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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Romanenko A. I., Anikeeva O. B., Tkachev E. N., Zhdanov K. R., Kuznetsov V. L., Mazov I. N., Elumeeva K. V., Popkov S. I., Shaykhutdinov K. A.
Заглавие : Influence of dielectric matrix on electrophysical properties of MWNT-based nanocomposites
Коллективы : International Conference on Composites Materials, ICCM 2011
Место публикации : ICCM International Conferences on Composite Materials/ 18th International Conference on Composites Materials, ICCM 2011 (2011 ; 21.08 - 26.08 ; Jeju). - 2011 (Шифр 20527840)
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Drokin N.A., Glushenko G.A., Maslennikov A.N., Fedotova A.V., Churilov G.N.
Заглавие : Impedance Spec troscopy in Investigation of Conductivity and Electric Relaxation of Composite Materials
Коллективы : Релаксационные явления в твердых телах
Место публикации : XXII Международная научная конференция "Релаксационные явления в твердых телах": тез. докл. - Воронеж: Кварта, 2010. - С. 72. - ISBN 978-5-89609-160-8
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Dudnik A. I., Bogdanova A.V.
Заглавие : Influence of Temperature and Humidity on Resistance and Permittivity of Composite Films of WO3 and B2O3 with Fullerene
Коллективы : International Conference and Seminar on Micro/Nanotechnologies and Electron Devices
Место публикации : 11th Annual International Conference and Seminar on Micro/Nanotechnologies and Electron Devices, EDM'2010: proceedings: IEEE, 2010. - С. 106-108. - (978-1-4244-6626-9). - DOI 10.1109/EDM.2010.5568647
Аннотация: The paper represents dependences of electrical resistance on irradiance and temperature for composite fullerene-WO3 films. It has been shown that the structure film-contacts is more sensitive to external influence when the film is placed between contacts. Dependencies of fullerene doped B2O3 films permittivity on temperature and humidity are given. Introduction of fullerenes results in approximately linear temperature dependence of permittivity
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Гардымова, Анна Петровна, Тихонов, Алексей Яковлевич, Зырянов, Виктор Яковлевич
Заглавие : Оптическая мультистабильность в композиционном материале на основе полимера, жидкого кристалла и ионного сурфактанта при воздействии электрического поля
Место публикации : Перспективные материалы. - 2011. - № 4. - С. 32-35. - ISSN 1028-978X
Ключевые слова (''Своб.индексиров.''): cholesteric liquid crystal--polymer--ionic surfactant--optical multistability--холестерический жидкий кристалл--полимер--ионный сурфактант--оптическая мультистабильность
Аннотация: Разработан композиционный материал на основе полимера, жидкого кристалла (ЖК) и ионного сурфактанта, характеризующийся оптической мультистабильностью и механической гибкостью. Оптические свойства данного материала варьируются за счет переключения капель холестерического ЖК между различными структурными состояниями, остающимися стабильными после выключения управляющего электрического сигнала. Функциональным инструментом для управления ориентационной структурой капель холестерика внешним электрическим полем является наноразмерный слой ионного сурфактанта. Подобраны параметры электрических сигналов, переключающих капли в новые стабильные состояния, а также возвращающих их в исходную радиальную структуру.A composite material based on polymer, liquid crystal and ionic surfactant is developed, which is characterized by the optical multistability and mechanical flexibility. Optical properties of the material are varied by switching the cholesteric droplets between different structural states remaining stable after breaking the control electrical signal. Functional tool to control the orientational structure of cholesteric droplets by an external electric field is a nanosized layer of ionic surfactant. The parameters of electrical signals switching the droplets in new stable states and returning them in the initial radial structure are chosen.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Morozov E. V., Voronin A. S., Kniga, S., V, Buznik V. M.
