Библиотека института физики им. Л.В. Киренского СО РАН

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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shalygina T. A., Rudenko M. S., Nemtsev I. V., Parfenov V. A., Voronina S. Y., Simonov-Emelyanov I. D., Borisova P. E.
Заглавие : Influence of the filler particles’ surface morphology on the polyurethane matrix’s structure formation in the composite
Место публикации : Polymers. - 2021. - Vol. 13, Is. 22. - Ст.3864. - ISSN 20734360 (ISSN), DOI 10.3390/polym13223864
Примечания : Cited References: 32. - This work was carried out by the team of the scientific laboratory “Intelligent Materials and Structures” within the state assignment of the Ministry of Science and Higher Education of the Russian Federation for the implementation of the project “Development of multifunctional smart materials and structures based on modified polymer composite materials capable to function in extreme conditions” (Project No. FEFE-2020-0015)
Аннотация: This article presents the surface morphology effect of silicon carbide (SiC) particles on the polyurethane binder’s structure formation in a dispersed-filled composite. The difference in the morphology and surface relief of filler particles was ensured by the implementation of plasma chemical modification. As a result of this modification, the filler consisted of core-shell particles characterized by a SiC core and a carbon shell (SiC@C), as well as a carbon shell decorated with silicon nanoparticles (SiC@C/SiNP) or nanos (SiC@C/SiNW). The study of the relaxation properties of polyurethane composites has shown that the strongest limiting effect on the molecular mobility of boundary layer’s chain segments is exerted by a highly developed surface with a complex relief of SiC@C/SiNP and SiC@C/SiNW particles. An empirical method was proposed to find the polymer fractions spent on the formation of the boundary, transition and bulk layers of the polymer matrix in the composite. It was shown that the morphology of the filler particles’ surface does not affect the dependence of the boundary layer thickness on the filler’s volume fraction. However, with an increase in the degree of surface development, the boundary layer thickness decreases.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Денисова, Елена Александровна, Чеканова, Лидия Александровна, Комогорцев, Сергей Викторович, Ли О.А., Рауцкий, Михаил Владимирович, Немцев, Иван Васильевич, Исхаков, Рауф Садыкович
Заглавие : Ферромагнитный резонанс Со-Ni композитных наностержней, осажденных в поликарбонатные мембраны
Коллективы : "Новое в магнетизме и магнитных материалах", международная конференция, Научный совет по физике конденсированных сред РАН, МИРЭА - Российский технологический университет, Московский государственный университет им. М.В. Ломоносова, Магнитное общество России
Место публикации : Новое в магнетизме и магнитных материалах: сборник трудов XXIV международной конференции/ прогр. ком.: Р. С. Исхаков, С. Г. Овчинников [и др.]. - 2021. - Секция 11: Магнитные наноструктуры. - Ст.11-35-38
Примечания : Библиогр.: 4. - Исследование выполнено при финансовой поддержке РФФИ, Правительства Красноярского края и Красноярского краевого фонда науки в рамках научного проекта No 20-43-240003
Аннотация: Пористый полимер, наполненный сегментированными наностержнями из магнитного металла, перспективен для создания новых микроволновых устройств. Массивы двухсегментных стержней Ni/Co и коаксиальных стержней Ni@Co получены методом химического осаждения в поликарбонатную трековую мембрану. Внутреннее эффективное магнитное поле магнитных композитных наностержней, упорядоченных на немагнитной подложке, исследовано с помощью ферромагнитного резонанса. Установлено влияние межфазных границ для двух типов стержней на эффективное поле. Обнаружено, что характеристиками ФМР можно управлять с помощью конструкции стержня (ядро-оболочка или двухсегментный стержень), свойств матрицы (пористость) и условий химического осаждения.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Belyaev B. A., Leksikov An. A., Tyurnev V. V., Shabanov D. A.
