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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Guan, Ming, Zheng, Hong, Huang, Zhaohui, Ma, Bin, Molokeev M. S., Huang, Saifang, Mei, Lefu
Заглавие : Ca/Sr ratio dependent structure and up-conversion luminescence of (Ca1-xSrx)In2O4 : Yb3+/Ho3+ phosphors
Место публикации : RSC Adv.: Royal Society of Chemistry, 2015. - Vol. 5, Is. 73. - P.59403-59407. - ISSN 2046-2069, DOI 10.1039/c5ra08467a
Примечания : Cited References:25. - This present work was supported by the National Natural Science Foundations of China (Grant no. 51202226), the Fundamental Research Funds for the Central Universities (Grant no. 2652014125, 2652013128, 2652013043), and the Research Fund for the Doctoral Program of Higher Education of China (Grant no. 20130022110006).
Предметные рубрики: CO-DOPED CAIN2O4
ENERGY-TRANSFER
PHOTOLUMINESCENCE
EMISSION
SRIN2O4
Аннотация: Up-conversion (UC) phosphors of (Ca1-xSrx)In2O4 : Yb3+/Ho3+ (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9, 1.0) were prepared. Based on the crystal structure evolution of these series solid solution samples, which were characterized by Rietveld refinement, the variation of UC luminescent properties was discussed in detail. Sr and Ca occupied one position and Yb/Ho dissolved in the In ion site in the (Ca1-xSrx)In2O4 lattice. With increasing Sr substituting Ca atoms, the cell parameters and cell volumes of these samples increased linearly, and distortions of (Ca/Sr)O-8 polyhedron were formed. The distortions on crystal structures showed a negative relation with UC luminescent intensities in these series phosphors.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ji H. P., Huang Z. H., Xia, Zhiguo, Molokeev M. S., Atuchin V. V., Huang S. F.
Заглавие : Cation substitution dependent bimodal photoluminescence in whitlockite structural Ca3-xSrx(PO4)2:Eu2+ (0 ≤ x ≤ 2) solid solution phosphors
Место публикации : Inorg. Chem.: American Chemical Society, 2014. - Vol. 53, Is. 20. - P.11119-11124. - ISSN 0020-1669, DOI 10.1021/ic501679f. - ISSN 1520-510X
Примечания : Cited References: 37. - This work was supported by the National Natural Science Foundations of China (Grant Nos. 51032007, 51002146, 51272242), the Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20130022110006), the Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), and Beijing Youth Excellent Talent Program (YETP0635). V.V.A. acknowledges the Ministry of Education and Science of the Russian Federation for financial support.
Предметные рубрики: LIGHT-EMITTING-DIODES
EFFICIENT ENERGY-TRANSFER
EMISSION-TUNABLE PHOSPHOR
EXCITED WHITE LEDS
CRYSTAL-STRUCTURE
LUMINESCENCE PROPERTIES
Mn2+ PHOSPHOR
COLOR TONE
PHASE
Eu2+
Аннотация: Cation substitution dependent tunable bimodal photoluminescence behavior was observed in the Ca3-xSrx(PO4)2:Eu2+ (0 ≤ x ≤ 2) solid solution phosphors. The Rietveld refinements verified the phase purity and whitlockite type crystal structure of the solid solutions. The tunable photoluminescence evolution was studied as a function of strontium content, over the composition range 0.1 ≤ x ≤ 2. In addition to the emission band peak at 416 nm in Ca3(PO4)2:Eu2+, the substitution of Ca2+ by Sr2+ induced the emerging broad-band peak at 493-532 nm. A dramatic red shift of the emission peak located in the green-yellow region was observed on an increase of x in the samples with 0.75 ≤ x ≤ 2.00. The two emission bands could be related to the EuOn-Ca9 and EuOn-Ca9-xSrx emitting blocks, respectively. The values for the two kinds of emitting blocks in the solid solutions can be fitted well with the observed intensity evolution of the two emission peaks.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shi X., Molokeev M. S., Wang X., Wang Z., Zhu Q., Li J. -G.