Заглавие : Nuclear magnetic resonance study of ice-based composite materials reinforced with nanodisperse aluminum oxide fibers
Коллективы : Institute of Chemistry and Chemical Technology (Siberian Branch, Russian Academy of Sciences) [0287-2021-0012]; Russian Science FoundationRussian Science Foundation (RSF) [18-1300392]
Место публикации : Inorg. Mater. Appl. Res. - 2022. - Vol. 13, Is. 1. - P.217-224. - ISSN 2075-1133, DOI 10.1134/S2075113322010270. - ISSN 2075-115X(eISSN)
Примечания : Cited References: 21. - This work was performed within the scope of state contract no. 0287-2021-0012 of the Institute of Chemistry and Chemical Technology (Siberian Branch, Russian Academy of Sciences) in the part of developing the MRI methods for studying composite materials; also the work was supported by the Russian Science Foundation (project no. 18-1300392) in the part of the study of the processes of water crystallization and ice melting in ice-based composite materials
Предметные рубрики: SELF-DIFFUSION
WATER
Аннотация: Pulsed-field gradient NMR spectroscopy and magnetic resonance imaging methods were used to investigate water suspensions of nanosized fibers of aluminum oxide and ice composite materials based on these fibers. Introduction of the nanofibers was shown to have no noticeable structural effect in the suspensions in the Al2O3 concentration range of 1-10 wt %. High content of the filler was found to change the morphology and texture of the ice matrix in the composites remarkably: it becomes more homogeneous and acquires a higher degree of continuity; the melting front does not visualize internal melting zones or integrity defects in the composite. At the same time, addition of the nanofibers to the ice composites weakly influences the quantitative dynamics of the heat transfer, which is manifested in close values of the propagation speeds of the freezing/melting front in the samples at similar temperatures.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Goncharova O. A., Chekanova L. A., Iskhakov R. S.
Заглавие : Synthesis, Structure and Magnetic Properties of Composite Powders UDD/Ni-P and UDD/Co-P
Коллективы : "Advanced Carbon Nanostructures", Joint International Conference
Место публикации : Joint International Conference "Advanced Carbon Nanostructures" (ACN 2011): Abstracts. - 2011. - Ст.P3.11. - С. 172
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mikhlin Y. L., Borisov R. V., Vorobyev S. A., Tomashevich Y. V., Romanchenko A. S., Likhatski M. N., Karacharov A. A., Bayukov O. A., Knyazev Yu. V., Velikanov D. A., Zharkov S. M., Krylov A. S., Krylova S. N., Nemtsev I. V.
Заглавие : Synthesis and characterization of nanoscale composite particles formed by 2D layers of Cu-Fe sulfide and Mg-based hydroxide
Место публикации : J. Mater. Chem. A. - 2022. - Vol. 10, Is. 17. - P.9621-9634. - ISSN 20507488 (ISSN), DOI 10.1039/d2ta00877g
Примечания : Cited References: 84. - This research was supported by the Russian Foundation for Basic Research, Krasnoyarsk Territory Administration and Krasnoyarsk Territory Science Foundation, project 20-43-242903. Facilities of the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” were employed in the work
Аннотация: We introduce here a multifunctional material composed of alternating atomic sulfide sheets close to the composition of CuFeS2 and Mg-based hydroxide ones (valleriite), which are assembled due to their electric charges of opposite sign. Valleriite particles 50-200 nm in lateral size and 10-20 nm in thickness were synthesized via a simple hydrothermal pathway using various concentrations of precursors and dopants, and examined with XRD, TEM, EDS, X-ray photoelectron spectroscopy, reflection electron energy loss spectroscopy (REELS), Mossbauer, Raman and UV-vis-NIR spectroscopies, and magnetization, dynamic light scattering, and zeta potential measurements. The electronic, magnetic and optical characteristics are found to be critically dependent on the charge (electron density) at the narrow-gap sulfide layers containing Cu+ and Fe3+ cations, and can be tuned via the composition of the hydroxide part. Particularly, substitution of Mg2+ with Al3+ increases the negative charge of the hydroxide layers and reduces the content of Fe3+-OH centers (10-45% of total iron); the effects of Cr and Co dopants entering both layers are more complicated. Mossbauer doublets of paramagnetic Fe3+ detected at room temperature transform into several Zeeman sextets at 4.2 K; the hyperfine fields up to 500 kOe and complex magnetic behavior, but not pure paramagnetism or antiferromagnetism, were observed for valleriites with the higher positive charge of the sulfide sheets, probably due to the depopulation of the minority-spin 3d states of S-bonded Fe3+ ions. Aqueous colloids of valleriite show optical absorption at 500-750 nm, which, along with the peaks at the same energies in REELS, may arise due to quasi-static dielectric resonance involving the vacant Fe 3d band and being dependent on the composition of both layers too. These and other findings call attention to valleriites as a new rich family of 2D materials for a variety of potential applications.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Belyaev B. A., Tyurnev V. V., Khodenkov S. A.
