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Morozov, E. V.
Temperature-Triggered Rearrangement of Asphaltene Aggregates as Revealed by Pulsed-Field Gradient NMR / E. V. Morozov, P. V. Yushmanov, O. N. Martyanov // Energy Fuels. - 2019. - Vol. 33, Is. 8. - P. 6934-6945, DOI 10.1021/acs.energyfuels.9b00600. - Cited References: 119. - This research was performed using the equipment of Krasnoyarsk Regional Research Equipment Centre of Siberian Branch of Russian Academy of Sciences with the financial support of Russian Science Foundation (Project No. 15-19-00119). . - ISSN 0887-0624. - ISSN 1520-5029

РУБ Energy & Fuels + Engineering, Chemical
Рубрики:
CRITICAL NANOAGGREGATE CONCENTRATION
ELECTRON-SPIN-RESONANCE
Аннотация: The tendency of asphaltenes for aggregation followed by precipitation and deposition plays a crucial role in the petroleum industry since these processes present severe problems during the production, recovery, and processing of crude oils and fossil hydrocarbon feedstocks. The dynamics of oil asphaltene aggregates dissolved in chloroform at different concentrations varied in a wide range that was investigated at temperatures from 0 to 55 °C using the Pulsed-Field Gradient NMR technique. The components attributed to nanoaggregates and macroaggregates were successfully resolved, which allowed us to measure their diffusion coefficients. The diffusion coefficients for all types of aggregates grow as the asphaltene concentration decreases, whereas the partial weight of the aggregates increases with the increase of asphaltene concentration. The difference in diffusion behavior of the aggregates of different types was registered when passing the critical concentration range 10–20 g/L. The nano- and macroaggregates behave independently when the asphaltene concentration is higher than 20 g/L (concentrated regime), while below 20 g/L (semidiluted regime) the components related to the different types of aggregates cannot be properly resolved. It was found that regardless of the asphaltene concentration, the diffusion coefficients for nano- and macroaggregates demonstrate similar temperature behavior giving the straight lines in the Arrhenius coordinates which change their slopes when passing the temperature range 20–30 °C. The phenomenon evidences the thermally induced cleavage of noncovalent bonds with subsequent rearrangement of asphaltene aggregates that is observed for all concentration regimes covering the existence of asphaltene aggregates of all types. The data obtained are well consistent with the modern concept of asphaltene aggregate structure and fairly agree with the data obtained earlier. We believe these results will contribute essentially to a better understanding of the fundamental behavior of asphaltenes and their aggregates, providing a deep insight into aggregate transformation triggered by the temperature.

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Держатели документа:
SB RAS, Inst Chem & Chem Technol, Fed Res Ctr, Krasnoyarsk Sci Ctr, Akademgorodok 50-24, Krasnoyarsk 660036, Russia.
SB RAS, Kirensky Inst Phys, Fed Res Ctr, Krasnoyarsk Sci Ctr, Akademgorodok 50-38, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Ak Lavrentieva 5, Novosibirsk 630090, Russia.
P&L Sci Instrument Serv, Box 1241, S-18124 Lidingo, Sweden.
Novosibirsk State Univ, Pirogova Str 2, Novosibirsk 630090, Russia.

Доп.точки доступа:
Yushmanov, Pavel, V; Martyanov, Oleg N.; Морозов, Евгений Владимирович; Russian Science FoundationRussian Science Foundation (RSF) [15-19-00119]
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    Processes underlying the laser photochromic effect in colloidal plasmonic nanoparticle aggregates* / A. E. Ershov, V. S. Gerasimov, I. L. Isaev [et al.] // Chin. Phys. B. - 2020. - Vol. 29, Is. 3. - Ст. 037802, DOI 10.1088/1674-1056/ab6551. - Cited References: 38. - Project funded by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science (Grant 18-42-243023), the RF Ministry of Science and Higher Education, and the State Contract with Siberian Federal University for Scientific Research. A.E. thanks the grant of the President of Russian Federation (agreement 075-15-2019-676). . - ISSN 1674-1056. - ISSN 1741-4199
Рубрики:
SELECTIVE PHOTOMODIFICATION
   LIGHT
   FORCES
   OPTICS
Кл.слова (ненормированные):
nanoparticle -- surface plasmon resonance -- photochromic process -- pulsed laser radiation
Аннотация: We have studied the dynamic and static processes occurring in disordered multiparticle colloidal Ag aggregates with natural structure and affecting their plasmonic absorption spectra under pico- and nanosecond pulsed laser radiations, as well as the physical origin responsible for these processes. We have shown that depending on the duration of the laser pulse, the mechanisms of laser modification of such aggregates can be associated both with changes in the resonant properties of the particles due to their heating and melting (picosecond irradiation mode) and with the particle shifts in the resonant domains of the aggregates (nanosecond pulses) which depend on the wavelength, intensity, and polarization of the radiation. These mechanisms result in formation of a narrow dip in the plasmonic absorption spectrum of the aggregates near the laser radiation wavelength and affect the shape and position of the dip. The effect of polydispersity of nanoparticle aggregates on laser photochromic reaction has been studied.