Заглавие : Crystal structure of NaLuW2O8·2H2O and down/upconversion luminescence of the derived NaLu(WO4)2:Yb/Ln phosphors (Ln = Ho, Er, Tm)
Место публикации : Inorg. Chem. - 2018. - Vol. 57, Is. 17. - P.10791-10801. - ISSN 00201669 (ISSN), DOI 10.1021/acs.inorgchem.8b01427
Примечания : Cited References: 60
Аннотация: Hydrothermally reacting Lu(NO)3 and Na2WO4·2H2O at 200 °C and pH = 8 produced the new compound NaLuW2O8·2H2O, which was analyzed via the Rietveld technique to crystallize in the orthorhombic system (space group: Cmmm) with cell parameters a = 21.655(1), b = 5.1352(3), and c = 3.6320(2) Å and cell volume V = 403.87(4) Å3. The crystal structure presents -(NaO6)-(NaO6)- and -(LuO4(H2O)2WO5)-(LuO4(H2O)2WO5)- alternating layers linked together by the O2- ion common to NaO6 octahedron and WO5 triangle bipyramid. Tetragonal structured and phase-pure Na(Lu0.87Ln0.03Yb0.1)(WO4)2 phosphors (Ln = Ho, Er, and Tm) were directly produced by calcining their NaLuW2O8·2H2O analogous precursors at 600 °C for 2 h, followed by a detailed study of their downconversion/upconversion (DC/UC) photoluminescence. It was shown that the UC luminescence is dominated by a red band at ∼650 nm for Ho3+ (5F5 →5I8 transition), green bands at ∼500-575 nm for Er3+ (2H11/2/4S3/2 →4I15/2 transitions) and a blue band at ∼476 nm for Tm3+ (1G4 →3H6 transition), all via a three-photon process. DC luminescence of the phosphors is characterized by a ∼545 nm green emission for Ho3+ (5F4/5S2 →5I8 transition, ex = 453 nm), ∼500-575 nm green emissions for Er3+ (2H11/2/4S3/2 →4I15/2 transitions, ex = 380 nm), and a ∼455 nm blue emission for Tm3+ (1D2 →3F4 transition, ex = 360 nm), with CIE chromaticity coordinates of around (0.27, 0.71), (0.26, 0.72), and (0.15, 0.04), respectively.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Lyu, Kuangnan, Liu, Gaochao, Molokeev M. S., Xia, Zhiguo
Заглавие : Double-site occupation triggered broadband and tunable NIR-I and NIR-II luminescence in AlNbO4:Cr3+ phosphors
Место публикации : Adv. Phys. Res. - 2023. - Vol. 2, Is. 4. - Ст.2200056. - ISSN 27511200 (eISSN), DOI 10.1002/apxr.202200056
Примечания : Cited References: 38. - This research was supported by the International Cooperation Project of the National Key Research and Development Program of China (2021YFB3500400 and 2021YFE0105700), National Natural Science Foundations of China (Grant No. 51972118), Guangzhou Science & Technology Project (202007020005), the State Key Laboratory of Luminescent Materials and Devices (Skllmd-2022-02), and the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (2017BT01×137). This work was also funded by RFBR according to the research project No. 19-52-80003
Аннотация: Near-infrared (NIR) phosphor-converted light-emitting diodes (pc-LEDs) are desired for optoelectronic and biomedical applications, while the development of target broadband NIR phosphors still remains a significant challenge. Herein, a kind of Cr3+-doped AlNbO4 phosphors with a broad NIR emission ranging from 650 to 1400 nm under 450 nm excitation are reported. A giant red-shift emission peak from 866 to 1020 nm together with broadened full width at half-maximum of 320 nm is achieved simply by varying the doped Cr3+ concentrations. Structural and spectroscopy analysis demonstrate that a concentration-dependent site-occupation of Cr3+ emitters in different Al3+ sites is responsible for the tunable NIR luminescence. The as-fabricated NIR pc-LED based on optimized AlNbO4:Cr3+ phosphor exhibits great potential in night-vision applications. This work provides a novel design principle on the Cr3+-doped AlNbO4 phosphor with tunable broadband luminescence from NIR-I to NIR-II, and these materials can be employed in NIR spectroscopy applications.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Qiao, Jianwei, Ning, Lixin, Molokeev M. S., Chuang, Yu-Chun, Liu, Quanlin, Xia, Zhiguo
Заглавие : Eu2+ site preferences in the mixed cation K2BaCa(PO4)2 and thermally stable luminescence
Место публикации : J. Am. Chem. Soc. - 2018. - Vol. 140, Is. 30. - P.9730-9736. - ISSN 0002-7863, DOI 10.1021/jacs.8b06021
Примечания : Cited References: 40. - This work is supported by the National Natural Science Foundation of China (No. 51722202, 91622125, 51572023, and 11574003), Natural Science Foundations of Beijing (2172036) and M.M. acknowledges support of the Russian Foundation for Basic Research (17-52-53031).