Заглавие : The effective permittivity of an anisotropic composite of spheroidal particles in a dielectric matrix
Место публикации : Tech. Phys. Lett. - 2022. - Vol. 48, Is. 3. - P.110-114. - ISSN 10637850 (ISSN), DOI 10.1134/S1063785022040058
Примечания : Cited References: 10. - This study was carried out within the framework of state order FEFE-2020-0013 of the Ministry of Science and Higher Education of the Russian Federation
Аннотация: The concentration dependences of the effective permittivity have been obtained for an anisotropic composite consisting of a dielectric matrix filled with codirectional particles in the form of oblate or prolate ellipsoids of revolution (spheroids). The calculation has been made by solving numerically a system of coupled quadratic and integral equations obtained using the rigorous modification of the quasi-static Bruggeman theory. It is shown that the traditional simplified modification of the Bruggeman theory, which is widely used for calculating anisotropic composites, leads to errors of different signs for electromagnetic waves of the longitudinal and transverse polarizations relative to the spheroid axes. The dependences of the errors on the particle concentration are nonmonotonic and extrema observed in them can exceed 100%. The positions and values of the extrema depend strongly on the ellipticity of particles and the contrast of their permittivity with that of the matrix.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Chekanova L. A., Shepeta N. A., Denisova E. A., Iskhakov R. S., Kuzovnikova L. A., Nemtsev I. V.
Заглавие : Comparison of the microstructure and magnetic properties of films and composite powders based on 3-D metal
Место публикации : J. Supercond. Novel Magn. - 2022. - Vol. 35, Is. 11. - P.3241-3247. - ISSN 15571939 (ISSN), DOI 10.1007/s10948-022-06339-w
Примечания : Cited References: 19. - This work was funded by the Russian Foundation for Basic Research, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, project number 20–43-240003
Аннотация: The comparison between the magnetic properties of materials with different curvature and spatial distribution of nanograins, such as particles (3D spatial distribution) and multilayer films (2D) was carried out. Functionally graded Co(P)/Ni(P) and Co(P)/CoNi(P) specimens have been fabricated by electroless deposition. The magnetic and structural properties are characterized by electron microscopy, X-ray diffraction, ferromagnetic resonance spectroscopy, and vibrating sample magnetometer. It was demonstrated that the interaction between the Ni(P) core and Co(P) shell of particles could form the functionally graded materials with tailored structure and coercive force. Furthermore, it was found that the magnetic parameters (the local anisotropy field, ferromagnetic resonance linewidth, and coercivity) are mainly determined by the artificially created interface boundaries for all grains’ spatial distribution. The magnetic anisotropy field and coercivity of Co(P)/Ni(P) flat films were characterized by lower values than those for spherical shell of particles with the same composition, produced by the same method.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sukhanova A., Boyandin A. N., Ertiletskaya N., Simunin M., Shalygina T., Voronin A., Vasiliev A. D., Nemtsev I., Volochaev M. N., Pyatina S.
Заглавие : Study of the effect of modified aluminum oxide nanofibers on the properties of PLA-based films
Место публикации : Materials. - 2022. - Vol. 15, Is. 17. - Ст.6097. - ISSN 19961944 (ISSN), DOI 10.3390/ma15176097
Примечания : Cited References: 37. - This research was carried out within the state assignment of the Ministry of Science and Higher Education of the Russian Federation for the implementation of the project “Development of multifunctional smart materials and structures based on modified polymer composite materials capable to function in extreme conditions” (project number FEFE-2020-0015)
Аннотация: To find out whether Al2O3 nanofiller is effective in improving the characteristics of polymer composites, composite polymer films based on biodegradable polylactide and epoxidized aluminum oxide nanofibers were obtained by solution casting. Surface morphology, mechanical and thermal properties of composites were studied by SEM, IR-Fourier spectroscopy, DSC and DMA. It was shown that, below and above the percolation threshold, the properties of the films differ significantly. The inclusion of alumina nanoparticles up to 0.2% leads to a plasticizing effect, a decrease in the crystallization temperature and the melting enthalpy and an increase in the tensile stress. An increase in the content of alumina nanoparticles in films above the percolation threshold (0.5%) leads to a decrease in the crystallinity of the films, an increase in stiffness and a drop in elasticity. Finding the percolation threshold of alumina nanoparticles in PLA films makes it possible to control their properties and create materials for various applications. The results of this study may have major significance for the commercial use of aluminum oxide nanofibers and can broaden the research field of composites.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stolyar S. V., Vazhenina I. G., Yaroslavtsev R. N., Chekanova L. A., Cheremiskina E., Mikhlin Y.
