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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova O. S., Ivantsov R. D., Edelman I. S., Petrakovskaja E. A.
Заглавие : A comparative study of γ-Fe2O3 and ε-Fe2O3 nanoparticles arising in borate glasses doped with Fe and Gd
Место публикации : J. Sib. Fed. Univ. Math. Phys. - 2016. - Vol. 9, Is. 4. - P.459–462. - ISSN 1997-1397, DOI 10.17516/1997-1397-2016-9-4-459-462; Журн. СФУ. Сер. "Математика и физика"
Примечания : Cited References: 6. - The work was supported partly by the RFBR, 14-02-01211-a, and by the President of Russia Grant NSh-7559.2016.2.
Ключевые слова (''Своб.индексиров.''): magnetic nanoparticles--magnetic circular dichroism--magnetic measurements--магнитные наночастицы--магнитный круговой дихроизм--магнитные измерения
Аннотация: Formation and properties of the iron oxides γ -Fe2O3 and ϵ-Fe2O3 nanoparticles arising in glasses of basic compositions Ge2O-K2O-Al2O3-B2O3 and K2O-Al2O3-B2O3 doped with different concentrations of Fe2O3 and Gd2O3 and subjected to the additional thermal treatment are studied. The X-ray diffraction, TEM microscopy, magnetooptical effects, and electron spin resonance study allow elucidating the matrix and Gd role in determining the nanoparticle properties.Изучены свойства наночастиц γ-Fe2O3 и ϵ-Fe2O3, формирующихся в стеклах основного состава Ge2O-K2O-Al2O3-B2O3 и K2O-Al2O3-B2O3, допированных Fe2O3 и Gd2O3 и подвергнутых дополни- тельной термической обработке. Результаты исследования рентгеновской дифракции, электрон- ной микроскопии, магнитооптических эффектов и электронного спинового резонанса позволили объяснить роль матрицы и гадолиния в определении свойств наночастиц.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Lin C. -R., Ivanova O. S., Petrov D. A., Sokolov A. Е., Chen Y. -Z., Gerasimova M. A., Zharkov S. M., Tseng Y. -T., Shestakov N. P., Edelman I. S.
Заглавие : Amino-functionalized Fe3O4@SiO2 core-shell magnetic nanoparticles for dye adsorption
Место публикации : Nanomaterials. - 2021. - Vol. 11, Is. 9. - Ст.2371. - ISSN 20794991 (ISSN), DOI 10.3390/nano11092371
Примечания : Cited References: 35. - The authors are thankful for the financial support the Russian Foundation for Basic Research, Grant № 19-52-52002, Ministry of Science and Technology of Taiwan, Grants MOST № 108-2923-M-153-001-MY3 and № 109-2112-M-153-003-, the Russian Foundation for Basic Research with Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, the research project number 19-42-240005: “Features of the electronic structure, magnetic properties and optical excitations in nanocrystals of the multifunctional magnetic chalcogenides Fe3S4 and FeSe”. We thank also the SFU Joint Scientific Center supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation, where the Transmission Electron Microscopy studies were carried out
Аннотация: Fe3O4@SiO2 core-shell nanoparticles (NPs) were synthesized with the co-precipitation method and functionalized with NH2 amino-groups. The nanoparticles were characterized by X-ray, FT-IR spectroscopy, transmission electron microscopy, selected area electron diffraction, and vibrating sample magnetometry. The magnetic core of all the nanoparticles was shown to be nanocrystalline with the crystal parameters corresponding only to the Fe3O4 phase covered with a homogeneous amorphous silica (SiO2) shell of about 6 nm in thickness. The FT-IR spectra confirmed the appearance of chemical bonds at amino functionalization. The magnetic measurements revealed unusually high saturation magnetization of the initial Fe3O4 nanoparticles, which was presumably associated with the deviations in the Fe ion distribution between the tetrahedral and octahedral positions in the nanocrystals as compared to the bulk stoichiometric magnetite. The fluorescent spectrum of eosin Y-doped NPs dispersed in water solution was obtained and a red shift and line broadening (in comparison with the dye molecules being free in water) were revealed and explained. Most attention was paid to the adsorption properties of the nanoparticles with respect to three dyes: methylene blue, Congo red, and eosin Y. The kinetic data showed that the adsorption processes were associated with the pseudo-second order mechanism for all three dyes. The equilibrium data were more compatible with the Langmuir isotherm and the maximum adsorption capacity was reached for Congo red.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Lin, Chun-Rong, Ivanova O. S., Edelman I. S., Knyazev Yu. V., Zharkov S. M., Petrov D. A., Sokolov A. Е., Svetlitsky E. S., Velikanov D. A., Solovyov, Leonid A., Chen, Ying-Zhen, Tseng, Yaw-Teng
