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1.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Malakhovskii A. V., Edelman I. S., Sokolov A. Е., Sukhachev A. L., Temerov V. L., Gnatchenko S. L., Kachur I. S., Piryatinskaya V. G., Valiev U. V.
Заглавие : Optical absorption and luminescence of Tm3+ and Yb3+ ions in huntite structure
Место публикации : Республиканская конференция «Оптические методы в современной физике», Ташкент, Узбекистан, 2008, с. 33-35
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Sokolov V. V., Karimov D.N.
Заглавие : Nature of magnetic circular dichroism and absorption spectra of f-f transitions in Na0.4Ho0.6F2.2 single crystal
Колич.характеристики :5 с
Место публикации : Chem. Phys. - 2024. - Vol. 581. - Ст.112257. - ISSN 03010104 (ISSN), DOI 10.1016/j.chemphys.2024.112257. - ISSN 18734421 (eISSN)
Примечания : Cited References: 25
Аннотация: We present first study of magnetic circular dichroism (MCD) spectra of Ho3+ ion in C4v local symmetry, which it has in fluorite Na0.4Ho0.6F2.2. Optical absorption and MCD spectra were studied in this single crystal in the region of 5I8 5F3, 5F2, 3K8 and 5G5 transitions in the temperature range 3.6–––90 K. It was revealed, that number of transitions observed in the MCD and absorption spectra coincides with the number of transitions only from the doublet E state to singlet excited states. The E-E type transitions are not active in MCD, but they are not observed in the absorption spectra either. Paramagnetic magneto-optical activities (MOA) of the absorption bands and their temperature dependences were measured and interpreted with the help of the theory based on the nature of f-f transitions allowance. The MCD spectra were also analyzed in approximation of the J,±MJ wave functions of the free atom. It was shown in particular, that the lowest initial state of the transitions observed at T ˃ 10 K had MJ = 7, but this is not the lowest state of the holmium ion in the crystal. A little lower there is a quasi-doublet with MJ = 8 and, accordingly, with a higher magneto-optical activity of transitions from it. However, the intensity of transitions from this state is low.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Sukhachev A. L., Sokolov V. V., Gudim I. A., Kuchesheva-Titova V. R.
Заглавие : Transformation of 5I8→5F5 Ho absorption band in Ho0.75Nd0.25Fe3(BO3)4 crystal during spin-reorientation transition
Место публикации : Phys. B: Condens. Matter. - 2023. - Vol. 654. - Ст.414706. - ISSN 09214526 (ISSN), DOI 10.1016/j.physb.2023.414706. - ISSN 18732135 (eISSN)
Примечания : Cited References: 17
Аннотация: Polarized absorption spectra of crystal Ho0.75Nd0.25Fe3(BO3)4 in the region of the 5I8→5F5 absorption band of Ho ions were investigated depending on temperature in the range of 5–20 K. Absorption spectra are decomposed into components of the Lorentz form. The spin-reorientation phase transition was detected at 6.9 K. The observed line position shifts during the reorientation transition were different for different lines, which indicated different local magnetic anisotropy of the Ho ion in its excited states. Significant changes in absorption line intensities as a function of temperature were observed during the reorientation transition and above. These were explained as a consequence of the change in even components of the local crystal field in excited states. These components mix the closely spaced 4f states. Distortion of local symmetry in the ground state was detected at one of the electron transitions.
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4.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Соколов В. В., Малаховский, Александр Валентинович, Сухачев, Александр Леонидович, Гудим, Ирина Анатольевна
Заглавие : Спектры поглощения кристалла HOAl3(BO3)4 в области переходов 5I8→5F3 и 5F2
Коллективы : "Невская фотоника-2023", Всероссийская научная конференция с международным участием, Университет ИТМО
Место публикации : Невская фотоника-2023: материалы Всероссийской научной конференции с международным участием. - СПб., 2023. - С. 257
Примечания : Библиогр.: 3
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5.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Malakhovskii A. V., Sokolov V. V., Sukhachev A. L., Gudim I. A.
Заглавие : Magnetic circular dichroism of f-f transitions in multiferroic antiferromagnet Ho0.75Nd0.25Fe3(BO3)4
Коллективы : "Functional materials", International conference, Крымский федеральный университет имени В.И. Вернадского
Место публикации : Ovchinnikov S. G. International conference "Functional materials": book of abstracts/ ed. V. N. Berzhansky ; org. com. S. G. Ovchinnikov [et al.]. - Simferopol, 2023. - P.100-101
Примечания : Cited References: 2
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6.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Sokolov V. V., Malakhovskii A. V., Sukhachev A. L., Gudim I. A.
Заглавие : Magnetic circular dichroism and absorption of a HoAl3(BO3)4 crystal in the region of 5I8 → 5I3 and 5F2 transitions
Коллективы : Российская академия наук, Физико-технический институт им. Е.К. Завойского ФИЦ Казанского научного центра РАН, Казанский (Приволжский) федеральный университет, Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium
Место публикации : VIII Euro-Asian symposium "Trends in magnetism" (EASTMAG-2022): Book of abstracts/ program com. S. G. Ovchinnikov [et al.]. - 2022. - Vol. 1, Sect.: Magnetotransport, magnetooptics and magnetophotonics. - Ст.D.P16. - P.470-471. - ISBN 978-5-94469-051-7
Примечания : Cited References: 4
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sukhachev A. L., Malakhovskii A. V., Nelson C. S., Gudim I. A., Temerov V. L.
