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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Timofeev I. V., Arkhipkin V. G., Vetrov S. Y., Zyryanov V. Ya., Lee W.
Заглавие : Enhanced light absorption with a cholesteric liquid crystal layer
Место публикации : Opt. Mater. Express. - 2013. - Vol. 3, Is. 4. - P.496-501. - DOI 10.1364/OME.3.000496
Аннотация: We discuss the trapping features of cholesteric liquid crystal as a self-organized photonic crystal and suggest it for absorption improvement. The imperfection of the absorbing surface is manifested by the reflection originating from the indispensable impedance mismatch. The reflection can be suppressed by an additional surface coating to reflect the light back to the absorber once again. In the simple consideration this reflection loop is possible only twice. For a right-handed CLC coating, the boundary reflection switches the light polarization from left to right circular in the first loop and it switches in the second loop back to the left circular polarization before the emerging light finally escapes from the absorbing process. The enhancement of light absorption is possible in the frequency range as large as the photonic bang gap of the cholesteric layer, which can be adjusted as desired.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kazak N. V., Platunov M. S., Ivanova N. B., Knyazev Yu. V., Bezmaternykh L. N., Eremin E. V., Vasil'ev A. D., Bayukov O. A., Ovchinnikov S. G., Velikanov D. A., Zubavichus Y. V.
Заглавие : Crystal structure and magnetization of a Co3B2O6 single crystal
Место публикации : J. Exp. Theor. Phys.: MAIK Nauka-Interperiodica / Springer, 2013. - Vol. 117, Is. 1. - P.94-107. - ISSN 1063-7761, DOI 10.1134/S1063776113060186
Примечания : Cited References: 43. - The synchrotron measurements were performed at the Kurchatov Center of Synchrotron Radiation and Nanotechnologies (state contract no. 16.552.11.7055).This work was supported by the Russian Foundation for Basic Research (project nos. 12-02-00175-a, 12-02-90410-Ukr_a, 12-02-31543mol_a, 13-02-00958-a), the President of the Russian Federation (grant no. NSh-1044.2012.2), the Siberian Branch of the Russian Academy of Sciences (project no. 38), the Ministry of Education and Science of the Russian Federation (project no. 8365), and an integration project of SO RAN-NAN of Belarus (project no. 29).
Предметные рубрики: ABSORPTION FINE-STRUCTURE
NICKEL ORTHOBORATE
RAY
GDFE3(BO3)(4)
LUDWIGITE
NI3(BO3)2
NI3B2O6
SPECTRA
Аннотация: The crystal structure and magnetic properties of Co3B2O6 single crystals are studied. Orthorhombic symmetry with space group Pnnm is detected at room temperature. The measurements of static magnetization and dynamic magnetic susceptibility reveal two magnetic anomalies at T (1) = 33 K and T (2) = 10 K and an easy-axis magnetic anisotropy. The effective magnetic moment indicates a high-spin state of the Co2+ ion. A spin-flop transition is found at low temperatures and H (sf) = 23 kOe. EXAFS spectra of the K-edge absorption of Co are recorded at various temperatures, the temperature-induced changes in the parameters of the local environment of cobalt are analyzed, and the effective Co-Co and Co-O distances are determined. The magnetic interactions in the crystal are analyzed in terms of an indirect coupling model.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ershov A. E., Isaev I. L., Semina P. N., Markel V. A., Karpov S. V.
Заглавие : Effects of size polydispersity on the extinction spectra of colloidal nanoparticle aggregates
Место публикации : Phys. Rev. B: American Physical Society, 2012. - Vol. 85, Is. 4. - Ст.045421. - P. - ISSN 1098-0121, DOI 10.1103/PhysRevB.85.045421
Примечания : Cited References: 41. - This work was supported by grants from the following foundations of the Russian Federation: Presidium of RAS, OFN RAS, and SB RAS.
Предметные рубрики: METAL FRACTAL CLUSTERS
OPTICAL-PROPERTIES
ABSORPTION
NONLINEARITIES
COMPOSITES
SCATTERING
PARTICLES
SPHERES
GRAINS
Аннотация: We investigate the effect of particle polydispersity on the optical extinction spectra of colloidal aggregates of spherical metallic (silver) nanoparticles, taking into account the realistic interparticle gaps caused by layers of stabilizing polymer adsorbed on the metal surface (adlayers). The spectra of computer-generated aggregates are computed using two different methods. The coupled-multipole method is used in the quasistatic approximation and the coupled-dipole method beyond the quasistatics. The latter approach is applicable if the interparticle gaps are sufficiently wide relative to the particle radii. Simulations are performed for two different particle size distribution functions (bimodal and Gaussian), varying the number of particles per aggregate, and different distribution functions of the interparticle gap width. The strong influence of the latter factor on the spectra is demonstrated and investigated in detail.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gerasimova Y. V., Oreshonkov A. S., Vtyurin A. N., Ivanenko A. A., Isaenko L. I., Ershov A. E., Pogoreltsev E. I.
