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1.


   
    Mössbauer Study of the Magnetic Transition in ϵ-Fe2O3 Nanoparticles Using Synchrotron and Radionuclide Sources / Y. V. Knyazev, A. I. Chumakov, A. A. Dubrovskiy [et al.] // JETP Letters. - 2019. - Vol. 110, Is. 9. - P. 613-617, DOI 10.1134/S0021364019210082. - Cited References: 23. - This work was supported by the Russian Science Foundation (project no. 17-12-01111) . - ISSN 0021-3640
Аннотация: Nuclear γ-resonance experiments with energy and time resolved detection are carried out with ϵ-F2O3 nanoparticles and a 57Co(Rh) laboratory Mössbauer source of γ radiation and a 14.4125 keV synchrotron radiation source on the ID18 beamline (ESRF) in the temperature range of 4–300 K. Both methods show a tremendous increase in the hyperfine field in tetrahedrally coordinated iron positions during the magnetic transition in the range of 80–150 K. As a result, the splitting of the quantum beat peaks in the nuclear scattering spectra is observed in the time interval of 20–170 ns with a periodicity of ∼ 30 ns. In addition, the first quantum beat is slightly shifted to shorter times. A correlation between the quadrupole shift and the orbital angular momentum of iron in ϵ-F2O3 nanoparticles is found. The magnetic transition leads to the rotation of the magnetic moment in the tetrahedral positions of iron around the axis of the electric field gradient by an angle of 44°.

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Публикация на русском языке Мессбауэровские исследования магнитного перехода в наночастицах ε-Fe2O3 на синхротронном и радионуклидном источниках [Текст] / Ю. В. Князев [и др.] // Письма в ЖЭТФ. - 2019. - Т. 110 Вып. 9. - С. 614-619

Держатели документа:
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
European Synchrotron Radiation Facility (ESRF), Grenoble Cedex 9, F-38043, France
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russian Federation

Доп.точки доступа:
Knyazev, Yu. V.; Князев, Юрий Владимирович; Chumakov, A. I.; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Yakushkin, S. S.; Kirillov, V. L.; Martyanov, O. N.; Balaev, D. A.; Балаев, Дмитрий Александрович
}
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2.


   
    Unusual magnetic behavior of polymorph iron oxide ϵ-Fe2O3 nanoparticles: magnetic phase diagram and surface effects / D. A. Balaev, A. A. Dubrovskiy, S. V. Semenov [et al.] // Euro-asian symposium "Trends in magnetism" (EASTMAG-2019) : Book of abstracts / чл. конс. ком.: S. G. Ovchinnikov, N. V. Volkov [et al.] ; чл. прогр. ком. D. M. Dzebisashvili [et al.]. - 2019. - Vol. 2. - Ст. J.I2. - P. 164-165. - Cited References: 15. - This work was supported by the Russian Science Foundation, project no. 17-12-01111 . - ISBN 978-5-9500855-7-4

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia
Boreskov Institute of Catalysis, SB RAS

Доп.точки доступа:
Ovchinnikov, S. G. \чл. конс. ком.\; Овчинников, Сергей Геннадьевич; Volkov, N. V. \чл. конс. ком.\; Волков, Никита Валентинович; Dzebisashvili, D. M. \чл. прогр. ком.\; Дзебисашвили, Дмитрий Михайлович; Balaev, D. A.; Балаев, Дмитрий Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Krasikov, A. A.; Красиков, Александр Александрович; Knyazev, Yu. V.; Князев, Юрий Владимирович; Bayukov, O. A.; Баюков, Олег Артемьевич; Yakushkin, S. S.; Kirillov, V. L.; Bukhtiyarova, G. A.; Martyanov, O. A.; Российская академия наук; Уральское отделение РАН; Институт физики металлов им. М. Н. Михеева Уральского отделения РАН; Уральский федеральный университет им. первого Президента России Б.Н. Ельцина; Российский фонд фундаментальных исследований; Euro-Asian Symposium "Trends in MAGnetism"(7 ; 2019 ; Sept. ; 8-13 ; Ekaterinburg); "Trends in MAGnetism", Euro-Asian Symposium(7 ; 2019 ; Sept. ; 8-13 ; Ekaterinburg)
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3.