Заглавие : Study of a composite consisting of metal nanoparticles in a dielectric matrix and multilayer bandpass filters based on it
Место публикации : Dokl. Phys. - 2021. - Vol. 66, Is. 3. - P.59-63. - ISSN 10283358, DOI 10.1134/S1028335821030010
Примечания : Cited References: 11. - This study was supported by the Ministry of Science and Higher Education of the Russian Federation within a State Assignment, project no. FEFE-2020-0013 “Development of the Theory of Self-Configuring Machine Learning Algorithms for Modeling and Predicting the Characteristics of Components of Complex Systems”
Аннотация: The frequency and concentration dependences of the effective complex permittivity of a composite consisting of silver nanoparticles in a polystyrene dielectric matrix have been investigated. It has been found that, with an increase in the volume concentration of particles in the composite to ~33%, the real part of its permittivity increases from 2.6 to ~103, while the loss tangent remains no higher than 10–2 up to a frequency of 1 THz. We show the possibility of designing bandpass filters based on composite layered structures, which can be tuned by selecting the particle concentration in the quarter-wavelength layers of the mirrors that ensure the optimal interaction of half-wavelength resonators with each other and the outer resonators with free space. The high contrast between the matrix and the composite permittivities makes it possible to create mirrors with a required reflectivity using a minimum number of layers.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Avdeeva A. Yu., Vetrov S. Ya., Timofeev I. V.
Заглавие : Splitting of a Tamm plasmon polariton at the interface between a metal and a resonant nanocomposite layer conjugated with a photonic crystal
Место публикации : J. Opt. Soc. Am. B. - 2021. - Vol. 38, Is. 6. - P.1792-1797. - ISSN 07403224 (ISSN), DOI 10.1364/JOSAB.420490
Примечания : Cited References: 36. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project No. 19-42-240004 and by Russian Foundation for Basic Research, project No. 19-52-52006. The authors are thankful to Pavel S. Pankin for valuable discussions and comments
Аннотация: Splitting of a Tamm plasmon polariton at the interface between a metal and a nanocomposite layer conjugated with a photonic crystal (Bragg mirror) has been theoretically investigated. The splitting can be implemented when the Tamm plasmon polariton frequency approaches the resonance frequency of the nanocomposite, which consists of metallic nanoballs dispersed in a transparent matrix. The reflectance spectrum of the p-polarized waves at the normal incidence of light has been calculated. It has been established that the Tamm plasmon polariton splitting significantly depends on the concentration of nanoballs in the nanocomposite layer and its thickness. The solution of the dispersion equation derived for a sample with semi-infinite mirrors has been compared with the spectra obtained for a finite structure by the transfer matrix method.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kuzovnikova L. A., Denisova E. A., Nemtsev I. V., Iskhakov R. S., Komogortsev S. V., Kuzovnikov A. A., Maltsev V. K., Shepeta N. A.
Заглавие : Magnetostructural study of nanostructured and amorphous bulk alloys (Co–P)100–xCux
Место публикации : J. Struct. Chem. - 2021. - Vol. 62, Is. 5. - P.802-809. - ISSN 00224766 (ISSN), DOI 10.1134/S0022476621050164
Примечания : Cited References: 19. - The study was supported by RFBR, the Government of the Krasnoyarsk Region, and the Krasnoyarsk Regional Science Foundation within project No. 20-43-240003
Аннотация: The work reports a magnetostructural study of bulk nanostructured composite materials Co–P/Cu prepared by dynamic compaction (DC) and uniaxial cold pressing (CP). The initial particles with amorphous and crystalline structure are synthesized by chemical deposition. Magnetic characteristics of composites (saturation magnetization, Bloch constant, local anisotropy field, ferro-magnetic resonance line width, coercive force) are studied. The phase compositions of initial composite particles and compacts prepared by two methods (DC and CP) are determined from the anisotropy field and the Bloch constant values using magnetic phase analysis. It is shown that the use of composite particles in dynamic compaction allows obtaining homogeneous nanostructured bulk materials while preserving magnetic characteristics of initial powders.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Denisova E. A., Chekanova L. A., Shepeta N.A., Kuzovnikova L. A.
Заглавие : Comparison of the microstructure and magnetic properties of films and composite powders based on 3-d metal
Коллективы : International Baltic Conference on Magnetism: focus on nanobiomedicine and smart materials, Балтийский федеральный университет им. И. Канта
Место публикации : 4th International Baltic Conference on Magnetism (IBCM 2021): Book of abstracts. - 2021. - P.193
Примечания : Cited References: 1. - The research was funded by RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, project number 20-43-240003.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Morozov E. V., Voronin A. S., Kniga, S., V, Buznik V. M.