Заглавие : Infrared absorption investigation of the role of octahedral groups upon the phase transition in the Rb2KMoO3F3 crystal
Коллективы : Russian Foundation for Basic Research [12-02-31205_mol_a]; Ministry of Education and Science of the Russian Federation [8379]; Interdisciplinary Integration Project of the Siberian Branch of the Russian Academy of Science [28]
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2013. - Vol. 55, Is. 11. - P.2331-2334. - ISSN 1063-7834, DOI 10.1134/S1063783413110097
Примечания : Cited References: 10. - This study was supported by the Russian Foundation for Basic Research (project no. 12-02-31205_mol_a), the Ministry of Education and Science of the Russian Federation within the framework of the Russian Federal Target Program "Scientific and Scientific-Pedagogical Human Resources for the Innovative Russia" (agreement no. 8379), and the Interdisciplinary Integration Project of the Siberian Branch of the Russian Academy of Science No. 28.
Аннотация: The infrared absorption spectra of the oxyfluoride Rb2KMoO3F3 have been measured in the frequency range corresponding to stretching vibrations of the Mo-O anion octahedron with the purpose of clarifying their role in the phase transition. A semi-empirical calculation of two possible configurations of quasioctahedral MoO3F3 groups has been performed. The results of the investigations have demonstrated that some octahedra in the crystal structure change the local symmetry from C (3v) to C (2v) due to the phase transition (T = 197 K).
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Герасимова, Юлия Валентиновна, Орешонков, Александр Сергеевич, Втюрин, Александр Николаевич, Иваненко, Александр Анатольевич, Исаенко Л. И., Ершов, Александр Андреевич, Погорельцев, Евгений Ильич
Заглавие : Изучение роли октаэдрических групп при фазовом переходе в кристалле Rb2KMoO3F3 методом инфракрасного поглощения
Место публикации : Физ. тверд. тела. - 2013. - Т. 55, Вып. 11. - С. 2215-2217
Аннотация: Получены спектры инфракрасного поглощения оксифторида Rb2KMoO3F3 в области частот, соответствующих валентным колебаниям Mo-O анионного октаэдра, с целью выяснения их роли при фазовом переходе. Проведен полуэмпирический расчет двух возможных конфигураций квазиоктаэдрических групп MoO3F3. Результаты исследований показали, что при фазовом переходе (T=197 K) в структуре кристалла часть октаэдров меняет локальную симметрию с C3v на C2v.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Kutsak T. V., Sukhachev A. L., Aleksandrovsky A. S., Krylov A. S., Gudim, Irina A., Molokeev M. S.
Заглавие : Spectroscopic properties of ErAl3(BO3)4 single crystal
Место публикации : Chem. Phys.: Elsevier Science, 2014. - Vol. 428. - P.137–143. - ISSN 0301-0104, DOI 10.1016/j.chemphys.2013.11.008. - ISSN 1873-4421
Примечания : Cited References: 43. - The work was supported by the Russian Foundation for Basic Researches grant 12-02-00026, by the Russian President Grants SS-1044.2012.2 and 4828.2012.2, by project No 3.9.5 PSB RAS, and by the Ministry of Education and Science of Russian Federation grant 8365
Предметные рубрики: RARE-EARTH IONS
GREEN UP-CONVERSION
ER3+ IONS
MICROCHIP LASER
ABSORPTION INTENSITIES
YAL3(BO3)4 CRYSTAL
OPTICAL-ABSORPTION
FIELD ANALYSIS
GROWTH
LUMINESCENCE
Ключевые слова (''Своб.индексиров.''): rare earth compounds--er3+--spectroscopic properties--judd-ofelt analysis--luminescence
Аннотация: Single crystal of ErAl3(BO3)4 was grown and its structure was studied. Polarized absorption spectra of ErAl3(BO3)4 single crystal were measured in the spectral range 1670–330 nm (6000–30000 cm−1). The Judd–Ofelt spectroscopic parameters have been determined: Ω2 = 4.87 × 10−20 cm2, Ω4 = 2.49 × 10−20 cm2, Ω6 = 2.72 × 10−20 cm2. These parameters have been used to calculate the radiative transition probabilities, the multiplet luminescence branching ratios and the fluorescence life times of the manifolds. The luminescence spectra due to transitions 2H11/2 → 4I15/2 (526 nm), 4S3/2 → 4I15/2 (548 nm), 4F9/2 → 4I15/2 (662 nm), 2H11/2 → 4I13/2 + 4I9/2 → 4I15/2 (800 nm) and 4S3/2 → 4I13/2 (855 nm) were recorded in α, σ and π polarizations. The most intensive luminescence belonged to 4S3/2 → 4I15/2 transition (548 nm).Поляризованные спектры поглощения ErAl3 (BO3) 4 монокристалла были измерены в спектральном диапазоне 1670-330 нм (6000-30000 см-1). Спектроскопические параметры Джадда-Офельта были определены как: Ω2 = 4,87 • 10-20 см2, Ω4 = 2.49 • 10-20 см2, Ω6 = 2,72 • 10-20 см2. Параметры были использованы для расчета вероятностей излучающих переходов, мультиплетные отношения люминесценции раскола и времена жизни мультиплетов. Спектры люминесценции за счет переходов 2П11 / 2 → 4I15 / 2 (526 нм), 4S3 / 2 → 4I15 / 2 (548 нм), 4F9 / 2 → 4I15 / 2 (662 нм), 2П11 / 2 → 4I13 / 2 + 4I9 / 2 → 4I15 / 2 (800 нм) и 4S3 / 2 → 4I13 / 2 (855 нм) были записаны в α, σ и π поляризации. Наиболее интенсивное свечение принадлежало переходу 4S3 / 2 → 4I15 / 2 (548 нм).