   
    The Low-Temperature Magnetic State and Magnetic Ordering Temperature of ϵ-Fe2O3 Iron Oxide Nanoparticles / A. Dubrovskiy [et al.] // IEEE Magn. Lett. - 2019. - Vol. 10. - Ст. 6110103, DOI 10.1109/LMAG.2019.2956674. - Cited References: 22 . - ISSN 1949-307X
Рубрики:
Magnetic resonance
   Magnetic hysteresis

   Temperature distribution

   Saturation magnetization

   Nanoparticles

   Perpendicular magnetic anisotropy

Кл.слова (ненормированные):
ε-Fe2O3 nanoparticles -- magnetic transition -- FMR spectra
Аннотация: The ϵ-Fe2O3 iron oxide polymorph is a well-known magnetic material with a complex magnetic structure, which undergoes a series of magnetic transitions in different temperature ranges. However, the ϵ-Fe2O3 phase diagram is still unclear. We report on the magnetic properties of a sample consisting of ϵ-Fe2O3 nanoparticles with an average size of 8 nm embedded in a SiO2 xerogel matrix without an admixture of foreign phases. Along with the features typical of the well-known ϵ-Fe2O3 magnetic transition in the temperature range 80–150 K, the temperature dependence of magnetization M(T) of ϵ-Fe2O3 includes other low-temperature anomalies. In an external field of H = 70 kOe, there is a noticeable temperature hysteresis of magnetization at 50–90 K, and near T ≈ 50 K, the M(T) curves have a characteristic bending, which may be indicative of an additional magnetic transition. The ferromagnetic resonance spectra shows that, near 500 K, a magnetic phase transition occurs, which was previously thought to be a transition to the paramagnetic state. An analysis of the temperature dependence of the ferromagnetic resonance spectra shows that the magnetically ordered phase in ϵ-Fe2O3 exists up to about 800 K.

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Держатели документа:
Kirensky Institute of Physics SB RAS, 133887 Krasnoyarsk, Russian Federation
Boreskov Institute of Catalysis SB RAS, 104675 Novosibirsk, Russian Federation

Доп.точки доступа:
Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Knyazev, Yu. V.; Князев, Юрий Владимирович; Popkov, S. I.; Попков, Сергей Иванович; Yakushkin, S.; Kirillov, V.; Martyanov, O.; Balaev, D. A.; Балаев, Дмитрий Александрович
}
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4.


   
    Size effects in the formation of an uncompensated ferromagnetic moment in NiO nanoparticles / S. I. Popkov [et al.] // J. Appl. Phys. - 2019. - Vol. 126, Is. 10. - Ст. 103904, DOI 10.1063/1.5109054. - Cited References: 54. - This study was supported by the Ministry of Science and Higher Education of the Russian Federation and by the Russian Foundation for Basic Research, Government of the Krasnoyarsk Territory, and Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project: "Magnetic Reversal of Magnetic Nanoparticles in Strong Pulsed Magnetic Fields-A New Approach to the Study of Dynamic Effects Associated with the Magnetization of Magnetic Nanoparticles," Project No. 18-42-240012. . - ISSN 0021-8979. - ISSN 1089-7550
РУБ Physics, Applied
Рубрики:
MAGNETIC-PROPERTIES
   TEMPERATURE

   SUSCEPTIBILITY

   NANOFERRIHYDRITE

Аннотация: The magnetic properties of samples of NiO nanoparticles with average sizes of 23, 8.5, and 4.5 nm were investigated. Using the magnetization curves measured in strong (up to 250 kOe) pulsed magnetic fields, the contributions of the free spin and ferromagnetic subsystems were extracted. It has been found that the ferromagnetic contribution increases with a decrease in the nanoparticle size and is proportional to the fraction of uncompensated exchange-coupled spins. It is demonstrated that the uncompensated spins form in the antiferromagnetic NiO oxide due to an increase in the fraction of surface atoms in the nanoparticles with decreasing particle size and defects in the bulk of particles.

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Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Fed Res Ctr, Krasnoyarsk Sci Ctr,Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia.

Доп.точки доступа:
Popkov, S. I.; Попков, Сергей Иванович; Krasikov, A. A.; Красиков, Александр Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Volochaev, M. N.; Волочаев, Михаил Николаевич; Kirillov, V. L.; Martyanov, O. N.; Balaev, A. D.; Балаев, Александр Дмитриевич; Ministry of Science and Higher Education of the Russian Federation; Russian Foundation for Basic Research, Government of the Krasnoyarsk Territory [18-42-240012]; Krasnoyarsk Territorial Foundation [18-42-240012]
}
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5.


   
    Size and surface effects in NiO nanoparticles: results of studies in strong pulse magnetic fields / D. A. Balaev [et al.] // Euro-asian symposium "Trends in magnetism" (EASTMAG-2019) : Book of abstracts / чл. конс. ком.: S. G. Ovchinnikov, N. V. Volkov [et al.] ; чл. прогр. ком. D. M. Dzebisashvili [et al.]. - 2019. - Vol. 1. - Ст. C.P29. - P. 317-318. - Cited References: 4. - This study was supported by the Russian Foundation for Basic Research, Government of the Krasnoyarsk Territory, and Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project: “Magnetic Reversal of Magnetic Nanoparticles in Strong Pulsed Magnetic Fields — a New Approach to the Study of Dynamic Effects Associated with the Magnetization of Magnetic Nanoparticles” project no. 18-42-240012 . - ISBN 978-5-9500855-7-4