Заглавие : Nuclear magnetic resonance study of ice-based composite materials reinforced with nanodisperse aluminum oxide fibers
Коллективы : Institute of Chemistry and Chemical Technology (Siberian Branch, Russian Academy of Sciences) [0287-2021-0012]; Russian Science FoundationRussian Science Foundation (RSF) [18-1300392]
Место публикации : Inorg. Mater. Appl. Res. - 2022. - Vol. 13, Is. 1. - P.217-224. - ISSN 2075-1133, DOI 10.1134/S2075113322010270. - ISSN 2075-115X(eISSN)
Примечания : Cited References: 21. - This work was performed within the scope of state contract no. 0287-2021-0012 of the Institute of Chemistry and Chemical Technology (Siberian Branch, Russian Academy of Sciences) in the part of developing the MRI methods for studying composite materials; also the work was supported by the Russian Science Foundation (project no. 18-1300392) in the part of the study of the processes of water crystallization and ice melting in ice-based composite materials
Предметные рубрики: SELF-DIFFUSION
WATER
Аннотация: Pulsed-field gradient NMR spectroscopy and magnetic resonance imaging methods were used to investigate water suspensions of nanosized fibers of aluminum oxide and ice composite materials based on these fibers. Introduction of the nanofibers was shown to have no noticeable structural effect in the suspensions in the Al2O3 concentration range of 1-10 wt %. High content of the filler was found to change the morphology and texture of the ice matrix in the composites remarkably: it becomes more homogeneous and acquires a higher degree of continuity; the melting front does not visualize internal melting zones or integrity defects in the composite. At the same time, addition of the nanofibers to the ice composites weakly influences the quantitative dynamics of the heat transfer, which is manifested in close values of the propagation speeds of the freezing/melting front in the samples at similar temperatures.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Goncharova O. A., Chekanova L. A., Iskhakov R. S.
Заглавие : Synthesis, Structure and Magnetic Properties of Composite Powders UDD/Ni-P and UDD/Co-P
Коллективы : "Advanced Carbon Nanostructures", Joint International Conference
Место публикации : Joint International Conference "Advanced Carbon Nanostructures" (ACN 2011): Abstracts. - 2011. - Ст.P3.11. - С. 172
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Romanenko A. I., Anikeeva O. B., Tkachev E. N., Zhdanov K. R., Kuznetsov V. L., Mazov I. N., Elumeeva K. V., Popkov S. I., Shaykhutdinov K. A.
Заглавие : Influence of dielectric matrix on electrophysical properties of MWNT-based nanocomposites
Коллективы : International Conference on Composites Materials, ICCM 2011
Место публикации : ICCM International Conferences on Composite Materials/ 18th International Conference on Composites Materials, ICCM 2011 (2011 ; 21.08 - 26.08 ; Jeju). - 2011 (Шифр 20527840)
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Patrin G. S., Mataev M. M., Abdraimova M. R., Tursinova, Zh. I., Kezdikbaeva A. T., Shiyan Ya. G., Plekhanov V. G.
Заглавие : Magnetic properties of the DyMn2O5-Mn3O4 nanoparticle composite
Коллективы : Ministry of Education and Science of the Republic of KazakhstanGovernment of the Republic of KazakhstanMinistry of Education and Science of the Republic of Kazakhstan [05130165]; Ministry of Science and Higher Education of the Russian Federation [FSRZ-2020-0011]
Место публикации : Tech. Phys. - 2021. - Vol. 66, Is. 4. - P.635-641. - ISSN 1063-7842, DOI 10.1134/S1063784221040137. - ISSN 1090-6525(eISSN)
Примечания : Cited References: 34. - This study was supported by the Ministry of Education and Science of the Republic of Kazakhstan (project no. 05130165) and within the framework of a state assignment of the Ministry of Science and Higher Education of the Russian Federation (theme no. FSRZ-2020-0011) in the framework of the Cooperation Agreement between Siberian Federal University, Kirensky Institute of Physics, and Kazakh National Women's Teacher Training University
Предметные рубрики: CRYSTAL-STRUCTURE
Аннотация: The magnetic and resonance properties of the DyMn2O5–Mn3O4 nanoparticle composite have been experimentally investigated. Two magnetic transitions at temperatures of T1 ≈ 65 K and T2 ≈ 230 K have been established; the T1 value differs from the temperatures of the transitions in the initial materials, which has been attributed to the interparticle interactions. Temperature T2 corresponds to the DyMnO3 impurity phase (1 at %). Three microwave absorption peaks have been observed in the magnetic resonance spectrum, which is explained within the model of a magnetically two-phase system. One resonance is attributed to Mn3O4, and the other two peaks are attributed to an ensemble of highly anisotropic DyMn2O5 particles with a random distribution of anisotropy axes.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova E. A., Iskhakov R. S., Stolyar S. V., Komogortsev S. V., Chekanova L. A., Maltsev V. K., Kalinin Y. E., Sitnikov A. V.
