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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krylov A. S., Shipilovskikh S. A., Krylova S. N., Slyusarenko N. V., Timofeeva M., Kenzhebayeva Yu. A., Bachinin S. V., Yushina I. D., Cherepakhin A. V., Shestakov N. P., Nemtsev I. V., Vtyurin A. N., Milichko V. A.
Заглавие : Application of DUT-4 MOF structure switching for optical and electrical humidity sensing
Колич.характеристики :6 с
Место публикации : Dalton Trans. - 2024. - Vol. 53, Is. 8. - P.3459-3464. - ISSN 14779226 (ISSN), DOI 10.1039/D4DT00038B. - ISSN 14779234 (eISSN)
Примечания : Cited References: 37. - The authors acknowledge the support by the state assignment of the Kirensky Institute of Physics FRC KSC SB RAS, also this work was financially supported by the RFBR (Russian Foundation for Basic Research), project no. 21-52-12018. S. A. S. acknowledges the financial support by the Russian Science Foundation (chemical part, Grant No. 22-73-10069 "Design and application of flexible metal organic frameworks for photonics devices"). V.A.M. acknowledges the Priority 2030 Federal Academic Leadership Program Ivan Sergeev (student in ITMO Univ.) for supporting in IV curve analysis. Raman, FTIR and SEM experiments were performed in the Center for Common Use of the Krasnoyarsk Scientific Center SB RAS (Krasnoyarsk, Russia)
Аннотация: The threshold structural transformation of the DUT-4 metal–organic framework (MOF) from an ordered to distorted phase during exposure to ambient conditions has been revealed. The in situ X-ray diffraction analysis, in situ Raman and FTIR spectroscopy, scanning electron microscopy and synchronous thermal analysis have been used for investigation. The reversible effect of exposure time and humidity on such a phase transition has been confirmed. We also demonstrated that the observed phase transition correlated well with changes in the optical and electronic properties of DUT-4, paving the way to a new family of MOF-based phase change materials for optoelectronic applications.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mikhaleva E. A., Flerov I. N., Gorev M. V., Molokeev M. S., Cherepakhin A. V., Kartashev A. V., Mikhashenok N. V., Sablina K. A.
Заглавие : Caloric characteristics of PbTiO3 in the temperature range of the ferroelectric phase transition
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 54, Is. 9. - P.1832-1840. - ISSN 1063-7834, DOI 10.1134/S1063783412090181
Примечания : Cited References: 31. - This study was supported by the Russian Foundation for Basic Research (project no. 12-08-00079) and the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation (grant no. NSh-4828.2012.2).
Предметные рубрики: SINGLE-CRYSTALS
LEAD TITANATE
DIELECTRIC PROPERTIES
SOLID-SOLUTIONS
PRESSURE
PEROVSKITES
DEPENDENCE
BEHAVIOR
HEAT
Аннотация: The heat capacity and thermal expansion of the PbTiO3 ceramic sample have been measured in the temperature range 80–970 K. The electrocaloric and barocaloric efficiencies of lead titanate in the ferroelectric phase transition range have been investigated by analyzing the experimental data in terms of the thermodynamic theory of phase transitions, the electrical equation of state P(T, E), the Pippard equation, and the S(T, p) diagram.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Mikhaleva E. A., Kartashev A. V., Gorev M. V., Cherepakhin A. V., Sablina K. A., Mikhashenok N. V., Flerov I. N.
Заглавие : Caloric effects and phase transitions in ferroelectric-ferromagnetic composites (x) La0.7Pb0.3MnO3 – (1-x) PbTiO3
Коллективы : Functional Materials and Nanotechnologies
Место публикации : International Conference “Functional materials and nanotechnologies” FM&NT 2012. - 2012. - P.82
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mikhaleva E. A., Flerov I. N., Kartashev A. V., Gorev M. V., Cherepakhin A. V., Sablina K. A., Mikhashenok N. V., Volkov N. V., Shabanov A. V.