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Доп.точки доступа:
Ovchinnikov, S. G. \чл. конс. ком.\; Овчинников, Сергей Геннадьевич; Volkov, N. V. \чл. конс. ком.\; Волков, Никита Валентинович; Dzebisashvili, D. M. \чл. прогр. ком.\; Дзебисашвили, Дмитрий Михайлович; Balaev, D. A.; Балаев, Дмитрий Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Volochaev, M. N.; Волочаев, Михаил Николаевич; Kirillov, V. L.; Martyanov, O. N.; Popkov, S. I.; Попков, Сергей Иванович; Российская академия наук; Уральское отделение РАН; Институт физики металлов им. М. Н. Михеева Уральского отделения РАН; Уральский федеральный университет им. первого Президента России Б.Н. Ельцина; Российский фонд фундаментальных исследований; Euro-Asian Symposium "Trends in MAGnetism"(7 ; 2019 ; Sept. ; 8-13 ; Ekaterinburg); "Trends in MAGnetism", Euro-Asian Symposium(7 ; 2019 ; Sept. ; 8-13 ; Ekaterinburg)
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6.


   
    Giant anisotropy of magnetic properties of hydrated iron fluoridotitanate single crystal / A. A. Dubrovskiy, Y. V. Knyazev, D. A. Velikanov [et al.] // J. Alloys Compd. - 2022. - Vol. 898. - Ст. 162748, DOI 10.1016/j.jallcom.2021.162748. - Cited References: 53. - The reported study was funded by Russian Foundation for Basic Research , Government of Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science according to the research project "Spectral and magnetic properties of single crystals of transition metal fluoride hexahydrates.” No. 20-42-240014 . - ISSN 0925-8388
   Перевод заглавия: Гигантская анизотропия магнитных свойств гидратированных ионов монокристалла флюоридотитаната
Аннотация: Study of the magnetic properties of the FeTiF6 ‧ 6 H2O single crystal has shown that this compound is a two-dimensional antiferromagnet with a Néеl temperature of TN = 8 K and its magnetic moment anisotropy attains 7000% at a temperature of T = 4.2 K. The Mössbauer spectroscopy data unambiguously indicate the paramagnetic state of iron cations in the temperature range of 4.2–300 K. However, a sharp change in the difference between the quadrupole doublet linewidths at 10 K has been observed, which is consistent with the temperature of magnetic ordering. It has been suggested that the long-range magnetic order is established in the crystal through the formation of the exchange coupling revealed by the electron spin resonance measurements on the oriented single crystals.

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Держатели документа:
Kirensky Institute of Physics, Siberian Branch of RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, 660079, Russian Federation
Institute of Chemistry, Far Eastern Branch of RAS, Vladivostok, 690022, Russian Federation

Доп.точки доступа:
Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Knyazev, Yu. V.; Князев, Юрий Владимирович; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Vorotynov, A. M.; Воротынов, Александр Михайлович; Laptash, N. M.; Gerasimova, Yu. V.; Герасимова, Юлия Валентиновна
}
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7.


   
    Relaxation of low-temperature magnetoresistance and magnetization of polycrystalline (La0.5Eu0.5)0.7Pb 0.3MnO3 / K. A. Shaykhutdinov [et al.] // Journal of Physics D: Applied Physics. - 2011. - Т. 44, № 25. - P255001, DOI 10.1088/0022-3727/44/25/255001 . - ISSN 0022-3727. - ISSN 1361-6463

РИНЦ
Держатели документа:
Kirensky Institute of Physics,Russian Academy of Sciences,Siberian Branch

Доп.точки доступа:
Shaykhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Balaev, D. A.; Балаев, Дмитрий Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Popkov, S. I.; Попков, Сергей Иванович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Sapronova, N. V.; Сапронова, Наталья Владимировна; Volkov, N. V.; Волков, Никита Валентинович
}
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8.


   
    Spectroscopy of structurally disordered hydrated iron fluoridotitanate in the regions of vibrational and electronic excitations / Y. V. Gerasimova, A. S. Aleksandrovsky, N. M. Laptash [et al.] // Spectrochim. Acta A. - 2022. - Vol. 264. - Ст. 120244, DOI 10.1016/j.saa.2021.120244. - Cited References: 28. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory and Krasnoyarsk Regional Foundation of Science according to the research project “Spectral and magnetic properties of single crystals of transition metal fluoride hexahydrates.” No. 20-42-240014 . - ISSN 1386-1425
Кл.слова (ненормированные):
Hydrated iron fluoridotitanate -- Phase transition -- Order-disorder -- Raman -- Dynamics -- Electronic excitations
Аннотация: Raman and optical absorption spectra of disordered hydrated iron fluoridotitanate (HITF) single crystal were studied. Temperature transformations of the Raman spectra indicate independent ordering processes of the [TiF6]2− and [Fe(H2O)6]2+ complexes below the structural phase transition. The absorption spectrum in the near-infrared and visible ranges includes transitions from the high spin ground state 5T2 of Fe2+ ion to the excited 5E state and a set of excited triplets. Analysis by Tanabe-Sugano method gives crystal field Dq = 490 cm−1 and Racah parameters B = 340 cm−1 and C = 1904 cm−1. Considerable decrease of B parameter as compared to the free ion value indicates a decrease of interelectron repulsion in the disordered neighborhood of Fe2+ ions.