Заглавие : Exchange interaction in the Co-SiO2 nanocomposite films
Место публикации : TRENDS IN MAGNETISM. - 2011. - Vol. 168-169. - С. 265-268. - ISSN 10120394 (ISSN); 9783037850213 (ISBN), DOI 10.4028/www.scientific.net/SSP.168-169.265
Ключевые слова (''Своб.индексиров.''): exchange coupling parameter--ferromagnetic resonance--granular composite films--cobalt--exchange coupling--exchange interactions--ferromagnetic materials--ferromagnetic resonance--ferromagnetism--magnetic resonance measurement--nanocomposite films--nanocomposites--nuclear magnetic resonance--resonance--silicon compounds--spin waves--cobalt--exchange coupling--exchange interactions--ferromagnetic materials--ferromagnetic resonance--ferromagnetism--magnetic resonance measurement--magnetism--nanocomposite films--nuclear magnetic resonance--spin fluctuations--spin waves--co content--coupling parameters--dispersion relations--granular composite films--magnetic measurements--nanogranulars--nmr studies--structural state--granular composites--nano-granular--standing spin waves--composite films--composite films
Аннотация: The properties of Co-SiO2 nanogranular composite films, containing a Co volume fraction ranging from 0.3 to 0.8, have been characterized by means of magnetic measurements, NMR study, and ferromagnetic resonance. Thermal decrease of CoX(SiO2)100-X magnetization follows the T3/2 law and allows to estimate the exchange interaction constant A. With growing nominal Co content the transitions from granular to continuous structural state at 36% Co are registered by FMR measurements. The spectrum of standing spin-wave has been detected in the perpendicular experiment configuration for films with the Co content above 52 vol. %. It is found that the type of the dispersion relation of spin waves in Co-SiO2 composite films is affected by the exchange coupling fluctuations.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Гардымова, Анна Петровна, Тихонов, Алексей Яковлевич, Зырянов, Виктор Яковлевич
Заглавие : Оптическая мультистабильность в композиционном материале на основе полимера, жидкого кристалла и ионного сурфактанта при воздействии электрического поля
Место публикации : Перспективные материалы. - Москва: Общество с ограниченной ответственностью "Интерконтакт Наука", 2011. - № 4. - С. 32-35. - ISSN 1028-978X
Ключевые слова (''Своб.индексиров.''): cholesteric liquid crystal--polymer--ionic surfactant--optical multistability--холестерический жидкий кристалл--полимер--ионный сурфактант--оптическая мультистабильность
Аннотация: Разработан композиционный материал на основе полимера, жидкого кристалла (ЖК) и ионного сурфактанта, характеризующийся оптической мультистабильностью и механической гибкостью. Оптические свойства данного материала варьируются за счет переключения капель холестерического ЖК между различными структурными состояниями, остающимися стабильными после выключения управляющего электрического сигнала. Функциональным инструментом для управления ориентационной структурой капель холестерика внешним электрическим полем является наноразмерный слой ионного сурфактанта. Подобраны параметры электрических сигналов, переключающих капли в новые стабильные состояния, а также возвращающих их в исходную радиальную структуру.A composite material based on polymer, liquid crystal and ionic surfactant is developed, which is characterized by the optical multistability and mechanical flexibility. Optical properties of the material are varied by switching the cholesteric droplets between different structural states remaining stable after breaking the control electrical signal. Functional tool to control the orientational structure of cholesteric droplets by an external electric field is a nanosized layer of ionic surfactant. The parameters of electrical signals switching the droplets in new stable states and returning them in the initial radial structure are chosen.
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13.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Denisova E. A., Kuzovnikova L. A., Nemtsev I. V., Kuzovnikov A. A., Iskhakov R. S., Lepeshev A. A., Telegin S. V., Yurkin G. Yu., Shepeta N. A.