Заглавие : Caloric effects and phase transitions in ferromagnetic-ferroelectric composites xLa(0.7)Pb(0.3)MnO(3)-(1-x)PbTiO3
Коллективы : Russian Foundation for Basic Research [12-02-31253-mol-a]; Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" [N 8379]; Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools [NSh-4828.2012.2]
Место публикации : J. Mater. Res. - 2013. - Vol. 28, Is. 24. - P.3322-3331. - ISSN 0884-2914, DOI 10.1557/jmr.2013.360. - ISSN 2044-5326
Примечания : Cited References: 24. - This study was supported in parts by The Russian Foundation for Basic Research (Grant No. 12-02-31253-mol-a), Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" (N 8379), and Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools (Grant NO. NSh-4828.2012.2). Dr. Maxim S. Molokeev is acknowledged for the x-ray characterization of the samples.
Предметные рубрики: PRESSURE
TEMPERATURE
Аннотация: Ceramic volumetric composites xLa(0.7)Pb(0.3)MnO(3)-(1-x)PbTiO3 (x = 0.18 and 0.85) were prepared. X-ray investigations have shown that rather low sintering temperature (800 degrees C) has allowed us to avoid the reaction and interdiffusion between two initial phases. Heat capacity, thermal expansion, and intensive magnetocaloric effect were measured in a wide temperature range. The sample composition has a low influence on temperatures of the ferromagnetic and ferroelectric phase transitions in composites. Electro- and barocaloric effects were determined by analysis in the framework of thermodynamic theory, electric equation of state, Maxwell relationships, and entropy-temperature-pressure phase diagram. Multicaloric efficiency of composites is discussed and compared with that of initial La0.7Pb0.3MnO3 and PbTiO3 compounds. Variation of a relationship between components can significantly increase both barocaloric and magnetocaloric efficiency of compositional material due to the mechanical stress appearing between grains of different ferroic phases under magnetic field.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Cherepakhin A. V., Zaitsev A. I., Zamkov A. V.
Заглавие : Optical and nonlinear optical properties of α-SrB4O7
Коллективы : International Conference on Crystallogenesis and Mineralogy (3; Sept. 27 – Oct. 1, 2013; Novosibirsk)
Место публикации : 3 Int. Conf. “Crystallogenesis and mineralogy”: Abstracts Vol. - Новосибирск: Изд-во СО РАН, 2013. - С. 71-72. - ISBN 978-5-7692-1320-5
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Churilov G. N., Nikolaev N. S., Osipova I. V., Cherepakhin A. V., Nemtsev I. V., Velikanov D. A., Andyuseva V. G.
Заглавие : Core-shell Nanosize Particles Mg@Ni: Synthesis and Properties
Место публикации : J. Sib. Fed. Univ. Math. Phys. - 2019. - Vol. 12, Is. 1. - P.28-35. - ISSN 1997-1397, DOI 10.17516/1997-1397-2019-12-1-28-35; \b Журнал СФУ. Математика и физика. - ISSN 2313-6022(eISSN)
Примечания : Cited References: 12
Ключевые слова (''Своб.индексиров.''): core-shell--nanopartials--nickel-magnesium--synthesis in plasma--surface coating--частицы ядро–оболочка--наночастицы--никель-магниевые частицы--плазмохимический синтез--покрытие поверхности частицы
Аннотация: In this paper, we study particles with metallic core (magnesium) - metal shell (nickel) structure, synthesized in metal-containing plasma of high frequency arc discharge. X-ray diffraction analysis, X-ray fluorescence analysis and scanning electron microscopy show that the particles have a uniform nickel shell, which is also indirectly confirmed by comparing the results of hydrogenation of Mg and Mg@Ni particles. Measurement of volume magnetization indicates that shell thickness of most particles is not more than 22 nm.В данной работе исследованы частицы со структурой металлическое ядро (магний) - металлическая оболочка (никель), полученные в металлсодержащей высокочастотной плазме дугового разряда. Методами рентгенофазового анализа, рентгенофлуоресцентного анализа, сканирующей электронной микроскопии показано, что частицы имеют сплошную никелевую оболочку, что также косвенно подтверждается сравнением результатов гидрирования частиц Mg и Mg@Ni. С помощью измерений объемной намагниченности установлено, что наибольшая часть частиц имеет толщину оболочек не более 22 нм.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Isakova V. G., Osipova I. V., Dudnik A. I., Cherepakhin A. V., Zharikova N. V., Nemtsev I. V., Volochaev M. N.
Заглавие : Decoration of carbon nanomaterial powders with dispersed platinum metal particles
Коллективы : Center for Shared Use of the Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences
Место публикации : Russ. J. Appl. Chem. - 2018. - Vol. 91, Is. 7. - P.1209-1216. - ISSN 1070-4272, DOI 10.1134/S1070427218070212. - ISSN 1608-3296(eISSN)
Примечания : Cited References: 22. - The study was performed with the support and equipment of the Center for Shared Use of the Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences.