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Держатели документа:
Kirensky Institute of Physics, Siberian Branch of RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, 660079, Russian Federation
Institute of Chemistry, Far Eastern Branch of RAS, Vladivostok, 690022, Russian Federation

Доп.точки доступа:
Gerasimova, Yu. V.; Герасимова, Юлия Валентиновна; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Laptash, N. M.; Gerasimov, M. A.; Герасимов, М. А.; Krylov, A. S.; Крылов, Александр Сергеевич; Vtyurin, A. N.; Втюрин, Александр Николаевич; Dubrovskiy, A. A.; Дубровский, Андрей Александрович
}
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9.


   
    Nuclear forward scattering application to the spiral magnetic structure study in epsilon-Fe2O3 / Y. V. Knyazev, A. I. Chumakov, A. A. Dubrovskiy [et al.] // Phys. Rev. B. - 2020. - Vol. 101, Is. 9. - Ст. 094408, DOI 10.1103/PhysRevB.101.094408. - Cited References: 44. - We thank Dr. Natalia Kazak for assistance with the NFS measurements. This study was supported by the Russian Science Foundation, Project No. 17-12-01111. We thank the European Synchrotron Radiation Facility for provision of the synchrotron radiation facilities at the beamline ID18 (Exp. No. SC-4708) . - ISSN 2469-9950. - ISSN 2469-9969
РУБ Materials Science, Multidisciplinary + Physics, Applied + Physics, Condensed Matter
Рубрики:
INCOMMENSURATE STRUCTURES
   MOSSBAUER-SPECTROSCOPY

   HIGH-TEMPERATURE

Аннотация: The ε−Fe2O3 magnetic structure has been analyzed using the synchrotron radiation source. Time spectra of nuclear forward scattering for isolated nanoparticles with an average size of 8 nm immobilized in a xerogel matrix have been recorded in the temperature range of 4–300K in applied magnetic fields of 0–4T in the longitudinal direction at the European Synchrotron Radiation Facility (ESRF, Grenoble, France). It has been found that the external magnetic field does not qualitatively change the Hhf(T) behavior, but makes a strong opposite impact on the hyperfine fields in the nonequivalent iron sites, leading to the divergence of Hhf polar angle dependences below 80 K. A complete diagram of the ε−Fe2O3 magnetic structure in the temperature range of 4–300K is proposed. At 300 K, the ε−Fe2O3 compound is confirmed to be a collinear ferrimagnet. The experimental results show that the magnetic transition at 150–80K leads to the formation of a noncollinear magnetic structure. Furthermore, in the range of the 80–4 K, the ground state of a magnetic spiral is established. The experimental results are supplemented by the analysis of the exchange interactions and temperature dependence of the magnetization in a magnetic field of 7 T.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Akademgorodok 50,Bldg 38, Krasnoyarsk 660036, Russia.
ESRF European Synchrotron, 71 Ave Martyrs CS40220, F-38043 Grenoble 9, France.
DESY, D-22607 Hamburg, Germany.
Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia.

Доп.точки доступа:
Knyazev, Yu. V.; Князев, Юрий Владимирович; Chumakov, A. I.; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Sergueev, I.; Yakushkin, S. S.; Kirillov, V. L.; Martyanov, O. N.; Balaev, D. A.; Балаев, Дмитрий Александрович; Russian Science FoundationRussian Science Foundation (RSF) [17-12-01111, SC-4708]
}
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10.