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Anghel L., Balasoiu M., Ishchenko L. A., Stolyar S. V., Kurkin T. S., Rogachev A. V., Kuklin A. I., Kovalev Yu.S., Raikher Yu.L., Iskhakov R. S., Duca G.
Заглавие : Characterization of bio-synthesized nanoparticles produced by Klebsiella oxytoca
Коллективы : International Workshop on SANS-YuMO User Meeting at the Start-up of Scientific Experiments on the IBR-2M Reactor: Devoted to the 75th Anniversary of Yu M Ostanevich's Birth
Место публикации : Journal of Physics: Conference Series. - 2012. - Vol. 351, Is. 1. - Ст.012005. - P. - ISSN 1742-6588, DOI 10.1088/1742-6596/351/1/012005
Ключевые слова (''Своб.индексиров.''): absorption peaks--biominerals--chemical compositions--exopolysaccharides--ferrihydrites--fitting procedure--ftir spectroscopy--klebsiella oxytoca--model calculations--morphological analysis--radius of gyration--scattering objects--small angle x-ray scattering--structural and morphological properties--structural investigation--uv-vis spectroscopy--water dispersion--water-dispersed--experiments--nanoparticles--polysaccharides--raman spectroscopy--scattering--ultraviolet visible spectroscopy--synthesis (chemical)
Аннотация: Structural and morphological properties of biogenic ferrihydrite nanoparticles produced by bacteria Klebsiella oxytoca are investigated. The stability of water dispersions of biomineral particles produced by Klebsiella oxytoca was monitored by UV-Vis spectroscopy. Their chemical composition was determined by FT-IR spectroscopy. The vibrational spectra of biogenic ferrihydrite nanoparticles revealed typical absorption peaks of exopolysaccharides. Morphological analysis based on Raman spectroscopy indicated the presence of exopolysaccharides on the surface as well as inside the pores of the ferrihydrite nanoparticles. Structural investigations of ultrasonic assisted samples of different concentration of water dispersed particles were performed using small angle X-ray scattering analysis. Model calculations and fitting procedures revealed scattering objects of an elongated shape with 6.73В±0.16 nm radius of gyration. В© Published under licence by IOP Publishing Ltd.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Popov E. A., Kotlyarskii M. M., Edelman I. S.
Заглавие : Temperature and field dependence of exciton-magnon absorption of NaMnCl//3.
Место публикации : Physica Status Solidi B - Basic Research. - 1985. - Vol. 132, Is. 2. - P.465-470. - ISSN 0370-1972
Ключевые слова (''Своб.индексиров.''): band structure--light - absorption--sodium compounds - optical properties--exciton-magnon absorption--sodium manganese chloride--magnetic materials
Аннотация: The behaviour of the optical absorption bands of NaMnCl//3 is experimentally studied in the region of the **6A//1//g to **4A//1//g, **4E//g(**4G) transition of the Mn**2** plus ion in the temperature range 1. 8 to 20 K and in magnetic fields up to 20 T. Exciton and its 'hot' magnon sidebands are observed in the spectrum. The anomalous temperature dependence of the exciton-magnon bands intensity is explained by participation of magnons with wave vector K does not equal 0 in absorption. The low energy exciton-magnon band is supposed to be due to simultaneous creation of an exciton and annihilation of three thermally created magnons.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ikonnikov D. A., Malakhovskii A. V., Sukhachev A. L., Zaitsev A. I., Aleksandrovsky A. S., Jubera V.