Заглавие : Magnetic properties of bulk amorphous composite coating Co58Ni10Fe5B16Si11–Al2O3, Co58Ni10Fe5B16Si11–ZrO2 and Co58Ni10Fe5B16Si11–SiO2 produced by plasma spray deposition and dynamic compaction
Коллективы : Российская академия наук, Уральское отделение РАН, Институт физики металлов им. М. Н. Михеева Уральского отделения РАН, Уральский федеральный университет им. первого Президента России Б.Н. Ельцина, Российский фонд фундаментальных исследований, Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium
Место публикации : Euro-asian symposium "Trends in magnetism" (EASTMAG-2019): Book of abstracts/ чл. конс. ком.: S. G. Ovchinnikov, N. V. Volkov [et al.] ; чл. прогр. ком. D. M. Dzebisashvili [et al.]. - 2019. - Vol. 2. - Ст.J.P42. - P.261. - ISBN 978-5-9500855-7-4 (Шифр В33/E12-125657784)
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Markevich I. A., Selyutin, G. Ye., Poluboyarov V. A., Drokin N. A., Selyutin A. G., Matzko M. A.
Заглавие : Influence of ultrasonic treatment on mechanical and electro-physical characteristics of UHMWPE/MWCNT composites
Коллективы : All-Russian Conference (with International Participation) "Hot Topics of Solid State Chemistry : From New Ideas to New Materials"
Место публикации : Mater. Today: Proc. - 2020. - Vol. 25. - P.532-535. - ISSN 2214-7853, DOI 10.1016/j.matpr.2020.02.746
Примечания : Cited References: 20
Предметные рубрики: NANOCOMPOSITE
Аннотация: The influence of ultrasonic treatment on the strength and dielectric properties of composites based on ultra-high molecular weight polyethylene (UHMWPE) and multi-walled carbon nanotubes (MWCNT) is studied. It is revealed that the ultrasonic treatment of composite melt at 130 °C results in the uniform distribution of nanotubes in the UHMWPE matrix, an increase in the degree of composite crystallinity by 10%, an increase in abrasion resistance by 37%, an increase in elongation at rupture by a factor of 2. The change in the physical and mechanical properties of the composite is caused by the change in the polymer matrix structure, taking place as a result of ultrasonic action, and does not depend on the presence of nanotubes in the polymer matrix.
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15.

Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Stebeleva O. P., Kashkina L. V., Petrakovskaya E. A., Rubleva T. V., Nikitin S. L., Vshivkova O. A.
Заглавие : Nonequilibrium carbon black suspensions used in synthesis of polymer composite material
Коллективы : International Scientific Conference on Metrological Support of Innovative Technologies
Место публикации : International Scientific Conference on Metrological Support of Innovative Technologies (2 ; 2020 ; 4 March ; Krasnoyarsk). Journal of Physics: Conference Series. - 2020. - Vol. 1515, Is. 2. - Ст.022003. - , DOI 10.1088/1742-6596/1515/2/022003
Примечания : Cited References: 9
Аннотация: Nowadays polymer matrix-based composite material with various carbon fillers are widely used to protect radioequipment from different interference, to improve characteristics of radar absorbing coatings. Current synthesis processes are sophisticated and rather costly. The challenge is to develop new methods of producing composite materials by efficient knowledge intensive technologies to reduce the cost of products. The paper studies possibility of producing composite material on the basis of elastic polyurethane foam with carbon fillers using polyurethane impregnation in nonequilibrium black carbon suspension. Suspension composition: running water and carbon-bearing powders of nanometer range: fullerene black carbon, Taunite (multi-layer carbon nano tube material), technical carbon T900, wood soot. Nonequilibrium suspension was produced by treatment in hydrodynamic generator of rotor type (cavitation mode). Angular rotation speed of the rotor ω = 10000 rpm.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bolbasov E. N., Buznik V. M., Stankevich K. S., Goreninskii S. I., Ivanov Y. N., Kondrasenko A. A., Gryaznov V. I., Matsulev A. N., Tverdokhlebov S. I.
Заглавие : Composite materials obtained via two-nozzle electrospinning from polycarbonate and vinylidene fluoride/tetrafluoroethylene copolymer
Место публикации : Inorg. Mater.: Appl. Res. - 2018. - Vol. 9, Is. 2. - P.184-191. - ISSN 20751133 (ISSN), DOI 10.1134/S2075113318020065
Примечания : Cited References: 36. - The membranes were prepared and studied by means of scanning electron microscopy and X-ray diffraction at the Tomsk National Research Polytechnic University under financial support of the Russian Science Foundation (project no. 16-13-10239). NMR studies were financially supported by the Russian Foundation for Basic Research (project no. 14-29-10178 ofi_m) and performed at the Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences.