   
    Features of the quasi-static and dynamic magnetization switching in NiO nanoparticles: Manifestation of the interaction between magnetic subsystems in antiferromagnetic nanoparticles / D. A. Balaev, A. A. Krasikov, S. I. Popkov [et al.] // J. Magn. Magn. Mater. - 2020. - Vol. 515. - Ст. 167307, DOI 10.1016/j.jmmm.2020.167307. - Cited References: 89. - We are grateful to A.D. Balaev for fruitful discussions. The TEM study and magnetic measurements using a PPMS-6000 facility were carried out on the equipment of the Krasnoyarsk Territorial Center for Collective Use, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences . - ISSN 0304-8853
Кл.слова (ненормированные):
Antiferromagnetic nanoparticle -- Dynamic magnetization -- Irreversible magnetization -- Magnetic subsystems -- Magnetization switching -- Quasi-static conditions -- Sub-micron particles -- Universal parameters
Аннотация: We report on the investigations of a system of 8-nm NiO particles representing antiferromagnetic (AFM) materials, which are weak magnetic in the form of submicron particles, but can be considered to be magnetoactive in the form of nanoparticles due to the formation of the uncompensated magnetic moment in them. The regularities of the behavior of magnetization switching in AFM nanoparticles are established by studying the magnetic hysteresis loops under standard quasi-static conditions and in a quasi-sinusoidal pulsed field of up to 130 kOe with pulse lengths of 4–16 ms. The magnetic hysteresis loops are characterized by the strong fields of the irreversible magnetization behavior, which is especially pronounced upon pulsed field-induced magnetization switching. Under the pulsed field-induced magnetization switching conditions, which are analogous to the dynamic magnetic hysteresis, the coercivity increases with an increase in the maximum applied field H0 and a decrease in the pulse length. This behavior is explained by considering the flipping of magnetic moments of particles in an external ac magnetic field; however, in contrast to the case of single-domain ferro- and ferrimagnetic particles, the external field variation rate dH/dt is not a universal parameter uniquely determining the coercivity. At the dynamic magnetization switching in AFM nanoparticles, the H0 value plays a much more important role. The results obtained are indicative of the complex dynamics of the interaction between magnetic subsystems formed in AFM nanoparticles.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center “Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences”, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russian Federation

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Popkov, S. I.; Попков, Сергей Иванович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Kirillov, V. L.; Martyanov, O. N.
}
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11.


   
    Magnetic Properties of Ultrafine ε-Fe2O3 Nanoparticles in a Silicon Xerogel Matrix / Y. V. Knyazev [et al.] // Bull. Russ. Acad. Sci. Phys. - 2019. - Vol. 83, Is. 7. - P. 875-877, DOI 10.3103/S1062873819070219. - Cited References: 11 . - ISSN 1062-8738
Кл.слова (ненормированные):
Hematite -- High resolution transmission electron microscopy -- Magnetic properties -- Nanoparticles -- Silica -- Silicon -- Silicon oxides -- Xerogels
Аннотация: A new metamaterial is obtained on the basis of ε-Fe2O3 nanoparticles immobilized in a xerogel matrix. Samples are synthesized by impregnating SiO2 hydrogel with iron (II) salts with subsequent drying and calcination. The structure and magnetic properties of the composites are probed using transmission electron microscopy, X-ray diffraction, Mössbauer spectroscopy, and static magnetic measurements. © 2019, Allerton Press, Inc.

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Публикация на русском языке

Держатели документа:
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russian Federation

Доп.точки доступа:
Knyazev, Yu. V.; Князев, Юрий Владимирович; Yakushkin, S. S.; Balaev, D. A.; Балаев, Дмитрий Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Bayukov, O. A.; Баюков, Олег Артемьевич; Kirillov, V. L.; Martyanov, O. N.
}
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12.


   
    ε-Fe2O3 nanoparticles embedded in silica xerogel – Magnetic metamaterial / S. S. Yakushkin [et al.] // Ceram. Int. - 2018. - Vol. 44, Is. 15. - P. 17852-17857, DOI 10.1016/j.ceramint.2018.06.254. - Cited References: 31. - This work was supported by the Russian Science Foundation, project no. 17-12-01111. . - ISSN 0272-8842
Кл.слова (ненормированные):
ε-Fe2O3 iron oxide nanoparticles -- Metamaterial -- Mossbauer spectroscopy -- Magnetic properties -- Magnetic circular dichroism
Аннотация: A novel method for synthesizing a new metamaterial based on ε-Fe2O3 nanoparticles immobilized in the xerogel matrix was proposed. Samples with different contents of ε-Fe2O3 nanoparticles dispersed in silica xerogel were synthesized by impregnation of as prepared hydrogel with iron (II) salts with the subsequent calcination. The structure and magnetic properties of the prepared composites were studied by transmission electron microscopy, X-ray diffraction, Mössbauer spectroscopy, and static magnetic measurements. The absence of other iron oxide polymorphs, controllable particle size distribution, and high ε-Fe2O3 nanoparticle concentration in combination with the weak interparticle magnetic interactions ensured the preservation of the unique magnetic properties of individual ε-Fe2O3 nanoparticles and allowed us to obtain a novel metamaterial. The high optical transparency and homogeneity of the prepared composites made it possible to detect the magnetic circular dichroism (MCD) of the magnetic silica xerogel, which is typical of the ε-Fe2O3-based systems.