Заглавие : Spectroscopic properties of Nd3+ in orthorhombic δ-BiB3O6 crystal
Место публикации : Opt. Mater.: ELSEVIER SCIENCE BV, 2012. - Vol. 34, Is. 11. - P.1839-1842. - ISSN 0925-3467, DOI 10.1016/j.optmat.2012.05.016
Примечания : Cited References: 23. - The work was supported by Ministry of Education and Science of Russian Federation (Contract 16.740.11.0150), by Russian Foundation for Basic Researches Grant 12-02-00026, Grant of President of Russian Federation for support of leading scientific schools No. SS-4828.2012.2, Grant No. SFU.F12, and Projects No. 28, 43 and No. 101 of SB RAS.
Предметные рубрики: SPECTRAL-LINE INTENSITIES
RARE-EARTH IONS
LASER CRYSTAL
NdAl3(BO3)(4) NAB
OPTICAL-SPECTRA
BiB3O6
SYSTEMS
GROWTH
Er3+
Tm3+
Ключевые слова (''Своб.индексиров.''): neodymium--orthorhombic bismuth triborate--absorption--judd-ofelt analysis
Аннотация: Absorption spectra of the Nd3+ ions in an orthorhombic δ-BiB3O6 single crystal were measured in the spectral range 11,000-20,500 cm-1. The f-f transition intensities were analyzed in terms of the Judd-Ofelt theory, and the following parameters of the theory were obtained: Ω2 = 6.35 × 10-20 cm2, Ω4 = 4.86 × 10-20 cm 2, and Ω6 = 11.233 × 10-20 cm 2. The strengths, spontaneous emission probabilities, branching ratios, spectroscopic quality factor and excited state radiative lifetime were calculated for laser transitions from the 4F3/2 state to 4IJ manifold. Spectroscopic properties of Nd 3+:δ-BiB3O6 crystal favor lasing at 1.3 μm, where this crystal possesses near non-critical phase matching for second harmonic generation. © 2012 Elsevier B.V. All rights reserved.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kuzubov A. A., Eliseeva N. S., Krasnov P. O., Tomilin F. N., Fedorov A. S., Tolstaya A. V.
Заглавие : Calculating the energy of vacancies and adatoms in a hexagonal SiC monolayer
Место публикации : Russ. J. Phys. Chem. A: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 86, Is. 7. - P.1091-1095. - ISSN 0036-0244, DOI 10.1134/S0036024412070138
Примечания : Cited References: 21
Предметные рубрики: INITIO MOLECULAR-DYNAMICS
ELECTRONIC-PROPERTIES
ABSORPTION-SPECTRA
Ключевые слова (''Своб.индексиров.''): silicon carbide--defects--adatoms--density functional method
Аннотация: It is noted that the development of semiconductor SiC-electronics is prevented by a low quality of grown silicon carbide single crystals. It is found that structural defects of a substrate penetrating into an epitaxial layer upon subsequent homoepitaxial growth can considerably degrade a device's characteristics. We investigate the effect of the deformation of a hexagonal SiC monolayer on vacancy stability and material properties, and study the processes of silicon and carbon adatom migration over a surface of SiC.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Gnatchenko S. L., Kachur I. S., Piryatinskaya V. G., Sukhachev A. L., Gudim, I. A.
Заглавие : Optical and magneto-optical properties of Nd0.5Gd0.5Fe3(BO3)4 single crystal in the near IR spectral region
Место публикации : J. Alloys Compd.: Elsevier, 2012. - Vol. 542. - P.157-163. - ISSN 0925-8388, DOI 10.1016/j.jallcom.2012.07.061
Примечания : Cited References: 23. - The work was supported by the Russian Foundation for Basic Researches Grant 12-02-00026 and by the Russian President Grant SS-1044.2012.2.
Предметные рубрики: MAGNETIC CIRCULAR-DICHROISM
GDFE3(BO3)(4)
YB3+
ER3+
ND3+
Ключевые слова (''Своб.индексиров.''): rare earth compounds--nd3+--antiferromagnets--multiferroics--magnetic circular dichroism--absorption spectra
Аннотация: Polarized optical absorption and magnetic circular dichroism (MCD) spectra of the trigonal multiferroic Nd0.5Gd0.5Fe3(BO3)4 were studied in the region of transitions 4I9/2 → 4F3/2 and 4I9/2 → (4F5/2 + 2H9/2) in Nd3+ ion. Components of the crystal field splitting of the states were identified with the help of MCD and polarized absorption spectra. Splitting of the Nd3+ absorption lines caused by the magnetic ordering were observed. Splitting of Nd3+ ground state in Fe-sublattice exchange field was found to be ∼9 cm−1 at 5.7 K. The Zeeman splitting of some absorption lines in the external magnetic field and changes of the effective Landé factors in the C3-direction as a result of the corresponding optical transitions were found. Peculiarities in the temperature behavior of the absorption lines connected both with the ground and excited states were revealed. Peculiarities connected with the excited states testify to the local crystal distortions in the excited states.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Sukhachev A. L., Leont'ev A. A., Gudim, I. A., Krylov A. S., Aleksandrovsky A. S.
