in a concentrated rare-earth-containing antiferromagnet, observed in the spectra of coupled 4f-electron-phonon modes under the influence of an external magnetic field. The effect was observed in the low-temperature far-infrared (terahertz) reflection spectra of a multiferroic easy-axis antiferromagnet PrFe3(BO3)4 in magnetic fields Bext||c. Both paramagnetic and magnetically ordered phases (including a spin-flop one) were studied in magnetic fields up to 30 T. We show that the field behavior of the coupled modes can be successfully explained and modeled on the base of the equation derived in the frame of the theory of coupled electron-phonon modes, with the same field-independent electron-phonon interaction constant |W|=14.8cm−1.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boldyrev K. N., Stanislavchuk T. N., Sirenko A. A., Kamenskyi D., Bezmaternykh L. N., Popova M. N.
Заглавие : Bifurcations of coupled electron-phonon modes in an antiferromagnet subjected to a magnetic field
Место публикации : Phys. Rev. Lett.: American Physical Society, 2017. - Vol. 118, Is. 16. - Ст.167203. - ISSN 00319007 (ISSN), DOI 10.1103/PhysRevLett.118.167203
Примечания : Cited References: 26. - This research was supported by the Russian Scientific Foundation under Grant No. 14-12-01033, the President of Russian Federation (MK-3577.2017.2, K. N. B.), and the U.S. Department of Energy under Grant No. DE-FG02-07ER46382 (experiments at U4-IR beam line NSLS-BNL, T. N. S. and A. A. S.). The National Synchrotron Light Source is operated as a user facility for the U.S. Department of Energy under Contract No. DE-AC02-98CH10886. Part of this work was supported by EMFL (Contract No. 26211). M. N. P. thanks B. Z. Malkin and A. V. Popov for helpful discussions.
Ключевые слова (''Своб.индексиров.''): antiferromagnetic materials--bifurcation (mathematics)--electron-phonon interactions--electrons--magnetic fields--magnetism--temperature--antiferromagnetic crystals--bifurcation points--electron phonon couplings--electronic excitation--external magnetic field--field independents--low temperatures--reflection spectra--phonons
Аннотация: We report on a new effect caused by the electron-phonon coupling in a stoichiometric rare-earth antiferromagnetic crystal subjected to an external magnetic field, namely, the appearance of a nonzero gap in the spectrum of electronic excitations in an arbitrarily small field. The effect was registered in the low-temperature far-infrared (terahertz) reflection spectra of an easy-axis antiferromagnet PrFe3(BO3)4 in magnetic fields Bext-c. Both paramagnetic and magnetically ordered phases (including a spin-flop one) were studied in magnetic fields up to 30 T, and two bifurcation points were observed. We show that the field behavior of the coupled modes can be successfully explained and modeled on the basis of the equation derived in the framework of the theory of coupled electron-phonon modes, with the same field-independent electron-phonon interaction constant |W|=14.8 cm-1. © 2017 American Physical Society.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boldyrev K. N., Stanislavchuk T. N., Sirenko A. A., Bezmaternykh L. N., Popova M. N.
Заглавие : Coupling between phonon and crystal-field excitations in multiferroic PrFe3(BO3)4
Коллективы : Russian Scientific Foundation [14-12-01033]; President of Russian Federation [MK-1700.2013.2]; U.S. Department of Energy [DE-FG02-07ER46382, DE-AC02-98CH10886]
Место публикации : Phys. Rev. B: American Physical Society, 2014. - Vol. 90, Is. 12. - Ст.121101. - ISSN 1098-0121, DOI 10.1103/PhysRevB.90.121101. - ISSN 1550-235X
Примечания : Cited References: 35. - This research was supported by the Russian Scientific Foundation under Grant No. 14-12-01033, the President of Russian Federation (MK-1700.2013.2; K.N.B.), and the U.S. Department of Energy under Grant No. DE-FG02-07ER46382 (experiments at U4-IR beamline NSLS-BNL; T.N.S. and A.A.S.). The National Synchrotron Light Source is operated as a User Facility for the U.S. Department of Energy under Contract No. DE-AC02-98CH10886. M.N.P. thanks B. Z. Malkin for drawing her attention to the work [33] and for helpful discussions.