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Держатели документа:
Boreskov Institute of Catalysis, Russian Academy of Sciences, Siberian Branch, Novosibirsk, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Yakushkin, S. S.; Balaev, D. A.; Балаев, Дмитрий Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Knyazev, Yu. V.; Князев, Юрий Владимирович; Bayukov, O. A.; Баюков, Олег Артемьевич; Kirillov, V. L.; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Edelman, I. S.; Эдельман, Ирина Самсоновна; Martyanov, O. N.
}
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13.


   
    ε-Fe2O3 nanoparticles anchored in different template materials / Yu. V. Knyazev [и др.] // Мёссбауэровская спектроскопия и её применения : сб. материалов XV международной конференции. - Ростов-на-Дону, 2018. - С. 66 . - ISBN 978-5-9275-2831-8
   Перевод заглавия: Наночастицы ε-Fe2O3 в матрицах из различных материалов

Материалы конференции

Доп.точки доступа:
Knyazev, Yu. V.; Князев, Юрий Владимирович; Balaev, D. A.; Балаев, Дмитрий Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Yakushkin, S. S.; Bukhtiyarova, G. A.; Martyanov, O. N.; Bayukov, O. A.; Баюков, Олег Артемьевич; Мёссбауэровская спектроскопия и её применения, международная конференция(15 ; 2018 ; сент ; 10-16 ; Сочи); Mössbauer Spectroscopy and Applications, International Conference(15 ; 2018 ; Sept. ; 10-16 ; Sochi); Южный федеральный университет; МИРЭА-Российский технологический университет; Российская академия наук; Институт кристаллографии им. А.В. Шубникова РАН; Федеральный научно-исследовательский центр "Кристаллография и фотоника" РАН; Московский государственный университет им. М.В. Ломоносова
}
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14.


   
    Dynamic magnetization switching in NiO nanoparticles: Pulsed field magnetometry study / D. A. Balaev [et al.] // J. Supercond. Novel Magn. - 2019. - Vol. 32, Is. 2. - P. 405–411, DOI 10.1007/s10948-018-4726-4. - Cited References: 32. - We are grateful to Yu.V. Knyazev, S.V. Semenov, and M.I. Kolkov for their help and to M.N. Volochaev for the TEM measurements. TEM studies were performed on the facility of Resource Sharing Center of Krasnoyarsk Scientific Center of Siberian Branch of Russian Academy of Sciences. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project no. 17-42-240138. . - ISSN 1557-1939
Кл.слова (ненормированные):
NiO nanoparticles -- Pulsed field magnetization -- Coercivity
Аннотация: The dynamic magnetization switching of antiferromagnetic nickel oxide nanoparticles with a characteristic size of 8 nm has been experimentally investigated by pulsed field magnetometry. It is shown that, due to the presence of defects in NiO nanoparticles, as in other antiferromagnetic particles, the uncompensated magnetic moment is induced by the incomplete compensation of spins at the antiferromagnetic ordering. The dynamic magnetic hysteresis loops have been studied in pulsed fields with the maximum field (Hmax) of up to 130 kOe and pulse lengths (τP) of 4, 8, and 16 ms. According to the results obtained, the coercivity (HC) depends on both the τP and Hmax values. The observed increase in the HC value with decreasing pulse length (i.e., with increasing switching field frequency) is unambiguously related with the relaxation processes typical of single-domain ferromagnetic nanoparticles. However, the observed effect of the maximum applied field (Hmax) on the HC value is assumed to be a feature of antiferromagnetic nanoparticles.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Boreskov Institute of Catalysis, Russian Academy of Sciences, Siberian Branch, Novosibirsk, Russian Federation

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Balaev, A. D.; Балаев, Александр Дмитриевич; Popkov, S. I.; Попков, Сергей Иванович; Kirillov, V. L.; Martyanov, O. N.
}
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15.


   
    ε-Fe2O3/SiO2 nanoparticles formation; spatial stabilization and the ε-Fe2O3 → α-Fe2O3 phase transition / S. S. Yakushkin [et al.] // International school/workshop on actual problems of condensed matter physics : Program. Book of abstracts / ed. S. G. Ovchinnikov. - Norilsk, 2018. - P. 16 . - ISBN 978-5-904603-08-3

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Доп.точки доступа:
Ovchinnikov, S. G. \ed.\; Овчинников, Сергей Геннадьевич; Yakushkin, S. S.; Balaev, D. A.; Балаев, Дмитрий Александрович; Shaikhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Bukhtiyarova, G. A.; Martyanov, O. N.; Federal Research Center KSC SB RAS; Kirensky Institute of Physics; Research Institute of Agriculture and Ecology of the Arctic; Siberian Federal Univercity
}
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16.