Заглавие : Carbon double coated Fe3O4@C@C nanoparticles: Morphology features, magnetic properties, dye adsorption
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [19-52-52002]; Ministry of Science and Technology of TaiwanMinistry of Science and Technology, Taiwan [108-2923-M-153-001-MY3, 109-2112-M-153-003]; Joint Scientific Center of the Siberian Federal University [FSRZ-2020-0011]; Ministry of Science and Higher Education of the Russian Federation
Место публикации : Nanomaterials. - 2022. - Vol. 12, Is. 3. - Ст.376. - ISSN 2079-4991(eISSN), DOI 10.3390/nano12030376
Примечания : Cited References: 44. - The work was supported financially by the Russian Foundation for Basic Research, Grant No. 19-52-52002 and Ministry of Science and Technology of Taiwan, Grants MOST No. 108-2923-M-153-001-MY3 and No. 109-2112-M-153-003-. The support was obtained also from the Joint Scientific Center of the Siberian Federal University supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation, where the Transmission Electron Microscopy studies were carried out
Предметные рубрики: SOLID-PHASE EXTRACTION
FE3O4 NANOPARTICLES
PROFILE REFINEMENT
Аннотация: This work is devoted to the study of magnetic Fe3O4 nanoparticles doubly coated with carbon. First, Fe3O4@C nanoparticles were synthesized by thermal decomposition. Then these synthesized nanoparticles, 20–30 nm in size were processed in a solution of glucose at 200 °C during 12 h, which led to an unexpected phenomenon – the nanoparticles self-assembled into large conglomerates of a regular shape of about 300 nm in size. The morphology and features of the magnetic properties of the obtained hybrid nanoparticles were characterized by transmission electron microscopy, differential thermo-gravimetric analysis, vibrating sample magnetometer, magnetic circular dichroism and Mössbauer spectroscopy. It was shown that the magnetic core of Fe3O4@C nanoparticles was nano-crystalline, corresponding to the Fe3O4 phase. The Fe3O4@C@C nanoparticles presumably contain Fe3O4 phase (80%) with admixture of maghemite (20%), the thickness of the carbon shell in the first case was of about 2–4 nm. The formation of very large nanoparticle conglomerates with a linear size up to 300 nm and of the same regular shape is a remarkable peculiarity of the Fe3O4@C@C nanoparticles. Adsorption of organic dyes from water by the studied nanoparticles was also studied. The best candidates for the removal of dyes were Fe3O4@C@C nanoparticles. The kinetic data showed that the adsorption processes were associated with the pseudo-second order mechanism for cationic dye methylene blue (MB) and anionic dye Congo red (CR). The equilibrium data were more consistent with the Langmuir isotherm and were perfectly described by the Langmuir–Freundlich model.
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4.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Lin C. R., Chen C. C., Li O., Hsu, Hua-Shu, Ivantsov R. D., Zharkov S. M., Edelman I. S., Velikanov D. A., Ovchinnikov S. G.
Заглавие : Chemically synthesized Cu1-xFexCr2Se4 nanoparticles. Morphology and magnetic properties
Коллективы : International Conference on Magnetism
Место публикации : 20th Int. Conf. on Magnetism (ICM-2015): book of abstracts. - 2015. - Ст.TU.F-P88
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5.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Samoshkina Yu. E., Petrov D. A., Rautskii M. V., Neznakhin D. S., Stepanova E. A., Stepanov A. L.
Заглавие : Co nanoparticles localized in matrices of Various types: magnetooptical and magnetotransport properties
Коллективы : Российская академия наук, Физико-технический институт им. Е.К. Завойского ФИЦ Казанского научного центра РАН, Казанский (Приволжский) федеральный университет, Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium
Место публикации : VIII Euro-Asian symposium "Trends in magnetism" (EASTMAG-2022): Book of abstracts/ program com. S. G. Ovchinnikov [et al.]. - 2022. - Vol. 1, Sect.: Magnetotransport, magnetooptics and magnetophotonics. - Ст.D.P14. - P.466-467. - ISBN 978-5-94469-051-7
Примечания : Cited References: 8. - This research was funded by the Russian Science Foundation grant No. 21-72-00061
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vorobyev S. A., Saikova S. V., Novikova S. A., Fetisova O. Y., Zharkov S. M., Krylov A. S., Likhatski M. N., Mikhlin Y. L.