Заглавие : Magnetic composite coatings FeC and NiC synthesized with arabinogalactan
Место публикации : IEEE Magn. Lett. - 2022. - Vol. 13. - Ст.2503505. - ISSN 1949307X (ISSN), DOI 10.1109/LMAG.2022.3164631
Примечания : Cited References: 23. - This work was supported by Russian Foundation for Basic Research, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science under Project 20-42-240010. The authors thank the Center of Collective Use of the Federal Research Center, Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences for the provided equipment
Аннотация: In this work, we investigated the ferromagnetic resonance spectra of metal/carbon composite coatings. FeC and NiC coatings were synthesized by electroless deposition using polysaccharide arabinogalactan. An analysis of the angular dependences of the resonance field showed that the coatings consist of three magnetic phases separated by a nonmagnetic phase of carbon.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ronzhin N. O., Posokhina E. D., Mikhlina E. V., Shestakov N. P., Nemtsev I. V., Bondar V. S., Ryzhkov I. I.
Заглавие : The effect of copper and iron adsorption on the catalytic performance of alumina nanofiber / nanodiamond composite in sensing applications
Место публикации : J. Phys. Chem. Solids. - 2022. - Vol. 167. - Ст.110785. - ISSN 00223697 (ISSN), DOI 10.1016/j.jpcs.2022.110785
Примечания : Cited References: 68. - This work is supported by the Russian Foundation for Basic Research, Project 18–29–19078. The authors would like to express their special thanks to Krasnoyarsk Regional Center of Research Equipment of Federal Research Center «Krasnoyarsk Science Center SB RAS» for providing the equipment to ensure the accomplishment of this project
Аннотация: Phenolic compounds are common environmental pollutants, which are used in many industries and contaminate water environment due to industrial wastewater discharge. Presently, there is an increasing demand for the development and improvement of inexpensive, easy-to-use analytical tools for in-situ detection of phenolic compounds. In this work, we investigate the effect of adsorption of Cu2+ and Fe2+ ions on the catalytic activity of a composite material based on alumina nanofibers (ANF) and detonation nanodiamonds (DND) in the co-oxidation of phenols with 4-aminoantipyrine in the presence of hydrogen peroxide. We have found more than two-fold increase of the catalytic activity for ANF + DND + Cu composite, while the activity of ANF + DND + Fe composite is found to decrease by several times in comparison with the original ANF + DND material. The results of FTIR analysis indicate that the adsorption of iron ions occurs with the formation of hydroxide surface groups and hydrogen bonds, which apparently block their catalytic activity in the Fenton redox cycle. The higher catalytic performance of AND + DND composite functionalized with copper ions makes it possible to detect two times lower concentrations of analytes (phenol and 4-chlorophenol) in comparison with the original composite. It is shown that the AND + DND + Cu composite provides a linear yield of the co-oxidation reaction product in a wide range of analyte concentrations (0.25–100 μM for phenol and 0.5–25 μM for 4-chlorophenol). Model experiments demonstrate the applicability of copper-functionalized composite as a reusable sensor for the determination of phenol in aqueous samples.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kudashev S. V., Kondrasenko A. A., Maiulev A. N., Babkin V. A., Belousova V. S., Andreev D. S., Zheltobryukhov V. F., Kuznetsova N. V.
Заглавие : Modification of polycaproamide composites based on 1H,1H,13H-rihydroperfluorotridecan-1-ol and montmorillonite
Место публикации : Fibre Chem. - 2022. - Vol. 53, Is. 5. - P.291-295. - ISSN 00150541 (ISSN), DOI 10.1007/s10692-022-10287-5
Примечания : Cited References: 24
Аннотация: Modification of polycaproamide by 1H,1H,13H-trihydroperfluorotridecan-1-ol immobilized on montmorillonite produced an F-containing polymer composite. The structure of the resulting composite was investigated using x-ray structure analysis and solid-state 19F NMR spectroscopy. The polymorphous composition of this heterochain polymer was shown to reorganize to enhance its thermal stability and diminish its flammability. Possible mechanisms for the stabilizing effect of the used modifier that were related to the involvement of organo-clay paramagnetic centers in the binding of macroradicals formed during thermal decomposition of macromolecular chains were discussed.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova E. A., Iskhakov R. S., Stolyar S. V., Komogortsev S. V., Chekanova L. A., Maltsev V. K., Kalinin Y. E., Sitnikov A. V.