   
    Bacterial ferrihydrite nanoparticles: preparation, magnetic properties, and application in medicine / S. V. Stolyar [et al.] // J. Supercond. Novel Magn. - 2018. - Vol. 31, Is. 8. - P. 2297-2304, DOI 10.1007/s10948-018-4700-1. - Cited References: 37. - The electron microscopy examination was carried out at the Center for Collective Use of the Krasnoyarsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences (Krasnoyarsk, Russia). . - ISSN 1557-1939
Кл.слова (ненормированные):
Nanoparticles -- Ferrihydrite -- Magnetic properties -- Drug delivery
Аннотация: Nanoparticles of antiferromagnetically ordered materials acquire the uncompensated magnetic moment caused by defects and surface effects. A bright example of such a nano-antiferromagnet is nanoferrihydrite consisting of particles 2–5 nm in size, the magnetic moment of which amounts to hundreds of Bohr magnetons per particle. We present a brief review of the studies on magnetic properties of ferrihydrite produced by bacteria. Special attention is focused on the aspects of possible biomedical applications of this material, i.e., the particle elimination, toxicity, and possible use for targeted drug delivery.

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Держатели документа:
Siberian Federal University, Krasnoyarsk, Russian Federation
Krasnoyarsk Scientific Center, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian Clinical Center, Krasnoyarsk, Russian Federation
Scientific Research Institute of Medical Problems of the North, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Balaev, D. A.; Балаев, Дмитрий Александрович; Ladygina, V. P.; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Popkov, S. I.; Попков, Сергей Иванович; Bayukov, O. A.; Баюков, Олег Артемьевич; Knyazev, Yu. V.; Князев, Юрий Владимирович; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Volochaev, M. N.; Волочаев, Михаил Николаевич; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Dobretsov, K. G.; Morozov, E. V.; Морозов, Евгений Владимирович; Falaleev, O. V.; Фалалеев, Олег Владимирович; Inzhevatkin, E. V.; Kolenchukova, O. A.; Chizhova, I. A.
}
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17.


   
    Temperature of the Magnetic Ordering of the Trivalent Iron Oxide ε-Fe2O3 / D. A. Balaev [et al.] // Phys. Solid State. - 2019. - Vol. 61, Is. 3. - P. 345-349, DOI 10.1134/S1063783419030053. - Cited References: 39. - This study was supported by the Russian Science Foundation, project no. 17-12-01111. . - ISSN 1063-7834
Аннотация: The trivalent iron oxide ε-Fe2O3 is a fairly rare polymorphic iron oxide modification, which only exists in the form of nanoparticles. This magnetically ordered material exhibits an intriguing magnetic behavior, specifically, a significant room-temperature coercivity HC (up to ~20 kOe) and a magnetic transition in the temperature range of 80–150 K accompanied by a sharp decrease in the HC value. Previously, the temperature of the transition to the paramagnetic state for ε-Fe2O3 was believed to be about 500 K. However, recent investigations have shown that the magnetically ordered phase exists in ε-Fe2O3 also at higher temperatures and, around 500 K, another magnetic transition occurs. Using the data on the magnetization and temperature evolution of the ferromagnetic resonance spectra, it is shown that the temperature of the transition of ε-Fe2O3 particles 3–10 nm in size to the paramagnetic state is ~850 K.

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Публикация на русском языке Температура магнитного упорядочения оксида трехвалентного железа ε-Fe2O3 [Текст] / Д. А. Балаев [и др.] // Физ. тверд. тела. - 2019. - Т. 61 Вып. 3. - С. 478-482

Держатели документа:
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch,Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russian Federation

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Yakushkin, S. S.; Bukhtiyarova, G. A.; Martyanov, O. N.
}
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18.


   
    Температура магнитного упорядочения оксида трехвалентного железа ε-Fe2O3 / Д. А. Балаев [и др.] // Физ. тверд. тела. - 2019. - Т. 61, Вып. 3. - С. 478-482, DOI 10.21883/FTT.2019.03.47239.277. - Библиогр.: 38. - Работа выполнена при поддержке Российского научного фонда, грант N 17-12-01111. . - ISSN 0367-3294
Аннотация: Оксид трехвалентного железа ε-Fe2O3 является достаточно редкой полиморфной модификацией оксида железа и существует только в виде наночастиц. Этот магнитоупорядоченный материал демонстрирует интересное магнитное поведение: значительную коэрцитивную силу HC при комнатной температуре (до ~ 20 kOe), магнитный переход в температурном диапазоне 80-150 K, сопровождающийся резким уменьшением величины HC. Ранее считалось, что температура перехода в парамагнитное состояние для ε-Fe2O3 составляет около 500 K. Однако недавние исследования показали, что магнитоупорядоченная фаза в ε-Fe2O3 существует до более высоких температур, и при этом в окрестности 500 K происходит ещё один магнитный переход. В настоящей работе на основании данных по намагниченности и температурной эволюции спектров ферромагнитного резонанса показано, что температура перехода в парамагнитное состояние для частиц ε-Fe2O3 размерами 3-10 nm составляет ~850 K.