Предметные рубрики: LIGHT-EMITTING-DIODES
SOLID-SOLUTION
PHOSPHORS
GREEN
BLUE
Аннотация: Site preferences of dopant Eu2+ on the locations of K+, Ba2+, and Ca2+ in the mixed cation phosphate K2BaCa(PO4)2 (KBCP) are quantitatively analyzed via a combined experimental and theoretical method to develop a blue-emitting phosphor with thermally stable luminescence. Eu2+ ions are located at K2 (M2) and K3 (M3) sites of KBCP, with the latter occupation relatively more stable than the former, corresponding to emissions at 438 and 465 nm, respectively. KBCP:Eu2+ phosphor exhibits highly thermal stable luminescence even up to 200 °C, which is interpreted as due to a balance between thermal ionization and recombination of Eu2+ 5d excited-state centers with the involvement of electrons trapped at crystal defect levels. Our results can initiate more exploration of activator site engineering in phosphors and therefore allow predictive control of photoluminescence tuning and thermally stable luminescence for emerging applications in white LEDs.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gao P., Li Q., Zhou C., Chen K., Luo Z., Zhang S., Molokeev M. S., Wang J., Zhou Z., Xia M.
Заглавие : High-efficiency continuous-luminescence-controllable performance and antithermal quenching in Bi3+-activated phosphors
Место публикации : Inorg. Chem. - 2022. - Vol. 61, Is. 33. - P.13104-13114. - ISSN 00201669 (ISSN), DOI 10.1021/acs.inorgchem.2c01784
Примечания : Cited References: 52. - The authors gratefully acknowledge funds from the National Natural Science Foundation of China (Grant 51974123), the Distinguished Youth Foundation of Hunan Province (Grant 2020JJ2018), the Key R&D Projects in Hunan Province (2020WK2016, 2020SK2032, 2021SK2047, and 2022NK2044), the Natural Science Foundation of Hunan Province, China (Grant 2021JJ40261), the Hunan High Level Talent Gathering Project (2020RC5007), Changsha Science and Technology Plan (KH2005114 and KH2201428), Hunan Graduate Scientific Research Innovation Project (2022XC017), and the College Students’ Innovative Training (s202210537079x)
Аннотация: Recently, Bi3+-activated phosphors have been widely researched for phosphor-converted light-emitting diode (pc-LED) applications. Herein, novel full-spectrum A3BO7:Bi3+ (A = Gd, La; B = Sb, Nb) phosphors with a luminescence-tunable performance were achieved by a chemical substitution strategy. In the La3SbO7 host material, a new luminescent center was introduced, with Gd3+ replacing La3+. The photoluminescence (PL) spectra show a large blue shift from 520 to 445 nm, thus achieving regulation from green to blue lights. Moreover, a series of solid solution-phase phosphors La3Sb1-xNbxO7:Bi3+ were prepared by replacing Sb with Nb, and a PL spectral tunability from green (520 nm) to orange-red (592 nm) was realized. Temperature-dependent PL spectra show that La3-xGdxSbO7:Bi3+ phosphors have excellent thermal stability. Upon 350 nm excitation, the PL intensity of La3-xGdxSbO7:Bi3+ phosphors at 150 °C remained at more than 93% at room temperature. With Gd3+ doping, the thermal stability gradually improved, and LaGd2SbO7:0.03Bi3+ represents splendid antithermal quenching (135.2% at 150 °C). Finally, a full-visible spectrum for pc-LED with a high color-rendering index (Ra = 94.4) was obtained. These results indicated that chemical substitution is an effective strategy to adjust the PL of Bi3+, which is of great significance in white-light illumination and accurate plant lighting.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kostyukov A. I., Snytnikov V. N., Snytnikov V. N., Ishchenko A. V., Rakhmanova M. I., Molokeev M. S., Krylov A. S., Aleksandrovsky A. S.