Заглавие : Exchange interaction in the Co-SiO2 nanocomposite films
Место публикации : Trends in magnetism. - 2011. - Vol. 168-169. - P.265-268. - ISSN 10120394 (ISSN); 9783037850213 (ISBN), DOI 10.4028/www.scientific.net/SSP.168-169.265
Ключевые слова (''Своб.индексиров.''): exchange coupling parameter--ferromagnetic resonance--granular composite films--cobalt--exchange coupling--exchange interactions--ferromagnetic materials--ferromagnetic resonance--ferromagnetism--magnetic resonance measurement--nanocomposite films--nanocomposites--nuclear magnetic resonance--resonance--silicon compounds--spin waves--cobalt--exchange coupling--exchange interactions--ferromagnetic materials--ferromagnetic resonance--ferromagnetism--magnetic resonance measurement--magnetism--nanocomposite films--nuclear magnetic resonance--spin fluctuations--spin waves--co content--coupling parameters--dispersion relations--granular composite films--magnetic measurements--nanogranulars--nmr studies--structural state--granular composites--nano-granular--standing spin waves--composite films--composite films
Аннотация: The properties of Co-SiO2 nanogranular composite films, containing a Co volume fraction ranging from 0.3 to 0.8, have been characterized by means of magnetic measurements, NMR study, and ferromagnetic resonance. Thermal decrease of CoX(SiO2)100-X magnetization follows the T3/2 law and allows to estimate the exchange interaction constant A. With growing nominal Co content the transitions from granular to continuous structural state at 36% Co are registered by FMR measurements. The spectrum of standing spin-wave has been detected in the perpendicular experiment configuration for films with the Co content above 52 vol. %. It is found that the type of the dispersion relation of spin waves in Co-SiO2 composite films is affected by the exchange coupling fluctuations.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Voronin A. S., Masiygin A. N., Molokeev M. S., Khartov S. V.
Заглавие : Atomic layer deposition ZnO on porous Al2O3 nanofibers film
Коллективы : International Scientific Conference on Applied Physics, Information Technologies and Engineering
Место публикации : J. Phys. Conf. Ser. - 2020. - Vol. 1679, Is. 2. - Ст.022072. - DOI 10.1088/1742-6596/1679/2/022072
Примечания : Cited References: 10. - Studies by scanning electron microscopy and X-ray powder diffraction were performed on the equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center «Krasnoyarsk Science Center SB RAS». The transmission electron microscopy investigations were conducted in the SFU Joint Scientific Center supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation
Аннотация: The paper presents the results of the formation and study of the morphological and structural characteristics of the mesoporous ZnO / Al2O3 nanofibers film (ZANF). The deposition of a ZnO layer on Al2O3 nanofibers film (ANF) ~ 1 µm thick was carried out by the method of atomic layer deposition. The morphology of the mesoporous composite layer ZnO / Al2O3 (ZANF) has been studied by scanning and transmission electron microscopy. It is shown that in the process of atomic layer deposition, the ZnO layer grows according to the Stranski-Krastanov mechanism. A ZnO layer less than 5 nm thick gives an island structure in which Al2O3 nanofibers are uniformly coated with ZnO particles, an increase in the ZnO layer thickness to 15 nm demonstrates a continuous coating of Al2O3 nanofibers. The system has a core-shell structure. The resulting composite structures are promising for applications in photocatalysis and gas sensing.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Морозов, Евгений Владимирович, Больбасов Е. Н., Горенинский С. И., Юрков Г. Ю., Бузник, Вячеслав Михайлович
Заглавие : МРТ исследование процессов замерзания воды и таяния льда в полимерных композиционных мембранах
Место публикации : Полимер. матер. и технол. - 2020. - Т. 6, № 4. - С. 20-29. - ISSN 2415-7260, DOI 10.32864/polymmattech-2020-6-4-20-29
Примечания : Библиогр.: 23
Аннотация: Полимерные композиционные мембраны, полученные методом электроформования, находят широкое применение в различных отраслях промышленности благодаря своей структуре и уникальным свойствам. Однако, вследствие высокой сорбционной активности изделия на основе таких мембран подвержены негативному влиянию атмосферной влаги в условиях знакопеременного температурного воздействия. В данной работе представлены новые полимерные композиционные мембраны с улучшенными водоотталкивающими свойствами, сочетающие слои гидрофобных и гидрофильных волокнистых материалов. Впервые проведены МРТ исследования процессов замерзания воды и таяния льда в них. Детально изучены качественная и количественная стороны протекающих процессов. Обнаружено, что