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GOREV, M. V.
PRESSURE EFFECT ON PHASE-TRANSITIONS IN CS2NAB3+CL6 / M. V. GOREV // Fiz. Tverd. Tela. - 1983. - Vol. 25, Is. 2. - P. 566-568. - Cited References: 8 . - ISSN 0367-3294

РУБ Physics, Condensed Matter

WOS
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THERMODYNAMIC PROPERTIES AND PHASE-TRANSITIONS IN CS2NABICL6 AND CS2NAPRCL6 / I. N. FLEROV [и др.] // Fiz. Tverd. Tela. - 1982. - Vol. 24, Is. 8. - P. 2267-2275. - Cited References: 16 . - ISSN 0367-3294

РУБ Physics, Condensed Matter

WOS
Доп.точки доступа:
FLEROV, I. N.; GOREV, M. B.; ISKORNEV, I. M.; KOKOV, I. T.
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Thermodynamic characteristics and phase transitions in Rb3B3+F6 (B3+=Ga, DY) cryolite fluoride crystals / I. N. Flerov [и др.] // Fiz. Tverd. Tela. - 1996. - Vol. 38, Is. 7. - P. 2203-2213. - Cited References: 26 . - ISSN 0367-3294

РУБ Physics, Condensed Matter
Рубрики:
HYDROSTATIC-PRESSURE
   ELPASOLITES
   CS2RBDYF6
   RB2KFEF6
   DIAGRAMS

WOS

Доп.точки доступа:
Flerov, I. N.; Gorev, M. V.; Voronov, V. N.; Bovina, A. F.
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THERMODYNAMICAL PROPERTIES OF ELPASOLYTES CS2RBDYF6 AND CS2KDYF6 / M. V. GOREV [и др.] // Fiz. Tverd. Tela. - 1985. - Vol. 27, Is. 6. - P. 1723-1729. - Cited References: 13 . - ISSN 0367-3294

РУБ Physics, Condensed Matter

WOS
Доп.точки доступа:
GOREV, M. V.; ISKORNEV, I. M.; KOT, L. A.; MISYUL, S. V.; FLEROV, I. N.
}
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ABSORPTION-SPECTRA AND FARADAY-EFFECT IN CS2NANDCL6 AND CS2NAPRCL CRYSTALS / I. S. EDELMAN [и др.] // Fiz. Tverd. Tela. - 1985. - Vol. 27, Is. 11. - P. 3467-3470. - Cited References: 8 . - ISSN 0367-3294

РУБ Physics, Condensed Matter

WOS
Доп.точки доступа:
EDELMAN, I. S.; GALANOV, E. K.; KOKOV, I. T.; MALAKHOVSKII, A. V.; ANISTRATOV, A. T.
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MN-2+ ELECTRON-PARAMAGNETIC-RES OF ISOLATED IONS AND EXCHANGE-COUPLED PAIRS IN CS2CDCL4 AND RB2CDCL4 / L. S. EMELYANOVA [и др.] // Fiz. Tverd. Tela. - 1984. - Vol. 26, Is. 6. - P. 1844-1846. - Cited References: 4 . - ISSN 0367-3294

РУБ Physics, Condensed Matter

WOS
Доп.точки доступа:
EMELYANOVA, L. S.; PETRAKOVSKAYA, E. A.; EFIMOV, V. N.; STEPANOV, V. G.
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    Manipulation of Bi3+/In3+ Transmutation and Mn2+-Doping Effect on the Structure and Optical Properties of Double Perovskite Cs2NaBi1-xInxCl6 / J. Zhou [et al.] // Adv. Opt. Mater. - 2019. - Vol. 7, Is. 8. - Ст. 1801435, DOI 10.1002/adom.201801435. - Cited References: 51. - J.Z. and X.M.R. contributed equally to this work. The present work was supported by the National Natural Science Foundation of China (Grant Nos. 51722202, 51572023, and 91622125) and Natural Science Foundations of Beijing (2172036). X.W.Z. acknowledges the support from National Key R&D Program of China (Grant No. 2016YFB0700700). . - ISSN 2195-1071
   Перевод заглавия: Влияние перестановок Bi3+/In3+ и Mn2+ -допирования на структуру и оптические свойства двойного перовскита Cs2NaBi1-xInxCl6

