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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Goryainov, Sergey, V, Tse, John S., Desgreniers, Serge, Kawaguchi, Saori, I, Pan, Yuanming, Likhacheva, Anna Yu, Molokeev M. S.
Заглавие : In situ X-ray diffraction study of chrysotile at high P–T conditions: transformation to the 3.65 Å phase
Коллективы :
Ministry of Science and Higher Education of the Russian Federation; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [21-55-14001]; Natural Science and Engineering Council CanadaNatural Sciences and Engineering Research Council of Canada (NSERC)
Место публикации : Phys. Chem. Miner. - 2021. - Vol. 48, Is. 10. - Ст.36. - ISSN 0342-1791, DOI 10.1007/s00269-021-01160-8. - ISSN 1432-2021(eISSN)
Примечания : Cited References: 68. - This work was performed under the auspicious of the state assignment of IGM SB RAS supported by Ministry of Science and Higher Education of the Russian Federation. The Russian Foundation for Basic Research (project no.21-55-14001) is gratefully acknowledged. Authors thank S.V. Rashchenko for fruitful discussion on XRD diffraction patterns of the talc-water system. We thank SPring-8 Synchrotron Radiation Facilities and BLXU-10 beamline for providing the synchrotron beam-time. JST, SD and YP would like to thank Natural Science and Engineering Council Canada for the award of individual Discovery Grants
Предметные рубрики: HIGH-PRESSURE STABILITY
HYDROUS MAGNESIUM SILICATES
SYSTEM MGO-SIO2-H2O MSH
Аннотация: The behavior of chrysotile Mg3(Si2O5)(OH)4 in water medium at simultaneously high pressure and high temperature was studied by in situ synchrotron X-ray diffraction using a diamond anvil cell. In contrast to previous ‘dry’ experiments, chrysotile in water-saturated conditions undergoes two-phase transitions and exhibits higher thermal stability. At 260 °C / 3.7 GPa the initial chrysotile (phase I) transforms to the ‘chrysotile-like’ phase II, followed by the appearance of the ‘chrysotile-like’ phase III at 405 °C / 5.25 GPa. Phase III is characterized by enlarged interlayer distances, presumably resulting from the H2O intercalation into the interlayer space. During further compression, the ‘chrysotile-like’ phase III is decomposed to the 10 Å phase Mg3(Si4O10)(OH)2·xH2O, the 3.65 Å phase MgSi(OH)6, phase D, forsterite, enstatite and coesite or stishovite. The 3.65 Å phase appears at 8.8 GPa / 500 °C. The series of transformations leads to a water deficiency in the system, restricting the complete transformation from the 10 Å phase to the 3.65 Å phase. These data emphasize the crucial role of excess water in the stabilization of the high-pressure hydrous phases. The present study is the first in situ observation of sequential transformations of hydrous phases: serpentine → 10 Å phase → 3.65 Å phase, important as a potential water transport mechanism to the deep mantle.
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