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Переводная версия Temperature of the Magnetic Ordering of the Trivalent Iron Oxide ε-Fe2O3 [Текст] / D. A. Balaev [et al.] // Phys. Solid State. - 2019. - Vol. 61 Is. 3.- P.345-349

Держатели документа:
Институт физики им. Л.В. Киренского Сибирского отделения Российской академии наук, Красноярск, Россия
Институт катализа им. Г.К. Борескова СО РАН, Новосибирск, Россия

Доп.точки доступа:
Балаев, Дмитрий Александрович; Balaev, D. A.; Дубровский, Андрей Александрович; Dubrovskiy, A. A.; Якушкин, С. С.; Бухтиярова, Г. А.; Мартьянов, О. Н.
}
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19.


   
    In Situ FMR Study of the Selective H2S-Oxidation Stability of ε-Fe2O3/SiO2 Catalysts / S. S. Yakushkin [et al.] // Appl. Magn. Reson. - 2019. - Vol. 50, Is. 5. - P. 725-733, DOI 10.1007/s00723-019-1109-3. - Cited References:32. - This work was supported by the Russian Science Foundation, project no. 17-12-01111. . - ISSN 0937-9347. - ISSN 1613-7507
РУБ Physics, Atomic, Molecular & Chemical + Spectroscopy
Рубрики:
HYDROGEN-SULFIDE
   CALCINATION TEMPERATURE

   OXIDATION

   PHASE

   BED

Аннотация: The stability of a catalyst for partial H2S oxidation has been studied by the ferromagnetic resonance (FMR) technique combined with transmission electron microscopy, X-ray diffraction, Mössbauer spectroscopy, and magnetostatic investigations. The ε-Fe2O3 iron oxide nanoparticles supported on silica have been examined for their stability under the selective H2S oxidation conditions. The combination of the physicochemical methods has been used to study the state of reacted catalysts. The ε-Fe2O3 phase has been found to remain stable under the selective H2S oxidation conditions at temperatures up to 300 °C. The active phase state during the catalytic reaction has been explored using in situ FMR experiments. It has been established that the ε-Fe2O3 nanoparticles retain their structure and magnetic properties in the presence of H2S at high temperatures. During the in situ FMR experiments, the ε-Fe2O3 sulfidation process has been studied.

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Держатели документа:
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Lavrentieva 5, Novosibirsk 630090, Russia.
RAS, Fed Res Ctr KSC SB, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Yakushkin, S. S.; Bukhtiyarova, G. A.; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Knyazev, Yu. V.; Князев, Юрий Владимирович; Balaev, D. A.; Балаев, Дмитрий Александрович; Martyanov, O. N.; Russian Science Foundation [17-12-01111]
}
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20.


   
    Magnetodielectric effect in a metamaterial consisting of xerogel with embedded ε-Fe2O3 iron oxide nanoparticles / A. A. Dubrovskiy [et al.] // Solid State Commun. - 2019. - Vol. 289. - P. 27-29, DOI 10.1016/j.ssc.2018.11.020. - Cited References: 30. - This work was supported by the Russian Science Foundation, project no. 17-12-01111. . - ISSN 0038-1098. - ISSN 1879-2766
РУБ Physics, Condensed Matter
Рубрики:
MAGNETIC-PROPERTIES
   HIGH-TEMPERATURE

   PHASE

   RAMAN

Аннотация: The ε-Fe2O3 iron oxide is a fairly rare polymorphic modification, which only exists in the form of nanoparticles embedded, as a rule, into a silica gel matrix. This magnetically ordered iron oxide, which exhibits a significant room-temperature coercivity, is a ferroelectric; therefore, the magnetoelectric and magnetodielectric properties of this material evoke keen interest. In this work, we investigate the magnetodielectric (MD) effect in a metamaterial consisting of xerogel SiO2 with embedded ε-Fe2O3 nanoparticles 9 nm in size on average in a concentration of 20 mass.%. This bulk material exhibits the MD effect in a wide temperature range. The temperature behavior of the permittivity is related to the magnetic state of the ε-Fe2O3 oxide, which undergoes the magnetic transition from the magnetically hard to magnetically soft phase in the temperature range of 80–150 K, indicating the interplay of the ε-Fe2O3 magnetic and charge subsystems.

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Держатели документа:
Russian Acad Sci, Siberian Branch, Kiresnky Inst Phys, Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia.

Доп.точки доступа:
Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Balaev, D. A.; Балаев, Дмитрий Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Yakushhkin, S. S.; Kirillov, V. L.; Martyanov, O. N.; Russian Science Foundation [17-12-01111]
}
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