Предметные рубрики: NANOPARTICLES
PALLADIUM
FULLERENE
ELECTRODE
NANOTUBES
OXIDATION
Ключевые слова (''Своб.индексиров.''): carbon nanomaterials--platinum metal nanoparticles--in situ one-step method
Аннотация: Carbon nanomaterials (fullerite, detonation nanodiamonds, Taunit, fullerenol, fullerene-containing black) were decorated with platinum group metal nanoparticles in situ in one step by low-temperature combustion (~250–270°С) of a powdered mixture of platinum metal acetylacetonate [Pt-M(асас)n, Pt-М = Pt(II), Pd(II), Rh(III), Ir(III), acac = CH3COCHCOCH3, n is the oxidation state of Pt-М] with carbon nanomaterials in air. As shown by thermal analysis, the process is based on thermal oxidative degradation of the organometallic complex, catalyzed by carbon nanomaterials, with oxidation (combustion) of the organic moiety and release of the metal into the condensed phase. The thermal process in an open system occurs in the glowing mode (210–250°С); the size of the nanoparticles formed is 7–30 nm. Under the conditions restricting the air access to the reaction mixture and free outflow of gaseous products formed by oxidation of acac ligands, the nanoparticle size decreases to 3–10 nm. The particle size depends on the metal amount in the initial powder mixture and on the support morphology.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Semenok D. V., Troyan I. A., Sadakov A. V., Zhou D., Galasso M., Kvashnin A. G., Ivanova A. G., Kruglov I. A., Bykov A. A., Terent'ev K. Yu., Cherepakhin A. V., Sobolevskiy O. A., Pervakov K. S., Seregin A. Y., Helm T., Forster T., Grockowiak A. D., Tozer S. W., Nakamoto Y., Shimizu K., Pudalov V. M., Lyubutin I. S., Oganov A. R.
Заглавие : Effect of magnetic impurities on superconductivity in LaH10
Место публикации : Adv. Mater. - 2022. - Vol. 34, Is. 42. - Ст.2204038. - ISSN 09359648 (ISSN), DOI 10.1002/adma.202204038. - ISSN 15214095 (eISSN)
Примечания : Cited References: 106. - In situ X-ray diffraction experiments at high pressure were performed on SPring-8, station BL10XU, Sayo, Japan (proposal No. 2020A0576). This work was supported by JSPS KAKENHI Grant Number 20H05644. Low-pressure studies were carried out on a synchrotron source of the Kurchatov institute (KISI-Kurchatov), station RKFM. The high-pressure experiments were supported by the Ministry of Science and Higher Education of the Russian Federation within the state assignment of the FSRC Crystallography and Photonics of the RAS. I.A.T. was supported by the Russian Science Foundation, project No. 22-12-00163. A.R.O. thanks the Russian Science Foundation (grant 19-72-30043). D.V.S. thanks the Russian Foundation for Basic Research (project 20-32-90099). I.A.K. thanks the Russian Science Foundation (grant No. 21-73-10261) for the financial support of the anharmonic phonon density of states calculations and molecular dynamics simulations. SEM, XRF, and XRD studies of the initial alloys were performed using the equipment of the Shared Research Center FSRC Crystallography and Photonics of the RAS. I.A.T. and A.G.I. acknowledge the use of the facilities of the Center for Collective Use “Accelerator Center for Neutron Research of the Structure of Substance and Nuclear Medicine” of the INR RAS for high-pressure cell preparation. The research used resources of the LPI Shared Facility Center. V.M.P acknowledge the support of the state assignment of the Ministry of Science and Higher Education of the Russian Federation (Project No. 0023-2019-0005) and A.V.S. and O.A.S. acknowledge the support of the Russian Science Foundation, grant 22-22-00570. K.S.P. thanks the Russian Foundation for Basic Research (project 19-02-00888). I.A.K. thanks the Russian Science Foundation (grant No. 19-73-00237) for the financial support of the development of T-USPEX method and anharmonic phonon density of states calculation algorithm. S.W.T was supported by NSF Cooperative Agreement No. DMR-1157490/1644779 and by the State of Florida. A.D.G. was supported by T.H. and T.F. funding. The authors acknowledge the support of the HLD at HZDR, member of the European Magnetic Field Laboratory (EMFL). The authors also thank Igor Grishin (Skoltech) for proofreading the manuscript, and Dr. C. Tantardini (University of Tromsø) for calculations using the virtual crystal approximation, and Dr. E. Talantsev (IMP RAS) for useful discussions