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Держатели документа:
RAS, SB, Inst Computat Modeling, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
RAS, SB, KSC, Kirensky Inst Phys,Fed Res Ctr, Krasnoyarsk 660036, Russia.
Siberian State Univ Sci & Technol, Krasnoyarsk 660014, Russia.

Доп.точки доступа:
Ershov, A. E.; Gerasimov, V. S.; Isaev, I. L.; Gavrilyuk, A. P.; Karpov, S. V.; Карпов, Сергей Васильевич; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of the Krasnoyarsk Territory [18-42-243023]; Krasnoyarsk Regional Fund of Science [18-42-243023]; RF Ministry of Science and Higher Education; Siberian Federal University for Scientific Research; Russian FederationRussian Federation [075-15-2019-676]
}
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Dynamic Changes of Optical Characteristics of Resonant Domains in Metal Nanoparticle Aggregates under Pulsed Laser Fields [Text] / Gavrilyuk A.P., Karpov S.V. // Applied Physics B: Lasers and Optics. - 2010. - Vol. 101. - P512

Доп.точки доступа:
Gavrilyuk, A.P.; Karpov, S.V.
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Surface plasmon resonances in liquid metal nanoparticles / A. E. Ershov [et al.] // Appl. Phys. B. - 2017. - Vol. 123, Is. 6. - Ст. 182, DOI 10.1007/s00340-017-6755-2. - This work was performed within the State contract of the RF Ministry of Education and Science for Siberian Federal University for scientifc research in 2017–2019. The numerical calculations were performed using the MVS-1000 M cluster at the Institute of Computational Modeling, Siberian Branch, Russian Academy of Sciences. . - ISSN 0946-2171
Кл.слова (ненормированные):
Aggregates -- Dimers -- Gold -- Liquids -- Metal nanoparticles -- Nanoparticles -- Nonlinear optics -- Silver -- Surface plasmon resonance -- Au nanoparticle -- Colloidal aggregates -- Experimental values -- Experimental verification -- Metallic nanoparticles -- Nonlinear optical response -- Plasmonic nanoparticle -- Surface plasmon frequency -- Plasmons
Аннотация: We have shown significant suppression of resonant properties of metallic nanoparticles at the surface plasmon frequency during the phase transition “solid–liquid” in the basic materials of nanoplasmonics (Ag, Au). Using experimental values of the optical constants of liquid and solid metals, we have calculated nanoparticle plasmonic absorption spectra. The effect was demonstrated for single particles, dimers and trimers, as well as for the large multiparticle colloidal aggregates. Experimental verification was performed for single Au nanoparticles heated to the melting temperature and above up to full suppression of the surface plasmon resonance. It is emphasized that this effect may underlie the nonlinear optical response of composite materials containing plasmonic nanoparticles and their aggregates. © 2017, Springer-Verlag Berlin Heidelberg.