Заглавие : Luminescence of monoclinic Y2O3:Eu nanophosphor produced via laser vaporization
Место публикации : Opt. Mater. - 2020. - Vol. 104. - Ст.109843. - ISSN 09253467 (ISSN), DOI 10.1016/j.optmat.2020.109843
Примечания : Cited References: 19. - This work is financially supported by the Russian Foundation for Basic Research № 19-32-60027
Аннотация: Europium doped Y2O3spherical nanoparticles with the diameter ~10 nmobtained via cw laser vaporization are shown to crystallize in monoclinic symmetry class (C2/m space group). The size of nanoparticles established via HRTEM coincides with coherent scattering region established by XRD. Luminescence spectrum in the vicinity of ultranarrow transition demonstrates three peaks consistent with three inequivalent positions of Eu3+ ion in monoclinic Y2O3 lattice. Hypersensitive transition dominates in the spectrum, admitting the lack of inversion symmetry at Cs sites occupied by Eu3+. The spectrum of hypersensitive transition is expanded to the red part of spectrum due intense transitions terminating at higher-lying components of crystal-field-split 7F2 energy level. Obtaining chromaticity coordinates (0.669, 0.331)and absolute quantum yield (~21%) is possible using red phosphor based on monoclinic Y2O3:Eu3+.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Wang X., Shi X., Molokeev M. S., Wang Z., Zhu Q., Li X., Sun X., Li J. -G.
Заглавие : NaLaW2O7(OH)2(H2O): Crystal structure and RE3+ luminescence in the pristine and annealed double tungstates (RE = Eu, Tb, Sm, and Dy)
Место публикации : Inorg. Chem. - 2018. - Vol. 57, Is. 21. - P.13606–13617. - ISSN 00201669 (ISSN), DOI 10.1021/acs.inorgchem.8b02228
Примечания : Cited References: 71. - This work is supported in part by the National Natural Science Foundation of China (Grants 51702020 and 51672039), the Doctoral Research Fund of Liaoning Province (Grant 20170520103), and RFBR via Research Project 17-52-53031.
Аннотация: Hydrothermal reaction of La(NO3)3 and Na2WO4·2H2O at 100 °C and pH 8 resulted in the formation of new compound NaLaW2O7(OH)2(H2O), as confirmed by the X-ray diffraction results, chemical composition, Fourier transform infrared, thermogravimetric/differential thermal analysis, and transmission electron microscopy analyses. The crystal structure was determined in the triclinic system (space group P1̅), with lattice constants a = 5.8671(2) Å, b = 8.2440(2) Å, and c = 9.0108(3) Å, axis angles α = 93.121(2)°, β = 75.280(2)°, and γ = 94.379(2)°, and cell volume V = 420.03(2) Å3. The structure contains two-dimensional layers of -(W1O6)-(W1O6)-(W2O6)-(W2O6)-(W1O6)-(W1O6)- and -LaO9-LaO9- chains alternating in the a–b plane, which are linked together through NaO6 octahedral trigonal prisms by edges to form a three-dimensional net. Dehydration of the compound proceeds up to a low temperature of ∼350 °C and results in the formation of technologically important NaLa(WO4)2 double tungstate, which is thus a unique precursor for the latter. Na(La,RE)W2O7(OH)2(H2O) and Na(La,RE)(WO4)2 solid solutions separately doped with the practically important activators for which RE = Eu, Tb, Sm, and Dy were also successfully synthesized and investigated for their structural features and photoluminescence properties, including excitation, emission, quantum yield, emission color, and fluorescence decay kinetics. The compounds were shown to exhibit dominantly strong red (∼616 nm for Eu3+; λex = 395 or 464 nm), green (∼545 nm for Tb3+; λex = 278 or 258 nm), deep red (∼645 nm for Sm3+; λex = 251 nm), and yellow (∼573 nm for Dy3+; λex = 254 nm) emission upon being irradiated with the peak wavelengths of their strongest excitation bands.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Qiao J., Zhou Y., Molokeev M. S., Zhang Q., Xia Z.