водопоглощение в композиционных мембранах осуществляется исключительно за счет слоев гидрофильного материала. Исследование также показало, что скорость протекания процессов замерзания/таяния оказалась чувствительна к присутствию гидрофобных слоев: обнаружено, что введение слоев гидрофобных волокон в композит приводит к существенному снижению скорости замерзания и таяния. Полученный результат демонстрирует возможности метода МРТ для исследования и диагностики полимерных волокнистых материалов и процессов замерзания/таяния в них, а также показывает пути оптимизации свойств готовых полимерных материалов для арктических и иных практических приложений.Electrospun polymer composite membranes are very attractive for many industrial applications due to their special structure and properties. However, high sorption capacity of fibrous material results in noticeable moisture content in the membranes which then, being exposed to natural environment, suffer from the freeze/thawing cycling. In this work, the new polymer composite membranes with advanced water resistance due to a layered hydrophobic/hydrophilic structure were manufactured via electrospinning. Using these membranes the NMR imaging study of water freezing and ice thawing were carried out for the first time. In result, the qualitative and quantitative character of the processes was elucidated. Thus, it was found out that the water uptake in membranes occurs solely due to the hydrophilic layers. From the other hand, the hydrophobic layers play a major role, affecting the rate of freeze/thawing: introduction the hydrophobic material into membranes structure makes the freeze/thawing front propagation slow down. The results obtained demonstrate the advantages of the NMR imaging as a tool for studying and control of the polymer fibrous materials, processes of water sorption and water freezing/thawing occurring under the natural environment conditions. New results also show the routes of polymer materials optimization for arctic and other practical applications.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mikhlin Y. L., Likhatski M. N., Bayukov O. A., Knyazev Yu. V., Velikanov D. A., Tomashevich Y. V., Romanchenko A. S., Vorobyev S. A., Volochaev M. N., Zharkov S. M., Meira D. M.
Заглавие : Valleriite, a natural two-dimensional composite: X-ray absorption, photoelectron, and Mossbauer spectroscopy, and magnetic characterization
Место публикации : ACS Omega. - 2021. - Vol. 6, Is. 11. - P.7533-7543. - ISSN 24701343 (ISSN), DOI 10.1021/acsomega.0c06052
Примечания : Cited References: 92. - This research was supported by the Russian Science Foundation, project 18-17-00135. The authors thank Dr. Y. Laptev for providing valleriite samples, the ESRF for allocating beamtime and the BM23 staff for their help during the experiments. Facilities of the Krasnoyarsk Regional Research Equipment Centre of SB RAS were employed in the work
Аннотация: Valleriite is of interest as a mineral source of basic and precious metals and as an unusual material composed of two-dimensional (2D) Fe-Cu sulfide and magnesium hydroxide layers, whose characteristics are still very poorly understood. Here, the mineral samples of two types with about 50% of valleriites from Noril'sk ore provenance, Russia, were examined using Cu K- and Fe K-edge X-ray absorption fine structure (XAFS) spectroscopy, X-ray photoelectron spectroscopy (XPS), 57Fe Mossbauer spectroscopy, and magnetic measurements. The Cu K X-ray absorption near-edge structures (XANES) spectra resemble those of chalcopyrite, however, with a higher electron density at Cu+ centers and essentially differ from those of bornite Cu5FeS4; the Fe K-edge was less informative because of accompanying oxidized Fe-containing phases. The post-edge XANES and extended XAFS (EXAFS) analysis reveal differences in the bond lengths, e.g., additional metal-metal distances in valleriites as compared with chalcopyrite. The XPS spectra confirmed the Cu+ and Fe3+ state in the sulfide sheets and suggest that they are in electron equilibrium with (Mg, Al) hydroxide layers. Mossbauer spectra measured at room temperature comprise central doublets of paramagnetic Fe3+, which decreased at 78 K and almost disappeared at 4.2 K, producing a series of hyperfine Zeeman sextets due to internal magnetic fields arising in valleriites. Magnetic measurements do not reveal antiferromagnetic transitions known for bornite. The specific structure and properties of valleriite are discussed in particular as a platform for composites of the 2D transition metal sulfide and hydroxide (mono)layers stacked by the electrical charges, promising for a variety of applications.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Markevich I. A., Selyutin G. E., Drokin N. A., Selyutin A. G.