Заглавие : Spectroscopic properties of Nd0.5Gd0.5Fe3(BO3)4 single crystal
Место публикации : J. Alloys Compd.: Elsevier, 2012. - Vol. 529. - P.38-43. - ISSN 0925-8388, DOI 10.1016/j.jallcom.2012.03.066
Примечания : Cited References: 51. - The work was supported by the Russian Foundation for Basic Researches grant 12-02-00026, by the Russian President Grants SS-1044.2012.2 and SS-4828.2012.2, by Ministry of Education and Science of Russian Federation (Contract 16.740.11.0150), by grant no. SFU.F12 and by Projects No. 28, 43 and No. 101 of SB RAS.
Предметные рубрики: SPECTRAL-LINE INTENSITIES
RARE-EARTH IONS
MAGNETIC-PROPERTIES
NDAL3(BO3)(4) NAB
OPTICAL-SPECTRA
LASER CRYSTAL
TRANSITIONS
ABSORPTION
ND3+
PR3+
Ключевые слова (''Своб.индексиров.''): magnetically ordered materials--rare earth alloys and compounds--transition metal alloys and compounds--optical properties
Аннотация: The polarized absorption spectra of trigonal single crystal Nd0.5Gd0.5Fe3(BO3)4 were measured in the spectral range 10,000–22,000 cm−1. The d–d and f–f transitions spectra were separated. The f–f transitions intensities were analyzed in terms of the Judd–Ofelt theory in a ferroborate with huntite structure for the first time, and the following parameters of the theory were obtained: Ω2 = 4.4 × 10−20 cm2, Ω4 = 8.04 × 10−20 cm2, and Ω6 = 8.25 × 10−20 cm2. The strengths, spontaneous emission probabilities, branching ratios, spectroscopic quality factor and excited state lifetime were calculated for transitions from the 4F3/2 state to 4IJ manifold. All the obtained spectroscopic characteristics were compared with those of alumoborates with the same crystal structure.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Sukhachev A. L., Vasil'ev A. D., Leont'ev A. A., Kartashev A. V., Temerov V. L., Gudim, I. A.
Заглавие : Nature of optical properties of GdFe3(BO3)4 and GdFe2.1Ga0.9(BO3)4 crystals and other 3d5 antiferromagnets
Место публикации : Eur. Phys. J. B: Springer, 2012. - Vol. 85, Is. 2. - P.80. - ISSN 1434-6028, DOI 10.1140/epjb/e2012-20953-1
Примечания : Cited References: 70. - The work was supported by the Russian Foundation for Basic Researches Grant 12-02-00026 and by Russian President Grant NSh-1044.2012.2.
Предметные рубрики: IRON BORATE GDFE3(BO3)4
D-D TRANSITIONS
EARTH FERROBORATES RFE3(BO3)4
ABSORPTION-SPECTRA
OCTAHEDRAL COMPLEXES
ELECTRONIC-STRUCTURE
NEEL TEMPERATURE
FINE-STRUCTURE
EXCHANGE
IONS
Аннотация: Influence of the partial substitution of paramagnetic Fe3+ ions by diamagnetic Ga3+ ions in the trigonal crystal GdFe3 (BO3)4 on its optical and magnetic properties is studied and discussed in connection with problems common for all antiferromagnets containing 3d 5 ions. Polarized optical absorption spectra and linear birefringence of GdFe3 (BO3)4 and GdFe2.1Ga0.9 (BO3)4 single crystals have been measured in the temperature range 85–293 K. Specific heat temperature dependence (2–300 K) and structure of GdFe2.1Ga0.9 (BO3)4 crystal have been also studied. As a result of substitution of 30% Fe to Ga the Neel temperature diminishes from 38 till 16 K, the strong absorption band edge shifts on 860 cm-1 (0.11 eV) to higher energy and the d-d transitions intensity decreases substantially larger than the Fe concentration does. Strong absorption band edge is shown to be due to Mott-Hubbard transitions. Correlation between position of the strong absorption band edge and the Neel temperature of antiferromagnets has been revealed. Properties of the doubly forbidden d-d transitions in the studied crystals and in other antiferromagnets are explained within the framework of the model of the exchange-vibronic pair absorption, which is theoretically analyzed in detail. The model permitted us to determine the connection between parameters of d-d absorption bands (intensity, width and their temperature dependences), on the one hand, and the exchange, spin-orbit and electron-lattice interactions, on the other hand.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Belyaev B. A., Zotov A. V., Solovev P. N.