Аннотация: Polyhydrides are a novel class of superconducting materials with extremely high critical parameters, which is very promising for sensor applications. On the other hand, a complete experimental study of the best so far known superconductor, lanthanum superhydride LaH10, encounters a serious complication because of the large upper critical magnetic field HC2(0), exceeding 120–160 T. It is found that partial replacement of La atoms by magnetic Nd atoms results in significant suppression of superconductivity in LaH10: each at% of Nd causes a decrease in TC by 10–11 K, helping to control the critical parameters of this compound. Strong pulsed magnetic fields up to 68 T are used to study the Hall effect, magnetoresistance, and the magnetic phase diagram of ternary metal polyhydrides for the first time. Surprisingly, (La,Nd)H10 demonstrates completely linear HC2(T) ∝ |T – TC|, which calls into question the applicability of the Werthamer–Helfand–Hohenberg model for polyhydrides. The suppression of superconductivity in LaH10 by magnetic Nd atoms and the robustness of TC with respect to nonmagnetic impurities (e.g., Y, Al, C) under Anderson's theorem gives new experimental evidence of the isotropic (s-wave) character of conventional electron–phonon pairing in lanthanum decahydride.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kashkina L. V., Stebeleva O. P., Petrakovskaya E. A., Cherepakhin A. V.
Заглавие : Efficiency of high energy impact in synthesis of coal-water suspensions
Коллективы : Carbon: Fundamental Problem, Material Science, Technology - International Conference
Место публикации : Mater. Today: Proc. - 2018. - Vol. 5, Is. 12, Pt. 3. - P.26033-26037. - ISSN 2214-7853, DOI 10.1016/j.matpr.2018.08.024
Примечания : Cited References: 18
Ключевые слова (''Своб.индексиров.''): coal-water slurry--cavitation--nanocarbon--man-made gas emission
Аннотация: A study of thermophysical and ecological properties of highly loaded (50% mass.) coal-water slurry based on Kansk-Achinsk brown coal and distilled water (coal-water slurry fuel – CWSF) with exposure of used water to cavitation-treatment, microwave processing of coal powder, T-900 nanocarbon additions is presented. The study shows that under the conditions of this experiment the thermal physical properties of CWSF are most affected by the use of cavitation-activated water.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : V'yunyshev A. M., Aleksandrovskii A. S., Cherepakhin A. V., Rovskii V. E., Zaitsev A. I., Zamkov A. V.
Заглавие : Frequency doubling of ultrashort pulses in a nonlinear photonic strontium tetraborate crystal
Коллективы : All-Russian Youth School Seminar on Innovative Aspects of Basic Research on Urgent Problems of Physics
Место публикации : Bull. Lebedev Phys. Inst. - 2010. - Vol. 37, Is. 3. - P.85-86. - ISSN 1068-3356, DOI 10.3103/S106833561003005X
Примечания : Cited References: 6
Ключевые слова (''Своб.индексиров.''): second harmonic generation--ultrashort pulses--nonlinear photonic crystal--nonlinear photonic crystal--second harmonic generation--ultrashort pulses
Аннотация: The second harmonic generation (SHG) of the femtosecond titanium-sapphire laser radiation was experimentally studied in the mode of nonlinear diffraction in the nonlinear photonic strontium tetraborate crystal. The spectrum of reciprocal lattice vectors of domain structures includes components responsible for the efficient frequency-tunable SHG in the spectral range of 355-510 nm. The maximum SHG efficiency was 1.9%. The SHG spectrum narrowing does not exceed 10-20%. The measured spectral dependence of the nonlinear diffraction angle is in good agreement with calculation.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Radionov N. V., Zaitsev A. I., Cherepakhin A. V., Zamkov A. V.