РУБ Materials Science, Multidisciplinary + Optics
Рубрики:
HALIDE DOUBLE PEROVSKITE
   LEAD-FREE
   ENERGY-TRANSFER
   NANOCRYSTALS
   BR
Кл.слова (ненормированные):
band gap engineering -- halide double perovskites -- Mn2+ doping
Аннотация: The halide double perovskite family represented by A2(B+,B3+)X6 can overcome the lead toxicity and enable generally large band gap engineering via B/B sites' transmutation or exotic dopants to fulfill the emerging applications in the optoelectronic fields. Herein, the design and the experimental synthesis of a new family of Mn2+‐doped Cs2NaBi1‐xInxCl6 crystals with an intense orange‐yellow emission band are reported, and the phase formation stability is discussed via a combined experimental–theoretical approach. Depending on the manipulation of Bi3+/In3+ combination, the band gap increases with In3+ content, and a subsequent evolution from indirect to direct band gap is verified. First‐principles calculations and parity analyses indicate a parity forbidden effect on Cs2NaInCl6, and a combination effect of absorption on Cs2NaBi1‐xInxCl6 from both Cs2NaBiCl6 and Cs2NaInCl6. The associated Mn2+‐doped photoluminescence depending on the Bi3+/In3+ substitution is also addressed from the variation of the different Mn–Cl environment and neighboring‐cation effect.

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Держатели документа:
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing Municipal Key Lab New Energy Mat & Techno, Beijing 100083, Peoples R China.
Shenzhen Univ, Coll Phys & Optoelect Engn, Shenzhen Key Lab Flexible Memory Mat & Devices, Shenzhen 518060, Peoples R China.
Shenzhen Univ, Coll Optoelect Engn, Minist Educ & Guangdong Prov, Key Lab Optoelect Devices & Syst, Shenzhen 518060, Peoples R China.
KSC SB RAS, Fed Res Ctr, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Dept Engn Phys & Radioelect, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
South China Univ Technol, State Key Lab Luminescent Mat, Guangzhou 510641, Guangdong, Peoples R China.
South China Univ Technol, Inst Opt Commun Mat, Guangzhou 510641, Guangdong, Peoples R China.

Доп.точки доступа:
Zhou, Jun; Rong, Ximing; Zhang, Peng; Molokeev, M. S.; Молокеев, Максим Сергеевич; Wei, Peijia; Liu, Quanlin; Zhang, Xiuwen; Xia, Zhiguo
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    Synthesis, structure and properties of K2(1-x)Rb2xAl2B2O7 and Cs1.39Tl0.61Al2B2O7 borates as the basis for preparing new oxide materials / V. G. Grossman [et al.] // Lett. Mater. - 2019. - Vol. 9, Is. 1. - P. 86-90 ; Письма о материалах, DOI 10.22226/2410-3535-2019-1-86-90. - Cited References:22. - The research was carried out within the state assignment of FASO of Russia (Theme No 0339-2016-0007). . - ISSN 2218-5046. - ISSN 2410-3535
   Перевод заглавия: Синтез, структура и свойства боратов K2(1-x)Rb2xAl2B2O7 и Cs1.39Tl0.61Al2B2O7 как основа получения новых оксидных материалов