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Держатели документа:
Institute of Computational Modeling, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, Russian Federation
Siberian State University of Science and Technologies, Krasnoyarsk, Russian Federation
L.V. Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Ershov, A. E.; Ершов, Александр Евгеньевич; Gerasimov, V. S.; Герасимов, Валерий Сергеевич; Gavrilyuk, A. P.; Karpov, S. V.; Карпов, Сергей Васильевич
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Morozov, E. V.
Reversibility of asphaltene aggregation as revealed by magnetic resonance imaging in situ / E. V. Morozov, O. N. Martyanov // Energy Fuels. - 2017. - Vol. 31, Is. 10. - P. 10639-10647, DOI 10.1021/acs.energyfuels.7b01755. - Cited References: 56. - This research was performed on the equipment of Krasnoyarsk Regional Research Equipment Centre of Siberian Branch of Russian Academy of Sciences with the financial support of Russian Science Foundation (Project No. 15-19-00119). . - ISSN 0887-0624
Кл.слова (ненормированные):
Aggregates -- Crude oil -- Flocculation -- Heavy oil production -- Magnetic resonance imaging -- Asphaltene aggregates -- Asphaltene aggregation -- Asphaltene precipitation -- Equilibrium compositions -- Flocculant concentrations -- Inhomogeneous distribution -- Mechanical stirring -- Multi-component systems -- Asphaltenes
Аннотация: Aggregation of asphaltenes followed by precipitation presents severe problems for existing technologies in the production, recovery, and processing of heavy oils. Better understanding of asphaltene behavior behind the processes of their precipitation and dissolution is vital to address this issue. While investigating the inhomogeneity of different oil systems, the reversibility of the asphaltene aggregation process initiated by flocculant in either asphaltene solution in toluene or crude heavy oil was revealed and investigated using magnetic resonance imaging methods. It was found that the inhomogeneous distribution of the flocculant initiates local spatial-selective asphaltene aggregation registered in a thin layer around the flocculant/oil sample interface. The local excess of flocculant concentration over the threshold of asphaltene precipitation onset is a driving force of this process. As the flocculant diffuses into the volume of the sample, a decrease of the asphaltene flocculated area is observed until it disappears when the equilibrium composition throughout the whole volume of the system is achieved. Depending on the overall flocculant concentration, the asphaltene aggregation may not be reversible and could be followed by subsequent precipitation of the asphaltene aggregates. The similarity of the phenomena observed for the model asphaltene solutions and crude heavy oil samples was established. Partial mechanical stirring of the multicomponent system comprising flocculant and oil or asphaltene solution does not prevent the formation of the local zones with increased concentration of asphaltene aggregates; those sizes evolve depending on the flocculant concentration. The results obtained in this work are consistent with the generally accepted concept of asphaltene precipitation reversibility depending on the system composition and are compatible with the observations obtained by other methods. The approach presented can provide deeper insight into the asphaltene precipitation reversibility issue and can facilitate the understanding of asphaltene behavior in heavy oils.

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Держатели документа:
Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50/24, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50/38, Krasnoyarsk, Russian Federation
Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Ak. Lavrentieva 5, Novosibirsk, Russian Federation
Novosibirsk State University, Pirogova str. 2, Novosibirsk, Russian Federation

Доп.точки доступа:
Martyanov, O. N.; Морозов, Евгений Владимирович
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Magnetic parameters of separation products and impurity aggregates in concentrates / E. K. Yakubailik [et al.] // J. Min. Sci. - 2017. - Vol. 53, Is. 6. - P. 1133-1140, DOI 10.1134/S1062739117063233. - Cited References: 14 . - ISSN 1062-7391. - ISSN 1573-8736

РУБ Mining & Mineral Processing

Кл.слова (ненормированные):
Processing circuit -- wet laboratory separation -- concentrate impurity -- magnetic characteristics
Аннотация: The changes in separation performance and magnetic characteristics of separation products is traced along the processing circuit of Abagur concentrator at a laboratory scale in order to determine the limit content of magnetite iron in impurity aggregates in the concentrate. The wet magnetic analysis is carried out in the field of H = 175 kA/m, and the magnetic characteristics are determined in the vibration magnetic detector in the field up to 800 kA/m. The concentrate impurity content is governed by the relative content of barren rock and ore aggregates removable in concentration at the given level of the technology.

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Публикация на русском языке Определение магнитных параметров продуктов сепарации и засоряющих концентрат рудных сростков [Текст] / Э. К. Якубайлик [и др.] // Физ.-техн. проблемы разраб. полез. ископаемых. - 2017. - № 6. - С. 182-190

Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.
EVRAZRUDA, Novokuznetsk 654018, Russia.

Доп.точки доступа:
Yakubailik, E. K.; Якубайлик, Эдуард Константинович; Ganzhenko, I. M.; Balaev, A. D.; Балаев, Александр Дмитриевич; Butov, P. Yu.
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Dynamic changes of optical characteristics of resonant domains in metal nanoparticle aggregates under pulsed laser fields [Text] / A. P. Gavrilyuk, S. V. Karpov. // Technical digest International conference ICONO/LAT 2010. - Казань, 2010. - Ст. ITuQ39

Доп.точки доступа:
Gavrilyuk, A.P.; Karpov., S.V.; International Conference on Coherent and Nonlinear Optics(2010 ; Aug. ; 23-26 ; Казань); International Conference on Lasers, Applications, and Technologies(2010 ; Aug. ; 23-26 ; Казань)
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Processes in Resonant Domains of Metal Nanoparticle Aggregates and Optical Nonlinearity of Aggregates in Pulsed Laser Fields [Текст] / A. P. Gavrilyuk, S. V. Karpov // arXiv. - 2008. - Ст. 0808.2355