Заглавие : Genesis and conformation of polar twin structures in czochralski grown α-SrB4O7 crystals
Коллективы : International Conference on Crystallogenesis and Mineralogy (3; Sept. 27 – Oct. 1, 2013; Novosibirsk)
Место публикации : 3 Int. Conf. “Crystallogenesis and mineralogy”: Abstracts Vol. - Новосибирск: Изд-во СО РАН, 2013. - С. 47-48. - ISBN 978-5-7692-1320-5
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Moiseev N. V., Popov P. A., Solomennik V. D., Zaitsev A. I., Cherepakhin A. V.
Заглавие : Heat capacity and thermodynamic properties of crystalline SrB4O7
Место публикации : Inorg. Mater.: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 48, Is. 5. - P.504-507. - ISSN 0020-1685, DOI 10.1134/S0020168512050123
Примечания : Cited References: 24. - This work was supported in part by the RF President's Grants Council (grant no. NSh-4645.2010.2), the RF Ministry of Education and Science (analytical departmental targeted program Development of the Scientific Potential of Higher Education Institutions, grant no. RNP 2.1.1/10747), Bryansk State University (project no. 1.1.11), and the Physical Sciences Division of the Russian Academy of Sciences (Physics of Advanced Materials and Structures Program, project no. 2.5.2).
Предметные рубрики: STRONTIUM TETRABORATE
SINGLE-CRYSTALS
LUMINESCENCE
Аннотация: The heat capacity of a strontium tetraborate (SrB4O7) single crystal has been determined in the temperature range 55-300 K by adiabatic calorimetry, and its Debye characteristic temperature, entropy change, enthalpy increment, and phonon mean free path have been calculated as functions of temperature.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Churilov G. N., Osipova I. V., Tomashevich Y. V., Glushchenko G. A., Fedorov A. S., Popov Z. I., Bulina N. V., Vereshchagin S. N., Zhizhaev A. M., Cherepakhin A. V.
Заглавие : Hydrogenation of the Nanopowders That Form in a Carbon-Helium Plasma Stream during the Introduction of Ni and Mg
Разночтения заглавия :авие SCOPUS: Hydrogenation of the nanopowders that form in a carbon-helium plasma stream during the introduction of ni and Mg
Место публикации : J. Exp. Theor. Phys.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2011. - Vol. 113, Is. 6. - P1057-1062. - ISSN 1063-7761, DOI 10.1134/S1063776111140135
Примечания : Cited References: 9. - This work was supported by the Russian Foundation for Basic Research, project no. 09-03-00383-a.
Ключевые слова (''Своб.индексиров.''): carbon atoms--composite nanoparticles--high temperature--hydrogen absorption--hydrogen atoms--island growth--magnesium hydride--magnesium surface--nano powders--nickel atoms--plasma streams--atoms--carbon--composite materials--density functional theory--electron beams--helium--hydrogen--hydrogenation--nanoparticles--nickel--scanning electron microscopy--thermogravimetric analysis--x ray photoelectron spectroscopy--magnesium
Аннотация: Composite nanoparticles consisting of magnesium, nickel, and carbon atoms are studied both theoretically and experimentally. The calculations performed in terms of the density functional theory show that the jump frequency of hydrogen atoms in nickel-containing magnesium hydride increases substantially near impurity nickel atoms; as a result, the rate of hydrogen absorption by magnesium also increases. Nickel on the magnesium surface is shown to be absorbed via an island growth mechanism. Composite Mg-C, Ni-C, and Mg-Ni-C powders are produced by plasmachemical synthesis in a carbon-helium plasma stream. Hydrogen is introduced into a chamber during synthesis. It is found by X-ray photoelectron spectroscopy and thermogravimetric analysis that, among these three composites, only Mg-Ni-C contains magnesium fixed in the MgH2 compound. The process of such "ultrarapid" hydrogenation of magnesium, which occurs in the time of formation of composite nanoparticles, can be explained by the catalytic action of nickel, which is enhanced by a high temperature. Scanning electron microscopy micrographs demonstrate the dynamics of the dehydrogenation of Mg-Ni-C composite nanoparticles in heating by an electron beam.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Nemtsev I. V., Shabanova O. V., Tambasov I. A., Ivanenko A. A., Cherepakhin A. V., Shestakov N. P., Zyryanov V. Ya.