Заглавие : Narrow bandwidth luminescence in Sr2Li(Al,Ga)O4:Eu2+ by selective site occupancy engineering for high definition displays
Место публикации : Laser Photon. Rev. - 2021. - Vol. 15, Is. 11. - Ст.2100392. - ISSN 18638880 (ISSN), DOI 10.1002/lpor.202100392
Примечания : Cited References: 39. - J.Q. and Y.Z. contributed equally to this work. This research was supported by the National Natural Science Foundation of China (grant nos. 51972118 and 51961145101), International Cooperation Project of National Key Research and Development Program of China (2021YFE0105700), Guangzhou Science & Technology Project (202007020005), the State Key Laboratory of Luminescent Materials and Devices (Skllmd-2021-09), and the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (2017BT01×137). This work is also funded by RFBR according to the research project no. 19-52-80003
Аннотация: It remains a critical challenge to develop narrow-band emitters for wide color gamut displays. Herein, it is designed by the selective site occupancy engineering and an unprecedented narrow-band green-emitting phosphor is prepared through chemical substitution. By introducing Ga3+ ions into Sr2LiAlO4:Eu2+ phosphor, the distribution of Eu2+ ions in Sr1 and Sr2 sites is effectively controlled, and only one type of luminescent centers Eu2+(Sr1) is remained in Sr2LiAl0.6Ga0.4O4:Eu2+ due to the compression effect of Sr2O8 polyhedra. Sr2LiAl0.6Ga0.4O4:Eu2+ phosphor presents an extremely narrow-band green emission centered at 512 nm with a full-width at half-maximum of only 40 nm. The wide color gamut (107% National Television System Committee) of the as-fabricated white liquid crystal displays and the vivid figures captured from the projector demonstrate the potential application of narrow-band emitter for wide-color gamut displays. This work provides the design principles of realizing narrow-band emission by selective site occupancy engineering and can set the stage for the exploring of Eu2+-activated phosphor for high definition displays.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Liu C., Xia, Zhiguo, Chen M., Molokeev M. S., Liu Q.
Заглавие : Near-infrared luminescence and color tunable chromophores based on Cr3+-Doped Mullite-Type Bi2(Ga,Al)4O9 solid solutions
Место публикации : Inorg. Chem.: American Chemical Society, 2015. - Vol. 54, Is. 4. - P.1876-1882. - ISSN 0020-1669, DOI 10.1021/ic502779d
Примечания : Cited References: 26. - The present work was supported by the National Natural Science Foundations of China (Grants 51002146, 51272242), Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), Beijing Youth Excellent Talent Program (YETP0635), the Funds of the State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University (KF201306), and Fundamental Research Funds for the Central Universities (FRF-TP-14-005A1).
Предметные рубрики: PERSISTENT LUMINESCENCE
PHOSPHORS
PIGMENT
GARNET
OXIDES
FIELD
RED
Аннотация: Cr3+-activated mullite-type Bi2Ga(4-x)AlxO9 (x = 0, 1, 2, 3, and 4) solid solutions were prepared by the solid state reaction, and their spectroscopic properties were investigated in conjunction with the structural evolution. Under excitation at 610 nm, Bi2[Ga(4-y)Aly]3.97O9:0.03Cr3+ (y = 0, 1, 2, 3, and 4) phosphors exhibited broad-band near-infrared (NIR) emission peaking at ?710 nm in the range 650?850 nm, and the optimum Cr3+ concentrations and concentration quenching mechanism were determined. Except for the interesting NIR emission, the body color changed from white (at x = 0) to green (at x = 0.08) for Bi2Ga4?xO9:xCr3+, and from light yellow (at x = 0) to deep brown (at x = 0.08) for Bi2Al4?xO9:xCr3+, respectively. Moreover, as a result of variable Al/Ga ratio, the observed body color for Bi2[Ga(4-y)Aly]3.97O9:0.03Cr3+ (y = 0, 1, 2, 3, and 4) varied from deep brown to green. The relationship between the observed colors and their diffuse reflectance spectra were also studied for the understanding of the different absorption bands. The results indicated that Cr3+-doped Bi2Ga(4-x)AlxO9 solid solutions appeared as the bifunctional materials with NIR phosphors and color-tunable pigments.
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