Предметные рубрики: MAGNETOELECTRIC PROPERTIES
GROUND-STATE
SM
Аннотация: Far-infrared reflection and ellipsometry measurements on multiferroic PrFe3(BO3)4 and SmFe3(BO3)4 single crystals were used to investigate the interaction between lattice phonons and electronic excitations associated with 4f crystal-field transitions. A temperature-dependent interference between two types of excitations was observed in PrFe3(BO3)4 in which the frequency of 4f crystal-field electronic excitation of Pr3+ falls into the TO-LO frequency interval of the optical phonon mode near 50 cm−1 (1.5 THz). Experimental data were explained on the basis of a theoretical model of coupled electron-phonon modes. The fitting procedure revealed the value 14.8 cm−1 for the electron-phonon coupling constant. This rather large value points to an essential role played by the electron-phonon interaction in the physics of multiferroics.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Popova M. N., Malkin B. Z., Boldyrev K. N., Stanislavchuk T. N., Erofeev D. A., Temerov V. L., Gudim, I. A.
Заглавие : Evidence for a collinear easy-plane magnetic structure of multiferroic EuFe3(BO3)4: Spectroscopic and theoretical studies
Место публикации : Phys. Rev. B: American Physical Society, 2016. - Vol. 94, Is. 18. - Ст.184418. - ISSN 10980121 (ISSN), DOI 10.1103/PhysRevB.94.184418
Примечания : Cited References: 49. - This work was supported by the Russian Science Foundation under Grant No. 14-12-01033. I.A.G. and V.L.T. are grateful to L. N. Bezmaternykh for useful comments concerning the crystal growth, to M. S. Molokeev for the XRD characterization of the samples, and to the Russian Foundation for Basic Research for a financial support (Grants No. 13-02-12442 and No. 14-02-00307a).
Аннотация: We performed high-resolution polarized optical transmission spectroscopy and theoretical studies of multiferroic EuFe3(BO3)4 single crystals in the three phases: paramagnetic R32(T˃Ts=84K) and P3121(Ts˃T˃TN=34K), and antiferromagnetic (T˂TN) ones. The analysis of the spectra reveals interesting details of the magnetic structure, namely, a collinear arrangement of the iron magnetic moments along the C2 symmetry axis in the ab crystallographic plane of EuFe3(BO3)4 below TN. Spectral signatures of the phase transitions and the spin-phonon interaction are observed and discussed. Reliable crystal-field and exchange-interaction parameters are obtained and used to model the magnetic susceptibility of the compound. The results of detailed calculations of the electric polarization of EuFe3(BO3)4 in the R32 phase are presented, and mechanisms of the magnetoelectric response are discussed. We detect a strong effect of impurities (that enter the crystal from a flux in the course of the crystal growth) on the structural phase-transition temperature and demonstrate a coexistence of both R32 and P3121 phases down to the lowest temperatures in a EuFe3(BO3)4 crystal grown with the Bi2Mo3O12 based flux, due to inhomogeneous distribution of impurity Bi3+ ions. Our study can be considered as a demonstration of the abilities of optical spectroscopy in delivering new information on a magnetic compound, even in the case when other methods fail. © 2016 American Physical Society.
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6.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Boldyrev K. N., Popova M. N., Pisarev R. V., Bezmaternykh L. N.
Заглавие : Exotic spin structures and phase transitions in a complex magnetoelectric CuB2O4 as evidenced by optical linear dichroism studies
Коллективы : International Conference on Magnetism
Место публикации : 20th Int. Сonf. on Magnetism (ICM-2015): book of abstracts. - 2015. - Ст.TH.C-P107
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Popova M. N., Boldyrev K. N., Petit P. O., Viana B., Bezmaternykh L. N.
Заглавие : High-resolution spectroscopy of YbAl(3)(BO(3))(4) stoichiometric nonlinear laser crystals
Коллективы :
Разночтения заглавия :авие SCOPUS: High-resolution spectroscopy of YbAl3(BO3) 4 stoichiometric nonlinear laser crystals
Место публикации : J. Phys.: Condens. Matter: IOP PUBLISHING LTD, 2008. - Vol. 20, Is. 45. - Ст.455210. - ISSN 0953-8984, DOI 10.1088/0953-8984/20/45/455210
Примечания : Cited References: 20. - The authors thank E Antic-Fidancev for helpful discussions on the 'barycenter curves', P Aschehoug for technical assistance, and B Mavrin for assistance in Raman spectra measurements. This work was supported by the CNRS-RAS exchange program (project No. 21241), by the Russian Foundation for Basic Research (Grants Nos 07-02-01185 and 06-02-16088), and by the Russian Academy of Sciences under the Programs for Basic Research.