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Доп.точки доступа:
Gavrilyuk, A.P.; Karpov, S.V.
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The model of resonant domain of metal nanoparticle aggregates in pulsed laser fields / A. P. Gavrilyuk, S. V. Karpov // Proceedings of SPIE - The International Society for Optical Engineering / sponsors: SPIE Russia Chapter, National Academy of Sciences, Belarus, Russian Academy of Sciences, Belarus Foundation for Basic Research, Russian Physical Society ; ICONO 2007: Novel Photonics Materials; Optics and Optical Diagnostics of Nanostructures (2007 ; 28.05 - 01.06 ; Минск) : S P I E - International Society for Optical Engineering, 2007. - 6728. - С. 67281T, DOI 10.1117/12.752386 . - ISBN 0819468851

ГРНТИ

31.15

РИНЦ,
Источник статьи
Держатели документа:
Institute of Computational Modeling,Russian Academy of Science
Institute of Physics,Russian Academy of Science
Доп.точки доступа:
sponsors: SPIE Russia Chapter, National Academy of Sciences, Belarus, Russian Academy of Sciences, Belarus Foundation for Basic Research, Russian Physical Society; Gavrilyuk, A. P.; Karpov, S. V.; Карпов, Сергей Васильевич; ICONO 2007: Novel Photonics Materials; Optics and Optical Diagnostics of Nanostructures(2007 ; 28.05 - 01.06 ; Минск)
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10.

Dynamics of asphaltene aggregates under high-pressure CO2 revealed by pulsed-field gradient NMR / E. V. Morozov, S. N. Trukhan, I. V. Kozhevnikov [et al.] // Energy & Fuels. - 2023. - Vol. 37, Is. 22. - P. 17215-17226, DOI 10.1021/acs.energyfuels.3c02862. - Cited References: 90. - The present research was performed with the financial support of the Russian Science Foundation (project no. 21-13-00171, http://rscf.ru/project/21-13-00171/) using the equipment of the Krasnoyarsk Regional Center of Research Equipment of the Federal Research Center “Krasnoyarsk Science Center SB RAS” . - ISSN 0887-0624. - ISSN 1520-5029
Аннотация: The work demonstrates the results of the first experimental PFG NMR study in situ of the complex phase behavior of asphaltenes in the presence of high-pressure CO2. To perform the experiments, a series of sealed, thick-walled quartz capillaries were prepared with a mixture of CO2 and asphaltenes dissolved either in chloroform or benzene at different initial concentrations. Then, the temperature dependence of the diffusion coefficients of the asphaltene aggregates was measured for each sample after the mixture reached its equilibrium state, at which, in accordance with the solubility limit, only part of the initial asphaltenes remained dissolved. Despite quite low residual asphaltene concentrations in solution, experimental data clearly demonstrated the presence of aggregated structures (up to 70–80 wt %) attributed solely to nanoaggregates, with no signs of the presence of macroaggregates in the samples. Temperature dependencies of aggregate diffusivity clearly showed that the scenario, according to which the evolution of the asphaltene aggregates will develop, strongly depends on the initial asphaltene concentration, mass fraction of CO2 loaded into the system, and chemical nature of the solvent used. In particular, the most diluted asphaltene solution, expected to be the most resistive to the aggregation processes in a high-pressure CO2 environment, revealed the most pronounced aggregation-dependent translational dynamics as compared to those with a moderate initial asphaltene concentration. Contrarily, the concentrated asphaltene solution may not show drastic aggregation processes if the mass fraction of the CO2 loaded will not appear to be so high. Finally, the experimental results provide evidence that the temperature-triggered structural transformation of asphaltene aggregates due to the noncovalent bond breakup is not hindered under high-pressure CO2, but instead becomes more emphasized. The results obtained shed new light on asphaltene aggregate dynamics and brought new knowledge about the fundamental behavior of asphaltene in high-pressure CO2 conditions.

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Держатели документа:
Institute of Chemistry and Chemical Technology, Federal Research Center “Krasnoyarsk Science Center of Siberian Branch of the Russian Academy of Sciences”, Akademgorodok 50/24, Krasnoyarsk 660036, Russia
Kirensky Institute of Physics, Federal Research Center “Krasnoyarsk Science Center of Siberian Branch of the Russian Academy of Sciences”, Akademgorodok 50/38, Krasnoyarsk 660036, Russia
Federal Research Center “Krasnoyarsk Science Center of Siberian Branch of the Russian Academy of Sciences”, Akademgorodok 50, Krasnoyarsk 660036, Russia
Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Ak. Lavrentieva 5, Novosibirsk 630090, Russia

Доп.точки доступа:
Morozov, E. V.; Морозов, Евгений Владимирович; Trukhan, Sergey N.; Kozhevnikov, Ivan V.; Peterson, Ivan V.; Martyanov, Oleg N.
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