Заглавие : Methods to determine crystal lattice parameters of opal-like structures
Место публикации : J. Struct. Chem. - 2021. - Vol. 62, Is. 4. - P.641-650. - ISSN 00224766 (ISSN), DOI 10.1134/S0022476621040168
Примечания : Cited References: 45. - The research was carried out within the state assignment of the Ministry of Science and Higher Education of the Russian Federation (theme No. AAAA-A18-118041990041-8)
Аннотация: Series of high-quality spherical poly(methyl methacrylate) particles with a polydispersity less than 5% are prepared by chain-growth emulsifier-free controlled radical emulsion polymerization of methyl methacrylate in water. The average diameters in the series varied from 237 nm to 447 nm. The physico-chemical properties of obtained submicrospheres can be varied to make them more stable and stronger by a modified classical synthesis technology whereby 4-10 vol.% of dispersion medium is replaced by acetone. 2D and 3D photonic crystal structures, opals, are prepared from poly(methyl methacrylate) submicrospheres. The crystal structure of the opals is studied by IR spectroscopy and scanning electron microscopy. According to the spectroscopic data, the poly(methyl methacrylate) particles contain significant amounts of water whose evaporation leads to the shrinkage of the spheres. The stereoregularity of the synthesized polymer is studied, the glass-transition temperatures of obtained samples are determined.
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15.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Zaitsev A. I., Cherepakhin A. V., Radionov N. V., Zamkov A. V.
Заглавие : Morphology of a polar twin structure in Czochralski grown α-SrB4O7 crystals
Коллективы : International Conference on Crystal Growth and Epitaxy (17; 2013 ; Aug. ; 11-16; Warsaw, Poland)
Место публикации : 17th Int. Conf. on Crystal Growth and Epitaxy (ICCGE-17): Book of Abstracts. - 2013. - P.444-445
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zaitsev A. I., Radionov N. V., Cherepakhin A. V., Vasiliev A. D., Zamkov A. V.
Заглавие : Morphology of the polar twin structure in Czochralski grown α-SrB4O7 crystals
Коллективы : Grant of the President of the Russian Federation for the support of leading scientific schools [SS-924.2014.2]
Место публикации : J. Cryst. Growth: Elsevier Science, 2015. - Vol. 416. - P.17-20. - ISSN 0022, DOI 10.1016/j.jcrysgro.2015.01.004. - ISSN 18735002(eISSN)
Примечания : Cited References:15. - This study is supported by Grant of the President of the Russian Federation for the support of leading scientific schools SS-924.2014.2.
Предметные рубрики: TETRABORATE
STRONTIUM
SRB4O7
Ключевые слова (''Своб.индексиров.''): optical microscopy--czochralski method--borates--growth twins--nonlinear--optic materials
Аннотация: The arrangement of a polar twin structure in Czochralski grown α-SrB4O7 crystals has been investigated. The transversal twin boundaries are stretched along [ 1 0 1 ] and [ 1 0 0 ] directions. The lateral twin boundaries are parallel to ( 0 1 0 ) plane. The twin structures have an extension up to centimeter size in all directions. Supposedly, they originate from polysynthetic polar microtwins revealed to form in ( 1 0 1 ¯ ) and ( 1 ¯ 0 1 ¯ ) growth pyramids. The dimensions, planarity and thickness stability of each individual twin are favorable for organizing quasi-phase matching conditions for nonlinear optical doubling of high-aperture beams.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Nemtsev I. V., Shabanova, Olga V., Shestakov N. P., Cherepakhin A. V., Zyryanov V. Ya.
Заглавие : Morphology stability of polymethylmethacrylate nanospheres formed in water-acetone dispersion medium
Место публикации : Appl. Phys. A. - 2019. - Vol. 125, Is. 10. - Ст.738. - ISSN 0947-8396, DOI 10.1007/s00339-019-3036-4. - ISSN 1432-0630(eISSN)
Примечания : Cited References: 93
Предметные рубрики: OPAL PHOTONIC CRYSTALS
POLY(METHYL METHACRYLATE)
UP-CONVERSION
Аннотация: The aim of this study is to develop a manufacturing technique of polymethylmethacrylate (PMMA) nanospheres to produce a more stable opal template. Water-acetone mixture was used as a dispersion medium to synthesize a PMMA opal structure. Morphology features, IR vibrational spectra and glass transition temperatures of the PMMA nanospheres formed in the water-acetone dispersion medium (nanospheres A) have been studied comparing with the same prepared in distilled water solution without acetone (nanospheres B). A dependence of a shrinkage degree of the nanoparticles on the acetone volume has been investigated. It has been revealed that under an electron beam action the shrinkage degree of the nanospheres A is in the range of 7-16% while the shrinkage of the nanospheres B is 18-25% at the same conditions. The nanospheres A are less flexible and soft as compared to the nanospheres B. Additionally, an ability of the PMMA nanoparticles fabricated in the water-acetone dispersion medium to form the ordered opal structures is demonstrated to be the similar to the nanospheres B.