Заглавие : Erratum to: Comparison of the absorption spectra of Nd3+ ions in the NdFe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4, and Ho0.75Nd0.25Fe3(BO3)4 crystals (Physics of the Solid State, (2021), 63, 1, (113-121), 10.1134/S1063783421010200)
Место публикации : Phys. Solid State. - 2021. - Vol. 63, Is. 3. - P.511. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783421030203
Аннотация: Section Funding should read as follows: The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, to the research project No. 19-42-240003 “Influence of the local environment on magnetooptical properties of f-f transitions in rare-earth aluminum and iron borates” and the Russian Foundation for Basic Research, project No. 19-02-00034.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Gnatchenko S. L., Kachur I. S., Piryatinskaya V. G., Gudim I. A.
Заглавие : Magnetic linear dichroism and features of the local magnetic structure of HoFe3(BO3)4 single crystal in 5F2 and 5F3 excited states of Ho3+ ion
Место публикации : J. Magn. Magn. Mater. - 2021. - Vol. 536. - Ст.168106. - ISSN 03048853 (ISSN), DOI 10.1016/j.jmmm.2021.168106
Примечания : Cited References: 22. - A.V. Malakhovskii acknowledges the financing of the reported study by the Russian Foundation for Basic Researches grant 19-02-00034 and by the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, to the research project: number 19-42-240003 “Influence of the local environment on magneto-optical properties of f-f transitions in rare-earth aluminum and iron borates”
Аннотация: We measured spectra of magnetic linear dichroism (MLD) of 5I8 → 5F2, 5F3 transitions in the basal plane of the HoFe3(BO3)4 single crystal in the light propagated along the trigonal c-axis at temperature 2 K as a function of magnetic field 0 – 65 kOe directed along a and b axes. The substantial anisotropy of the MLD in the basal plane was revealed. The anisotropy of the MLD is strongly different for different electron transitions, that is, the MLD is mainly connected with the excited electron states. Transformations of the MLD spectra permitted us to retrace variations of the Ho ion magnetic moment orientation in different excited electron states as a function of the magnetic field. It was shown that in the excited states the local Ho magnetic moments do not reveal reorientation transitions synchronously with that of the Fe-sublattice. A small splitting of the ground doublet of the Ho3+ ion was observed during certain electron transitions. This means that during these electron transitions the local crystal field can change not only in the excited but in the ground state as well.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Sokolov V. V., Karimov D. N.
Заглавие : Magnetic circular dichroism of 5I8→ 5F3, 5F2 and 3K8 transitions in Na0.4Ho0.6F2.2 single crystal
Место публикации : Opt. Mater. - 2021. - Vol. 114. - Ст.110953. - ISSN 09253467 (ISSN), DOI 10.1016/j.optmat.2021.110953
Примечания : Cited References: 23. - A.V. Malakhovskii and V.V. Sokolov acknowledge the financing of the reported study by the Russian Foundation for Basic Researches grant 19-02-00034 and by the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, to the research project: number 19-42-240003 “Influence of the local environment on magneto-optical properties of f-f transitions in rare-earth aluminum and iron borates.” D.N. Karimov acknowledges the financing support by the Ministry of Science and Higher Education of Russia within the State assignment FSRC «Crystallography and Photonics» of Russian Academy of Sciences
Аннотация: We measured optical absorption and magnetic circular dichroism spectra of Na0.4Ho0.6F2.2 single crystal in the region of 5I8→ 5F3, 5F2 and 3K8 transitions in Ho3+ ion at 90 K and room temperature. Paramagnetic magneto-optical activities (MOA) of the transitions were found for these two temperatures and compared with the theory based on the nature of f-f transitions allowance. It was shown that nature of allowance of three considered transitions is different. The MCD spectra were also analyzed in approximation of the |J, ±MJ› wave functions of the free atom and using concept of the crystal quantum number. Using this concept and experimental paramagnetic MOA, we found that MJeff = 2.1 for the initial state of the 5I8→ 5F3 transition.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sukhachev A. L., Malakhovskii A. V., Nelson C. S., Gudim I. A., Temerov V. L.
Заглавие : Comparison of the absorption spectra of Nd3+ ions in the NdFe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4, and Ho0.75Nd0.25Fe3(BO3)4 crystals
Место публикации : Phys. Solid State. - 2021. - Vol. 63, Is. 1. - P.113-121. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783421010200
Примечания : Cited References: 21. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, to the research project: number 19-42-240003 “Influence of the local en-vironment on magneto-optical properties of f–f transitions in rare-earth aluminum and iron borates”
Аннотация: The polarized optical absorption spectra in the region of a series of the f–f transitions of Nd3+ ions in the Ho0.75Nd0.25Fe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4, and NdFe3(BO3)4 crystals at 90 K have been compared. The spectral features related to the difference in the local environment of Nd3+ ions in these crystals have been established. In the region of the transition 4I9/2 → 4G5/2 + 2G7/2 of Nd3+ ions in the Ho0.75Nd0.25Fe3(BO3)4 crystal, the appearance of some absorption lines at the structural transition R32 → P3121 around ~200 K due to the local symmetry variation has been found. The intensity of these lines smoothly increases with a decrease in temperature from the transition point. The temperature dependence of the lattice parameters of the Ho0.75Nd0.25Fe3(BO3)4 crystal has been measured. It has been found that, at the transition temperature, the lattice parameter a changes stepwise, which is indicative of the occurrence of a first-order phase transition. The lattice parameter c changes smoothly.
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