Ключевые слова (''Своб.индексиров.''): electrospinning--two-nozzle electrospinning--nonwoven composite materials--vinylidene fluoride/tetrafluoroethylene copolymer--polycarbonate--fluoropolymers
Аннотация: Nonwoven composite membranes based on polycarbonate (PC) and vinylidene fluoride/tetrafluoroethylene copolymer were obtained via the two-channel electrospinning method with a common collector. Three groups of materials were studied: the first one was a polymer membrane made of a vinylidene fluoride/tetrafluoroethylene copolymer, the second one was a polymer membrane based on PC, and the third one involved a composite polymer membrane. Scanning electron microscopy studies of morphology of the polymeric membranes showed that a composite material with a variable pore area could be obtained, which allows selection of this parameter depending on the purpose. The resulting composite material and its constituents are studied with nuclear magnetic resonance, IR spectroscopy, X-ray diffraction, and differential scanning calorimetry. There are electrically active crystalline phases in the composite membranes. The obtained nonwoven composite membrane formed is presented as a two-phase system without any chemical interactions between the phases. © A.V. Alekseev, D.Yu. Dubov, M.R. Predtechenskiy, 2017 and Pleiades Publishing, Ltd., 2018.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Knyazev Yu. V., Shishkina N. N., Bayukov O. A., Kirik N. P., Solovyov L. A., Zhizhaev A. M., Rabchevsky E. V., Anshits A. G.
Заглавие : Cation Distribution in the Composite Materials of the CaFe2O4-α-Fe2O3 Series
Коллективы : Russian Foundation for Basic Research; Government of the Krasnoyarsk Krai; Krasnoyarsk Regional Science Foundation [18-42-243011]; UMNIK program
Место публикации : J. Struct. Chem. - 2019. - Vol. 60, Is. 5. - P.763-771. - ISSN 0022-4766, DOI 10.1134/S0022476619050081. - ISSN 1573-8779(eISSN)
Примечания : Cited References: 25. - The study was performed with the financial support of the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Krai, the Krasnoyarsk Regional Science Foundation within the project No. 18-42-243011 "The effect of the composition and the defective structure of CaFe2O4 based "core-shell" composite materials on their electronic and catalytic properties" and the UMNIK program.
Предметные рубрики: PD/P-TYPE CAFE2O4
OXYGEN
CONDUCTIVITY
Аннотация: Structured composite materials CaFe2O4-α-Fe2O3 (α-Fe2O3 content is 2–82 wt.%) are obtained with the method of solid-phase synthesis at 1000 °C. The phase composition of the samples is studied using powder X-ray diffraction. It is shown that the content of CaFe2O4 and α-Fe2O3 phases changes linearly, depending on the composition of the starting material. The scanning electron microscopy data indicate the formation of a two-phase system α-Fe2O3-CaFe2O4. The Mössbauer spectroscopy data at room temperature testify the formation of cationic iron vacancies in the CaFe2O4 crystal structure in the absence of α-Fe2O3 structural defects. Cationic vacancies can be formed during the synthesis in the atmosphere of air.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Markevich I. A., Drokin N. A., Selyutin G. E.
Заглавие : Impedance Spectroscopy Study of a Polymer Composite with Carbon Nanotubes in Contact with an Electrolyte
Место публикации : Tech. Phys. - 2019. - Vol. 64, Is. 9. - P.1324-1329. - ISSN 1063-7842, DOI 10.1134/S1063784219090093. - ISSN 1090-6525(eISSN)
Примечания : Cited References: 14
Предметные рубрики: BEHAVIOR
CONDUCTIVITY
RELAXATION
Аннотация: The measured frequency dependence of the electric impedance of a composite based on ultra-high molecular weight polyethylene reinforced with carbon nanotubes in contact with an electrolyte is presented. The behavior of the active and reactive impedance components, permittivity, and conductivity in the frequency range from 0.1 Hz to 120 MHz is analyzed. An equivalent electric circuit simulating the dispersion of the impedance of the polymer composite making contact with the electrolyte is proposed. The formation of a double electric layer at the interface between the polymer composite and electrolyte layer is demonstrated and the electrical characteristics of this layer are determined.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Voronin A. S., Masiygin A. N., Molokeev M. S., Khartov S. V.