Заглавие : Electrical and mechanical properties of the high-permittivity ultra-high-molecular-weight polyethylene-based composite modified by carbon nanotubes
Место публикации : Tech. Phys. - 2020. - Vol. 65, Is. 7. - P.1106-1113. - ISSN 10637842 (ISSN), DOI 10.1134/S1063784220070129
Примечания : Cited References: 39
Аннотация: A composite based on ultra-high-molecular-weight polyethylene (UHMWPE) added with 1 wt % of multiwalled carbon nanotubes (MWCNTs) with a high permittivity (ε = 4.5) and a low dielectric loss (tanδ = 10–2) in the frequency range from 100 Hz to 100 MHz has been synthesized, and its main mechanical characteristics have been studied. The material has a low (22 MPa) breaking strength, a high (700%) tensile elongation, and an abrasion resistance higher than that of pure UHMWPE by 37%. It is shown using the X-ray diffraction and differential scanning calorimetry data that the changes in the mechanical properties of the composite are related to the changes in the polymer matrix structure under the action of the high-intensity ultrasonic radiation used for embedding MWCNTs into the polymer.
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19.

Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Denisova E. A., Nemtsev I. V., Telegin S. V., Iskhakov R. S., Kuzovnikova L. A., Shepeta N. A.
Заглавие : Microstructure and magnetic properties of Co58Ni10Fe5B16Si11 and Co58Ni10Fe5B16Si11-Al2O3 bulk amorphous coatings prepared by plasma spraying
Коллективы : International Conference on High-Tech and Innovations in Research and Manufacturing
Место публикации : J. Phys.: Conf. Ser. - 2020. - Vol. 1582, Is. 1. - Ст.012078. - DOI 10.1088/1742-6596/1582/1/012078
Примечания : Cited References: 18. - This work was funded by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory, the Krasnoyarsk Regional Fund for the Support of Scientific and Technical Activities (project no. 18-42-240006 Nanomaterials with magnetic properties determined by the topological features of the nanostructure). The authors thank the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” for the provided equipment
Аннотация: The bulk soft magnetic glassy Co58Ni10Fe5B16Si11 alloy specimens have been prepared by plasma spray deposition. In order to increase resistivity of the material, the bulk Co58Ni10Fe5B16Si11-Al2O3 composite materials were fabricated. The investigations of structure and magnetic properties of the bulk samples were carried out by X-ray diffraction, electron microscopy and magnetic measurements. The relation of the structural features and magnetic characteristics of the bulk coating to the main parameters of the deposition regimes was determined. Optimized plasma spray deposition parameters allowed obtaining bulk glassy samples with magnetic parameters that are not inferior to the characteristics of a thermally treated rapidly quenched ribbon with the same composition. It was found that the bulk amorphous coatings can be characterized as a heterophase system. The relaxation annealing of the Co58Ni10Fe5B16Si11 bulk coating leads to a phase transition in this alloy in the precrystallization temperature range. The magnetic properties of the both kinds of coatings are correlated with changes in the microstructure. The appearance of nanocrystalline phase with TC640 K during relaxation heat treatment leads to a decrease of the coercivity and to an increase of the permeability. A comparison between the magnetic properties of the CoNiFe-BSi coating and (CoNiFe-BSi)-Al2O3, composite coating is carried out.
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20.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Tarasov I. A., Yakovlev I. A., Volochaev M. N., Nazarova Z.I., Nazarov A., Fedorov A. S., Varnakov S. N., Ovchinnikov S. G.
Заглавие : Growth and thermoelectric properties of composite thin films based on higher iron and manganese silicides
Коллективы : Asian School-Conference on Physics and Technology of Nanostructured Materials, Азиатская школа-конференция по физике и технологии наноструктурированных материалов
Место публикации : The Fifth Asian School-Conference on Physics and Technology of Nanostructured Materials: Proceedings. - VLadivostok: Dalnauka Publishing, 2020. - Ст.III.30.04p. - P.90. - ISBN 978-5-8044-1698-1
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