РУБ Materials Science, Multidisciplinary
Рубрики:
OPTICAL-PROPERTIES
   CRYSTAL-STRUCTURE
   K2Al2B2O7
   GROWTH
Кл.слова (ненормированные):
borate -- solid-phase synthesis -- optical properties -- борат -- твердофазный синтез -- оптические свойства
Аннотация: With the development of technology, the need for highly efficient functional materials is steadily increasing. Currently, borates attract the attention of researchers, as they are promising nonlinear materials. Potassium rubidium aluminum borate based on potassium aluminum borate (trigonal syngony, space group P321, Z = 3) was obtained by solid-phase synthesis. The individuality and purity of the borates were confirmed by X-ray diffraction. Analysis of differential scanning calorimetry and thermogravimetric method for K2(1‑x)Rb2xAl2B2O7 (x = 0.1– 0.8) was performed in the temperature range of 25–1075°С. Potassium rubidium borates decompose in the temperature range of 900 –1000°C. Differential scanning calorimetry, dielectric loss tangent, and second-harmonic generation data revealed phase transitions for K0.6Rb1.4Al2B2O7. A significant SHG effect was found at room temperature for K0.6Rb1.4Al2B2O7 (Q = 70). Then the SHG effect increases to Q = 85 at a temperature of 645°C and remains constant with a further increase in temperature. The new triple borate Cs1.39Tl0.61Al2B2O7 was synthesized by the solid-phase synthesis, and its crystallographic parameters were obtained by the Rietveld method. This borate crystallizes in the monoclinic space group P21 / c with the unit cell parameters: Z = 2, a = 6.6669(3) Å, b = 7.2991(3) Å , c = 9.3589(4) Å , β =116.6795(18)°, V = 406.94(3) Å 3. The structure can be considered to be built up from the nearly planar [Al2B2O10] rings, which are composed of two AlO4 tetrahedra and two BO3 triangles, connected, alternately to each other by corner-sharing.
С развитием технологии потребность в высокоэффективных функциональных материалах растет. В настоящее время бораты привлекают внимание исследователей, поскольку они являются перспективными нелинейными материалами. Твердофазным синтезом получены бораты K2(1-x)Rb2xAl2B2O7 (x = 0.1–0.8) на основе калий-алюминиевого бората (тригональная сингония, пространственная группа P321, Z = 3). Индивидуальность и чистота боратов подтверждена рентгеновской дифракцией. Анализ дифференциально-сканирующей калориметрией и термогравиметрическим методом для K2(1-x)Rb2xAl2B2O7 (x = 0.1–0.8) был проведен в интервале температур 25–1075 ºС. Калий-рубидиевые бораты разлагаются в интервале температур 900–1000 °C. Дифференциальной сканирующей калориметрией, диэлектрическими измерениями и методом генерации второй оптической гармоники выявлены фазовые переходы для K0.6Rb1.4Al2B2O7. Значительный ГВГ-эффект был обнаружен при комнатной температуре для K0.6Rb1.4Al2B2O7 (Q = 70). Эффект генерации второй гармоники возрастает до Q = 85 при температуре 645 °C и остается постоянным при дальнейшем увеличении температуры. Новый тройной борат Cs1.39Tl0.61Al2B2O7 был синтезирован методом твердофазного синтеза, а его кристаллографические параметры были получены с помощью метода Ритвельда. Этот борат кристаллизуется в моноклинной пространственной группе P21/c с параметрами элементарной ячейки: Z = 2, a = 6.6669 (3) Å, b = 7.2991 (3) Å, c = 9.3589 (4) Å, β = 116.6795 (18)º, V = 406.94 (3) Å3. Структуру можно представить в виде почти плоских колец [Al2B2O10], которые состоят из двух тетраэдров AlO4 и двух BO3 треугольников, соединенных попеременно друг с другом посредством вершин.