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18.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Aleksandrovsky A. S., Zaitsev A. I., Cherepakhin A. V., Vyunishev A. M., Rovsky V. E., Slabko V. V.
Заглавие : Nonlinear photonic crystals of strontium tetraborate: Properties and conversion of radiation
Место публикации : Proceedings of SPIE - The International Society for Optical Engineering. - 2010. - Vol. 7728: Nonlinear Optics and Applications IV (12 April 2010 through 15 April 2010, Brussels, ) Conference code: 81010. - ISBN 0277786X (ISSN); 9780819482013 (ISBN), DOI 10.1117/12.853713
Ключевые слова (''Своб.индексиров.''): nonlinear photonic crystal--second harmonic generation--strontium tetraborate--as-grown--average power--domain shape--efficiency enhancement--femtoseconds--fourth harmonics--nonlinear diffraction--nonlinear optical process--nonlinear photonic crystals--quasi-phase-matched--second harmonic generation--tetraborate--ti: sapphire laser--ti:sapphire oscillators--ferroelectricity--harmonic analysis--nonlinear optics--optical materials--photonic crystals--sapphire--strontium--harmonic generation
Аннотация: Random nonlinear photonic crystal (NPC) structures formed by as-grown domains in a non-ferroelectric strontium tetraborate (SBO) are investigated. The domain shape and orientation are similar to those in ferroelectric KTP. Nonlinear diffraction is the simplest way to detect, evaluate and characterize these structures. Reciprocal superlattice vectors spectra of NPC in SBO are very wide and enable broadband efficiency enhancement of nonlinear optical processes. Second harmonic (SH) generation of femtosecond Ti:sapphire oscillator radiation with 1.9% efficiency is obtained using nonlinear diffraction geometry. Random quasi phase matched generation at the wavelengths of fourth harmonic of Ti:sapphire laser is obtained with average power up to 1 ?W. © 2010 Copyright SPIE - The International Society for Optical Engineering.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Cherepakhin A. V., Zaitsev A. I., Aleksandrovsky A. S., Zamkov A. V.
Заглавие : Optical and nonlinear optical properties of orthorhombic BiB3O6
Место публикации : Opt. Mater.: Elsevier Science BV, 2012. - Vol. 34, Is. 5. - P.790-792. - ISSN 0925-3467, DOI 10.1016/j.optmat.2011.11.004
Примечания : Cited References: 13. - The work was supported by Ministry of Education and Science of Russian Federation (Contract 16.740.11.0150), Grant of President of Russian Federation for support of leading scientific schools No. SS-4645.2010.2, Grant No. RNP.2.1.1.3455, Project 3.9.1 of PSB RAS, and Projects No. 27.1 and No. 5 of SB RAS.
Предметные рубрики: BISMUTH BORATE BIB3O6
CRYSTAL
LASER
GENERATION
GROWTH
BIBO
Ключевые слова (''Своб.индексиров.''): orthorhombic bismuth triborate delta-bibo--refractive indices--nonlinear optical coefficients--nonlinear optical materials--phase matching
Аннотация: Dispersion of refraction coefficients of orthorhombic BiB3O6 in the wavelength range between 435.8 and 1060 nm is studied, nonlinear optical coefficients are determined, and phase matching angles, angular and spectral bandwidths for second harmonic generation processes are calculated. delta-BiBO may be suitable for doubling of lasers with a wavelength in the 1.3 mu m region as well as the matrix for self-doubling lasing media. (C) 2011 Elsevier B.V. All rights reserved.
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20.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Zaitsev A. I., Molokeev M. S., Cherepakhin A. V., Radionov N. V., Zamkov A. V.
Заглавие : Optical birefringence of β-SrB4O7 crystals with strontium substitutions
Коллективы : International Conference on Crystal Growth and Epitaxy (17; 2013 ; Aug. ; 11-16; Warsaw, Poland)
Место публикации : 17th Int. Conf. on Crystal Growth and Epitaxy (ICCGE-17): Book of Abstracts. - 2013. - P.464-465
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