Заглавие : Colloidal and immobilized nanoparticles of lead xanthates
Место публикации : ACS Omega. - 2019. - Vol. 4, Is. 7. - P.11472-11480. - ISSN 24701343 (ISSN), DOI 10.1021/acsomega.9b00841
Примечания : Cited References: 56. - This research was supported by Russian Science Foundation, project 18-17-00135.
Аннотация: Although nanoparticles of heavy metal xanthates and their hydrosols can play important roles in froth flotation, environmental issues, analytics, and manufacturing of metal sulfide nanocomposites, they have received little attention. We studied colloidal solutions and immobilized particles prepared via interaction of aqueous lead nitrate with alkyl xanthates applying UV−vis absorption spectroscopy, dynamic light scattering, zeta potential measurement, thermogravimetry analysis, Fourier transform infrared spectroscopy, Raman scattering, X-ray photoelectron spectroscopy, atomic force microscopy, and transmission electron microscopy. The hydrodynamic diameter of colloidal particles of Pb(SSCOR)2 decreased from 500 to 50 nm with an increase in the alkyl radical length and the initial xanthate to lead ratio (X/Pb); the zeta potential magnitude varied similarly, although it remained negative. The effect of pH in the range of 4.5−11 was minor, but the colloids produced using excess of Pb2+ in alkaline media were close to PbX and decomposed much easier than PbX2. The uptake of lead xanthates on supports was generally low because of negative charges of the colloids; however, 50−100 nm thick PbX2 films were deposited on PbS and SiO2 from the media of X/Pb 2 and pH 9 because of preadsorption of Pb2+, while nanorods formed on highly oriented pyrolytic graphite.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Churilov G. N., Nikolaev N. S., Osipova I. V., Cherepakhin A. V., Nemtsev I. V., Velikanov D. A., Andyuseva V. G.
Заглавие : Core-shell Nanosize Particles Mg@Ni: Synthesis and Properties
Место публикации : J. Sib. Fed. Univ. Math. Phys. - 2019. - Vol. 12, Is. 1. - P.28-35. - ISSN 1997-1397, DOI 10.17516/1997-1397-2019-12-1-28-35; \b Журнал СФУ. Математика и физика. - ISSN 2313-6022(eISSN)
Примечания : Cited References: 12
Ключевые слова (''Своб.индексиров.''): core-shell--nanopartials--nickel-magnesium--synthesis in plasma--surface coating--частицы ядро–оболочка--наночастицы--никель-магниевые частицы--плазмохимический синтез--покрытие поверхности частицы
Аннотация: In this paper, we study particles with metallic core (magnesium) - metal shell (nickel) structure, synthesized in metal-containing plasma of high frequency arc discharge. X-ray diffraction analysis, X-ray fluorescence analysis and scanning electron microscopy show that the particles have a uniform nickel shell, which is also indirectly confirmed by comparing the results of hydrogenation of Mg and Mg@Ni particles. Measurement of volume magnetization indicates that shell thickness of most particles is not more than 22 nm.В данной работе исследованы частицы со структурой металлическое ядро (магний) - металлическая оболочка (никель), полученные в металлсодержащей высокочастотной плазме дугового разряда. Методами рентгенофазового анализа, рентгенофлуоресцентного анализа, сканирующей электронной микроскопии показано, что частицы имеют сплошную никелевую оболочку, что также косвенно подтверждается сравнением результатов гидрирования частиц Mg и Mg@Ni. С помощью измерений объемной намагниченности установлено, что наибольшая часть частиц имеет толщину оболочек не более 22 нм.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Semenov S. V., Balaev D. A., Shaykhutdinov K. A., Rogozin D. Y.