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Держатели документа:
RAS, Baikal Inst Nat Management, Siberian Branch, 6 Sakhyanova St, Ulan Ude 670047, Russia.
Lomonosov Moscow State Univ, GSP 1,1-3 Leninskie Gory, Moscow 119991, Russia.
RAS, Siberian Branch, Kirensky Inst Phys, Fed Res Ctr KSC, 50-38 Akademgorodok, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, 82 Svobodniy Av, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Grossman, V. G.; Гроссман В. Г.; Bazarov, B. G.; Базаров Б. Г.; Stefanovich, S. Y.; Стефанович С. Ю.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bazarova, J. G.; Базарова Ж. Г.; [0339-2016-0007]

}
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    Lead-Free Perovskite Derivative Cs2SnCl6−xBrx Single Crystals for Narrowband Photodetectors / J. Zhou [et al.] // Adv. Opt. Mater. - 2019. - Vol. 7, Is. 10. - Ст. 1900139, DOI 10.1002/adom.201900139. - Cited References: 26. - J.Z., J.J.L., X.M.R. contributed equally to this work. The present work was supported by the National Natural Science Foundation of China (Grants 51722202, 91622125, 51572023, and 11774239), Natural Science Foundations of Beijing (2172036), and National Key R&D Program of China (grant no. 2016YFB0700700). . - ISSN 2195-1071
   Перевод заглавия: Бессвинцовые монокристаллы производного перовскита Cs2SnCl6-xBrx для узкополосных фотоприемников
Кл.слова (ненормированные):
band structure -- Cs2SnBr6 -- Cs2SnCl6 -- lead-free perovskite derivatives -- narrowband photodetection
Аннотация: Lead-free and stable Sn halide perovskites demonstrate tremendous potential in the field of optoelectronic devices. Here, the structure and optical properties of the “defect” perovskites Cs2SnCl6−xBrx are reported, as well as their use as photodetector materials. Millimeter‐sized Cs2SnCl6−xBrx single crystals are grown by the hydrothermal method, with the body color continuously changing from transparent to yellow and finally to dark red. Narrowband single‐crystal photodetectors using Cs2SnCl6−xBrx crystals are presented, which show a high detectivity of ≈2.71 × 1010 Jones, with narrowband photodetection (full‐width at half‐maximum ≈45 nm) and high ion diffusion barriers. Moreover, the response spectra are continuously tuned from near violet to orange depending on the variation of the bandgap of the single crystals by changing the halide compositions. The strong surface charge recombination of the excess carriers near the crystal surfaces produced by short wavelength light elucidates the narrowband photodetection behavior. This work provides a new paradigm in the design of lead‐free, stable, and high‐performance perovskite derivatives for optoelectronics applications.

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Держатели документа:
The Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, 100083, China
Sargent Joint Research Center, Wuhan National Laboratory for Optoelectronics (WNLO) and School of Optical and Electronic Information, Huazhong University of Science and Technology (HUST), Wuhan, 430074, China
Shenzhen Key Laboratory of Flexible Memory Materials and Devices, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen, 518060, China
Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen, 518060, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Department of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation
State Key Laboratory of Luminescent Materials and Devices and Institute of Optical Communication Materials, South China University of Technology, Guangzhou, 510641, China

Доп.точки доступа:
Zhou, J.; Luo, J.; Rong, X.; Wei, P.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Huang, Y.; Zhao, J.; Liu, Q.; Zhang, X.; Tang, J.; Xia, Z.
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10.

Microwave sol-gel derived MMoO4 (M=Ba,Cs,Sr) nanoparticles doped with Er/Yb, Ho/Yb, Ho/Yb/Tm and their upconversion photoluminescence properties for biomedical applications / V. V. Atuchin [et al.] // The 10th International conference on multifunctional materials and application. - 2016. - Ст. 43-P. - P. 76

Материалы конференции,
Материалы конференции

Доп.точки доступа:
Atuchin, V. V.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Park, Hee Kook; Lee, Beom Hyun; Won, Dong Min; Oh, Won-Chun; Lim, Chang Sung; International Conference on Multifunctional Materials and Application (10 ; 2016 ; Dec. 1-3 ; Khon Kaen, Tailand)
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