Заглавие : Atomic layer deposition ZnO on porous Al2O3 nanofibers film
Коллективы : International Scientific Conference on Applied Physics, Information Technologies and Engineering
Место публикации : J. Phys. Conf. Ser. - 2020. - Vol. 1679, Is. 2. - Ст.022072. - DOI 10.1088/1742-6596/1679/2/022072
Примечания : Cited References: 10. - Studies by scanning electron microscopy and X-ray powder diffraction were performed on the equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center «Krasnoyarsk Science Center SB RAS». The transmission electron microscopy investigations were conducted in the SFU Joint Scientific Center supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation
Аннотация: The paper presents the results of the formation and study of the morphological and structural characteristics of the mesoporous ZnO / Al2O3 nanofibers film (ZANF). The deposition of a ZnO layer on Al2O3 nanofibers film (ANF) ~ 1 µm thick was carried out by the method of atomic layer deposition. The morphology of the mesoporous composite layer ZnO / Al2O3 (ZANF) has been studied by scanning and transmission electron microscopy. It is shown that in the process of atomic layer deposition, the ZnO layer grows according to the Stranski-Krastanov mechanism. A ZnO layer less than 5 nm thick gives an island structure in which Al2O3 nanofibers are uniformly coated with ZnO particles, an increase in the ZnO layer thickness to 15 nm demonstrates a continuous coating of Al2O3 nanofibers. The system has a core-shell structure. The resulting composite structures are promising for applications in photocatalysis and gas sensing.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Морозов, Евгений Владимирович, Больбасов Е. Н., Горенинский С. И., Юрков Г. Ю., Бузник, Вячеслав Михайлович
Заглавие : МРТ исследование процессов замерзания воды и таяния льда в полимерных композиционных мембранах
Место публикации : Полимер. матер. и технол. - 2020. - Т. 6, № 4. - С. 20-29. - ISSN 2415-7260, DOI 10.32864/polymmattech-2020-6-4-20-29
Примечания : Библиогр.: 23
Аннотация: Полимерные композиционные мембраны, полученные методом электроформования, находят широкое применение в различных отраслях промышленности благодаря своей структуре и уникальным свойствам. Однако, вследствие высокой сорбционной активности изделия на основе таких мембран подвержены негативному влиянию атмосферной влаги в условиях знакопеременного температурного воздействия. В данной работе представлены новые полимерные композиционные мембраны с улучшенными водоотталкивающими свойствами, сочетающие слои гидрофобных и гидрофильных волокнистых материалов. Впервые проведены МРТ исследования процессов замерзания воды и таяния льда в них. Детально изучены качественная и количественная стороны протекающих процессов. Обнаружено, что водопоглощение в композиционных мембранах осуществляется исключительно за счет слоев гидрофильного материала. Исследование также показало, что скорость протекания процессов замерзания/таяния оказалась чувствительна к присутствию гидрофобных слоев: обнаружено, что введение слоев гидрофобных волокон в композит приводит к существенному снижению скорости замерзания и таяния. Полученный результат демонстрирует возможности метода МРТ для исследования и диагностики полимерных волокнистых материалов и процессов замерзания/таяния в них, а также показывает пути оптимизации свойств готовых полимерных материалов для арктических и иных практических приложений.Electrospun polymer composite membranes are very attractive for many industrial applications due to their special structure and properties. However, high sorption capacity of fibrous material results in noticeable moisture content in the membranes which then, being exposed to natural environment, suffer from the freeze/thawing cycling. In this work, the new polymer composite membranes with advanced water resistance due to a layered hydrophobic/hydrophilic structure were manufactured via electrospinning. Using these membranes the NMR imaging study of water freezing and ice thawing were carried out for the first time. In result, the qualitative and quantitative character of the processes was elucidated. Thus, it was found out that the water uptake in membranes occurs solely due to the hydrophilic layers. From the other hand, the hydrophobic layers play a major role, affecting the rate of freeze/thawing: introduction the hydrophobic material into membranes structure makes the freeze/thawing front propagation slow down. The results obtained demonstrate the advantages of the NMR imaging as a tool for studying and control of the polymer fibrous materials, processes of water sorption and water freezing/thawing occurring under the natural environment conditions. New results also show the routes of polymer materials optimization for arctic and other practical applications.
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