Заглавие : Day plots of bacterial magnetite from sediments of shira lake (Khakassia, Russia)
Место публикации : J. Sib. Fed. Univ. Math. Phys. - 2017. - Vol. 10, Is. 2. - P.252-256. - ISSN 1997-1397, DOI 10.17516/1997-1397-2017-10-2-252-256; Журн. СФУ. Сер. "Математика и физика"
Примечания : Cited References: 4
Ключевые слова (''Своб.индексиров.''): nanoparticles--magnetic hysteresis--bacterial magnetite--наночастицы--магнитный гистерезис--бактериальный магнетит
Аннотация: The domain state of magnetite detected in sediments of Shira lake (Khakassia, Russia) was examined by means of magnetic hysteresis. Analysis of experimental data obtained on samples from different parts of bottom sediment cores in terms of Day plots allowed us to conclude that magnetite particles are in the pseudo-single-domain state. This indicates respectively small size of magnetite particles (˂ 100 nm) and reveals their bacterial origin. Biogenic magnetite buried in the bottom sediments can indicate the climatic changes in the Shira lake level in the Late Holocene.Исследовано доменное состояние магнетита, обнаруженного в донных отложениях озера Шира (Хакасия, Россия). Из анализа экспериментальных данных по намагниченности образцов с разных участков керна донных отложений, а также на основе графиков Дэя сделан вывод, что частицы магнетита находятся в псевдооднодоменном состоянии. Это указывает на малый размер частиц магнетита (˂ 100 nm) и подтверждает их бактериальное происхождение. Биогенный магнетит, содержащийся в донных отложениях, может служить индикатором климатических изменений в уровне озера Шира в позднем голоцене.
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9.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Tarasov A. S., Smolyarova T. E., Yakovlev I. A., Lukyanenko A. V., Lyashchenko S. A., Nemtsev I. V.
Заглавие : Hybrid Au-Fe crystalline nanoparticles obtained by MBE
Коллективы : Asian School-Conference on Physics and Technology of Nanostructured Materials, Азиатская школа-конференция по физике и технологии наноструктурированных материалов, Институт автоматики и процессов управления ДВО РАН, Дальневосточный федеральный университет
Место публикации : Fourth Asian school-conference on physics and technology of nanostructured materials (ASCO-NANOMAT 2018): proceedings. - Vladivostok: Dalnauka, 2018. - P.77
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Saikova S., Pavlikov A., Trofimova T., Mikhlin Y., Karpov D., Asanova A., Grigoriev Y., Volochaev M. N., Samoilo A., Zharkov S. M., Velikanov D. A.
Заглавие : Hybrid nanoparticles based on cobalt ferrite and gold: Preparation and characterization
Место публикации : Metals. - 2021. - Vol. 11, Is. 5. - Ст.705. - ISSN 20754701 (ISSN), DOI 10.3390/met11050705
Примечания : Cited References: 74
Аннотация: During the past few decades, hybrid nanoparticles (HNPs) based on a magnetic material and gold have attracted interest for applications in catalysis, diagnostics and nanomedicine. In this paper, magnetic CoFe2O4/Au HNPs with an average particle size of 20 nm, decorated with 2 nm gold clusters, were prepared using methionine as a reducer and an anchor between CoFe2O4 and gold. The methionine was used to grow the Au clusters to a solid gold shell (up to 10 gold deposition cycles). The obtained nanoparticles (NPs) were studied by X-Ray diffraction (XRD), transmis-sion electron microscopy (TEM), Fourier-transform infrared (FT-IR) spectroscopy, X-Ray photoelectron spectroscopy (XPS) and UV-vis spectroscopy techniques. The TEM images of the obtained HNPs showed that the surface of cobalt ferrite was covered with gold nanoclusters, the size of which slightly increased with an increase in the number of gold deposition cycles (from 2.12 ± 0.15 nm after 1 cycle to 2.46 ± 0.13 nm after 10 cycles). The density of the Au clusters on the cobalt ferrite surface insignificantly decreased during repeated stages of gold deposition: 21.4 ± 2.7 Au NPs/CoFe2O4 NP after 1 cycle, 19.0 ± 1.2 after 6 cycles and 18.0 ± 1.4 after 10 cycles. The magnetic measurements showed that the obtained HNPs possessed typical ferrimagnetic behavior, which corresponds to that of CoFe2O4 nanoparticles. The toxicity evaluation of the synthesized HNPs on Chlorella vulgaris indicated that they can be applied to biomedical applications such as magnetic hyperthermia, photothermal therapy, drug delivery, bioimaging and biosensing.
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