Заглавие : Micromagnetic modeling of static and dynamic properties of ferromagnetic/antiferromagnetic bilayer
Коллективы : International Siberian Conference on Control and Communications
Место публикации : Int. Sib. Conf. on Control and Communicat.: Proc.: IEEE, 2013. - Conference code: 102462Cт. 6693573. - ISSN 978-1-4799-1060-1, DOI 10.1109/SIBCON.2013.6693573
Примечания : Cited References: 13
Предметные рубрики: EXCHANGE-BIAS
DEPENDENCE
Ключевые слова (''Своб.индексиров.''): absorption spectrum--exchange bias--micromagnetic modeling
Аннотация: Static and dynamic properties of ferromagnetic (F) antiferromagnetic (AF) bilayer have been studied by using micromagnetic calculations. The reasonable value of exchange bias field has been obtained. In addition, we have shown the strong dependence of a resonance frequency F/AF structure on an angle between an external magnetic field and an easy axis of the bilayer.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Slyusareva E. A., Sizykh A. G., Gerasimova M. A., Slabko V. V., Myslivets S. A.
Заглавие : Laser photolysis of fluorone dyes in a chitosan matrix
Место публикации : Quantum Electron.: Turpion LTD, 2012. - Vol. 42, Is. 8. - P.687-692. - ISSN 1063-7818, DOI 10.1070/QE2012v042n08ABEH014860
Примечания : Cited References: 32
Предметные рубрики: POLY(VINYL ALCOHOL) MATRIX
XANTHENE DYES
ROSE-BENGAL
FLUORESCENCE PROPERTIES
DELAYED FLUORESCENCE
ORGANIC-MOLECULES
TRIPLET-STATE
EXCITATION
ABSORPTION
PHOSPHORESCENCE
Ключевые слова (''Своб.индексиров.''): laser photolysis--fluorescein--dibromofluorescein--eosin y--erythrosin b--rose bengal--chitosan--photobleaching kinetics--two-step absorption
Аннотация: Kinetics of laser-induced photobleaching of fluorone dyes (fluorescein, dibromofluorescein, eosin Y, erythrosin B, Rose Bengal) is studied in a chitosan matrix. For all dyes the bleaching kinetics at the intensities of laser radiation 0.7 — 11.9 W cm-2 demonstrates quasi-monomolecular behaviour. The results are analysed using a kinetic model, based on the four-level (S0, S1, T1, Tn) scheme of the dye with chemically active triplet states taken into account. It is shown that the rate constants of the chemical reaction involving higher triplet states in the dyes studied amount to (3.9 — 18.6) × 106 s-1 and exceed the analogous values for the reaction involving the first lower triplet states by nine orders of magnitude. The rate of reaction involving the first triplet states appeared to be higher by one — two orders of magnitude than that in the case of higher triplet states involved because of low population of the latter. The possible mechanism of dye bleaching with participation of chitosan that consists in reduction of the dye to the leuco form by transfer of hydrogen from the chitosan matrix is discussed.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Slyusareva E. A., Tomilin F. N., Sizykh A. G., Tankevich E. Y., Kuzubov A. A., Ovchinnikov S. G.
Заглавие : The effect of halogen substitution on the structure and electronic spectra of fluorone dyes
Место публикации : Opt. Spectrosc.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2012. - Vol. 112, Is. 5. - P.671-678. - ISSN 0030-400X, DOI 10.1134/S0030400X12040194
Примечания : Cited References: 44. - This work was supported by the FTsP Kadry GK-P333 and by the Siberian Branch of the Russian Academy of Sciences (Integration project no. 2). We are grateful to the Joint Supercomputer Center of the Russian Academy of Sciences (Moscow) and to the Complex of High-Performance Computations of the IKIT of Siberian Federal University. E. A. Slyusareva acknowledges support from the German Academic Exchange Service and the Ministry of Education and Science of the Russian Federation (the program "Mikhail Lomonosov II") of scientific research at the University of Regensburg and in the Helmholtz Center in Berlin (Germany).
Предметные рубрики: POLARIZABLE CONTINUUM MODEL
BORIC-ACID GLASS
XANTHENE DYES
FLUORESCEIN DERIVATIVES
DELAYED FLUORESCENCE
EOSIN-Y
ABSORPTION
PHOSPHORESCENCE
TRANSITIONS
EXCITATION
Аннотация: By means of the B3LYP density functional method with the use of the polarized continuum model PCM, we have performed quantum-chemical computations of the electronic absorption and fluorescence spectra of fluorone dianions: fluorescein, dibromofluorescein, eosin, erythrosine, and Rose Bengal in vacuum and methanol. We have revealed conformational features of the structure of fluorone dianions (charge redistribution, changes in the bond lengths and angles between bonds) second by the halogen substitution, the transition from the ground state to an excited state, and the change of the solvent (vacuum-methanol). Absorption and fluorescence wavelengths, constant dipole moments, transition dipole moments, and oscillator strengths have been calculated. We have showed that, upon halogenation of fluorones, the absorption spectra are redshifted and the Stokes shift decreases, which is qualitatively consistent with experimental results.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mikhlin Y. L., Vishnyakova E. A., Romanchenko A. S., Saikova S. V., Likhatski M. N., Larichev Y. V., Tuzikov F. V., Zaikovskii V. I., Zharkov S. M.