Предметные рубрики: YB-YAB LASER
GROWTH
FREQUENCY
BORATE
Ключевые слова (''Своб.индексиров.''): crystal symmetry--crystals--light emission--light sources--luminescence--spectroscopic analysis--ytterbium--electronic levels--high resolutions--luminescence spectroscopies--main lines--nonlinear laser crystals--raman spectrums--vibronic structures--weak lines--single crystals
Аннотация: We present temperature-dependent high-resolution polarized transmittance spectroscopy as well as luminescence spectroscopy of YbAl(3)(BO(3))(4) single crystals. Positions and symmetries of all the Yb(3+) crystal-field electronic levels have been found from the analysis of the spectra. Near the main line of the optical transition (2)F(7/2)(0) - (2)F(5/2)(0) we observe a lot of narrow weak lines. These lines point to the presence of several different distorted sites of Yb(3+). We analyze the possible origin of the distorted sites. Vibronic structure in transmittance and luminescence spectra was observed and compared with room-temperature Raman spectra.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Popova M. N., Malkin B. Z., Stanislavchuk T. N., Chukalina E. P., Boldyrev K. N., Gudim, I. A.
Заглавие : High-resolution spectroscopy, crystal-field calculations, and quadrupole helix chirality of DyFe3(BO3)(4)
Коллективы : Congress on Spectroscopy
Место публикации : XXV Congress on Spectroscopy: E D P Sciences, 2017. - Vol. 132. - Ст.03041. - (EPJ Web of Conferences). - ISSN 2100-014X, DOI 10.1051/epjconf/201713203041
Примечания : Cited References:2
Аннотация: High-resolution polarized transmission spectra of DyFe3(BO3)(4) single crystals were investigated in broad spectral (10-23000 cm(-1)) and temperature (3.5-300 K) ranges. Energies of the dysprosium levels in the paramagnetic and antiferromagnetic phases were determined. On the basis of these data and preliminary calculations in the frameworks of the exchange-charge model, we determined the crystal-field and Dy-Fe exchange interaction parameters of the Dy3+ ions at sites with the point C-2 symmetry corresponding to the enantiomorphic P3(1)21 and P3(2)21 space groups. The values of electronic quadrupole moments of the Dy3+ ions were calculated, which enabled us to interpret results of the work [Usui et al., Nature Mater. 13, 611 (2014)] on the observation of domains of different quadrupole chirality in DyFe3(BO3)(4).
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9.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Boldyrev K.N., Popova M. N., Bezmaternykh L. N., Bettinelli M., Loiseau P., Leonyuk N. I.
Заглавие : Higt-resolution spectroscopy of Yb3+ centers in RAl3(BO3)4:Yb single crystals
Коллективы : Excited States of Transition Elements and Workshop on Luminescence
Место публикации : Excit. St. of Trans. Elem. and Worksh. on Luminesc.: ESTE2010: book of abstracts. - Wrocław: Wydział Chemii Uniwersytetu Wrocławskiego, 2010. - Ст.Tu-7
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10.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Molchanova A. D., Boldyrev K. N., Moshkina E. M., Bezmaternykh L. N.
Заглавие : Investigation of manganese-doped copper metaborate Cu1-xMnxB2O4 by linear antiferromagnetic dichroism
Коллективы : "Магнитные материалы. Новые технологии", Байкальская международная конференция, "Magnetic materials. New tecnologies", Baikal International Conference, Байкальская международная конференция "Магнитные материалы. Новые технологии", Иркутский государственный университет
Место публикации : Магнитные материалы. Новые технологии: тез. докл. VII Байкал. Междунар. конф./ Иркутский гос. ун-т. - Иркутск, 2016. - P.166. - ISBN 978-591-345-152-1: тез. докл. VII Байкал. Междунар. конф. BICMM-2016/ "Magnetic materials. New tecnologies", Baikal International Conference (7 ; 2016 ; Aug. ; 22–26 ; Listvyanka, Irkutsk region), Иркутский гос. ун-т; чл. прогр. ком.: Р. С. Исхаков, С. С. Аплеснин, С. Г. Овчинников. - ISBN 978-591-345-152-1
Примечания : Библиогр.: 4 назв. - This work was supported by the Russian Foundation for Basic Research (Grant No 15-02-07451a) and the President of the Russian Federation (Grant No MK-3521-2015.2)
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