Заглавие : Oxidation of Ag nanoparticles in aqueous media: Effect of particle size and capping
Место публикации : Appl. Surf. Sci.: Elsevier Science, 2014. - Vol. 297. - P.75-83. - ISSN 0169-4332, DOI 10.1016/j.apsusc.2014.01.081. - ISSN 1873-5584
Примечания : Cited References: 58. - This work was partially financially supported by the Ministry of Education and Science of RF (Grant 8580) and RFBR (12-03-31178).
Предметные рубрики: EX-SITU XPS
POLYCRYSTALLINE SILVER ELECTRODES
RAY PHOTOELECTRON-SPECTROSCOPY
METAL NANOPARTICLES
ELECTROCHEMICAL OXIDATION
ABSORPTION SPECTROSCOPY
PYROLYTIC-GRAPHITE
OXYGEN-ADSORPTION
TRANSFORMATIONS
DISSOLUTION
Ключевые слова (''Своб.индексиров.''): silver nanoparticles--oxidation--resistive switching effect--x-ray photoelectron spectroscopy
Аннотация: Many applications and environmental impact of silver-bearing nanomaterials critically depend upon their specific reactivity, which is still poorly understood. Here, silver nanoparticles (Ag NPs) of about 3-5 nm and 10-12 nm in diameter, uncapped and capped with l-glucose or citrate, were prepared, characterized using UV-vis absorption spectroscopy, SAXS, TEM, and their (electro) chemical oxidation was examined in comparison with each other and bulk metal applying scanning tunneling microscopy and spectroscopy, cyclic voltammetry, and XPS. A resistive switching effect was found in the tunneling spectra measured in air at the smaller uncapped Ag NPs deposited on HOPG and was interpreted in terms of Ag transfer between the particle and the probe. The anodic oxidation of these Ag NPs in 1 M NaOH yielded 3D Ag2O, while only a layer of "primary"Ag(I) oxide emerged on larger uncapped nanoparticles during the potential sweep. The formation of AgO at higher potentials proceeded readily at the "primary"oxide but was retarded at the smaller NPs. The citrate- and glucose-capping substantially impeded the formation both of Ag2O and AgO. The findings highlighted, particularly, a non-trivial effect of particle size and transient mobilization of Ag species on the reactions of silver nanoparticles. (c) 2014 Elsevier B.V. All rights reserved.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kosyrev N. N., Shvets V. A., Mikhailov N. N., Varnakov S. N., Ovchinnikov S. G., Rykhlitskii S. V., Yakovlev I. A.
Заглавие : Ellipsometric technique for determining in situ the absorption coefficient of semiconducting nanolayers
Коллективы : Ministry of Education and Science of the Russian Federation [14.513.11.0016, 14.132.21.1709, 14.V37.21.1276]; Program Supporting Leading Scientific Schools [NSh-1044.2012.2]; Russian Foundation for Basic Research [13-02-01265]; Physics Division, Russian Academy of Sciences [2.4.1]; Presidium of the Russian Academy of Sciences [23.34]; Siberian-Far East Branches, Russian Academy of Sciences [85]; Siberian Branch, Russian Academy of Sciences [38]
Место публикации : Tech. Phys.: MAIK Nauka-Interperiodica / Springer, 2014. - Vol. 59, Is. 5. - P.736-739. - ISSN 1063-7842, DOI 10.1134/S1063784214050144. - ISSN 1090-6525
Примечания : Cited References: 17. - This work was supported financially by the Ministry of Education and Science of the Russian Federation (state contract no. 14.513.11.0016, agreement nos. 14.132.21.1709 and 14.V37.21.1276), the Program Supporting Leading Scientific Schools (project no. NSh-1044.2012.2), Russian Foundation for Basic Research (project no. 13-02-01265), Physics Division, Russian Academy of Sciences (program no. 2.4.1), Presidium of the Russian Academy of Sciences (program no. 23.34), Siberian-Far East Branches, Russian Academy of Sciences (project no. 85), and integration project no. 38 of the Siberian Branch, Russian Academy of Sciences.
Предметные рубрики: LAYERS
Аннотация: An algorithm that makes it possible to solve the inverse problem of ellipsometry aimed at determining the absorption coefficient on the basis of a single-zone ellipsometric experiment during the growth of thin semiconducting films is developed and implemented. The technique is based on analysis of the variation of ellipsometric parameters I and Delta directly during the growth. The algorithm is tested in synthesis of Si/SiO2/Si(100) and Hg1 - x Cd (x) Te structures.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sofronova S. N., Gerasimova Y. V., Vtyurin A. N., Gudim, I. A., Shestakov N. P., Ivanenko A. A.
Заглавие : Infrared absorption spectrum of HoFe3(BO3)4 crystal
Коллективы : RFBR [13-02-00825, 13-02-98041, SS-4828.2012.2]
Место публикации : Vib. Spectrosc.: Elsevier Science, 2014. - Vol. 72. - P.20-25. - ISSN 0924-2031, DOI 10.1016/j.vibspec.2014.02.005. - ISSN 1873-3697
Примечания : Cited References: 18. - The work was partially supported by the RFBR through Grants No. 13-02-00825 and 13-02-98041, SS-4828.2012.2.
Предметные рубрики: MAGNETOELASTIC INTERACTIONS
IRON
GDFE3(BO3)4
Ключевые слова (''Своб.индексиров.''): holmium ferroborate--infrared absorption
Аннотация: Infrared (IR) absorption spectra of HoFe3(BO3)4 crystal have been obtained in spectral range 30–7000 cm−1 at temperatures from 4 to 423 K. Vibrational frequencies have been simulated with ‘Lady’ software package both for high-temperature and low-temperature phases. The experimental spectra have been analyzed on the basis of calculated data, and interpreted within the framework of internal vibrations of ionic complexes of HoFe3(BO3)4 crystal lattice. The spectral range under study was observed to have no Davydov splitting of internal vibrational modes due to unit cell multiplication. No effects of magnetic ordering on the IR spectra of the crystal under study were observed in the low-temperature range.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Avramov P. V., Kuzubov A. A., Sakai S., Ohtomo M., Entani S., Matsumoto Y., Eleseeva N. S., Pomogaev V. A., Naramoto H.
Заглавие : Atomic structure and physical properties of fused porphyrin nanoclusters
Коллективы : JAEA Research fellowship; Russian Scientific Foundation [14-13-00139]
Место публикации : J. Porphyr. Phthalocyanines: World Scientific Publishing, 2014. - Vol. 18, Is. 7. - P.552-568. - ISSN 1088-4246, DOI 10.1142/S1088424614500291. - ISSN 1099-1409
Примечания : Cited References: 66. - This work was supported by JAEA Research fellowship (P. V. A.). P. V. A. also acknowledges JAEA ASRC and Molecular Spintronics Group for hospitality and fruitful collaboration. This work was supported by the Russian Scientific Foundation, Project No. 14-13-00139. Authors are grateful for Prof. S. G. Ovchinnikov for fruitful discussions.
Предметные рубрики: AUGMENTED-WAVE METHOD
HOLONOMIC QUANTUM COMPUTATION
INITIO MOLECULAR-DYNAMICS
VAPOR ABSORPTION SPECTRA
BORON-NITRIDE NANOTUBES
ELECTRONIC-STRUCTURE
REDOX REACTIONS
EXCITED-STATES
SPIN-STATES
GRAPHENE
Ключевые слова (''Своб.индексиров.''): nanoclusters--fused porphyrins--electronic structure--mechanical properties
Аннотация: The atomic and electronic structures, mechanical properties and potential barriers of formation of a set of meso–meso β–β fused porphyrin/metalloporphyrin nanopages, nanotapes, nanotubes and 2D nanofabrics were studied by GGA LC-DFT technique using cluster and PBC models. The porphyrin pages of the nanoclusters are connected with each other by graphene fragments formed by meso–meso β–β links. Fusion of all the edges of six porphyrin/metalloporphyrin units produces a novel ~ 1 nm sized molecule of cubic symmetry with a hollow cage inside. It was found that all studied nanoclusters are metastable with formation energies 0.36–7.57 kcal/mol per atom. Under applied mechanical stress, the nanoclusters exhibit superelastic and ultrastrong properties with binding graphene fragments being the weakest links for mechanical rupture. Depending on the spin-dependent reaction pathways, the hollow caged nanoclusters exhibit almost zero or low potential energy barriers (1–10 kcal/mol) during the initial stages of self-assembly. All nanoclusters exibit the main features of the electronic structures of the parent porphyrins, in particular the nature of HOMO/LUMO states and the relative energetic positions of the metal d states. The induced curvature of the hollow cage nanoclusters leads to admixture of more than 2% of the dπ⊥ states to the dσ energy region and formation of vacant superatomic molecular orbitals of d character in cubic ligand field. The Fe-derived hollow-caged nanoclusters reveal extremely high spin states with small energy differences between ferromagnetic and antiferromagnetic configurations, which can be utilized for quantum holonomic computations.
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